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1- Unary system
2- Binary system
3- Ternary system
4- Quaternary system
5- Multicomponent system
1
p-T diagram of a pure component
For water like substances if we increase pressure, the solid melts to liquid.
So, for water, ice melts to liquid water and is helpful for skating.
2
Phase behavior of a mixture of
components
For mixture of
components
3
pv diagram of mixture of components
4
p-T diagram of a mixture of
components
Cricondenbar
Cricondentherm
5
T-x-y diagram of a near ideal binary mixture
6
p-x-y diagram of a near ideal binary mixture
7
p-T diagram of a mixture of components
S = 20% A + 70% B + 10% C, L = 40% A+ 30% B+ 30% C
One part of S mixed with 3 parts of L
Isotherm, Isobars and VLE compositions
Isobars of mixtures of water, methanol and acetone at 100 oC Isotherms of mixtures of water, methanol and acetone at 1 atm.
Full lines y1 ; Broken lines y3
Equilibrium compositions of liquid and vapor phases in Equilibrium compositions of liquid and vapor phases in
the system at 150 atm and -195 oC. the system at 150 atm and -185 oC.
Compositions of coexisting phases in the system of CH4, decane, butane at 280 F and several pressures.
Ternary mixture with one 3 phase-region, 3 each of two-phase and one phase regions.
Naphtha (A), Furfural (B), Isobutane (C), Butadiene (D) at 20 oF.
DC
KK is the locus of the plait points.
At 25 oC
Broken lines y2
Full lines y3