Answer Solution 4 PDF

1
AITS-CRT-II-PCM (Sol)-JEE (Main)/14
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ANSWERS, HINTS & SOLUTIONS

CRTII
(Main)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. B C C
2. A B A
3. A C C
4. A C B
5. B B B
6. C B C
7. C D A
8. C B D
9. A B D
10. C A A
11. D B B
12. A C A
13. B D A
14. C A B
15. A C C
16. D C D
17. D B D
18. A C C
19. B C B
20. A B C
21. B D C
22. B C D
23. D A A
24. B C D
25. A B B
26. A D C
27. D A D
28. B A D
29. D C A
30. C B A
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2
Physics PART I
SECTION A
1. Net force on the system is

F = 3 mg sin k 3 mg cos
3mgsin 3 k mgcos 2
acm = = 4 m/s
3m
2. Consider an arbitrary moment when the wedge has travelled a distance x

into region II.
The area of the top surface inside the region II = ax sec
h
Force on it = ax sec P = ax sec [P =1]
Component of the force opposite velocity = ax sec . sin = ax tan .
If it further moves by dx then the work done = ax tan dx x
b
1
mv 02 a tan xdx
2 0
abh
v0 =
M
1
3. S A = v 0t A gt 2
2
1
SB = v0t B gt 2
2
2 L
SA S B = L t =
B A g

4. N/N0 = et
5. First law of motion.
6. For vertical oscillation time period

m
T1 = 2 . . . (1)
k

For the transverse oscillation period of simple pendulum T2 = 2
g
4mg
But 2T1 = T2 k =

3GMm 1
8. mv 2 0
2R 2
v = 3gR
9. Tension in the string T = mg FB = 3vg vg = 2vg

Balancing torque
kxR/2 = TR
x = 2T/k = 4vg/k
3
10. II and IV quadrant field will be added.
1600 x 10 6
11. vP = 4 m/s
4 x 104
1600 x 10 6
vQ = 8 m/s
2 x 10 4
1
A B A v Q2 vP2 gh
2
h = 3.6 mm
12. mg T ma ----- (1)

2
mr a
Tr x ----- (2)
2 r
2g mg
From (1) and (2), a &T mg
3 3
1

3
13. J1 x 0.1 = 5 x I 0.5 5 mA

J1 = 50 mA
I = 50 + 5 = 55 mA 5 mA
0.1 0.2 0.3
J1 I
I
S B C D
1
16. Let Vx and Vy be components of velocity. At contact point A Vx

and B,
the velocity along normal should be same.
ucos60o Vy cos30o Vx cos 60o . (1) 60o
2u
v x 2u
30o
u
v Vx2 Vy2 60o Vy
1
19. qEy mv 2
2
Magnetic force will not do any work.
20. Conceptual.
21. Now downward force on the right T T

block is more.
mg mg
22. IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2
23. Coulombic force between them remains same.
4
24. Circuit is forming a wheatstone bridge Req = 2R R R

For maximum power transfer 2R = r.
R R
R 4R
r
3 2
25. = B
4
d 3 2 dB
=
dt 4 dt
32
i=
R 4R
dx
RT 5RT x
26. C=
M0 3M0
A B
5R TL T0
dx = C. dt = T0 x dt T0 TL
3M0 L L
2L 3M
t
( TL T0 ) 5R
27. Equivalent circuit is 2RT

V RT
90 V 20
V = 500C
2R T RT
P (900C) 0
RT R (30 C)
2I P
28. Leftward Force =
C t
29. Conceptual, torque of pseudo force.
30. Effective length = (r2 + r1)
5
Chemistry PART II
SECTION A
1. P1V1 P2 V2

P1 V2 1 7
32 5
P2 V1 2
7
25 5
27 128 .
2.

NH3 g HCl
NH4 Cl
t0 0.20 0 0
At eqm. 0.2 x x x
2
K P PNH3 PHCl P P K P
= 0.36 0.6 atm .
PV 0.6 10
NH3 formed
RT 0.0821 600
= 0.122 mole = moles of NH4Cl decomposed.
Moles of NH4Cl left = 0.2 0.122 = 0.078.
7. Na2B 4 O7 H2 SO4 Na2 SO4 H2B 4 O7

X
H2B4 O7 5H2O 4H3BO3

2H3BO3 B2O3 3H2O
B 2O3 6Na 2B 3Na 2O
X
8. Go Ho TSo

H2 O
H OH

Ho 13.7 kcal
Ho Go 13.7 19.14
So
T 298
-1 -1 -1
= 0.1102 kcal mol = 110.2 cal k mol
3a
9. In bcc, r
4
Edge length = a
Edge length not covered by atom = a 2r
3 2 3
a a a
2 3
2 3
a
2
percentage fraction not covered = 100 0.134 100 = 13.4%
a
6
1
10. Al3 3e Al K
Al3

Al OH3 3
Al 3OH

pH = 14, [H+] = 1 10-14

(OH) = 1 M
3+ 3
Ksp = [Al ][1]
Al3 1 10 33 M
0.0591 1
E Eo log
3 Al3
0.0591 0.0591
1.66 log1033 1.66 33
3 3
= - 2.31 V
11. Br
H 3C MgCl
CH3Cl CH3CH2CH3
Cl2 Br2 /h
CH4
h KCN
H3 O
C N COOH
M1V1 MV
13.
n1

CO23 2 2 H
n2

M1 50 4 49.35
M1 1.974
1 2
x d 10 x 1.25 10
M 1.974
mB 106
x 16.7
15. H2O is weak field ligand while CN is a strong field ligand. In complex (i), the distribution is t 32g eg 2 ,
i.e. all electrons are unpaired while in (ii) complex, the distribution is t 52g eg0 , i.e. two t2g orbitals are
paired while one is unpaired.
16. O
Cl C O HO
LiAlH4
C Cl Conc. H2 SO4

OH
Cl C HO
O
17. O O
H3 O

HO
O
OH (A) H (B)
Aldehyde and ketone can be differentiated by Fehlings solution.
7
18. +
OH OH2
O O
H

O

O HO
19. The rate can be compared by stability of carbocation.
C C C
H3C O NH
(I) (II) (III)
N has more tendency to donate electron than O.
21. H = E + PV H = E + nRT
H2 = E2 + nRT2
H1 = E1 + nRT1
(H2 H1) = (E2 E1) + nR(T2 T1)
H E nRT 4 8.314 50
= 1660 J
22.

H2 S
2H S
2

CdS 2
Cd S
2

K spCdS 2
Cd S
2
8 10 27 1 10 14 S 2
S2 8 10 13 M
2
K H2 S H S2
2
H 8 1013 1 10 22
2
H 1.25 1010
[H+] = 1.11 10-5
pH 5 .
23.

N2 O 4 g
2NO 2 g
1 0
1 x 2x
Total moles = 1 x + 2x = 1 + x
Since PV = nRT, V n
2x
% of NO2 100 50
1 x
8
1
x
3
D Theoretical VD
1 x
d Experimental VD
4 46 46 3
d 34.5
3 d 4
28. Species NO NO CN CN
Bond order 2 3 3 2
1
Bond order
Bondlength
Bondlength of NO > CN+ due to greater number of antibonding electrons.
29. Tf i K f m 86 0.001
0.0054 i 1.86 0.001
0.0054
i 2.9 3
1.86 0.001
i.e. there are 3 ions in the solution of complex.
So, [Pt(NH3)4Cl2]Cl2 is the correct choice.
Mathematics PART III
SECTION A
2 3a 4b c 3 4a 3b c
1. 10
a2 b2
18a 17b 5c
10
a2 b2
18 17
a bc
5 5 2
a2 b2
2. b2 = 4 2 = 8, 2ae 40
a2e2 = 10 = b2 + a2
a2 = 2
Centre = (1, 5)
Equation of transverse axis x 3y + 14 = 0
Equation of conjugate axis 3x + y 8 = 0
3x y 8 2 x 3y 14 2
Equation of hyperbola = 20
1 4
25
4 2 x 2 x 2 2 14
x 14x 25 x
3. f x =
5 5
x 2 x 2
x x
9
2
5
x2 x 4
= x = x2 x 5 2

5 x
x 2
x
x2 2x 5 = 0
2 4 20 22 6
x = = 1 6
2 2
9
4. 6 places can be selected in C6 ways and 6 can be placed only at 5 places, except the right most
of other 6 selected. Remaining numbers i.e. 7, 8, 9 in 3! ways
Hence number of ways = 9 C6 5 3!
13
5. z = 18 + 26i, r 10 10 , tan , 0, 0,
9 2 3 6
1/ 3
z1/ 3 10 10 cos isin 10 cos isin
3 3
3t t 3
tan , t tan
2
1 3t 3
1
tan
3 3
1/ 3
z = 3 + i, a = 3, b = 1
6. Let parabola is y2 = 4ax

= at1t2, = a(t1 + t2), Q = (at1t3, a(t1 + t3)), R (at2t3, a(t2 + t3))
at t
Let T = (h, k) then h = 3 t1 t 2 3
2 2
4ah
2k = a(t1 + t2) + 2at3 =

2
The locus id 4ax 2y + = 0
7. We observe that = Q(z2)

because of perpendicularity of two secant R(z3)
Now SOR + SOQ SOP = ( = )
(arg(z3) arg(z) + (arg(z2) arg(z)) (arg(z1) arg(z)) = P(z1)

arg(z3) + arg(z2) = + arg(z1) + arg(z) O(0)
= arg(z2z3) = + arg(zz1) S(z)
z2z3 = zz1
zz1 + z2z3 = 0
1
1 tan1 t
8. Cn
n
n
sin1 t
dt
n 1
1
tan1 t
L = lim n2 Cn lim n dt ( 0)
n n
n
sin1 t
n 1
10
1
tan1 t
n
sin1 t
dt
n 1
L = lim (Applying Leibniz rule)
n 1
n
9. We have to find non negative integral solution of equation 2x + y + z = 21

Note that x can take a maximum value of 10 and a minimum value of 0.
We rearrange equation so that we get an integer equation with y and z as variables, x as a
constant
y + z = 21 2x
The number of non negative integer solution is 21 2x + 2 1C1 = 22 2x C1 = 22 2x
We now add the number of solutions so obtained for all the possible values of x.
10
The total number of solution is therefore 22 2x 132
x 0
10. As a > 0 R.H.S. > 0 hence x > 0

Applying AM GM we get,
1
1 x
x ax a 11
x
x a x 2

2
1 1
x
2 x
L.H.S. 2 a
1
But x 2x>0
x
1 1
x
2 x
2 a 2 a a 1 L.H.S. 2 a and equality holds if x = 1.
1 12 C2

4 51C2 11
11. The required probability is p 12 13

1 C2 C2 50
51
51
4 C2 C2
12. x 2 2 3 y 13 = latus rectum = 3

3
x 3 2 y 2 2
Other conic is 1 which an ellipse is
72 7
2

2
2b2 2 49 7
Latus rectum =
a 47 2
7 1
Positive difference 3
2 2
13. B = adj (2A) |B| = |2A|n 1

1024 = 4n 1 2n(n 1)
2
210 2n n2
n=3
11
f x x
14. 2f(x) and have the same domain as f(x), f(2x) and f(x + 2), f have the range as f(x)
2 2
m = 2, n = 3

Verify by f(x) = sin1 x, d : |x| 1, R : ,
2 2

2 a2
15. a1 a2 a1 a2 sin
n 2/n
2
a1 a2 a1 a2 cos
n 2/n
2 2 a1
nsin ncos
n n
2
2
tan 1 m
n n 4
8
n
1 4m
Smallest possible value of n corresponds to m = 0 n = 8
17. f 1 x x x
5
A x
1/ 2
xdx
5 1 2
1 40
=
x dx
xdx 4
xdx = 2 1 sq. unit
1/ 2 1/ 2 0
3 2
18. tan2 a, tan2 B b

1/ 4 1/ 2
a 12 b 12 a2 1 b2 1 a b a2 1 b2 1 a b
2 4 22 8
b a b b a a b a b b a a b a
0 0 1
1 c 1 c2
19. A 0 1 0
2 b 2 ab
c
0 1
a
If A is independent of a, b, c then C2 = ab a, c, b are G.P.
20. Using cosine rule b2 2bc cos A + (c2 a2) = 0

2 2
b1 + b2 = 2c cos A b1b2 = c a
Using b2 = 2b1
2c c 2 a2
b1 = cos A and b12
3 2
4c 2 c 2 a2 2 2 2 2
cos2 A 9(c a ) = 8c cos A
9 2
c
1 8 sin2 A 3
a
3 2 2
22. x x x 2 = 0 (x 2) (x + x + 1) = 0 x = 2 (1)
12
x y2 + 2 x y + 4 x 2 y2 4 y 8 = 0 (x 2) (y2 + 2 y + 4) = 0 x = 2 (2)
Both the equation represent same line. So number of triangle formed are zero.
3 2
23. f (x) = sin x + sin x
f (x) = 3 sin2 x cos x + 2 sin x cos x
for exactly one minimum and one maximum

f (x) = 0 at two points in <x<
2 2
2
therefore f (x) = 0 cos x = 0 or, sin x (3 sin x + 2 ) = 0 sin x = or sin x = 0, cos x
3
0
2
1< <1
3
3 3
< but > 0 0 < <
2 2
24. P(x) = ax2 + bx + c

P(x) = Q1(x) + 4 = Q2(x + 1) + 3 = Q3(x 1) + 1
P(0) = c = 4
P(1) = a b + 4 = 3 (b a = 1)
P(1) = a + b + 4 = 1 (b + a = 3)
b = 1, a = 2
P(x) = 2x2 x + 4
P(2) = 8 2 + 4 = 6
25. Center (3, 5)

Radius 2
For L1 to be a chord its distance from center must be less than radius
Since P is an integer p can take value S1 = {17, 18, 31}
L2 to be chord of a circle, P can take value from the set S2 = {11, 12, .. 25}
S1 S2 has 21 elements while
S1 S2 has 9 elements
9 3
Required probability or
21 7
1 n
26. lim n
divided N and D by 3 n
n x 2 1
n
3
3 n
1 1
lim to equal to lim 0
n 3 n n
n
x2
lim 0 1 < x < 5
n 3
27. Let the equations of circle be y

x2 + (y )2 = 16
= 2 6
13
28. |x + y + z| = |x| + |y| + |z|

x2 2 < 0, sin x < 0
x 2, 0
1 1 1
29. The normal to the plane will have direction cosine , , and the distance of this plane
3 3 3
from the origin will be OP = 3
x y z
3 x y z 3
3 3 3
Intercepts lengths (3, 3, 3)
(3)2 + (3)2 + (3)2 = k2
k

3
x2 e 2
30. (1, e], f x ln x e 0, 1
2 2
x 1 x 1
g sin cos where (0, 1]
cos sin
g' 0
2 sin 2 cos 4

g() has an extremum point
4
g(0) = 1 g 1 sin1 cos1

While g 23 / 4 g(1) > g(0) = 1
4

Since g g 0 1
2

g x 1, 23/4

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AITS-CRT-II-PCM (Sol)-JEE (Main)/14

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. Net force on the system is

2. Consider an arbitrary moment when the wedge has travelled a distance x

5. First law of motion.

6. For vertical oscillation time period

9. Tension in the string T = mg FB = 3vg vg = 2vg

10. II and IV quadrant field will be added.

12. mg T ma ----- (1)

13. J1 x 0.1 = 5 x I 0.5 5 mA

16. Let Vx and Vy be components of velocity. At contact point A Vx

21. Now downward force on the right T T

22. IC = I0 + M(OC)2 = I0 + M(OB2 + BC2) = IB + M(BC)2

23. Coulombic force between them remains same.

24. Circuit is forming a wheatstone bridge Req = 2R R R

27. Equivalent circuit is 2RT

29. Conceptual, torque of pseudo force.

30. Effective length = (r2 + r1)

7. Na2B 4 O7 H2 SO4 Na2 SO4 H2B 4 O7

pH = 14, [H+] = 1 10-14

19. The rate can be compared by stability of carbocation.

Mathematics PART III

6. Let parabola is y2 = 4ax

7. We observe that = Q(z2)

9. We have to find non negative integral solution of equation 2x + y + z = 21

10. As a > 0 R.H.S. > 0 hence x > 0

12. x 2 2 3 y 13 = latus rectum = 3

13. B = adj (2A) |B| = |2A|n 1

18. tan2 a, tan2 B b

20. Using cosine rule b2 2bc cos A + (c2 a2) = 0

24. P(x) = ax2 + bx + c

25. Center (3, 5)

27. Let the equations of circle be y

28. |x + y + z| = |x| + |y| + |z|

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