RESULT

Concentration Number of Raffinate, V11 Feed, V13 Extract, V1

of NaOH, M titration
First 0.30 19.40 6.80
0.1 M NaOH Second 0.50 21.00 7.00
Third 0.50 19.30 7.10
Average 0.43 19.90 6.97
First 0.80 47.20 23.50
0.025 M NaOH Second 0.90 39.00 21.10
Third 0.50 61.50 22.80
Average 0.73 49.23 22.47

CALCULATION
Concentration of Raffinate Feed Extract
NaOH, M
0.1 M M 1 V 1=M 2 V 2 M 1 V 1=M 2 V 2 M 1 V 1=M 2 V 2

( 0.1 ) ( 0.00043 )=M 2 (0.015)

( 0.1 ) ( 0.0199 )=M 2 (0.015)( 0.1 ) ( 0.00697 )=M 2 (0.015)

M 2=X 1=0.002867 M M 2=0.13267 M M 2=Y 1=0.04647

0.025 M M 1 V 1=M 2 V 2 M 1 V 1=M 2 V 2 M 1 V 1=M 2 V 2

( 0.0025 ) ( 0.00073 )=M 2 (0.015)

( 0.025 ) ( 0.04923 )=M 2 (0.015)
( 0.025 ) ( 0.02247 )=M 2 (0.015)

M 2=X 1=0.0012167 M M 2=0.08205 M M 2=Y 1=0.03745 M

A) WORKING TO FIND MASS TRANSFER COEFFICIENT (0.1 M)

i) Distribution coefficient
Y
K=
X

Y-concentration of solute in extract phase

X-concentration of solute in raffinate phase

ii) Finding concentration of raffinate and extract

 M 1 V 1=M 2 V 2

M1 - concentration of NaOH
M2 concentration of propionic acid
V1 volume of NaOH
V2 volume of propionic acid

iii) Rate of acid transfer

Rate of acid transfer =V W (Y 1 0)

Rate of acid transfer = 0.3 L/min(0.04647-0)M

=0.013941 mol/min

V o ( X 1 X 2 )=V W (Y 10)

L mol
0.3 ( 0.002867X 2 ) M =0.013941
min min
X 2=0.043603 M

Y1
iv) K=
X

Y 1 0.04647
K= = =16.2806
X 1 0.002867

Y 1 0.04647
X = = =0.002869
K 16.2

X 1 =|X 2 0|=|0.0436030|=0.043603

X 2=|X 1 X |=|0.0028670.002869|=0.000002

v) LMDF

( X 1 X 2 )

X1
ln
X2

X1: Driving force at the top of the column = (X2-0)

 X2: Driving force at the bottom of the column = (X1-X*1)

( X 1 X 2 ) (0.0436030.000002)
LMDF= = =0.004365
X1 0.043603
ln ln
X2 0.000002

vi) Packing dimension

Length=1.2 m
Diameter=50 mm
Packing volume, V=r2L
=()(0.025 m)2(1.2 m)
=2.36 L

vii) Mass Transfer Coefficient

rate of acid transfer

volume of packing meandriving force
0.013941

2.36 0.004365
mol
1.3533
L .min
M
1.095298
min
kg
1.095298
min

B) WORKING TO FIND MASS TRANSFER COEFFICIENT (0.025 M)

i) Distribution coefficient
Y
K=
X

Y-concentration of solute in extract phase

X-concentration of solute in raffinate phase

ii) Finding concentration of raffinate and extract

M 1 V 1=M 2 V 2

M1 - concentration of NaOH
M2 concentration of propionic acid
V1 volume of NaOH
V2 volume of propionic acid

iii) Rate of acid transfer

 Rate of acid transfer =V W (Y 1 0)

Rate of acid transfer = 0.3 L/min( 0.03745 -0)M

=0.011235 mol/min

V o ( X 1 X 2 )=V W (Y 10)

L mol
0.3 ( 0.0012167X 2 ) M =0.011235
min min
X 2=0.0362333 M

Y1
iv) K=
X

Y1 0.03745
K= = =30.78
X 1 0.0012167

Y 1 0.03745
X = = =0.001208
K 31

X 1 =|X 2 0|=|0.03623330|=0.0362333

X 2=|X 1 X |=|0.00121670.001208|=0.0000087

v) LMDF

( X 1 X 2 )

X1
ln
X2

X1: Driving force at the top of the column = (X2-0)

X2: Driving force at the bottom of the column = (X1-X*1)

( X 1 X 2 ) (0.03623330.0000087)
LMDF= = =0.00434639
X1 0.0362333
ln ln
X2 0.0000087
vi) Packing dimension
Length=1.2 m
Diameter=50 mm
Packing volume, V=r2L
=()(0.025 m)2(1.2 m)
=2.36 L
vii) Mass Transfer Coefficient
rate of acid transfer

volume of packing meandriving force
0.011235

2.36 0.00434639
mol
1.095298
L .min
M
1.095298
min
kg
1.095298
min