SUCCESS STUDY CIRCLE

DAILY ASSIGNMENT
NAME.....................................SUB- CHEMISTRY NO/3 DATE 06/04/2017
VERY SHORT AHSWER TYPE QUESTIONS: (1 MARK EACH)
1. Why is the third ionization energy of Mg z=25 unexpectedly is high ?
2. In the transition series with an increase in atomic number the atomic radius does not
changes very much Why it is so ?
3. Write the atomic no. of the element in which the filling of 3d subshell in the atom just
starts ?
4. Name one ore of Mg and Cr?
5. Write the ionic equation representing the 0xidising properties of acidified KMnO4 solution
6. Why are the compounds of transition metals generally coloured?
7. Which property of the transition metal makes them good catalyst ?
8. Why is transition metals shows high enthalpy of hydration?
9. What are coinage metals?
10. Why is Cu considered as a transition metal?

SHORT ANSWER TYPE QUESTION : ( OF 2 MARKS EACH)

11 Write chemical equation for the reactions involved in manufactured of potassium
permanganate frpm pyrolusite ore ?
12. Describe with chemical equation the step involved in the preparation of potassium
dichromate from sodium chromate?
13. What are interstitial compounds ? Mention their two important propertieis?
14. Explain why the first ionization energies of the element of the first transition series do
not vary much with increase in atomic number ?
15. To what extent do the electronic configuration decide the stability of oxidation state in
the first series of transition elements? Illustrate with example?
16. How would you account for the irregular variations of first and second ionization
enthalpies in the first series of transition elements?
17. What is meant by disproportionate of an oxidation states?Give an example
18. Discuss the general characteristics of 3d series of the transition element with special
reference to their:
(i) Atomic sizes
(ii) Enthalpies of atomisation
19. Which is stronger reducing agent Cr2+ or Fe2+ and why?
20. Evaluate the magnetic moment of a divalent ion in aqueous solution of atomic No 25?
21. Explain why Cu2+ is stable in aqueous solution?
SHORT ANSWER TYPE QUESTION : ( OF 3 MARKS EACH)
22. What are interstitial compounds and mentioned two important properties?
23. Which out of Se3+ and Cr3+ exhibits paramagnetism and why?
24. Explain why the first ionization energies of the element of the first series does not vary
much with increase in atomic number?
25. What is meant by dis proportationation reaction?
26 Explain the following :
(i) Transition elements tend to be unreactive with increasing atomic no. in the series
(ii) d block elements exhibits more oxidation states than f block elements
(iii) A green chromium compounds A on fusion with alkali gives yellow compounds B which on
acidification gives an orange coloured compounds C . C on treatment with NH4Cl gives an
orange coloured product D Which on heating decomposes to give back A Identify A B C and
D.Write equation for reaction 37 (i) Give the balanced chemical equation of two reaction in
which KMnO4 acts as an oxdising agent in the acidic medium
(ii) Chemistry of the actinoids is much more compliciated than that of lanthanoids .Why
27. Calculate the unpaired electrons in following gaseous ions : Mn 3+ ,Cr+3,V+3,and Ti+3.
Which one of these is the most stable in aquesous solution?
28. What are paramagnetic and ferromagnetic substances ?Account for the paramagnetic
character of transition memtal compounds. How does the paramagnetic character of the
bivalent ions of first transition metal series vary from Ti (z=22) to copper (z=29)?
29. How would you account for the following ?
(i) Only transition metals form complex compouonds with ligand such as CO.
ii) Sc, the first member of first transition series does not exhibit variable oxidation state.