Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Nanoparticles
Nor Syahirah Mohamad 1,2, Salmiah Kasolang 1,2, Mimi Azlina Abu Bakar1,2
1)
Faculty of Mechanical Engineering, Universiti Teknologi MARA,
40450 Shah Alam Selangor,Malaysia.
2)
Tribology Group, Faculty of Mechanical Engineering, Universiti Teknologi MARA,
40450 Shah Alam, Selangor Malaysia
*
Corresponding e-mail: salmiahk@salam.uitm.edu.my
Keywords: lubricant, nanoparticles, friction, Box-Behnken design, response surface method
2 2
0.029238 x3 0.000188 x 2 0.009755 x 3 concent.*concent. 0.009755 0.007897 -1.235
0.000025
x 1 x 3 0.000305
x2 x3 speed*concentration -0.000025 0.000004 -5.988
2
load*concentration -0.000305 0.000759
3
(a)
(b) (b)
Figure 3 Effect of speed and concentration of TiO2 on Figure 4 Effect of speed and load on COF at the zero
COF at the zero level: level:
(a) response surface and (b) contour plot (a) response surface and (b) contour plot.
As shown in Figure 3, the CoF decreases as With respect to the load, it is clear that the CoF
speed increases. The region with the lowest friction is increases with increasing load from 10 kg to 18 kg.
indicated by dark blue between 1000 rpm to 2000 rpm However, beyond this load, the CoF begins to reduce. It
and beyond 0.5 by weight percentage of of TiO 2 can be explained that the lubricant film might not
concentration. Generally, high sliding speed may result effectively separate the contact surfaces. Besides that, at
in high interface temperatures that can significantly lower normal load, the contact asperities is smaller
reduce the strength of most materials [18]. There is hence increasing the CoF [22]. As the normal load
always an optimal speed beyond where the properties increases, an oxide layer may have formed on the
and performance of materials start to reduce. Beyond surface due to the elevation of surface contact
the optimal speed, the temperature may reach the temperature and hence provide lubricating action to
melting point causing high adhesion between contact reduce the friction [23]. From observation in Figure 4, it
surfaces and eventually an increase in friction [19]. The can be seen that as speed increases at low normal load,
region with the highest friction is beyond 0.4 wt% of the COF tend to reduce. The dark blue zone represents a
concentration of TiO2 at speed below 250 rpm with 0.10 large region of lower friction values (<0.04) at load
as shown in Figure 3. This is similar to what has been between 17 to 20 kg and a speed range of 1200 to 1900
reported in Ettefaghi et. al [5]. They found that the rpm. At these optimal conditions, the contribution of
concentration of nanoparticles has a great effect on the separation is believed due to the higher speeds causing
functionality of nano-lubricants. A range of 0.1 to 0.5 the distance between interfacial surfaces become far
wt% of concentration was reported as the optimum apart as the duration of asperities compressing each
values in many studies [20, 21]. others is reduced. .
(a)
4
Optimal speed (r load (kg concentr
D High
Cur
2000.0
[1781.8182]
20.0
[20.0]
1.0
[1.0]
1.0000 Low 200.0 10.0 0.0 In general, it has been shown that RSM is an effective
and powerful tool in experimental optimization of
multi-variants.
Composite
Desirability
1.0000
6. REFERENCES
[1] S. M. Alves, B. S. Barros, M. F. Trajano, K. S.
B. Ribeiro, and E. Moura, Tribological
behavior of vegetable oil-based lubricants with
SAE10W40
Minimum nanoparticles of oxides in boundary lubrication
y = 0.0191
d = 1.0000 conditions, Tribol. Int., vol. 65, pp. 2836, Sep.
2013.
Figure 5 Response Optimization values of COF. [2] Y. Y. Wu, W. C. Tsui, and T. C. Liu,
Experimental analysis of tribological
properties of lubricating oils with nanoparticle
Table 6 Optimum conditions, predicted and additives, Wear, vol. 262, no. 78, pp. 819
experimental value of COF. 825, Mar. 2007.
Optimum Condition COF value
ii) The optimization zone for low friction was observed [8] L. Wu, K. L. Yick, S. P. Ng, and J. Yip,
at a region of optimum concentration of more than 0.5 Application of the Box-Behnken design to the
wt% with speed in the range of 1000 rpm to 2000 rpm optimization of process parameters in foam cup
with respect to the concentration. molding, Expert Syst. Appl., vol. 39, no. 9, pp.
80598065, 2012.
iii) The optimization zone for low friction was observed
at a large region for load between 17 to 20 kg and a
[9] R. H. Myers, D. C. Montgomery, and C. M.
speed range of 1200 to 1900 rpm with respect to load.
Anderson-Cook, Response surface
methodology: process and product optimization
iv) The optimal conditions for the CoF reveals that that
using designed experiments. .
the minimum value of CoF (0.0191)was given at the
speed, load, and concentration of TiO2 of 1782 rpm, 20
kg and 1.0 wt% respectively [10] B. Abbasi and H. Mahlooji, Improving
5
response surface methodology by using artificial statistical modeling for ultrasound-assisted
neural network and simulated annealing, extraction of corn silk polysaccharide,
Expert Syst. Appl., vol. 39, no. 3, pp. 3461 Carbohydr. Polym., vol. 92, no. 1, pp. 604611,
3468, Feb. 2012. 2013.
[12] P. Qiu, M. Cui, K. Kang, B. Park, Y. Son, E. [19] M. A. Chowdhury and D. M. Nuruzzaman,
Khim, M. Jang, and J. Khim, Application of Experimental Investigation of Friction
Box-Behnken design with response surface Coefficient and Wear Rate of Different Sliding
methodology for modeling and optimizing Pairs Faculty of Manufacturing Engineering ,
ultrasonic oxidation of arsenite with H2O2, University Malaysia Pahang , Malaysia, vol.
Cent. Eur. J. Chem., vol. 12, no. 2, pp. 164172, 28, no. 5, pp. 608619, 2013.
2013.
[20] Q. Sunqing, D. Junxiu, and C. Guoxu,
[13] Design and analysis of experiments. 2005. Tribological properties of CeF3 nanoparticles
as additives in lubricating oils, Wear, vol. 230,
[14] R. V Lenth, Response-surface methods in R , no. 1, pp. 3538, May 1999.
using rsm, J. Stat. Softw., vol. 32, no. 7, pp. 1
17, 2009. [21] M. Schirru and R. Dwyer-joyce, Development
of New Ultrasonic Instrumentation to Measure
[15] Y. Sun, T. Li, J. Yan, and J. Liu, Technology Lubricant Properties in Auto Engines, 2014.
optimization for polysaccharides (POP)
extraction from the fruiting bodies of Pleurotus [22] E. Rabinowics, Friction and Wear of Materials,
ostreatus by BoxBehnken statistical design, 2nd ed. New York, NY: Wiley, 1995.
Carbohydr. Polym., vol. 80, no. 1, pp. 242247,
Mar. 2010. [23] M. Kathiresan and T. Sornakumar, Friction and
wear studies of die cast aluminum alloy
[16] S. Kotz and N. L. Johnson, Eds., Breakthroughs aluminum oxidereinforced composites, Ind.
in Statistics. New York, NY: Springer New Lubr. Tribol., vol. 62, no. 6, pp. 361371, Sep.
York, 1992. 2010.