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JEE MAIN ONLINE PAPER (12.04.2014)

PART A : PHYSICS coefficient of friction between the block and the table is 0.3,
how far will the block slide approximately?
1. From the following combinations of physical constants (a) 0.19 m (b) 0.379 m
(expressed thr ough their usual symbols) the only (c) 0.569 m (d) 0.758 m
combination, that would have the same value in different 5. A spring of unstretched length l has a mass m with one end
systems of units, is: fixed to a rigid support. Assuming spring to be made of a
uniform wire, the kinetic energy possessed by it if its free
ch
(a) end is pulled with uniform velocity v is:
2peo2
1
(a) mv 2 (b) mv2
2 2
e
(b) (me = mass of electron)
2pe o Gme2 1 2 1
(c) mv (d) mv 2
3 6
m o eo G
(c) 6. A particle is moving in a circular path of radius a, with a
c2 he 2 constant velocity v as shown in the figure. The centre of
circle is marked by C. The angular momentum from the
2p m o eo h origin O can be written as:
(d)
ce 2 G y
2. A person climbs up a stalled escalator in 60 s. If standing on
the same but escalator running with constant velocity he
a
takes 40 s. How much time is taken by the person to walk up O q
the moving escalator?
C x
(a) 37 s (b) 27 s
(c) 24 s (d) 45 s
3. Three masses m, 2m and 3m are moving in x-y plane with
speed 3u, 2u and u respectively as shown in figure. The (a) va (1 + cos 2q) (b) va (1 + cos q)
three masses collide at the same point at P and stick together. (c) va cos 2q (d) va
The velocity of resulting mass will be: m1 m2
v1 v2
y
7.
2m, 2u d
Two hypothetical planets of masses m1 and m2 are at rest
60 when they are infinite distance apart. Because of the
x gravitational force they move towards each other along the
m, 3u P 60
line joining their centres. What is their speed when their
3m, u separation is d?
(Speed of m1 is v1 and that of m2 is v2)
(a)
12
(
u
i + 3j ) (b) (
u
12
i - 3j ) (a) v1 = v2
2G
(b) v1 = m 2
d ( m1 + m 2 )
(c)
u
12
(-i + 3j ) (d)
u
12
-i - 3j ( )
4. A bullet of mass 4g is fired horizontally with a speed of 300 2G
v 2 = m1
m/s into 0.8 kg block of wood at rest on a table. If the d ( m1 + m 2 )
2
reflected from ground of frequency nearly: (Speed of sound
2G = 343 m/s)
(c) v1 = m1
d ( m1 + m 2 ) (a) 2150 Hz (b) 2500 Hz
(c) 1800 Hz (d) 2400 Hz
2G 16. A spherically symmetric charge distribution is characterised
v 2 = m2
d ( m1 + m 2 ) by a charge density having the following variations:
r
2G r ( r ) = ro 1 - for r < R
(d) v1 = m 2 R
m1 r(r) = 0 for r R
Where r is the distance from the centre of the charge
2G distribution ro is a constant. The electric field at an internal
v2 = m 2
m2 point (r < R) is:
8. Steel ruptures when a shear of 3.5 108 N m2 is applied. ro r r 2 ro r r 2
The force needed to punch a 1 cm diameter hole in a steel (a) - (b) -
4e o 3 4R e o 3 4R
sheet 0.3 cm thick is nearly:
(a) 1.4 104 N (b) 2.7 104 N
4
(c) 3.3 10 N (d) 1.1 104 N ro r r 2 ro r r 2
- -
9. A cylindrical vessel of cross-section A contains water to a (c) 3e o 3 4R (d) 12e o 3 4R
height h. There is a hole in the bottom of radius a. The time
in which it will be emptied is: 17. The space between the plates of a parallel plate capacitor is
filled with a dielectric whose dielectric constant varies
2A h 2A h with distance as per the relation:
(a) 2 (b) K(x) = Ko + lx (l = a constant)
pa g pa 2 g
The capacitance C, of the capacitor, would be related to its
2 2A h A h vacuum capacitance Co for the relation :
(c) (d)
pa 2 g 2pa 2 g ld
(a) C= Co
10. Two soap bubbles coalesce to form a single bubble. If V is ln (1 + K o ld )
the subsequent change in volume of contained air and S
change in total surface area, T is the surface tension and P l
(b) C= Co
atmospheric pressure, then which of the following relation d.ln (1 + K o ld )
is correct?
(a) 4PV + 3ST = 0 (b) 3PV + 4ST = 0 ld
(c) C= Co
(c) 2PV + 3ST = 0 (d) 3PV + 2ST = 0 ln (1 + ld / K o )
11. Hot water cools from 60C to 50C in the first 10 minutes and
to 42C in the next 10 minutes. The temperature of the l
(d) C= Co
surroundings is: d.ln (1 + K o / ld )
(a) 25C (b) 10C
18. The circuit shown here has two batteries of 8.0 V and 16.0 V
(c) 15C (d) 20C
and three resistors 3 W, 9 W and 9 W and a capacitor of 5.0
12. A Carnot engine absorbs 1000 J of heat energy from a
mF.
reservoir at 127C and rejects 600 J of heat energy during
each cycle. The efficiency of engine and temperature of sink I
will be:
(a) 20% and 43C (b) 40% and 33C 5 mF
(c) 50% and 20C (d) 70% and 10C 3W 9W
13. At room temperature a diatomic gas is found to have an
r.m.s. speed of 1930 ms1. The gas is: 9W
8.0 V 16.0 V
(a) H2 (b) Cl2
(c) O2 (d) F2
14. Which of the following expressions corresponds to simple I1 I2
harmonic motion along a straight line, where x is the How much is the current I in the circuit in steady state?
displacement and a, b, c are positive constants? (a) 1.6 A (b) 0.67 A
(a) a + bx cx2 (b) bx2 (c) 2.5 A (d) 0.25 A
(c) a bx + cx2 (d) bx 19. A positive charge q of mass m is moving along the + x
15. A source of sound A emitting waves of frequency 1800 Hz axis. We wish to apply a uniform magnetic field B for time Dt
is falling towards ground with a terminal speed v. The so that the charge reverses its direction crossing the y axis
observer B on the ground directly beneath the source receives at a distance d. Then:
waves of frequency 2150 Hz. The source A receives waves,
 3

mv pd m
(a) B= and Dt =
qd v
m1 m1
mv pd
(b) B= and Dt =
2qd 2v
2mv pd (c)
(c) B= and Dt =
qd 2v
2mv pd
(d) B= and Dt =
qd v
m
20. Consider two thin identical conducting wires covered with
very thin insulating material. One of the wires is bent into a
m1
loop and produces magnetic field B1, at its centre when a
current I passes through it. The ratio B1 : B2 is: m1
(a) 1 : 1 (b) 1 : 3
(c) 1 : 9 (d) 9 : 1 (d)
21. A sinusoidal voltage V(t) = 100 sin (500t) is applied across a
pure inductance of L = 0.02 H. The current through the coil
is:
(a) 10 cos (500 t) (b) 10 cos (500t) 24. Interference pattern is observed at P due to
(c) 10 sin (500t) (d) 10 sin (500t) superimposition of two rays coming out from a source S as
22. A lamp emits monochromatic green light uniformly in all shown in the figure. The value of l for which maxima is
directions. The lamp is 3% efficient in converting electrical obtained at P is:
power to electromagnetic waves and consumes 100 W of (R is perfect reflecting surface)
power. The amplitude of the electric field associated with
the electromagnetic radiation at a distance of 5 m from the 21
S P
lamp will be nearly:
(a) 1.34 V/m (b) 2.68 V/m
(c) 4.02 V/m (d) 5.36 V/m
23. The refractive index of the material of a concave lens is m. It
is immersed in a medium of refractive index m1. A parallel 30
beam of light is incident on the lens. The path of the emergent R
rays when m1 > m is:
2nl ( 2n - 1) l
m l=
(a) l=
3 -1
(b) 2 ( 3 -1 )
m1
m1 ( 2n - 1) l
l=
3 ( 2n - 1) l
l=
(a)
(c)
(
4 2- 3 ) (d)
3 -1
25. In an experiment of single slit diffraction pattern, first
minimum for red light coincides with first maximum of some
other wavelength. If wavelength of red light is 6600 , then
wavelength of first maximum will be:
m (a) 3300 (b) 4400
(c) 5500 (d) 6600
26. A beam of light has two wavelengths of 4972 and 6216
m1 with a total intensity of 3.6 103 Wm2 equally distributed
m1
among the two wavelengths. The beam falls normally on an
area of 1 cm2 of a clean metallic surface of work function 2.3
(b) eV. Assume that there is no loss of light by reflection and
that each capable photon ejects one electron. The number
of photoelectrons liberated in 2s is approximately:
(a) 6 1011 (b) 9 1011
(c) 11 10 11 (d) 15 1011
27. A piece of bone of an animal from a ruin is found to have 14C
activity of 12 disintegrations per minute per gm of its carbon
4
content. The 14 C activity of a living animal is 16 NA NA
disintegrations per minute per gm. How long ago nearly did (a) (b)
the animal die? (Given half life of 14C is t1/2 = 5760 years) 20 10
(a) 1672 years (b) 2391 years NA NA
(c) 3291 years (d) 4453 years (c) (d)
5 2
28. For LEDs to emit light in visible region of electromagnetic
light, it should have energy band gap in the range of: 37. The (S) of the following substances are:
(a) 0.1 eV to 0.4 eV (b) 0.5 eV to 0.8 eV CH4 (g) 186.2 JK1 mol1
(c) 0.9 eV to 1.6 eV (d) 1.7 eV to 3.0 eV O2 (g) 205.2 JK1 mol1
29. For sky wave propagation, the radio waves must have a CO2 (g) 213.6 JK1 mol1
frequency range in between: H2O (g) 69.9.JK1 mol1
(a) 1 MHz to 2 MHz (b) 5 MHz to 25 MHz The entropy change (DS) for the reaction :
(c) 35 MHz to 40 MHz (d) 45 MHz to 50 MHz CH4(g) + 2O2(g) CO2(g) + 2H2O(l) is:
30. In the experiment of calibration of voltmeter, a standard cell (a) 312.5 J K1 mol1
of e.m.f. 1.1 volt is balanced against 440 cm of potential wire. (b) 242.8 J K1 mol1
The potential difference across the ends of resistance is (c) 108.1 J K1 mol1
found to balance against 220 cm of the wire. The (d) 37.6 J K1 mol1
corresponding reading of voltmeter is 0.5 volt. The error in 38. The conjugate base of hydrazoic acid is:
the reading of volmeter will be: (a) N3 (b) N3-
(a) 0. 15 volt (b) 0.15 volt
(c) 0.5 volt (d) 0.05 volt (c) N -2 (d) HN3-
39. In a monoclinic unit cell, the relation of sides and angles are
PART B : CHEMISTRY respectively:
(a) a = b c and a = b = g = 90
31. If m and e are the mass and charge of the revolving electron (b) a b c and a = b = g = 90
in the orbit of radius r for hydrogen atom, the total energy of (c) a b c and b = g = 90 a
the revolving electron will be: (d) a b c and a b g 90
40. The standard enthalpy of formation (Df H 298) for methane,
1 e2 e2
(a) (b) - CH4 is 74.9 kJ mol1. In order to calculate the average
2 r r energy given out in the formation of a C H bond from this
it is necessary to know which one of the following?
me2 1 e2
(c) (d) - (a) The dissociation energy of the hydrogen molecule, H2.
r 2 r (b) The first four ionisation energies of carbon.
32. The de-Broglie wavelength of a particle of mass 6.63 g moving (c) The dissociation energy of H2 and enthalpy and
with a velocity of 100 ms1 is: sublimation of carbon (graphite).
(a) 1033 m (b) 1035 m (d) The first four ionisation energies of carbon and electron
(c) 10 m 31 (d) 1025 m affinity of hydrogen.
33. What happens when an inert gas is added to an equilibrium 41. Which of the following xenon-oxo compounds may not be
keeping volume unchanged? obtained by hydrolysis of xenon fluorides?
(a) More product will form (a) XeO2F2 (b) XeOF4
(b) Less product will form (c) XeO3 (d) XeO4
(c) More reactant will form 42. Excited hydrogen atom emits light in the ultraviolet region at
(d) Equilibrium will remain unchanged 2.47 1015 Hz. With this frequency, the energy of a single
34. The amount of BaSO4 formed upon mixing 100 mL of 20.8% photon is:
BaCl2 solution with 50 mL of 9.8% H2SO4 solution with 50 (h = 6.63 1034 Js)
mL of 9.8% H2SO4 solution will be: (a) 8.041 1040 J (b) 2.680 1019 J
(Ba = 137, Cl = 35.5, S = 32, H = 1 and O = 16) (c) 1.640 10 J 18 (d) 6.111 1017 J
(a) 23.3 g (b) 11.65 g 43. Which one of the following exhibits the large number of
(c) 30.6 g (d) 33.2 g oxidation states?
35. The rate coefficient (k) for a particular reactions is 1.3 10 (a) Ti (22) (b) V (23)
4 M 1 s 1 at 100C, and 1.3 10 3 (c) Cr (24) (d) Mn (25)
M s1 at 150C. What is the energy of activation (EA) (in
1
44. Copper becomes green when exposed to moist air for a long
kJ) for this reaction? (R = molar gas constant = 8.314 JK 1 period. This is due to:
mol1) (a) the formation of a layer of cupric oxide on the surface
(a) 16 (b) 60 of copper.
(c) 99 (d) 132 (b) the formation of a layer of basic carbonate of copper
36. How many electrons would be required to deposit 6.35 g of on the surface of copper.
copper at the cathode during the electrolysis of an aqueous (c) the formation of a layer of cupric hydroxide on the
solution of copper sulphate? (Atomic mass of copper = 63.5 surface of copper.
u, NA = Avogadros constant):
 5

(d) the formation of basic copper sulphate layer on the

surface of the metal. CH2 COOH
45. Among the following species the one which causes the (d)
highest CFSE, D0 as a ligand is:
(a) CN (b) NH3
52. In the Victor-Meyers test, the colour given by 1, 2 and 3
(c) F (d) CO
alcohols are respectively:
46. Similarity in chemical properties of the atoms of elements in
(a) Red, colourless, blue
a group of the Periodic table is most closely related to:
(b) Red, blue, colourless
(a) atomic numbers
(c) Colourless, red, blue
(b) atomic masses
(d) Red, blue, violet
(c) number of principal energy levels
53. Conversion of benzene diazonium chloride to chlorobenzene
(d) number of valence electrons
is an example of which of the following reactions?
47. Which of the following arrangements represents the
(a) Claisen (b) Friedel-craft
increasing order (smallest to largest) of ionic radii of the
(c) Sandmeyer (d) Wurtz
given species O2, S2, N3, p3?
54. In the presence of peroxide, HCl and HI do not give anti-
(a) O2 < N3 < S2 < p3
Markownikoffs addition of alkenes because:
(b) O2 < p3 < N3 < S2
(a) One of the steps is endothermic in HCl and HI
(c) N3 < O2 < p3 < S2
(b) Both HCl and HI are strong acids
(d) N3 < S2 < O2 < p3
(c) HCl is oxidizing and the HI is reducing
48. Global warming is due to increase of:
(d) All the steps are exothermic is HCl and HI
(a) methane and nitrous oxide in atmosphere
55. The major product obtained in the photo catalysed
(b) methane and CO2 in atmosphere
bromination of 2--methylbutane is:
(c) methane and O3 in atmosphere
(a) 1-bromo-2-methylbutane
(d) methane and CO in atmosphere
(b) 1-bromo-3-methylbutane
49. Hydrogen peroxide acts both as an oxidising and as a
(c) 2-bromo-3-methylbutane
reducing agent depending upon the nature of the reacting
(d) 2-bromo-2-methylbutane
species. In which of the following cases H2O2 acts as a
56. Which of the following molecules has two sigma (s) and
reducing agent in acid medium?
two pi (p) bonds?
(a) MnO-4 (b) Cr2 O72- (a) C2H4 (b) N2F2
(c) C2H2Cl2 (d) HCN
(c) SO32- (d) KI 57. Which one of the following acids does not exhibit optical
50. Which one of the following complexes will most likely absorb isomerism?
visible light? (a) Lactic acid (b) Tartaric acid
(At nos. Sc = 21, Ti = 22, V = 23, Zn = 30) (c) Maleic acid (d) a-amino acids
(a) [Sc(H2O)6]3+ (b) [Ti(NH3)6]4+ 58. Aminoglycosides are usually used as:
(c) [V(NH3)6]3+ (d) [Zn(NH3)6]2+ (a) antibiotic (b) analgesic
(c) hypnotic (d) antifertility
CH2 CH = CH2 59. Which of the following will not show mutarotation?
51. (a) Maltose (b) Lactose
(c) Glucose (d) Sucrose
60. Phthalic acid reacts with resorcinol in the presence of
on mercuration-demercuration produces the major product: concentrated H2SO4 to give:
(a) Phenolphthalein (b) Alizarin
CH2 CH CH3 (c) Coumarin (d) Fluorescein
(a)
OH PART C : MATHEMATICS

61. A relation on the set A = {x : |x| < 3, x Z },

CH2 CH2 CH2 OH where Z is the set of integers is defined by
(b) R = {(x, y) : y = |x|, x 1}. Then the number of elements in
the power set of R is:
(a) 32 (b) 16
(c) 8 (d) 64
CH2 CH CH3
(c) z-i
OH OH 62. Let z i be any complex number such that is a purely
z+i
imaginary number.
1
Then z + is:
z
6
(a) 0
(b) any non-zero real number other than 1. 1
x sin , x 0
(c) any non-zero real number. f (x) = x , and g(x) = x f(x)
(d) a purely imaginary number. 0, ,x = 0

63. The sum of the roots of the equation,
x2 + |2x 3| 4 = 0, is: Statement I: f is a continuous function at x = 0.
(a) 2 (b) 2 Statement II: g is a differentiable function at x = 0.
(a) Both statement I and II are false.
(c) 2 (d) - 2 (b) Both statement I and II are true.
64. If (c) Statement I is true, statement II is false.
(d) Statement I is false, statement II is true.
a2 b2 c2 1
71. If f (x) = x2 x + 5, x > , and g(x) is its inverse function,
(a + l) ( b + l) (c + l)
2 2 2
= 2
then g(7) equals:
( a - l )2 ( b - l )2 ( c - l )2
1 1
(a) - (b)
a2 b2 c2 3 13
kl a b c ,l 0 1 1
1 1 1 (c) (d) -
3 13
72. Let f and g be two differentiable functions on R such that f
then k is equal to: (x) > 0 and g(x) < 0 for all x R . Then for all x:
(a) 4labc (b) 4labc (a) f (g (x)) > f (g (x 1))
(c) 4l2 (d) 4l2 (b) f (g (x)) > f (g (x + 1))
y (c) g(f (x)) > g (f (x 1))
1 2 x 6 (d) g(f (x)) < g (f (x + 1))
65. If A = and B = x be such that AB = ,
3 - 1 2 8 5
1
a i (1 + x )
i
73. If 1 + x4 + x5 = , for all x in R, then a2 is:
then: i =0
(a) y = 2x (b) y = 2x (a) 4 (b) 6
(c) y = x (d) y = x (c) 8 (d) 10
66. 8-digit numbers are formed using the digits 1, 1, 2, 2, 2, 3, 4,
4. The number of such numbers in which the odd digits do sin 2 x cos2 x
74. The integral dx is equal to:
( )
no occupy odd places, is: 2
(a) 160 (b) 120 sin 3 x + cos3 x
(c) 60 (d) 48
1 1
55 +c - +c
( )
(a) (b)
67.
x
If 2 +
3
is expanded in the ascending powers of x and (1 + cot x) 3 3 1 + tan 3 x

the coefficients of powers of x in two consecutive terms of

the expansion are equal, then these terms are: sin 3 x cos3 x
- +c
( )
(c) +c (d)
(a) 7th and 8th
(b) 8th and 9th
(1 + cos3 x ) 3 1 + sin 3 x

(c) 28th and 29th 75. If [ ] denotes the greatest integer function, then the integral
(d) 27th and 28th p
68. Let G be the geometric mean of two positive numbers a and [ cos x ] dx is equal to:
0
1 1 1
b, and M be the arithmetic mean of and . If : G is 4 p
a b M (a) (b) 0
: 5, then a : b can be: 2
(a) 1 : 4 (b) 1 : 2 p
(c) 2 : 3 (d) 3 : 4 (c) 1 (d) -
2
69. The least positive integer n such that
t
2 2 2
1 - - 2 - .... - n -1 <
3 3
1
100
, is: 76. If for a continuous function f(x), ( f ( x ) + x ) dx = p2 t2,
3 -p
(a) 4 (b) 5
(c) 6 (d) 7 p
for all t p, then f - is equal to:
70. Let f, g: R R be two functions defined by 3
 7

p 85. y and z are three unit vectors in three-dimensional

If x,
(a) p (b) space, then the minimum value of
2
2 2 2
p p x + y + y + z + z + x
(c) (d)
3 6
3
77. The general solution of the differential equation, sin 2x (a) (b) 3
2
dy
- tan x - y = 0 , is : (c) 3 3 (d) 6
dx
86. Let X and M.D. be the mean and the mean deviation about
(a) y tan x = x + c (b) y cot x = tan x + c
X of n observations xi, i = 1, 2, ........, n. If each of the
(c) y tan x = cot x + c (d) y cot x = x + c observations is increased by 5, then the new mean and the
78. If a line intercepted between the coordinate axes is trisected mean deviation about the new mean, respectively, are :
at a point A(4, 3), which is nearer to x-axis, then its equation (a) X, M.D. (b) X + 5, M.D.
is:
(a) 4x 3y = 7 (b) 3x + 2y = 18 (c) X, M.D. + 5 (d) X + 5, M.D. + 5
(c) 3x + 8y = 36 (d) x + 3y = 13 87. A number x is chosen at random from the set {1, 2, 3, 4, ....,
79. If the three distinct lines x + 2ay + a = 0, x + 3by + b = 0 and 100}. Define the event: A = the chosen number x satisfies
x + 4ay + a = 0 are concurrent, then the point (a, b) lies on a:
(a) circle (b) hyperbola
( x - 10 )( x - 50) 0
(c) straight line (d) parabola ( x - 30 )
80. For the two circles x2 + y2 = 16 and Then P (A) is:
x2 + y2 2y = 0, there is/are (a) 0.71 (b) 0.70
(a) one pair of common tangents (c) 0.51 (d) 0.20
(b) two pair of common tangents 88. Statement I : The equation (sin 1 x) 3 +
(c) three pair of common tangents
(d) no common tangent 1
(cos1 x)3 ap3 = 0 has a solution for all a .
81. Two tangents are drawn from a point ( 2, 1) to the curve, 32
y2 = 4x. If a is the angle between them, then |tan a| is equal Statement II: For any x R ,
to:
p
sin -1 x + cos-1 x = and
1 1 2
(a) (b)
3 3 2
p 9p2
(c) 3 (d) 3 0 sin -1 x -
4 16
82. The minimum area of a triangle formed by any tangent to the
(a) Both statements I and II are true.
x 2 y2 (b) Both statements I and II are false.
ellipse + = 1 and the co-ordinate axes is: (c) Statement I is true and statement II is false.
16 81
(d) Statement I is false and statement II is true.
(a) 12 (b) 18
(c) 26 (d) 36 1 cos q 1
83. A symmetrical form of the line of intersection of the planes x
89. If f(q) = - sin q 1 - cos q and
= ay + b and z = cy + d is
-1 sin q 1
x - b y -1 z - d
(a) = = A and B are respectively the maximum and the minimum
a 1 c
values of f(q), then (A, B) is equal to:
x - b - a y -1 z - d - c
(b)
a
=
1
=
c
(a) (3, 1) (b) ( 4, 2 - 2 )
(c) x-a y-0 z-c
= =
(c) (2 + 2, 2 - 2 ) (d) ( 2 + 2, -1)
b 1 d 90. Let p, q, r denote arbitrary statements. Then the logically
(d) x - b - a = y - 1 = z - d - c equivalent of the statement p ( q r ) is:
b 0 d
84. If the distance between planes, 4x 2y 4z + 1 = 0 and 4x (a) (p q) r
2y 4z + d = 0 is 7, then d is:
(a) 41 or 42 (b) 42 or 43 (c)
(b) ( p q) (p r )
41 or 43 (d) 42 or 44 (c) ( p ~ q ) ( p r )
(d) ( p q) (p ~ r)
8

HINTS & SOLUTION

Physics Let the velocity when they stick = v

Then, according to question,

1. (b) The dimensional formulae of Y
2m, 2u
e = M0 L0T1A1

j sin 60
e0 = M -1L3T 4 A 2 j
60
m, 3u X
-1 3 -2
G = M L T P 60 i i cos 60

(j) sin 60
and me = M L T
1 0 0
3m, u
e2 () (
m 3u i + 2m 2u -i cos 60 - jsin 60
)
Now,
( )

2pe 0 Gme2 + 3 m u -i cos 60 + jsin 60 = (m + 2m + 3m) v
2 i 3 i
M0 L0 T1A1 3mui - 4mu - 4mu j - 3mu
2
= 2
2 2
2 p M -1L-3T 4 A 2 M -1L3T -2 M1L0 T 0 3

+ 3mu j = 6m v
T 2 A 2 2

= 3 3

2p M -1-1+ 2 -3+ 3 4 - 2 2
L T A mui - mui - muj = 6m v
2 2
1 3
T 2 A 2 - mui - muj = 6m v
2 2
=
2 p M 0 L0 T 2 A 2

v=
u
12
(
- i - 3j )
1
= 4. (b) Given, m1 = 4g, u1 = 300 m/s
2p
m2 = 0.8 kg = 800 g, u2 = 0 m/s
1 e2 From law of conservation of momentum,
Q is dimensionless thus the combination m1u1 + m2u2 = m1v1 + m2v2
2p 2 pe 0 Gm e2 Let the velocity of combined system = v m/s
would have the same value in different systems of units. then,
4 300 + 800 0 = (800 + 4) v
1 "escalator"
2. (c) Persons speed walking only is
60 second 1200
v= = 1.49 m / s
Standing the escalator without walking the speed is 804
1 "escalator" Now, m = 0.3 (given)
a = mg
40 second
a = 0.3 10 (take g = 10 m/s2)
Walking with the escalator going, the speed add. = 3 m/s2
1 1 15 "escalator" then, from v2 = u2 + 2as
So, the persons speed is + = (1.49)2 = 0 + 2 3 s
60 40 120 second
So, the time to go up the escalator (seconds per escalator)
(1.49 )2
120 s=
is t = = 24 second. 6
5
3. (d) From the law of conservation of momentum we know 2.22
s=
that, 6
m1u1 + m2u2 + .... = m1v1 + m2v2 + .... = 0.379 m
Given m1 = m, m2 = 2m and m3 = 3m 5. (d)
and u1 = 3u, u2 = 2u and u3 = u 6. (a)
 9

7. (b) We choose reference point, infinity, where total energy = 3.297 104 ; 3.3 10 4 N
of the system is zero.
So, initial energy of the system = 0 dh
9. (b) Let the rate of falling water level be -
1 1 Gm 1m 2 dt
Final energy = m 1 v12 + m 2 v 22 - Initially at t = 0 ; h = h
2 2 d
t=t;h=0
From conservation of energy, A
Initial energy = Final energy dh 2
Then, A - = pa .v
dt
1 1 Gm 1 m 2
\0= m 1 v12 + m 2 v 2 2 -
2 2 d A
dt = - 2
dh h
1 1 Gm 1 m 2 pa 2 gh
or m 1 v12 + m 1 v 22 = ...(1) a
2 2 d [Q velocity of efflux of
By conservation of linear momentum liquid v = 2 gh ]
v1 m m Integrating both sides
m1v1 + m 2 v 2 = 0 or = - 2 v2 = 1 v1
v2 m1 m2 t 0
A -1 2
dt = - h dh
Putting value of v2 in equation (1), we get 0 2 g pa 2 h
2
m v 2Gm1m 2 0
m1v12 + m 2 - 1 1 = A h1 2
m2 d [t] t
0
=- .
2 g pa 2 1 2 h
m1m 2 v12 + m12 v12 2Gm1m 2
=
m2 d 2A h
t=
2Gm 22 2G pa 2 g
v1 = = m2 10. (b)
d ( m1 + m 2 ) d (m1 + m 2 )
11. (b) By Newtons law of cooling
2G q1 - q2 q + q2
Similarly v 2 = - m1 = -K 1 - q0
d ( m1 + m 2 ) t 2

where q0 is the temperature of surrounding.
8. (c) D Now, hot water cools from 60C to 50C in 10 minutes,
60 - 50 60 + 50
= -K - q0 ...(i)
10 2
F Again, it cools from 50C to 42C in next 10 minutes.
50 - 42 50 + 42
= -K - q0 ...(ii)
10 2
Dividing equations (i) by (ii) we get
h
1 55 - q0
=
0.8 46 - q0

Shearing strain is created along the side surface of the 10 55 - q 0

=
punched disk. Note that the forces exerted on the disk are 8 46 - q 0
exerted along the circumference of the disk, and the total
460 - 10q0 = 440 - 8q0
force exerted on its center only.
Let us assume that the shearing stress along the side surface 2q0 = 20
of the disk is uniform, then
q0 = 10c
F> dFmax = s max dA = smax dA 12. (b) Given : Q1 = 1000 J
surface surface surface Q2 = 600 J
T1 = 127C = 400 K
D T2 = ?
= s max .A = smax .2p h
2 h=?
Efficiency of carnot engine,
8 1 -2 -2
= 3.5 10 10 0.3 10 2p
2
10

W 343 + 55.83
h= 100% = 1800
Q1 343 - 55.83
Q2 - Q1 = 2499.44 2500Hz
or, h= 100% 16. (b) Let us consider a spherical shell of radius x and
Q1 thickness dx.
1000 - 600
or, h= 100%
1000
h = 40% dx
x
Q 2 T2 O
Now, for carnot cycle Q = T
1 1 Shell
600 T
= 2
1000 400
600 400 Charge on this shell
T2 =
1000 x
dq = r.4px2dx = r0 1 - .4px 2dx
= 240 K R
= 240 273 \ Total charge in the spherical region from centre to r (r < R) is
\ T2 = -33C r
x
q = dq = 4pr0 1 - x 2dx
3RT R
13. (a) Q C= 0
M
r
3 8.314 300 x3 x 4
(1930 ) 2
= = 4pr0 -
M 3 4R 0
3 8.314 300
M= 2 10 -3 kg r3 r 4
1930 1930 = 4pr0 -
The gas is H2. 3 4R
14. (d) In linear S.H.M., the restoring force acting on particle
should always be proportional to the displacement of the 1 r
= 4pr0 r3 -
particle and directed towards the equilibrium position. 3 4R
i.e., F x
1 .q
or F = - bx where b is a positive constant. \ Electric field at r, E =
4pe 0 r 2
15. (b) Given f A = 1800Hz
vt = v 1 4pr0 r3 1 r
fB = 2150 Hz =
4pe 0
. -
r 2 3 4R
Reflected wave frequency received by A, f A = ?
r r r2
Applying dopplers effect of sound, = 0 -
e0 3 4R
vs f
f = 17. (c) The value of dielectric constant is given as,
vs - v t
K = K 0 + lx
f
here, v t = vs 1 - A d
fB And, V = Edr
0
1800
= 343 1 -
2150 d
s
vt = 55.8372 m/s V= dx
K
Now, for the reflected wave, 0

v + vt d
1
f A = s
\ fA
vs - v t = s ( K + l x ) dx
0 0
 11

s mv2
= ln ( K 0 + ld ) - ln K0 \ Bqv =
l d/2
s ld 2mv
= l ln 1 + K or, B=
0 qd
Now it is given that capacitance of vacuum = C0. Time interval for which a uniform magnetic field is
applied
Q
Thus, C = d
V p.
s.s Dt = 2
= (Let surface area of plates = s) v
v (particle reverses its direction after time Dt by covering
s.s semi circle).
=
s ld pd
ln 1 + Dt =
l K0 2v
m 0 nI
d 1 20. (b) For loop B =
= sl. (Q in vacuum e0 =1) 2a
d ld where, a is the radius of loop.
ln 1 +
K 0 m0 I
Then, B1 =
ld s 2a
c= . C0 here, C0 =
ld d m I 2nA
ln 1 + Now, for coil B = 0 .
K 0 4p x 3
at the centre x = radius of loop
18. (b) line 1 line 2 line 3
2
m 2 3 ( I / 3) p ( a / 3 )
5m F I B2 = 0 .
3W 9W 4p ( a / 3)3
8.0 V 16.0 V m 0 .3I
I1 I2
=
2a
In steady state capacitor is fully charged hence no current
B1 m I / 2a
will flow through line 2. \ = 0
By simplyfing the circuit B2 m0 .3I / 2a
B1 : B2 = 1: 3
21. (b) In a pure inductive circuit current always lags behind
3W 9W
p
the emf by .
8.0 V 16.0 V 2
If v ( t ) = v0 sin wt
Hence resultant potential difference across resistances will p
be 8.0 V. then I = I0 sin wt -
2
V Now, given v(t) = 100 sin (500 t)
Thus current I =
R
E0 100
8.0 8 and I0 = = [Q L = 0.02H ]
= = wL 500 0.02
3 + 9 12
p
2 I0 = 10sin 500t -
or, I = = 0.67 A 2
3
19. (c) The applied magnetic field provides the required I0 = -10cos ( 500t )
centripetal force to the charge particle, so it can move 22. (b) Wavelength of monochromatic green light
= 5.5 105 cm
d
in circular path of radius Power
2 Intensity I =
Area
12

100 ( 3 /100 ) l = 4400

=
4p ( 5 )
2 26. (b) Given, l1 = 4972

3
and l 2 = 6216
= Wm -2
100p and I = 3.6 10 -3 Wm -2
Now, half of this intensity (I) belongs to electric field and half Intensity associated with each wavelength
of that to magnetic field, therefore,
3.6 10-3
I 1 =
= e0 E 02 C 2
2 4 = 1.8 103 Wm2
2I work function f = hv
or E 0 = e C
0 hc
=
l
3

=
2
100
p
=
( 6.62 10-34 )( 3 108 )


1
9
4p 9 10
(
3 108 ) l

12.4 103
= ev
6 l
= 30
25 for different wavelengths
= 7.2 12.4 103 12.4 103
f1 = = = 2.493 eV
\ E 0 = 2.68 V / m l1 4972
23. (a) If a lens of refractive index m is immersed in a medium of = 3.984 1019 J
refractive index m1, then its focal length in medium is given
by 12.4 103 12.4 103
f2 = = = 1.994 eV
1 1 1 l2 6216
= ( m m l - 1) -
fm R1 R 2 = 3.184 1019 J
Work function for metallic surface f = 2.3 eV (given)
If fa is the focal length of lens in air, then f2 < f
1 1 1 Therefore, f2 will not contribute in this process.
= ( a m l - 1) -
fa R1 R 2 Now, no. of electrons per m2-s = no. of photons per m2-s

f m ( a ml - 1) 1.8 10-3
no. of electrons per m2-s = 10-4
= -19
fa ( m ml - 1) 3.984 10
If m1 > m, then fm and fa have opposite signs and the nature
of lens changes i.e. a convex lens diverges the light rays and
(Q1 cm 2
= 10-4 m 2 )
concave lens converges the light rays. Thus given option (a) = 0.45 1012
is correct. So, the number of photo electrons liberated in 2 sec.
24. (c) = 0.45 1012 2
25. (b) In a single slit experiment, = 9 1011
For diffraction maxima, 27. (b) Given, for 14C
l A0 = 16 dis min1 g1
a sin q = ( 2n + 1) A = 12 dis min1 g1
2 t1/2 = 5760 years
and for diffraction minima,
0.693
a sin q = nl Now, l =
According to question, t1/ 2
l 0.693
( 2 1 + 1) = 1 6600 l= per year
2 5760
(Q l R = 6600 ) 2.303 A
Then, from, t = log10 0
6600 2 l A
l=
3
 13

2.303 5760 16 pressure of each reactant and product remains the

= log10 same. Hence no effect on the state of equilibrium.
0.693 12
34. (a) BaCl 2 + H 2SO 4
BaSO 4 + 2HCl
2.303 5760
= log10 1.333 208 g 98 g 233 g 73 g
0.693
20.8 g 9.8 g 23.3 g 7.3 g
2.303 5760 0.1249
= = 2390.81 2391 years. 35. (b) According to Arrhenius equation
0.693
28. (d) Energy band gap range is given by, k2 Ea 1 1
log = -
hc k1 2.303R T1 T2
Eg =
l
1.3 10-3 Ea 1 1
(
For visible region l = 4 10
-7
: 7 10 -7
) m
log
1.3 10 -4
= -
2.303 8.314 373 423

6.6 10 -34 3 108 Ea 1 1

Eg = 1= 373 - 423
2.303 8.314
7 10-7
Ea = 60 kJ / mole
19.8 10-26 36. (c) Cu Cu++ + 2e
=
7 10 -7 i.e, to deposit 1 mole of Cu at cathode from Cu 2+ SO42
solution = 2 moles of electrons are required
2.8 10-19
= 6.35 2 1
1.6 10-19 i.e, To deposit 6.35g = 2 = = moles
63.5 10 5
Eg = 1.75 eV
NA
29. (b) Sky wave propagation is suitable for frequency range Thus total no. of electrons required =
5
5 MHz to 25 MHz.
30. (d) In a voltmeter
V l
37. (b) (
D S = SCO 2 + 2 SH 2O - SCH 4 + 2 SO 2 )
= (213.6 + 2 69.9) (186.2 + 2 205.2)
V = kl
= 242. 8 J K1 mol1.
Now, it is given E = 1.1 volt for l1 = 440 cm
and V = 0.5 volt for l2 = 220 cm 38. (b) N 3H N3- + H +
Let the error in reading of voltmeter be DV then, Hydrazoic acid
1.1 = 400 K and (0.5 DV) = 220 K. i.e, conjugate base of hydrazoic acid is N3.
1.1 0.5 - DV 39. (c)
= 40. (a) To calculate average enthalpy of C H bond in
440 220
methane following informations are needed
\ DV = -0.05 volt (i) dissociation energy of H2 i.e.
1
CHEMISTRY H( g ); DH = x ( suppose )
H 2 ( g )
2
31. (d) Total energy of a revolving electron is the sum of its (ii) Sublimation energy of C(graphite) to C(g)
kinetic and potential energy.
Total energy = K.E. + P. E. C( g ); DH = y ( Suppose )
C( graphite)
Given
e 2 e2
= +- CH 4 ( g ); DH = 75 kJ mol - 1
C( graphite ) + 2H 2 ( g )
2r r
41. (d) Partial
XeF6 + H 2 O
XeOF4 + 2HF
2
e
=- XeF6 + 2H 2 O
Partial
XeO2 F2 + 4HF
2r
Compute
h XeF6 + 3H 2 O XeO3 + 6HF
32. (a) De Broglie wavelength (l) =
mv 42. (c) E = hn
- 34 = 6.63 1034 2.47 1015
6.63 10
= 1033 = 1.640 1018 J
6.63 10-3 100 43. (d) Maganese exhibits the large number of oxidation states.
33. (a) On adding inert gas at constant volume the total The most common oxidation states of Mn are +2, +3,
pressure of the system is increased, but the partial + 4, + 6 and +7.
 14
44. (d) Copper when exposed to moist air having CO2. It gets +
superficially coated with a green layer of basic R H R NO
H O NO KOH
carbonate CuCO3. Cu (OH)2. C H2O C blue colour
45. (d) Following is the order of increasing value of Do for the R NO2 R NO2
ligands.
I < Br < Cl < F < H2O < Py = NH3 < en < NO2 << HI AgNO 2 HNO 2
(iii) R 3 COH R 3 CI R 3 CNO 2 N.R.
CN < CO
46. (a) If elements are arranged in order of their increasing HNO KOH

2 No reaction Colourless
atomic numbers, element coming at intervals of 2, 8, 8,
18, 18, 32 and 32 will have similar physical and chemical CuCl/HCl
53. (c) C6 H 5 N 2 Cl
C6H 5Cl + N2
properties and thus grouped in one particular group. Benzene or Cu + HCl Chloro benzene
47. (a) For isoelectronic species ionic radii decreases as the diazoniumchloride
charge on ion decreases. Further on moving down in a The above reaction is known as Sandmayers reaction.
group ionic radii increases. Hence the correct order is 54. (a) Anti-Markownikoff addition is possible only in case
O2 < N3 < S2 < P3 of HBr and not in HCl and HI. In HBr both the chain
48. (a) The main gas responsible for the global warming is initiation and propagation steps are exothermic, while
carbon dioxide. Other contributors include methane in HCl, first step is exothermic, and second step is
released from landfills and agriculture, nitrous oxide endothermic and in HI, no step is exothermic. Hence
from fertilizers etc. HCl and HI do not undergo anti-Markownikoff s
49. (a) H2O2 acts as a reducing agent only in presence of addition.
strong oxidising agents (i.e., MnO4) in acidic as well 55. (d) The order of substitution in different alkanes is
as alkaline medium. 3 > 2 > 1
2KMnO4 + 3H 2SO 4 + 5H 2O 2 Thus the bromination of 2-methyl butane mainly gives
2-Bromo - 2 - methyl butane
K 2SO 4 + 2MnSO 4 + 8H 2 O + 5O 2
50. (c) The absorption of visible light and hence coloured CH3
| Br2
nature of the transition metal cation is due to the
CH3 - CH 2 - CH - CH3
promotion of one or more unpaired - d - electron from 2-methyl butane
a lower to higher level withing same d-subshell. Hence
higher will be the number of unpaired electron higher CH3 CH3
will be the absorpion in visible light. | |
The electronic configuration of the given elements is CH3 - CH 2 - C H - CH 2 Br + CH3 - CH 2 - C - CH3
Sc3+ (18) = 1s2 2s2 2p6 3s2 3p6 3d0 4s0 - no unpaired e. 1-Bromo-2methyl butane |
Ti4+ (18) = 1s2 2s2 2p6 3s2 3p6 3d0 4s0 - no unpaired e. (minor) Br
2-Bromo-2-methyl butane
V3+ (20) = 1s2 2s2 2p6 3s2 3p6 3d2 4s0 - Two unpaired e. (major)
Zn2+ (28) = 1s2 2s2 2p6 3s2 3p6 3d10 4s0 - no unpaired e.
p, s
hence [V(NH3)6]3+ will most likely absorb visible light. 56. (d) H C N
s p
CH2-CH=CH2 i.e 2 p and 2 s bonds.
(i) Hg(OAC)2
51. (a) 57. (c) Optical isomers contain an asymmetric (chiral) carbon
(ii) NaBH 4
atom (a carbon atom attached to four different atoms
CH2CHCH3 or groups). Therefore all except maleic acid exhibit
optical isomerism.
58. (a) The aminoglycosides are among the oldest antibiotics.
OH 59. (d) Sucrose does not contain a free aldehydic or ketonic
52. (b) Victor Meyers test: The various steps involved are group hence it does not show mutarotation.
HI
(i) RCH 2 OH AgNO 2
RCH 2 I
HNO 2
RCH 2 NO 2 HO
COOH
Conc. H2SO 4
KOH 60. (d) +2 OH

RCH 2 NO2
R - C - NO2 Blood red colour
|| COOH
NOH
Nitrolic acid

HI R
(ii) RCHOHR R > CHI
AgNO
R > CHNO2
R2 HNO
2 KOH
C - NO2 Blue colour
 15

O 3
(2 x - 3) if x>
2
C |2x 3| =
- (2 x - 3) if 3
x<
O 2

C 3
for x > , x2 + 2 x - 3 - 4 = 0
2
+ H2O x2 + 2x 7 = 0
HO O OH -2 4 + 28 -2 4 2
Fluorescein
x= = = -1 2 2
2 2
3
Here x = 2 2 - 1 2 2 - 1 <
2
Mathematics for x <
3
2
61. (b) A = {x : |x | < 3, x Z } x2 2x + 3 4 = 0
A = {2, 1, 0, 1, 2} x2 2x 1 = 0
R = {(x, y) : y = |x |, x -1}
2 4+4 2 2 2
R = {(2, 2), (0, 0), (1, 1), (2, 2)} x= = = 1 2
2 2
R has four elements
Number of elements in the power set of R 3
= 24 = 16 Here x = 1 - 2 (1 - 2) <
2
62. (c) Let z = x + iy
Sum of roots : (2 2 - 1) + (1 - 2) = 2
z-i
is purely imaginary means its real part is zero.
z+i
a2 b2 c2
x + iy - i x + i ( y - 1) x - i ( y + 1)
= (a + l)2 (b + l )2 (c + l ) 2
x + iy + i x + i ( y + 1) x - i ( y + 1) 64. (c) Let D =
(a - l)2 (b - l )2 (c - l ) 2
2 2
x - 2ix ( y + 1) + xi ( y - 1) + y - 1
= Apply R2 R2 R3
x 2 + ( y + 1) 2
a2 b2 c2
x2 + y2 -1 2 xi
= - 2 2 2 2 2
D = (a + l ) - ( a - l) (b + l) - (b - l) (c + l) - (c - l)
2
x 2 + ( y + 1) 2 x 2 + ( y + 1) 2
for pure imaginary, we have (a - l )2 (b - l)2 (c - l )2

x2 + y2 -1
=0 a2 b2 c2
x 2 + ( y + 1) 2
= 4al 4bl 4c l
x2 + y2 = 1
(x + iy) (x iy) = 1 (a - l )2 (b - l ) 2 (c - l ) 2
1
x + iy = =z (Q ( x + y )2 - ( x - y )2 = 4 xy )
x - iy
Taking out 4 common from R2
1
and
z
= x iy a2 b2 c2
=4 al bl cl
1
z+ = ( x + iy ) + ( x - iy ) = 2 x a + l - 2al b + l - 2bl c + l 2 - 2cl
2 2 2 2 2
z
1 Apply R3 [R3 (R1 2R2)]
z + is any non-zero real number
z

63. (c) x2 + 2 x - 3 - 4 = 0
16

r
a2 b2 c2 x
rth term = 255 55Cr
= 4 al bl cl 6

l2 l2 l2 1
Coefficient of xr is 255 55Cr r
Taking out l common from R2 and l2 from R3. 6
r +1
a2 b2 c2 x
(r +1)th term = 255 55Cr +1
2 6
= 4l ( l ) a b c
1 1 1 55 55 1
Coefficient of xr+1 is 2 Cr +1. r +1
6
a2 b2 c2 Both coefficients are equal
= kl a b c 1 1
255 55Cr r
= 255 55Cr +1 r +1
1 1 1 6 6

k = 4l2 1 1 1
= .
r 55 - r r + 1 54 - r 6
y
1 2 x x 6 (r + 1) = 55 r
65. (a) Let A = 3 -1 2 and B = 6r + 6 = 55 r
1 7r = 49
r=7
y (r + 1) = 8
1 2 x Coefficient of 7th and 8th terms are equal.
x
AB = 3 -1 2 68. (a) G=
1 ab
1 1
6 y + 2x + x +
8 = 3 y - x + 2 M= a b
2

6 y + 3x a+b
8 = 3 y - x + 2 M=
2ab
y + 3x = 6 and 3y x = 6 1
Given that :G = 4 :5
On solving, we get M
6 12 2ab
x= and y = 4
5 5 =
(a + b) ab 5
y = 2x
66. (b) In 8 digits numbers, 4 places are odd places. a+b 5
Also, in the given 8 digits, there are three odd digits =
2 ab 4
1, 1 and 3.
No. of ways three odd digits arranged at four even a + b + 2 ab 5+ 4
=
4 P3 4! a + b - 2 ab 5- 4
places = =
2! 2! {Using Componendo & Dividendo}
No. of ways the remaining five digits 2, 2, 2, 4 and
( a )2 + ( b ) 2 + 2 ab 9
5! 2 2 =
4 arranged at remaining five places = ( a ) + ( b ) - 2 ab 1
3!2!
Hence, required number of 8 digits number 2
b + a 9 b+ a 3
4! 5! = =
= = 120 b - a 1 b- a 1
2! 3!2!
67. (a) Let rth and (r + 1)th term has equal coefficient b+ a+ b- a 3 +1
=
x
55 55 b+ a- b+ a 3 -1
x
2 + = 255 1 + {Using Componendo & Dividendo}
3 6
 17

= 02 a finite quantity between 1 and 1

b 4 =0
= =2
a 2
1
RHL = lim h2 sin = 0
b 4 h 0 + h
=
a 1 Also g(0) = 0
a 1 \ g(x) is continuous at x = 0
= a:b=1:4 71. (c) f (x) = y = x2 x + 5
b 4
1 1
2 2 2 1 x2 x + - +5 = y
69. (b) 1- - 2 .... n-1 < 4 4
3 3 3 100
2
1 19
2 1 1 1 1 1 x - + =y
1- + + + ... < 2 4
3 3 32 3 n-1
3 3 100
2
1 19
1 1
1 - 2 n - 1
x - = y-
2 4
3 3
<
1
1 100 1 19
-1 x- = y-
3 2 4

3n - 1 1 1 19
1- 2 < x= y-
n 2 4
2.3 100
1
3n - 1 1 As x >
1- < 2
n
3 100
1 19
x= + y-
1 1 2 4
1 -1 + n <
3 100
1 19
100 < 3n g(x) = + x-
2 4
Thus, least value of n is 5
1
1 g(x) =
x sin , x 0
70. (b) f (x) = x 2 x-
19
0, 4
x=0

and g ( x) = x f ( x ) 1 1 1
g(7) = = =
For f (x) 19 28 - 19 3
2 7- 2
4 2
1
LHL = lim- - h sin - 72. (b) Since f (x) > 0 and g(x) < 0, therefore
h 0 h
f (x) is increasing function and g(x) is decreasing
= 0 a finite quantity between 1 and 1 function.
=0 f (x + 1) > f (x) and g (x + 1) < g (x)
1 g [f (x + 1)] < g [ f (x)] and f [g (x + 1)] < f [g (x)]
RHL = lim+ h sin =0 Hence option (b) is correct.
h 0 h
5
Also, f (0) = 0
Thus LHL = RHL = f(0) 73. (a) 4
1+ x + x = 5 ai (1 + x)i
i= 0
\ f (x) is continuous at x = 0
1 2 3
2 1 = a0 + a1 (1 + x) + a2 (1 + x ) + a3 (1 + x )
x sin , x 0
g(x) = x + a4 (1 + x )4 + a5 (1 + x )5
0, x=0
1 + x 4 + x5
For g(x)
= a0 + a1 (1 + x) + a2 (1 + 2 x + x 2 ) + a3 (1 + 3 x + 3 x 2 + x3 )
1
LHL = lim - h 2 sin
-
h 0 h
18

+ a4 (1 + 4 x + 6 x 2 + 4 x3 + x 4 ) + a5 (1 + 5x + 10 x 2 + 10 x3 + 5x 4 + x5 ) 1 dt 1 -2
3 t2
\I= = t dt
3
1 + x 4 + x5
2
= a0 + a1 + a1 x + a2 + 2a2 x + a2 x + a3 + 3a3 x 1 t -2+1 -1 1
I = 3 -2 + 1 + c = +c
3 t
+3a3 x 2 + a3 x3 + a4 + 4a4 x + 6a4 x 2 + 4a4 x3 + a4 x 4 + a5
1
+5a5 x + 10a5 x 2 + 10a5 x3 + 5a5 x 4 + a5 x5 or I = - +c
3(1 + tan 3 x)
1 + x 4 + x5
p
= (a0 + a1 + a2 + a3 + a4 + a5 ) + x(a1 + 2a2 + 3a3 + 4a4 + 5a5 )
75. (d) Let I = [cos x]dx ...(1)
2 3 0
+ x (a2 + 3a3 + 6a4 + 10a5 ) + x ( a3 + 4 a4 + 10a5 )
p p
+ x 4 (a4 + 5a5 ) + x5 (a5 )
On comparing the like coefficients, we get
I= [cos(p - x )]dx = [ - cos x ]dx ...(2)
0 0
a5 = 1 ...(1) ; a4 + 5a5 = 1 ...(2); On adding (1) and (2), we get
p p
a3 + 4a4 + 10 a5 = 0 ...(3) and a2 + 3a3 + 6 a4 + 10a5 = 0 ...(4)
from (1) & (2), we get
2I = [cos x]dx + [ - cos x]dx
0 0
a4 = -4 ...(5) from (1), (3) & (5), we get p

a3 = +6 ...(6) 2I = [cos x ] + [ - cos x]dx

0
Now, from (1), (5) and (6), we get
p
a2 = 4 2I = 0 - 1dx (Q [ x ] + [ - x] = -1 if x Z )
sin 2 x cos 2 x
74. (b) Let I = (sin 3 x + cos3 x)2 dx 2I = - x 0 = -p
p

2
-p
sin x.cos x I=
I = 3 dx 2
sin x + cos3 x
t
2
76. (a) Let -p ( f ( x ) + x)dx = p2 t2
sin x. cos x
I= dx

t
-p f ( x )dx +
t
xdx = p2 t2
cos3 x (1 + tan 3 x) -p

2 t t 2 p2
sin x.sec 2 x
= dx
-p f ( x )dx + - = p2 t2
2 2
(1 + tan3 x )
Put 1 + tan 3 x = t t 3 2 2
-p (p - t )
f ( x )dx =
2
dt
dt = 3tan 2 x sec2 x dx or dx = differentiating with respect to t
3tan x sec 2 x
2
d t 3 d 2 2
f ( x)dx = (p - t )
2 4 dt -p 2 dt
sin x.sec x dt
\I= t 2

3 tan x sec 2 x
2
dt d
f (t ). - f ( -p) ( -p) = 3t
dt dt
1 sin 2 x.sec 4 x dt
I=
3 t 2

2
sin x
f (t) = 3t
sec2 x p p
cos 2 x f - = -3 - = p
3 3

1 sin 2 x.sec4 x dt dy
= 3 2
77. (d) Given, sin 2 x - tan x - y = 0
dx
t sin x sec 4 x
2
 19

dy y x + 4ay + a = 0 ...(3)
or, = + tan x
dx sin 2 x Subtracting equation (3) from (1)
2ay = 0
dy ay = 0 y = 0
or, - y cosec2 x = tan x ...(1)
dx Putting value of y in equation (1), we get
x+0+a=0
Now, integrating factor (I.F) = e
- cosec2 x
x=a
Putting value of x and y in equation (2), we get
or, I.F =
1
- log|tan x|
e 2 = e
log ( tan x ) -1 a+b=0
a=b
1 Thus, (a, b) lies on a straight line
= = cot x
tan x 80. (d) Let, x2 + y2 = 16 or x2 + y2 = 42
Now, general solution of eq. (1) is written as radius of circle r1 = 4, centre C1 (0, 0)
we have, x2 + y2 2y = 0
y (I. F.) = Q(I.F.) dx + c x2 + (y2 2y + 1) 1 = 0 or x2 + (y 1)2 = 12
Radius 1, centre C2 (0, 1)
\ y cot x = tan x . cot x dx + c |C1C2 | = 1
| r2 r1| = |4 1| = 3
\ y cot x = 1.dx + c | C1C2| < |r2 r1|
no common tangents for these two circles.
\ y cot x = x + c 81. (d) The locus of the point of intersection of tangents to
the parabola y2 = 4 ax inclined at an angle a to each
other is
78. (b) tan2a (x + a)2 = y2 4ax
C(0, b) Given equation of Parabola y2 = 4x {a = 1}
Point of intersection (2, 1)
2 tan2a (2 + 1)2 = (1)2 4 1 (2)
tan2a = 9
tan a = 3
A(4, 3) |tan a| = 3
1
O (0, 0) 82. (d) 81
A 0,
k
B(a, 0) (h, k)

A divides CB in 2 : 1
O
1 0 + 2 a 2a 16
4 = = B , 0
1+ 2 3 h
a = 6 coordinate of B is B (6, 0)
1 b + 2 0 b
3 = =
1+ 2 3
Let (h, k) be the point on ellipse through which
b = 9 and C (0, 9)
tangent is passing.
Slope of line passing through (6, 0), (0, 9)
9 3 xh yk
slope, m = =- Equation of tangent at (h, k) = + =1
-6 2 16 81
-3 16
Equation of line y 0 = ( x - 6) at y = 0, x =
2 h
2y = 3x + 18 81
3x + 2y = 18 at x = 0, y =
k
79. (c) x + 2ay + a = 0 ...(1)
1 16 81 648
x + 3by + b = 0 ...(2) Area of AOB = =
2 h k hk
20

(648)2 d -1
A2 = ...(1) Distance between them is 7 =
h2k 2 16 + 4 + 16
(h, k) must satisfy equation of ellipse d -1
= 7
6
h2 k 2
+ =1 d = 42 + 1
16 81
or 42 + 1
16 i.e. d = 41 or 43.
h2 = (81 - k 2 )
81 85. (b) ( x + y + z)2 0
Putting value of h2 in equation (1)
3 + 2 S x. y 0
81(648) 2 a
A2 = = 2 S x. y -3
16 k 2 (81 - k 2 ) 81k 2 - k 4
2 2 2
differentiating w.r. to k Now, x + y + y + z + z + x

-1 = 6 + 2 S x. y 6 + ( -3)
2AA = a (162k - 4 k 3 )
81k - k 4
2
2 2 2
x + y + y + z + z + x 3
2AA = 2A (81k 4k3) A= 81k 4k3
Put A = 0 86. (b) Let xi be n observations, i = 1, 2, ...n
162k 4k3 = 0, k (162 4k2) = 0 Let X be the mean and M.D be the mean deviation
9 about X .
k = 0, k = If each observation is increased by 5 then new mean
2
A = (81 12k2) will be X + 5 and new M.D. about new mean will
For both value of k, A = 405 > 0 n
x
9 be M.D. Q Mean = ni
Area will be minimum for k = i =1
2
( x - 10)( x - 50)
16 87. (a) Given 0
2
h = (81 - k 2 ) = 8 ( x - 30)
81
Let x 10, x 50 equation will be true " x 50
h = 2 2
x - 50
as 0, " x [10, 30)
Area of triangle AOB =
648 2
= 36 sq unit x - 30
2 2 9
83. (b) Given two planes : ( x - 10)( x - 50)
0 " x [10, 30)
x ay b = 0 and cy z + d = 0 x - 30
Let, l, m, n be the direction ratio of the required line. Total value of x between 10 to 30 is 20.
Since the required line is perpendicular to normal of Total values of x between 50 to 100 including 50 and
both the plane, therefore l am = 0 and cm n = 0 100 is 51.
l am + 0.n = 0 and 0.l + cm n = 0 Total values of x = 51 + 20 = 71
l m n 71
\ = = P (A) = = 0.71
a - 0 0 +1 c - 0 100
Hence, d.R of the required line are a, 1, c. p p
Hence, options (c) and (d) are rejected. 88. (a) sin -1x - ,
2 2
Now, the point (a + b, 1, c + d) satisfy the equation
of the two given planes. 3p -1 p p
\ Option (b) is correct. - sin x -
4 4 4
84. (c) Given planes are
2
4x - 2 y - 4z + 1 = 0 p 9
0 sin -1 x - p 2 ..(1)
4 16
and 4 x - 2 y - 4 z + d = 0
Statement II is true
They are parallel.
(sin -1 x)3 + (cos -1 x )3 = ap
3
 21

(sin -1 x + cos -1 x) (sin -1 x + cos -1 x ) 2 - 3 sin -1 x cos -1 x 1 cos q 1

= ap3 - sin q 1 - cos q
89. (c) Let f (q) =
p 2 -1 sin q 1
- 3sin -1 x cos -1 x = 2ap2
4
= (1 + sin q cos q) - cos q( - sin q - cos q) + 1( - sin 2 q + 1)
-1 p p2
sin x - sin -1 x = (1 - 8a )
2 12 = 1 + sin q cos q + sin q cos q + cos2 q - sin 2 q + 1
2 = 2 + 2sin q cos q + cos 2q
-1 p p2 p2
sin x - = (8a - 1) + = 2 + sin 2q + cos 2q ...(1)
4 12 16
Now, maximum value of (1)
2
-1 p p2
sin x - = (32a - 1) is 2 + 12 + 12 = 2 + 2
4 48
Putting this value in equation (1) and minimum value of (1) is

p2 9 2 - 12 + 12 = 2 - 2 .
0 (32 a - 1) p 2 90. (b) Given statement is
48 16
0 32a - 1 27 p (q r ) which is equivalent to

1 7 ( p q) ( p r )
a
32 8
Statement-I is also true.