RESULTS AND DATA :

A. DATA FOR A BIMODAL SOLUBILITY CURVE

TABLE 1 : Result for titration of 10g acetic acid chloroform mixture with water.

Mass % Mass of Volume of Mass of Volume of Volume of Mass of

of acetic acetic acid acetic acid chlorofor chlorofor water (g) water (g)

acid (g) (ml) m (g) m (ml)

90 9 8.58 1 0.67 17.00 17.00

80 8 7.63 2 1.35 8.90 8.90

70 7 6.67 3 2.02 3.50 3.50

60 6 5.72 4 2.70 3.00 3.00

50 5 4.77 5 3.37 2.60 2.60

40 4 3.81 6 4.05 1.20 1.20

30 3 2.86 7 4.75 0.70 0.70

20 2 1.91 8 5.39 0.60 0.60

10 1 0.95 9 6.07 0.30 0.30

Densities of chloroform, acetic acid, and water are 1.483, 1.049 and 1.000 g/ml respectively.
 B. DATA FOR TIE LINE AND PLAIT POINT

Tables 2 : Result for titration of phases with IM NaOH

Mass (g) Volume (ml) of 1.0M

NaOH to titrate

Chlorofor Acetic Water Heavy Light Heavy Light

m acid phase phase phase phase

10 6 6 9.8801 11.1347 32.50 81.20

8 6 6 7.2659 11.3149 15.90 77.80

6 4 10 4.5504 13.7406 4.5 55.00

CALCULATION

Using formula:

Mass of A
Mass fraction, A = Total mass

Mass fraction of acetic acid Mass fraction of Mass fraction of water

chloroform
0.33 0.05 0.63
0.42 0.11 0.47
0.52 0.22 0.26
0.46 0.31 0.23
0.40 0.40 0.21
0.36 0.54 0.11
0.28 0.65 0.07
0.19 0.75 0.06
0.10 0.87 0.03
Heavy Phase
1) CH3COOH + NaOH H2O + CH3COONa

0.0325

Mole of NaOH : Molarity x Volume

: 1 x 0.0325

: 0.0325 mol

1 mol of NaOH = 1 mol of CH3COOH

Therefore,

Mass of acetic acid: Mole x Molar mass

: 0.0325 x 60

: 1.95 g

1.95 g
Mass fraction : 9.8801 g

: 0.20

2) CH3COOH + NaOH H2O + CH3COONa

0.0159

Mole of NaOH : Molarity x Volume

: 1 x 0.0159

: 0.0159 mol
1 mol of NaOH = 1 mol of CH3COOH

Therefore,

Mass of acetic acid: Mole x Molar mass

: 0.0159 x 60

: 0.9454 g

0.9454 g
Mass fraction : 7.2659 g

: 0.13

3) CH3COOH + NaOH H2O + CH3COONa

0.0045

Mole of NaOH : Molarity x Volume

: 1 x 0.0045

: 0.0045 mol

1 mol of NaOH = 1 mol of CH3COOH

Therefore,

Mass of acetic acid: Mole x Molar mass

: 0.0045 x 60

: 0.27 g
 0.27 g
Mass fraction : 4.5504 g

: 0.06

Light Phase
1) CH3COOH + NaOH H2O + CH3COONa

0.0812

Mole of NaOH : Molarity x Volume

: 1 x 0.0812

: 0.0812 mol

1 mol of NaOH = 1 mol of CH3COOH

Therefore,

Mass of acetic acid: Mole x Molar mass

: 0.0812 x 60

: 4.872 g

4.872 g
Mass fraction : 11.1347 g

: 0.43
2) CH3COOH + NaOH H2O + CH3COONa

0.0778

Mole of NaOH : Molarity x Volume

: 1 x 0.0778

: 0.0778 mol

1 mol of NaOH = 1 mol of CH3COOH

Therefore,

Mass of acetic acid: Mole x Molar mass

: 0.0778 x 60

: 4.668 g

4.668 g
Mass fraction : 11.3149 g

: 0.41

3) CH3COOH + NaOH H2O + CH3COONa

0.0550

Mole of NaOH : Molarity x Volume

: 1 x 0.0550

: 0.0550 mol
1 mol of NaOH = 1 mol of CH3COOH

Therefore,

Mass of acetic acid: Mole x Molar mass

: 0.0550 x 60

: 3.30 g

3.3 g
Mass fraction : 13.7406 g

: 0.24

Heavy Phase Light Phase (Extract)

0.20 0.43
0.13 0.41
0.06 0.24