PT-1 - JEE Adv

PART A : MATHEMATICS
SECTION I : (Maximum Marks - 24)

This section contains 8 multiple choice questions.
Each question has FOUR choices (A), (B), (C) and (D) out of which only ONE option is correct.
Marking Scheme: +3 Marks - If only the bubble corresponding to correct answer is darkened. 0 in all other cases.

nx
1. Let (k) 2 2
dx, k 0 and k(k) (1) then value of k is
0 x kx k 3
1 3
(A) (B) 3 (C) e (D) e3/2
3
xy
2. If e f xy e x f x e y f y , x, y R and f 1 e, then f(x) is
2
(A) e x nx 1 (B) e x nx (C) e x nx (D) ex nx
x 1 y 3 z 4
3. Let image of the line in the plane 2x y + z + 3 = 0 be L. A plane 7x + By + Cz
3 5 2
+ D = 0 is such that it contains the line L and perpendicular to the plane 2x y + z + 3 = 0, then find
the value of B + 3C + D.
(A) 0 (B) 4 (C) 3 (D) 5
a2
4. A hunter's chance of shooting an animal at a distance r is (r a). He fires when r = 2a if he
r2
misses, he reloads and fires again when r = 3a. Further if he misses at r = 3a then the he tries again
at r = 4a. This process continuous till r = na. If he misses at a distance na, the animal escape. Find
odd against the event that animal is shot
(A) (n + 1) : 2n (B) (n +1) : (n 1) (C) (n 1) : 2n (D) (n 1) : (n + 1)
Space for rough work
2
5. In a game a coin is tossed (2n + m) times and a player wins if he does not get any two consecutive
outcomes same for atleast 2n times in a row. The probability that he win the game is
n2 m 1 2n 2 m2
(A) 2n
(B) 2n (C) 2n1 (D)
2 1 2 2 22n
6. Let A be a m n matrix of distinct real numbers. If x is the minimum of maximums of each row and y
is the maximum of minimums of each column, then
(A) x > y (B) x = y (C) x < y (D) nothing can be said surely
d2 y 2 dy
7. The equation of the curve satisfying the differential equation
dx 2
x 1 2x
dx
passing through
the point (0, 1) and having slope of tangent at x = 0 is 3, is

(A) y = x2 + 3x + 2 (B) y2 = x3 + 3x + 1 (C) y = x3 + 3x + 1 (D) y = x2 3x + 1
8. If f(x) be a twice differentiable function from R R such that t 2 f x 2tf x f x 0 has two
f x 1 t
equal values of t for all x and f(0) = 1, f(0) = 2, then lim is
x 0
x 2
1
(A) 1 (B)1 (C) (D) 0
2
3
SECTION II : (Maximum Marks - 40)
Each question has FOUR choices (A), (B), (C) and (D) out of which ONE or MORE THAN ONE option(s) is(are) correct.
Marking Scheme: + 5 Marks - If all the bubble(s) corresponding to correct answer(s) is/are darkened. 0. if unattempted and 2 in all other cases.

9. A vector a has component 1 and 2 while vector b has component 2 and 1 with respect to a
rectangular cartesian system. This system is rotated through a certain angle about the origin in the

counter-clockwise sense. If, with respect to the new system, a has absolute value of components 0

and 5 while b has components and respectively, then
3 4 3 4
(A) , (B) ,
5 5 5 5
3 4 3 4
(C) , (D) ,
5 5 5 5
th
10. Let be a complex p root of unity with 1. Let p numbers r1, r2 ..... rp are selected one by one
with replacement from a set S where S = {1, 2, 3 ... np}, p N and n N. Then probability that
r
r1 r2 .... p 0 is
(A) Independent of only p (B) Independent of both
2
(C) Independent of only n (D)
9

x a; x
2

cos x; x 0
11. If f x
2
x b; 0 x 1
cnx; x 1

(A) f(x) is continuous and differentiable at x if a ,b,c R
2 2
(B) f(x) is not differentiable at x = 0
(C) f(x) is continuous at x = 1 if b = 1, a , c R
(D) f(x) is differentiable at x = 1 if b = 1 and c = 1, a R
4
12. Let f : [0, ) R be a function such that f(x) = x2 x sin x cos x, then which of the following are
CORRECT ?
(A) f(x) is one-one (B) f(x) = 0 has one solution
(C) f(x) is onto (D) f(x) = 2 has one solution
0 50 a b
13. Let A and A 50A , then
0 0 c d
(A) a + d = 2 (B) a + b = 1 (C) b + c = 0 (D) a + d = 1
e /2
100 101
14. Consider the integral 1 1 x x nx dx, 2 1 esin x nsin x cos x dx.
1 1
sin1
e
101
e e 1 e k
If 1 2 , then k is greater than or equal to
101 101
(A) 0 (B) 1 (C) 2 (D) 1
15. If z axis be vertical, then the equation of the line of greatest slope through the point (2, 1, 0) on
the plane 2x + 3y 4z = 1 is
x 6 y 13 z 13 x 2 y 1 z 0
(A) (B)
8 12 13 3 4 5
x 2 y 1 z 0 x 2 y 1 z
(C) (D)
3 4 12 8 12 13

16. A function f is defined by f x cos t cos x t dt; 0 x 2 then which of the following hold(s)
0
good ?
(A) f (x) is continuous but not differentiable in (0, 2)
(B) Maximum value of f is
(C) There exists atleast one c (0, 2) such that f(c) = 0.

(D) Minimum value of f is
2
5
SECTION III : (Maximum Marks - 16)
This section contains 2 Paragraphs Based on each paragraph, there are 2 questions.
Marking Scheme: + 4 Marks if the bubble corresponding to correct answer is darkened, 0 if unattempted and 1 in all other cases.
Passage
Let a,b,c are the roots of the equation x3 3x2 + 5x 1 = 0. A and B are two matrices given as
a b c bc a 2 ca b 2 ab c 2

A b c a , B ca b 2 ab c 2 bc a 2
c a b ab c 2 bc a 2 ca b 2

If , and are the roots of the equation |B x| = 0, where is the unit matrix of order 3.
17. The value of + + is equal to
(A) 3 (B) 6 (C) 9 (D) 18
18. The value of the det (A). det (B) is equal to
(A) 18 (B) 182 (C) 183 (D) 184
Passage
2 1
A biased coin, for which probability of getting head is and that of tail is , is tossed till the
3 3
difference of number of head and tail is 2.
19. It is given that the game ends with more number of heads than tail then the probability that the
game starts with a head.
1 7 4 4
(A) (B) (C) (D)
2 9 5 9
20. It is given that game ends with a head then the probability that it ends in minimum number of throw
is
4 5 4 7
(A) (B) (C) (D)
5 9 9 9
6
PART B : PHYSICS
21. Starting from t = 0, activity of a radioactive sample is A1 at time t1 and A2 at time t2. If is average
life of sample then the number of nuclei decayed in time (t2 t1) is
(A) A1 t A2 t2 (B)
A1 A2 (C) (A1 A2) (t2 t1) (D) (A1 A2)
2
22. An infinitely long, straight wire carrying current I1 passes through the center of
a circular loop of wire carrying current I2 as shown in figure. The infinite wire is
perpendicular to the plane of the loop. Which of the following describes the
magnetic force on the loop due to the infinite wire.
(A) Force on the loop due to infinite wire is upward, along the axis of the loop.
(B) Force on the loop due to infinite wire is downward, along the axis of the loop.
(C) Although net force on the loop due to infinite wire is zero, but due to magnetic interaction
between infinite wire and loop, a tensile stress is developed in the loop.
(D) There is no magnetic force on the loop due to infinite wire
23. A ray of light traveling along the positive zaxis is reflected twice by plane mirrors :
(i) for the first time, by a mirror whose normal is along i k
(ii) for the second time, by a mirror whose normal is along i j k
where the symbols have their usual meanings. The final ray is along
(A) j k (B) k i (C) 2j 2k i (D) j k 2i
24. In the circuit shown in the figure key K1 is open. The charge on
capacitor C in steady state is q1. Now the key is closed and at
steady state charge on C is q2. The ratio of charges q1/q2 is
(A) 5/3 (B) 3/5
(C) 1 (D) 2/3
7
25. Three protons and a positron are held stationary by the means of external forces of proper
magnitude and direction, such that a proton is at each vertex of an equilateral triangle of side a and
positron is lying on the axis of the equilateral triangle, separation between positron and centroid of
2
equilateral triangle is a. Mass of positron is negligible in comparison to mass of proton. Now
3
binding forces are sudden removed, kinetic energy of positron after sufficiently long time will be :
e2 e2 3e2
(A) (B) (C) (D) Data insufficient
0 A 4 0 a 4 0 a
26. An ac circuit consists of L(XL = 7), R = 4 and C(XC = 4 ) in series. The potential difference
across R and C is V1 and that across L, C and R is V2. The phase angle between V1 and V2 is :
(A) 45 (B) 82 (C) 98 (D) 53
27. A ray is incident normally on face AC of a right angled prism as shown in the figure.
The total deviation in the path of this ray as it emerges out of the prism is :
(A) 120 (B) 0
(C) 180 (D) 150
28. In the circuit shown, after sufficiently long time in position 1 of the
switch, so that current is steady in the circuit, the switch is
changed over to position 2. the maximum voltage that can be
develop across L.
(A) 100 V (B) 100 2V
(C) 100 5V (D) 200 V
8
Marking Scheme: + 5 Marks - If all the bubble(s) corresponding to correct answer(s) is/are darkened. , 0 if unattempted and 2 in all other cases
29. The graph between 1/, where is wavelength of incident light and
stopping potential (V) of three metals having threshold wavelengths
th1 , th2 and th3 in an experiment of photo-electric effect is plotted as
shown in the figure. Which of the following statements is correct ?
(A) Ratio of work functions 1 : 2 : 3 1: 2 : 3
(B) Ratio of work functions 1 : 2 : 3 2 : 3 : 6
hc
(C) tan is directly proportional to , where h is Plancks constant and c is the speed of light
e
hc
(D) tan is inversely proportional to , where h is Plancks constant and c is the speed of light
e
30. In the shown circuit diagram all capacitors are initially uncharged and cells are ideal. If C1 = 1 F,
C2 = 2 F and potential of earth is taken zero. Choose the correct options.
(A) Potential of point A is (4/3) volts
(B) Potential of point B is (14/3) volts
(C) Potential of point C is (10/3) volts
(D) Potential of point A is (4/3) volts
9
31. In the circuit shown if point O is earthed, the potential of
2
point X is equal to 15V
X
(A) 10 V
2
(B) 15 V
(C) 25 V 10 V
5 10 V
(D) 12.5 V 5V
O
5V 5
32. A bird in air is diving vertically downward over a tank with speed 5 cm/s while
base of tank is silvered. A fish in the tank is rising upward along the same line
with speed 2 cm/s. Water level is falling at rate of 2 cm/s. Take water = 4/3.
(A) Speed of image of fish as seen by bird directly is 6 cm/s.
(B) Speed of image of fish as seen by bird directly is 3 cm/s.
(C) Speed of image of fish as seen by bird after reflection from mirror is 3 cm/s.
(D) Speed of image of fish as seen by bird after reflection from mirror is 6 cm/s.
33. As shown in figure there are two fixed uniformly charged concentric coplanar conducting rings
having radius 'R' and 4R and charges '+Q' and '8Q' respectively. A charge particle of mass 'm' &
charge 'q' is projected along the axis of rings from point 'P' so that particle can just reach the centre
of rings (point 'O'). (Assume Qq > 0.)
(A) required minimum velocity is zero
(B) speed of particle at the position O will be non zero
(C) particle perform oscillatory motion about O
(D) particle will not perform oscillatory motion about O
10
34. A wire shaped as a semicircle of radius a, is rotating about an axis PQ with a constant angular
1
velocity , with the help of an external agent. A uniform magnetic field B exists in space and
LC
is directed into the plane of the figure. (circuit part remains at rest) (left part is at rest)
Ba2
(A) The rms value of current in the circuit is
R 2LC
Ba2
(B) The rms value of current in the circuit is
2R 2LC
2B2 a 4
(C) The maximum energy stored in the capacitor is
8R2C
2B2a4
(D) The maximum power delivered by the external agent is
4LCR
35. In the diagram shown, a uniform magnetic field is present perpendicular to the plane of the paper.
Both the rings are identical and have a constant resistance per unit length. The left ring has been
kept fixed at its position and the right ring is slid uniformly on the left ring towards the right hand
side. Which of the following statements is/are true ?
(A) The emf induced in the left ring is zero
(B) The emf induced in both the rings is non zero
(C) The magnetic force acting on the right ring is zero
(D) The magnetic force acting on both the rings is non-zero
36. The maximum kinetic energy of photoelectrons ejected from a photometer when it is irradiated with
radiation of wavelength 400 nm is 1 eV. If the threshold energy of the surface is 1.9 eV.
(A) The maximum K.E. of photo electrons when it is irradiated with 500 nm photons will be about
0.4 eV.
(B) The maximum K.E. in case (A) will be 1.725 eV.
(C) The longest wavelength which will eject the photo electrons from the surface is nearly 610 nm.
(D) Maximum K.E. will increase if the intensity of radiation is increased
Paragraph
In standard YDSE the intensity on screen varies with position according to following graph as we
move away from the central maxima :
Wave length of light used is 400 nm and distance between the two slits is 1 mm.
37. If the distance between the two slits is kept 1 mm and then a thin film of refractive index 1.5 and
thickness 2.2 m is used to cover the one of the slit. What will be intensity at y = 2 mm.
(A) 0/2 (B) 0 (C) 0/4 (D) zero
38. If the distance between two slits is reduce to 0.5 mm then the intensity :
(A) will become zero at y = 4 mm and y = 8 mm
(B) will remain same 0 at y = 4 mm and y = 8 mm
(C) will become zero at y = 4 mm and will remain 0 at y = 8 mm
(D) will become zero at y = 8 mm and will remain 0 at y = 4 mm
Paragraph
An ammeter and a voltmeter are connected in series to a battery with emf E = 6 volt and negligible
resistance. When a resistance R = 3 is connected in parallel to voltmeter, reading of ammeter
increases three times while that of voltmeter reduces to one third.
39. Reading of ammeter before the connection of the resistance is
3 6 3
(A) A (B) A (C) A (D) 1 A
4 7 16
40. The resistance of voltmeter is
(A) 24 (B) 8 (C) 4 (D) 3
12
PART C : CHEMISTRY
41. Which of the following statements is incorrect ?
(A) CH3COCH3 & CHCl 3 Hsolution < 0 & Vsolution < 0
(B) When mercuric iodide is added to an aqueous solution of potassium iodide then freezing point of
KI solution is raised and its boiling point is lowered.
(C) NaCl is less soluble in acetone than H2O.
(D) H2O and (CH3)3COH Hsolution < 0 & Vsolution < 0
42. Consider the following complex : [Cr(NH3)4(NO2)2]
The oxidation number, number of d-electrons of metal ion, number of unpaired d-electrons on the
metal ion and number of isomers are respectively :
(A) 3, 3, 3, 2 (B) 2, 4, 0, 6 (C) 2, 4, 2, 6 (D) 2, 4, 4, 4
43.
Which statement is incorrect :

(A) Reduced product of P and Q will be metamers to each other.
(B) By dry distillation of hydrolysed products of P with Ca(OH)2, gives benzophenone.
(C) Hydrolysed product of Q, reacts with NaNO2 + HCl followed by reaction with phenol, gives
orange red dye.
(D) Electrophile involved in the formation of Q is dichlorocarbene.
13
44. Fe(+III) and Ru(+III) form basic acetates of the type H2O
[Fe3O(CH3COO)6(H2O)3]+.
The structure consists of a triangle of three Fe atoms C C
O O
with an O atom at the centre. The six acetate groups act C C
as bridges between the Fe atoms, two groups across Fe
each edge of the triangle. Thus each Fe atoms is linked
O O
to four acetate groups and the central O and the sixth O
position of the octahedron is occupied by water or Fe Fe H2O
another ligand. Spin only magnetic moment of
[Fe3O(CH3COO)6(H2O)3]+ per octahedral unit is :
O O
(A) Zero C
H 2O
(B) 1.73 BM
C
(C) 4.9 BM
+
(D) 5.9 BM Structure of [Fe3O(CH3COO)6(H 2O)3]
45. A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH = 10 and by
passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of
electrode would be:
(A) 0.59 V (B) 0.118 V (C) 1.18 V (D) 0.059 V
46. Which of the below reactions give one of the product as precipitate?
(i) S8 + NaOH(aq) (ii) SF4 + H2O(l)
(iii) Na2S2O3 + HCl(aq) (iv) H2S(aq) + SO2(g)
(A) (i) only (B) (i) and (iii) (C) (iii) and (iv) (D) (ii) and (iv)
47. What is difference in the density (in gram/litre) of dry air at 1 atm and 27C and moist air with
relative humidity 40% under same condition. Given that the vapour pressure of water is 19 torr at
1
27C and dry air has 80% N2 and 20% O2 by volume. [Take R L atm mol1K ]
12
(A) 2.32 103 g/L (B) 6.24 103 g/L (C) 1.64 103 g/L (D) 4.32 103 g/L
48. Dry air is first passed through a 0.1M KCl in water & then through 6M KCl solution. Which of the
following statements is not true ?
(A) dilute solution will show loss in weight
(B) dilute solution will show gain in weight
(C) change in weight of dilute solution is proportional to its vapour pressure.
(D) concentrated solution will show gain in weight.
14
Marking Scheme: + 5 Marks - If all the bubble(s) corresponding to correct answer(s) is/are darkened. 0 if unattempted and 2 in all other cases.
K
49. 3A Products. Rate law is rate = K[A], then (Here Ct = Concentration of reactant at time t,
C0 = concentration of reactant at time t = 0)
(A) Slope of graph of Ct vs t is K (B) Slop of graph of Ct vs t is 3K
(C) Slope of graph of (C0 Ct) vs t is 3K (D) Slope of graph of (C0 Ct) vs t is K
50. Observe the following reaction
KHSO4 / (i) C H
2 5 2 CuLi
M
(ii) H O
N
3
Choose the correct options

(A) M is CH2=CHCH=O
(B) Conversion of M to N is a nucleophilic addition
(C) N is C2H5CH2CH2CH=O
(D) M is CH2 CH CH2 OH
51. Alternate tetrahedral void in FCC are not occupied in following :
(A) NaCl (B) ZnS (C) CaF2 (D) Na2O
52. Which of the following statements is/are correct ?
(A) Extractive metallurgy of iron involves reduction by carbon monoxide and carbon
(B) Extration of zinc from ore sphalerite involves the roasting and carbon reduction
(C) Langbeinite is sulphate ore of mangnesium
(D) Cuprite and argentite are oxide ores
15
53. In which of the following reaction (s), reactant and products are correctly matched ?
(A)
(B)
(C)
(D)
54. Which of the following can give two or more gases on heating?
(A) Zn (ClO3)2 (B) NH4ClO4 (C) K2Cr2O7 (D) KMnO4
16
55. In which of the following reaction(s) the product is/are correctly matched.
(A)
(B)
Hg2 /H SO aq
2 4
(C)
(D)
56.
In the above series of reactions, the correct products are;
(A) (B)
(C) (D)
17
Paragraph
57. The product U is :
(A) (B)
(C) (D)
58. Which of the following will not be the products when S on reaction with Cl 2 / NaOH or on reaction
with Cl 2/NaOH followed by acidification.
(A) (B)
(C) CHCl3 (D)
18
Paragraph
A solution capable of maintaining its pH relatively constant, when either excess acid or excess base
is added, is said to be buffered. While it is not usually considered a buffered solution, a
concentrated solution (102 M and higher) of a strong acid or strong base is buffered against large
changes in pH when acids or bases are added.
Buffered solutions are usually those containing a weak acid and a salt of that weak acid or a weak
base and the salt of that weak base. For example a solution containing HAC and NaAC resists
large changes in pH when acid or alkali is added.
For a buffer solution Buffer capacity is defined as the number of moles of a strong acid or a strong
base that causes 1L of the buffer to undergo a 1 unit change in pH. Buffer capacity is maximum
when the molar ratio of the two components is unity and the buffer solution is considered good.
59. Which is the best buffer ? CH3COOH (pKa = 4.7) CH3COONa (M = 82)CH3COOH(M = 60)
(A) 8.2 g CH3COONa & 6g CH3COOH in 1 litre
(B) 8.2 g CH3COONa & 8.2 g CH3COOH in 10 litre
(C) 8.2 g CH3COONa & 6g CH3COOH in 2 litre
(D) 16.4 g CH3COONa & 12 g CH3COOH in 4 litre
60. How many mole of strong acid should be added to dereases pH by one unit
(A) 0.0102 (B) 0.02045 (C) 0.0409 (D) 0.115
19

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PART A : MATHEMATICS

SECTION I : (Maximum Marks - 24)

the point (0, 1) and having slope of tangent at x = 0 is 3, is

Space for rough work

(B) Ratio of work functions 1 : 2 : 3 2 : 3 : 6

Space for rough work

Space for rough work

Which statement is incorrect :

Choose the correct options

In the above series of reactions, the correct products are;

Space for rough work

57. The product U is :

(C) CHCl3 (D)

Space for rough work

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