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DEPARTMENT OF CHEMISTRY
SEMESTER II (2013-14)
a. Nitrosyl complex
b. Metallocene complex.
c. Alkene complex
d. Carbene and carbyne complexes
e. Alkyne complex.
f. Alkyl complex.
2. How would you obtain the following compounds from the given starting material.
Mention the reagent(s) used and the condition(s) of the reaction in each case.
3. Complete and balance the following reactions. Then identify the type of reaction in each
balanced equation.
5. Draw a Tolman catalytic loop for the hydrogenation of alkenes into alkanes using
Wilkinsons catalyst, [RhCl(PPh3)3]- . Identify oxidative addition and reductive
elimination steps in the loop.
6. Discuss and draw a Tolman catalytic cycles for the conversion of alkenes
to aldehydes using Wacker and hydroformylation processes.
THF
(i) Fe3(CO)12 + Na
(iv) Mn2(CO)10 + py
THF
(v) Fe(CO)5 + NaOH
(vii) [Co(CO)4]- + H+
NaBH4
(viii) 2W(CO)6
Me2NH
(ix) FeCl2 + C5H6