CHE1401

Homework 5
Name___________________________________

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the
question.
1) For a given process at constant pressure, H is negative. This means 1) _______
that the process is _E_________.
A) energy
B) equithermic
C) a state function
D) endothermic
E) exothermic

2) Under what condition(s) is the enthalpy change of a process equal to the 2) _______
amount of heat transferred into or out of the system?
B
(a) temperature is constant
(b) pressure is constant
(c) volume is constant

A) a only
B) b only
C) c only
D) b and c
E) a and b

3) In the reaction below, is zero for _B_________. 3) _______

Ni (s) + 2CO (g) + 2P (g) Ni (P (l)

A) Ni (P (l)
B) Ni (s)
C) CO (g)
D) P (g)
E) both CO (g) and P (g)

4) Of the following, is not zero for _A_________. 4) _______

A) (s)
B) C (graphite)
C) (g)
D) (g)
E) (g)

5) For which one of the following reactions is the value of Hrxn equal to 5) _______
Hf for the product? E
A) 2 (g) + (g) 2 O (l)
B) (g) + (g) 2 NO (g)
C) O (l) + 1/2 (g) (l)
 D) 2 (g) + (g) 2 O (g)
E) none of the above

6) What is the enthalpy change (in kJ) of a chemical reaction that raises the 6) _______
temperature of 250.0 ml of solution having a density of 1.25 g/ml by
7.80 oC? (The specific heat of the solution is 3.74 joules/gram-K.)
B
A) -12.51
B) -9.12
C) 6.51
D) -7.43
E) 8.20

7) Which one of the choices below is not considered a fossil fuel? 7) _______
C
A) anthracite coal
B) crude oil
C) hydrogen
D) petroleum
E) natural gas

8) The units of of specific heat are _A_________. 8) _______

A) J/g-K or J/g-C
B) g-K/J or g-C/J
C) J/K or J/C
D) J/mol
E) K/J or C/J

9) Which one of the following is an exothermic process? 9) _______

D
A) water evaporating
B) ice melting
C) boiling soup
D) condensation of water vapor
E) Ammonium thiocyanate and barium hydroxide are mixed at 25C:
the temperature drops.

10) Which one of the following statements is true? E 10) ______

A) H is the value of q measured under conditions of constant volume.
B) The enthalpy change of a reaction is the reciprocal of the H of the
reverse reaction.
C) The enthalphy change for a reaction is independent of the state of
the reactants and products.
D) Enthalpy is an intensive property.
E) Enthalpy is a state function.

11) The specific heat capacity of liquid mercury is 0.14 J/g-K. How many 11) ______
joules of heat are needed to raise the temperature of 5.00 g of mercury
from 15.0C to 36.5C?
C
A) 7.7 102
B) 36
 C) 15
D) 1.7
E) 0.0013

12) The reaction 12) ______

4Al (s) + 3 (g) 2 (s) H = -3351 kJ

is __D________, and therefore heat is __________ by the reaction.
A) endothermic, released
B) exothermic, absorbed
C) endothermic, absorbed
D) exothermic, released
E) thermoneutral, neither released nor absorbed

13) For the species in the reaction below, is zero for __E________. 13) ______

2Co (s) + (g) + 8P (g) 2HCo(P (l)

A) P (g)
B) HCo(P (l)
C) Co (s)
D) (g)
E) both Co(s) and (g)

14) A chemical reaction that absorbs heat from the surroundings is said to 14) ______
be ____A______ and has a __________ H at constant pressure.
A) endothermic, positive
B) endothermic, negative
C) exothermic, negative
D) exothermic, positive
E) exothermic, neutral

15) When a system _____D_____, E is always negative. 15) ______

A) absorbs heat and does work
B) absorbs heat and has work done on it
C) gives off heat and has work done on it
D) gives off heat and does work
E) none of the above is always negative.

16) At what velocity (m/s) must a 20.0 g object be moving in order to 16) ______
possess a kinetic energy of 1.00 J? C
A) 100
B) 1.00
C) 10.0
D) 1.00
E) 50.0

17) The specific heat capacity of liquid water is 4.18 J/g-K. How many joules 17) ______
of heat are needed to raise the temperature of 5.00 g of water from
25.1C to 65.3C? B
 A) 54.4
B) 840
C) 1.89
D) 2.08
E) 48.1

18) The specific heat capacity of solid copper metal is 0.385 J/g-K. How 18) ______
many joules of heat are needed to raise the temperature of a 1.55-kg
block of copper from 33.0C to 77.5C?
D
A) 0.00558
B) 1.79
C) 5.58
D) 2.66
E) 26.6

19) The combustion of titanium with oxygen produces titanium dioxide: 19) ______
D
Ti (s) + (g) (s)

When 0.721 g of titanium is combusted in a bomb calorimeter, the

temperature of the calorimeter increases from 25.00C to 53.80C. In a
separate experiment, the heat capacity of the calorimeter is measured to
be 9.84 kJ/K. The heat of reaction for the combustion of a mole of Ti in
this calorimeter is __________ kJ/mol.
A) -311
B) 4.98
C) 2.67
D) -1.49
E) -0.154

20) Of the substances below, the highest fuel value is obtained from 20) ______
____A______.
A) hydrogen
B) charcoal
C) bituminous coal
D) natural gas
E) wood

21) A 50.0-g sample of liquid water at 25.0 C is mixed with 29.0 g of water 21) ______
at 45.0C. The final temperature of the water is __E______C. The
specific heat capacity of liquid water is
A) 142 B) 27.6 C) 102 D) 35.0 E) 32.3

22) Fuel values of hydrocarbons increase as the H/C atomic ratio increases. 22) ______
Which of the following compounds has the highest fuel value?
C
A)
B)
C)
C
D)
E)

23) The internal energy of a system is always increased by B__________. 23) ______
A) a volume compression
B) adding heat to the system
C) withdrawing heat from the system
D) having the system do work on the surroundings
E) adding heat to the system and having the system do work on the
surroundings

24) For which one of the following equations is equal to for 24) ______
the product?
B
A) (g) + (g) (g)
B) Xe (g) + 2 (g) Xe (g)
C) 2CO (g) + (g) 2C (g)
D) C (diamond) + (g) C (g)
E) C (g) + 2 (g) C (l) + 2HCl (g)

25) Of the following, which one is a state function? 25) ______

D
A) heat
B) q
C) w
D) H
E) none of the above

26) Hydrogen peroxide decomposes to water and oxygen at constant 26) ______
pressure by the following reaction:
C
(l) O (l) + (g) H = -196 kJ

Calculate the value of q (kJ) in this exothermic reaction when 4.00 g of

hydrogen peroxide decomposes at constant pressure?
A) 1.44
B) -23.1
C) -11.5
D) -0.0217
E) -2.31 104

27) The energy released by combustion of 1 g of a substance is called the 27) ______
_____B_____ of the substance.
A) enthalpy
B) fuel value
C) specific heat
D) heat capacity
E) nutritional calorie content
28) The most abundant fossil fuel is ____C______. 28) ______
A) petroleum
B) hydrogen
C) coal
D) uranium
E) natural gas

29) The specific heat capacity of methane gas is 2.20 J/g-K. How many joules 29) ______
of heat are needed to raise the temperature of 5.00 g of methane from
36.0C to 75.0C?
B
A) 88.6
B) 429
C) 22.9
D) 1221
E) 0.0113

30) The British thermal unit (Btu) is commonly used in engineering 30) ______
applications. A Btu is defined as the amount of heat required to raise
the temperature of 1 lb of water by 1F. There are ___A_______ joules in
one Btu. 1 lb = 453.59 g; C = (5/9)(F - 32); specific heat of H2O (l) =
4.18 J/g-K.
A
A) 1054
B) 3415
C) 5.120 10-3
D) 60.29
E) Additional information is needed to complete the calculation.

31) A 6.50-g sample of copper metal at 25.0C is heated by the addition of 31) ______
84.0 J of energy. The final temperature of the copper is __D______C.
The specific heat capacity of liquid water is
A) 29.9 B) 34.0 C) 9.0 D) 59.0 E) 25.0

32) Which of the following is a statement of the first law of 32) ______
thermodynamics?
E
A)
= m
B) 1 cal = 4.184 J (exactly)
C) A negative H corresponds to an exothermic process.
D) E = -
E) Energy lost by the system must be gained by the surroundings.

33) A _____B_____ H corresponds to an __________ process. 33) ______

A) negative, endothermic
B) negative, exothermic
C) positive, exothermic
D) zero, exothermic
E) zero, endothermic
34) For which one of the following reactions is the value of Hrxn equal to 34) ______
Hf for the product?
E
A) 2 (g) + (g) 2 O (l)
B) O (l) + 1/2 (g) (l)
C) 2 (g) + (g) 2 O (g)
D) (g) + (g) 2 NO (g)
E) 2 C (s, graphite) + 2 (g) (g)

35) The internal energy can be increased by __A________. 35) ______

(a) transferring heat from the surroundings to the system

(b) transferring heat from the system to the surroundings
(c) doing work on the system

A) a and c
B) b only
C) a only
D) b and c
E) c only

36) The units of of heat capacity are __A________. 36) ______

A) J/K or J/C
B) J/mol
C) J/g-K or J/g-C
D) K/J or C/J
E) g-K/J or g-C/J

37) In the presence of excess oxygen, methane gas burns in a constant- 37) ______
pressure system to yield carbon dioxide and water:
E

(g) + (g) (g) + O (l) H = -890 kJ

Calculate the value of q (kJ) in this exothermic reaction when 1.70 g of

methane is combusted at constant pressure.
A) -0.0106
B) 32.7
C) 0.0306
D) -9.46 104
E) -94.6

38) For which one of the following reactions is Hrxn equal to the heat of 38) ______
formation of the product? E
A) P (g) + 4H (g) + Br (g) P Br (l)
B) (g) + 3 (g) 2N (g)
C) 6C (s) + 6H (g) (l)
D)
12C (g) + 11 (g) + 11O (g) (g)
E) (1/2) (g) + (g) N (g)

39) A 5.00-g sample of liquid water at 25.0 C is heated by the addition of 39) ______
84.0 J of energy. The final temperature of the water is _A_________ C.
The specific heat capacity of liquid water is
A) 29.0 B) -21.0 C) 25.2 D) 95.2 E) 4.02

40) Which of the following is a statement of Hess's law? 40) ______

D
A) If a reaction is carried out in a series of steps, the H for the
reaction will equal the product of the enthalpy changes for the
individual steps.
B) The H of a reaction depends on the physical states of the
reactants and products.
C) The H for a process in the forward direction is equal to the H
for the process in the reverse direction.
D) If a reaction is carried out in a series of steps, the H for the
reaction will equal the sum of the enthalpy changes for the
individual steps.
E) The H for a process in the forward direction is equal in
magnitude and opposite in sign to the H for the process in the
reverse direction.
 1) E
2) B
3) B
4) A
5) E
6) B
7) C
8) A
9) D
10) E
11) C
12) D
13) E
14) A
15) D
16) C
17) B
18) D
19) D
20) A
21) E
22) C
23) B
24) B
25) D
26) C
27) B
28) C
29) B
30) A
31) D
32) E
33) B
34) E
35) A
36) A
37) E
38) E
39) A
40) D