Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
K. C. Panda
Associate Professor, Department of Civil Engineering,
SOA University, Bhubaneswar, Odisha, India
ABSTRACT
This paper investigates the influence of sea water on pre-cast concrete containing
industrial by-product materials such as fly ash (FA) and silpozz. The mix design is targeted for
M30 grade concrete. Ten concrete mixtures were designed to have the same degree of
workability with water to cementitious material ratio of 0.43. The studied parameters include
the compressive strength of normal water curing (NWC) and sea water curing (SWC) samples
after 28 days of NWC for 7, 28, 90, 180 and 365 days curing period. The carbonation depth of
concrete samples for 28, 90, 180 and 365 days SWC after 28 days of NWC was measured. It
was found that the higher the FA content the higher is the carbonation process occurred. The
percentage increase in compressive strength for blended cement concrete in NWC is better
than the samples in SWC after 28 days of NWC.
1. INTRODUCTION
Deterioration of reinforced concrete structures in marine environments is generally associated with
external agents such as chlorides that penetrate into concrete and carbonation induced corrosion
causing damage. A number of factors affecting durability may be defined as the concrete type, cover
depth to reinforcement, site practice and severity of exposure. Durability of concrete may be enhanced
by utilizing waste by-products possessing hydraulic and pozzolanic properties such as fly ash and
silipozz. Some of the researchers have reported the utilization of supplementary cementitious materials
(SCM) to improve concrete properties in marine climate. Jena and Panda (2015) studied the
development of compressive strength in blended concrete made with silpozz which is used as a
substitute material of silica fume (SF) to improve the durability of marine structures. Anwar and
Roushdi (2014) showed the properties of concrete containing PC, FA and SF as blended cements for
improvements in concrete to resist environmental causes of deterioration. Anwar et al. (2013)
concluded that the combinations of 15 to 25% of FA with 5 to 10% SF show satisfactory performance
in both fresh and hardened concrete. The SF improves early age performance of concrete with FA
continuously refining the properties of hardened concrete as it matures and the replacement of 35% of
cement quantity with 25% FA and 10% SF increased the compressive strength by 20% at 180 days.
Wegian (2010) investigated on the effects of mixing and curing concrete with seawater on the
compressive, tensile, flexural and bond strengths of concrete and the reduction in strength increases
with an increase in exposure time, which may be due to salt crystallization formation affecting the
strength gain. Sunil (2009) investigated the effects of the quality of mixing water and initial curing on
plain and blended cement concrete made with FA were exposed to seawater attack for a period of 1
year and the performance of these concrete specimens were evaluated by reduction in compressive
strength. The results of this study showed that the use of pre casting in place of casting-in-situ
mitigates the effect of marine environments on concrete specimens considerably. Thomas et al. (1999)
reported that the combination of PC, SF and FA in a ternary cement system should result in a number of
obvious synergistic effects. Maltais and Marchand (1997) showed that carbonation could have both
positive and negative effect on concrete durability. Naik and Singh (1998) mentioned that the steel
passivation layer of oxide film may be destroyed due to carbonation and accelerating the start of
uniform corrosion. On the contrary, the carbonation process seems to densify the concrete surface
reducing surface porosity and reduce chloride ion permeability (Mehta, 1994). Ho and Lewis (1987)
conclude that due to replacement of cement with FA, the rate of carbonation increases significantly.
However, Papadakis (2003) reported that in the case FA is introduced as a fine aggregate replacement,
the carbonation rate is reduced. This paper focuses the compressive strength and carbonation of pre-
cast concrete with FA and silpozz in sea water for different curing periods and the utilization of waste
by-product such as FA and silpozz which creates environmental problems after disposal.
2. EXPERIMENTAL SETUP
The experimental study was carried out using ten different mixes of concrete mixed and cured in
normal water for 7, 28, 90, 180 and 365 days and subsequently cured in sea water after 28 days of
NWC. Among ten concrete mixes, one is control mix with 100% OPC and the rest nine mixes are
blended cement concretes. From nine blended concrete mixes, five are FA based ranging 10 50%
replacement with OPC and the rest four mixes are FA and silpozz based concrete with FA replacement
is 10% fixed and the replacement of silpozz is 10 - 40% with OPC. The fresh concrete properties such
as slump and compaction factor were studied for workability of concrete. The hardened concrete
property such as compressive strength was measured at 7, 28, 90, 180 and 365 days for NWC samples
and SWC precast samples. Carbonation depth was determined at 28, 90, 180 and 365 days for SWC
precast samples.
Table 3 Mix Proportions and identity for plain and blended cement concrete.
Mix Identity Cement (%) FA (%) Silpozz (%)
MC100F0S0 100 0 0
MC90F10S0 90 10 0
MC80F20S0 80 20 0
MC70F30S0 70 30 0
MC60F40S0 60 40 0
MC50F50S0 50 50 0
MC80F10S10 80 10 10
MC70F10S20 70 10 20
MC60F10S30 60 10 30
MC50F10S40 50 10 40
strength of SWC samples after 28 days of NWC have a little more or equal to NWC samples but after
28 days the sea water has a negative effect on compressive strength by Wegian (2010).
4. DURABILITY PROPERTY
Durability of hydraulic-cement concrete is defined as its ability to resist weathering action, chemical
attack, abrasion, or any other process of deterioration. Durable concrete will retain its original form,
quality, and serviceability when exposed to its environment (ACI 201-2R). Deterioration of reinforced
concrete structures in marine environments is generally associated with external agents when carbon
dioxide intrusion takes place into concrete cover and reaches the reinforcement causing corrosion in
presence of moisture and oxygen. In this article the durability property in term of carbonation depth
measurement is presented for SWC precast concrete samples at 28, 90, 180 and 365 days.
5. CONCLUDING REMARKS
Much attention must be given to the development of a new generation of cements incorporating
combination of by-product materials in binary and ternary systems. The test results show that ternary
blends of PC, silpozz, and FA offer significant advantages over binary blends and plain PC. Also, the
combination of silpozz and FA is complementary.
The silpozz improves the early age performance of concrete with the FA continuously refining the
properties of the hardened concrete as it matures. Combinations of 10-20% silpozz with 1030% FA
show satisfactory performance in both fresh and hardened concrete. Such combinations produce
concrete with generally good properties especially the resistance to carbonation.
Silpozz is having most particles size of 25 microns and below, so that it fills the interstices in between
the cement in the aggregate as fine filler which gives better strength and resistance to chloride and
carbonation.
It is expected that the sea water attack will be less in structures made of precast elements and the
hardened concrete will be subjected to seawater attack at mature state.
It may be concluded that resistance against all possible forms of deterioration is distinctly improved by
using mineral admixtures like FA and silpozz up to certain percentage of cement.
It is found from the experimental results that the use of precast concrete increases the resistance of
concrete against marine environments appreciably. Blending a suitable proportion of FA and silpozz
with PC can further reduce the effect of seawater on marine structures.
The utilization of silpozz and FA solves the problem of its disposal thus keeping the environment free
from pollution. It may be recommended that while manufacturing of concrete, care should be taken to
produce impermeable and dense concrete in order to resist the sea water attack.
6. ACKNOWLEDGEMENTS
The author would like to thanks S O A University for the support of conducting the experimental
work and also thankful to the N K Enterprises, Jharsuguda and Nalco, Angul for supplying of
materials.
REFERENCES
[1] Anwar, M., Roushdi, M., Improved concrete properties to resist the saline water using
environmental by-product. Water Sci. J., 27, 2014, pp. 30- 38.
[2] Anwar, M., Roushdi, M., Mustafa, H., Investigating the usage of environmental by-product materials
in concrete for sustainable development. Aust. J. Basic Appl. Sci. 7 (9), 2013, pp. 132139.
[3] DWS, Ho., RK, Lewis. Carbonation of concrete and its prediction. Cement Concrete Res; 17, 1987,
pp. 489504.
[4] IS: 8112:1989, Indian Standard, 43 Grade Ordinary Portland cement Specification, (First Revision).
Bureau of Indian Standards, New Delhi, India.
[5] IS: 383-1970, Indian Standard Specification for Coarse and Fine aggregates from Natural Sources
for Concrete, (Second Revision). Bureau of Indian Standards, New Delhi, India.
[6] IS: 10262:2009, Concrete Mix Proportioning-Guidelines. Bureau of Indian Standards, New Delhi,
India.
[7] IS: 516 1959. Methods of tests for strength of concrete, Bureau of Indian Standards, New
Delhi, India.
[8] Jena, T., Panda, K.C., Influence of sea water on strength and durability properties of concrete.
Advances in structural engineering 03, Springer India, 2015, pp. 1863-1873.
[9] Maltais, Y.M., Marchand, J., Influence of curing temperature on cement hydration and mechanical
strength development of Fly Ash Mortars. Cement Concrete Res. 27 (7), 1997, pp. 365377.
[10] Mehta, P.K., Mineral admixtures for concrete an overview of recent developments. In: Grutzeck,
M.W., Sarkar, S.L. (Eds.), Advances in Cement and Concrete. ASCE, New York, 1994, pp. 243
256.
[11] Naitik Patel, Raviraj Dave, Shubham Modi, Chirag Joshi, Savan Vora and Manish Solanki, Effect
of Binary and Quaternary Blends on Compressive Strength. International Journal of Civil
Engineering and Technology, 7(5), 2016, pp.242246.
[12] Naik, T.R., Singh, S.S., Fly ash generation and utilizationan overview. In: Suri, A.K.,
Harapanahalli, A.B. (Eds.), Recent Trends in Fly Ash Utilization. SOFEM Publisher, New Delhi,
India, 1998, pp. 125.
[13] Papadakis VG., Effect of supplementary cementing materials on concrete resistance against
carbonation and chloride ingress. Cement Concrete Res; 30, 2000. pp. 2919.
[14] Sunil, K., Influence of water quality on the strength of plain and blended cement concretes in
marine environments. Cem Concr Res 30, 2009, pp. 345-350.
[15] Thomas, M.D.A., Shehata, M.H., Shashiprakash, S.G., Hopkins, D.S., Cail, K., Use of ternary
cementitious systems containing silica fume and fly ash in concrete. Cement Concrete Res. 29 (8),
1999, pp. 12071214.
[16] Zahid Ahmad Chat, Umer Salam and Shahid Bashir, Compressive Strength of Concrete using
Natural Aggregates (Gravel) and Crushed Rock Aggregates-A Comparative Case Study.
International Journal of Civil Engineering and Technology (IJCIET), 6(1), 2016, pp.2126.
[17] Wegian, M.F., Effect of sea water for mixing and curing on structural concrete. The IES Journal
Part A: Civil & Structural Engineering 3 (4), 2010, pp. 235243.
AUTHORS PROFILE
Trilochan Jena is a research scholar in department of civil engineering, SOA University,
Bhubaneswar, Odisha, India. He obtained his Master degree in Structural Engineering and Natural
Disaster Management from GITAM University in 2008. His research interest is mechanical and
durability properties of construction materials.
Dr. Kishor Chandra Panda is currently working as Associate Professor in the Department of Civil
Engineering, Institute of Technical Education and Research, Siksha O Anusandhan University,
Bhubaneswar, Odisha, 751030, India. In 2010, he obtained Ph.D (Engg.) from Indian Institute of
Technology, Kharagpur, India. He received the degrees of B.E. (Civil) from Utkal University, IGIT,
Saranga, Talcher in 1990 and M.Sc. Engg. (Civil) with specialization in Structural Engineering in
1992, from Sambalpur University, REC, Rourkela, India (Presently NIT Rourkela). His research
interests are FRP-Concrete Composite Systems, Strengthening, Rehabilitation and Retrofitting of
structures, Durability of concrete structure in marine environment, Self Compacting Concrete using
different types of waste material, Sustainable material in construction field and bacterial concrete. He
has published more than 70 papers in journals and Conference proceedings and Book chapters. He has
guided 14 M Tech Students and 1 Ph. D student. He has member of some professional bodies like ICI,
ISTE and IET.