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a. ammonium is reduced
b. zinc is oxidized
c. nitrogen is the reducing agent
d. zinc is reduced
a. causes reduction
b. gains electrons
c. is oxidized
d. loses electrons
a. 2
b. 1
c. 0
d. +5
a. The pH is basic as the H3O+ ion donates protons, leaving OH ions in the solution.
b. The pH is neutral; the anion has no affinity for protons.
c. The pH is acidic as the water accepts protons.
d. The pH is neutral; the salt has neither H+ nor OH ions.
a. Kb = Kw + Ka
b.
Kb =
c.
Kb =
d. Kb = Kw Ka
17.If pOH = 0.700 for a 0.100 mol/L solution of Ca(OH)2, what would its pH be?
a. 13.8
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b. 14.7
c. 14.2
d. 13.3
18. What is true about the association between the strength of an acid and the strength of its conjugate
base?
a. urea
b. sodium hydroxide
c. ammonia
d. arganine, an amino acid
20. Solution A has a pH of 5 and solution B has a pH of 8. Which has the greater concentration of OH
ions?
a. Solution B
b. Solution A
c. It depends on the percent ionization of A and B.
d. It depends on the molarity of A and B.
a. H2O
b. H3O+
c. A
d. None exists because hydroxide is not present.
a. The acid shifts the equilibrium to the left, removing only a few H +(aq) ions, so the pH is
decreased.
b. The acid shifts the equilibrium to the right, producing H +(aq) ions, so the pH is decreased.
c. The acid shifts the equilibrium to the right, producing a few H +(aq) ions and maintaining
the pH.
d. The acid shifts the equilibrium to the left, removing H+(aq) ions and maintaining the pH.
2
24. Nitrogen dioxide (brown) and dinitrogen tetroxide (colourless) are placed in a syringe. The syringe is
depressed to half its volume. What happens to the pressure in the syringe?
2 NO2(g) N2O4(g)
a. It will initially double, then decrease as the equilibrium shifts left (brown).
b. It will double, driving the reaction to the right (clear).
c. It will double, driving the reaction to the left (brown).
d. It will initially double, then decrease slightly as the equilibrium shifts right (clear).
25. How are the equilibrium constants for the forward and reverse reactions related?
26.The trial ion product, Q, when compared to the Solubility Product Constant, Ksp, will indicate if the
final products will be insoluble. The equilibrium will shift left if Q is
a. equal to Ksp
b. less than Ksp
c. 100 times less than the value of Ksp
d. greater than Ksp
27. The Ksp for an ionic substance is taken into consideration when studying
a. thermal energy
b. the release of anions and cations
c. the dissolving and forming of precipitates
d. the release of acidic and basic ions
29. How does an increase in temperature affect the equilibrium of an endothermic reaction?
30. Methanol is a useful substrate for the production of esters, aldehydes, and other industrial chemicals.
Carbon dioxide is reacted with hydrogen to produce methanol.
H = 238.7 kJ/mol. Low temperatures will
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d. favour the production of methanol
31.Which of the following equilibrium constant values best represents a reaction where the concentration
of products is almost equal to the concentration of reactants?
a. 3.4 106
b. 2.9 106
c. 9.8 101
d. 1.5 101
33. Consider the equilibrium reaction where carbon monoxide reacts with steam to produce hydrogen
and carbon dioxide. The equilibrium position occurs far to the right. This means that once
equilibrium has been established,
A + B2 + C AB + CB
A + B2 AB + B (slow)
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B+C BC (fast)
Based on this mechanism, the rate law expression for this reaction is
a. rate = k[A][B2]
b. rate = k[A][B2][C]
c. rate = k[B2][C]
d. rate = k[A][C]
36. Acetone, CH3COCH3(l), reacts with bromine according to the reaction equation below.
The reaction was carried out, and the following data were obtained:
Run Initial [CH3COCH3(l)] Initial [Br2(l)] (mol/L) Initial rate (mol/(L s))
(mol/L)
1 0.0250 0.0500 2.25 106
2 0.0250 0.1000 2.25 106
3 0.0500 0.1000 4.50 106
37. If the rate constant has units of s1, what is the order of the reaction?
a. 2
b. 0
c. 1
d. none of the above
38. If the rate law for a reaction is determined to be rate = k[X]1[Y]2[Z]0, then doubling the initial
concentration of Y will
39. If the rate law for a reaction is determined to be rate = k[X]1[Y]2[Z]0, then the order of the reaction is
a. 0
b. 1
c. 2
d. 3
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b. increasing the kinetic energy of the reactant molecules
c. increasing the number of collisions between reactant molecules
d. colliding with the reactant molecules, increasing their energy, and adjusting their
orientation
41. Copper metal will react with silver nitrate solution to produce silver metal and blue copper(II) nitrate
solution. Which of the following will affect the rate of this reaction?
42. Temperature will affect the reaction rate of a reacting system. If the temperature of a system is
decreased from 40 C to 20 C , what is the reaction rate most likely to do?
43. One way to increase the rate of a heterogeneous reaction is to increase the surface area of one of the
reactants. Which of the following examples demonstrates this?
44. From the reaction equation 2 SO2(g) + O2(g) 2 SO3(g), if the average rate of appearance of sulfur
trioxide gas is 0.025 mol/L s, what is the average rate of disappearance of sulfur dioxide gas?
a. 0.050 mol/(L s)
b. 0.0125 mol/(L s)
c. 0.025 mol/(L s)
d. 0.075 mol/(L s)
45.The following data were obtained for the reaction represented by the equation
2 SO2(g) + O2(g) 2SO3(g)
Time (s) [SO2(g)] (mol/L)
0 0.1000
10 0.0078
15 0.0053
20 0.0040
What is the average rate of disappearance of sulfur dioxide gas, SO 2(g), for the first 15 s?
a. 0.0005 0 mol/(L s)
b. 0.0063 mol/(L s)
c. 0.0070 mol/(L s)
d. 0.10 mol/(L s)
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46. Butane is the liquid found in lighter fluid. If it reacts with oxygen, it can undergo a combustion
reaction represented by the following equation:
Use the enthalpy of formation data below to determine the enthalpy of this reaction.
Compound Hf (kJ/mol)
CO(g) 110.5
CO2(g) 393.5
H2O(l) 285.8
H2O(g) 241.8
C4H10(l) 125.6
a. 2657 kJ
b. 1745 kJ
c. 2241 kJ
d. 3127 kJ
48. Find H for the reaction below, given the following reactions and H values:
N2O4(g) + 2 NO2(g)
a. 39 kJ
b. 29 kJ
c. 39 kJ
d. 29 kJ
49. Use the graphs below to determine the enthalpy of reaction for the conversion of butane, C 4H10, to
butanol, C4H9OH.
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a. 169 kJ/mol
b. 169 kJ/mol
c. 5594.8 kJ/mol
d. 5594.8 kJ/mol
50. Hydrogen peroxide is clear solution that can be used as a bleaching agent or for cleaning. Hydrogen
peroxide will decompose readily to produce water and oxygen gas. Estimate the enthalpy of the
reaction using the given bond energies.
53. Suppose 15.0 kJ of energy are added to a 0.100 kg sample of water. What will happen to the
temperature?
(cwater = 4.18 J/(g C))
a. increase by 35.9 C
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b. decrease by 35.9 C
c. decrease by 6.27 C
d. increase by 6.27 C
54. What quantity of heat is required to raise the temperature of 2.0 g of iron by 5.0 C?
(cFe= 0.444 J/(g C))
a. 2.2 J
b. 4.4 J
c. 0.44 J
d. 0.89 J
55. A chemical reaction is carried out in a coffee cup calorimeter. The temperature of the water changes
from 25.2 C to 19.8 C. Which statement is correct?
56. To conduct an experiment, a scientist places a small piece of aluminum in a test tube and adds
sodium hydroxide solution. Bubbles of gas are produced and the outside of the test tube becomes
hot to the touch. Which of the following is true?
a. The reaction is endothermic, and the system gains energy from the surroundings.
b. The reaction is exothermic, and the system loses energy to the surroundings.
c. The reaction is endothermic, and the system loses energy to the surroundings.
d. The reaction is exothermic, and the system gains energy from the surroundings.
a. 3-propylbutanoic acid
b. 3-methylhexanoic acid
c. 4-methylhexanoic acid
d. 4-propylbutanoic acid
a. methoxybutane
b. methoxyhexane
c. 1-ethoxypropane
d. ethoxyhexane
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a. a secondary alcohol
b. a tertiary alcohol
c. a primary alcohol
d. none of the above
60. Alcohol is produced in the reaction shown here. What type of reaction is this?
a. a substitution reaction
b. a multiplication reaction
c. a hydrogenation reaction
d. a hydration reaction
a.
b.
c.
d.
62. Many alcohols are made by the addition reaction of what two types of compounds?
63. A benzene ring (minus one hydrogen atom) that behaves as a substituent group in an organic
hydrocarbon is known as a
a. hydroxyl group.
b. carbonyl group.
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c. phenyl group.
d. benzyl group.
a. toluene-1,2-diol
b. hexen-1,6-diol
c. benzene-1,2-diol
d. none of the above
a. 2-ethoxypropene
b. 2-ethoxypropane
c. 2-methoxyethene
d. 2-methoxyethane
66. An alcohol that has 2 hydroxyl groups includes which of the following in its name?
a. -ene
b. -diol
c. -triol
d. -ane
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67. Hydrohalogenation involves the reaction of an alkene with which of the following?
a. water
b. a hydrogen halide
c. a halogen
d. hydrogen
a an amide
b an alkyne
c an alcohol
d an aldehyde
70. Which rule or principal states that orbitals of equal energy fill with one unpaired electron
each before electrons begin to pair up?
a. Hunds rule
b. aufbau principle
c. Pauli exclusion principle
d. Heinsenbergs uncertainty principle
71. The electronic configuration of the element whose atomic number is 26 is:
a. 1s2 2s2 2p6 3s2 3p6 4s0 3d8
b. 1s2 2s2 2p6 3s2 3p6 3d6 4s2
c. 1s2 2s2 2p6 3s2 3p6 4s2 3d6
d. 1s2 2s2 2p6 3s2 3p6 4s2 3d4 4p2
e. none of the above
72. The orbital with quantum numbers n=3 and quantum number l=0 must be
a. 1s
b. 3s
c. 2p
d. 4d
Answers:
11b 12b 13d 14c 15c 16c 17d 18d 19b 20a
21a 22d 23d 24d 25b 26d 27c 28d 29a 30d
31c 32c 33c 34b 35a 36c 37c 38a 39d 40a
41d 42b 43d 44c 45b 46c 47a 48d 49b 50d
51b 52c 53a 54b 55c 56b 57b 58c 59b 60d
61d 62b 63c 64d 65b 66b 67b 68a 69c 70a
71c 72b