Presiones de Vapor Comp-Puro Mezclas Ideal Arrastre de Vapor

Table 2-6.
Vapor Pressure of Inorganic and Organic Liquids
Pvap=10
[ ( ) C1 +
C2
T
+ C 3 ln( T) + C 4 T C 5
]
Cmpd. No. Name Formula CAS no. C1 C2 C3 C4 C5 Tmin. K Ps at Tmin Tmax Ps at Tmax
5 Pentane C5H12 109660 78.741 -5420.3 -8.8253 9.61700E-06 2 143.42 6.86420E-02 469.7 3.36420E+06
6 Hexane C6H14 110543 104.65 -6995.5 -12.702 1.23810E-05 2 177.83 9.01690E-01 507.6 3.04490E+06
7 Heptane C7H16 142825 87.829 -6996.4 -9.8802 7.20990E-06 2 182.57 1.82690E-01 540.2 2.71920E+06
8 Octano C8H18 111659 96.084 -7900.2 -11.003 7.18020E-06 2 216.38 2.10830E+00 568.7 2.46730E+06
231 Water H2O 7732185 73.649 -7258.2 -7.3037 4.1653E-006 2 273.16 610.56 647.13 2.19400E+07
60 Cyclohexane C6H12 110827 116.51 -7103.3 -15.49 1.69590E-02 1 279.69 5.38020E+03 553.58 4.09580E+06
67 Benzene C6H6 71432 83.918 -6517.7 -9.3453 7.11820E-06 2 278.68 4.76200E+03 562.16 4.88190E+06
68 Toluene C7H8 108883 80.877 -6902.4 -8.7761 5.80340E-06 2 178.18 4.23480E-02 591.8 4.10120E+06
72 Ethylbenzene C8H10 100414 88.09 -7688.3 -9.7708 5.88440E-06 2 178.15 4.0140E-03 617.2 3.59680E+06
82 Methanol CH4O 67561 81.768 -6876 -8.7078 7.19260E-06 2 175.47 1.11470E-01 512.64 8.14020E+06
83 Ethanol C2H6O 64175 74.475 -7164.3 -7.327 3.13400E-06 2 159.05 4.84590E-04 513.92 6.11710E+06
84 1-Propanol C3H8O 71238 88.134 -8498.6 -9.0766 8.33030E-18 6 146.95 3.08280E-07 536.78 5.12140E+06
85 1-Butanol C4H10O 71363 93.173 -9185.9 -9.7464 4.77960E-18 6 184.51 5.72200E-04 563.05 4.33920E+06
89 1-Pentanol C5H12O 71410 168.96 -12659 -21.366 1.15910E-05 2 195.56 3.18160E-04 586.15 3.86570E+06
123 Acetone C3H6O 67641 69.006 -5599.6 -7.0985 6.22370E-06 2 178.45 2.78510E+00 508.2 4.70910E+06
135 Formic Acid CH2O2 64186 50.323 -5378.2 -4.203 3.46970E-06 2 281.45 2.40240E+03 588 5.80740E+06
136 Acetic Acid C2H4O2 64197 53.27 -6304.5 -4.2985 8.88650E-18 6 289.81 1.27690E+03 591.95 5.73900E+06
137 Propionic Acid C3H6O2 79094 54.552 -7149.4 -4.2769 1.18430E-18 6 252.45 1.31420E+01 600.81 4.60800E+06
214 Oxygen O2 7782447 51.245 -1200.2 -6.4361 2.84050E-02 1 54.36 1.48E+02 154.58 5.02060E+06
215 Nitrogen N2 7727379 58.282 -1084.1 -8.3144 4.41270E-02 1 63.15 1.25E+04 126.2 3.39060E+06
216 Ammonia NH3 7664417 90.483 -4669.7 -11.607 1.71940E-02 1 195.41 6.11E+03 405.65 1.13010E+07
PERRYS CHEMICAL ENGINEERS' HANDBOOK T en K Pa*9.869233*10^-06=atm

SEVENTH EDITION Pvap en Pa (Pascales) Pa*1.450377*10^-04=psia
Section 2, Physical and Chemical data Pa*0.00750062=mm de Hg
Vapor pressures of pure subtances
VERIFICACIN DE PRESIONES
Cmpd. No. Name Formula CAS no. Tneb exp Pa atm mm hg Variacin %
5 Pentane C5H12 109660 36.1 309.25 11.52789 101507.68404 1.0018 761.37 0.1803
6 Hexane C6H14 110543 68.7 341.85 11.52501 101216.18109 0.9989 759.184 -0.1074
7 Heptane C7H16 142825 98.4 371.55 11.52612 101328.29202 1 760.025 0.0033
8 Octano C8H18 111659 125.7 398.85 11.52638 101354.95871 1 760.225 0.0296
231 Water H2O 7732185 100 373.15 11.52545 101260.56298 0.9994 759.517 -0.0636
60 Cyclohexane C6H12 110827 80.7 353.85 11.52777 101495.79386 1.0017 761.281 0.1686
67 Benzene C6H6 71432 80.1 353.25 11.52506 101220.4599 0.999 759.216 -0.1032
68 Toluene C7H8 108883 110.6 383.75 11.5272 101438.04777 1.0011 760.848 0.1116
72 Ethylbenzene C8H10 100414 136.2 409.35 11.52714 101431.68748 1.0011 760.8 0.1053
82 Methanol CH4O 67561 64.7 337.85 11.5347 102201.44791 1.0086 766.574 0.8650
83 Ethanol C2H6O 64175 78.4 351.55 11.52969 101690.81521 1.0036 762.744 0.3610
84 1-Propanol C3H8O 71238 97.8 370.95 11.54756 103524.44832 1.0217 776.497 2.1707
85 1-Butanol C4H10O 71363 117.5 390.65 11.5109 99798.151179 0.9849 748.548 -1.5069
89 1-Pentanol C5H12O 71410 137.8 410.95 11.52259 100971.10496 0.9965 757.346 -0.3493
123 Acetone C3H6O 67641 56.5 329.65 11.5385 102590.09666 1.0125 769.489 1.2486
135 Formic Acid CH2O2 64186 100.6 373.75 11.52101 100811.69796 0.9949 756.15 -0.5066
136 Acetic Acid C2H4O2 64197 118.1 391.25 11.5289 101610.33175 1.0028 762.14 0.2816
137 Propionic Acid C3H6O2 79094 141.1 414.25 11.52472 101186.06423 0.9986 758.958 -0.1371
214 Oxygen O2 7782447 -183 90.15 11.5204 100750.37636 0.9943 755.69 -0.5671
215 Nitrogen N2 7727379 -195.8 77.35 11.52587 101302.52932 1.000 759.831 -0.0222
216 Ammonia NH3 7664417 -33.4 239.75 11.52621 101337.33495 1.000 760.093 0.0122
Promedio 0.1035
Cmpd. No. Name Formula CAS no. C1 C2 C3 C4 C5 Tmin. K Ps at Tmin Tmax Ps at Tmax
5 Pentane C5H12 109660 78.741 -5420.3 -8.8253 ### 2 143.42 ### 469.7 3.36420E+06
6 Hexane C6H14 110543 104.65 -6995.5 -12.702 ### 2 177.83 ### 507.6 3.04490E+06
231 Water H2O 7732185 73.649 -7258.2 -7.3037 4.165E-006 2 273.16 610.56 647.13 2.19400E+07
72 Ethylbenzene C8H10 100414 88.09 -7688.3 -9.7708 ### 2 178.15 4.0140E-03 617.2 3.59680E+06
PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS HASTA 1 atm.
COMPONENTES Presin en mm de Hg
1 5 10 20 40 60 100 200 400 760
Temperatura C
Pentane C5H12 -76.6 -62.5 -50.1 -40.2 -29.2 -22.2 -12.6 1.9 18.5 36.1
Hexane C6H14 -53.9 -34.5 -25 -14.1 -2.3 5.4 15.8 31.6 49.6 68.7
Heptane C7H16 -34 -12.7 -2.1 9.5 22.3 30.6 41.8 58.7 78 98.4
Octane C8H18 -14 8.3 19.2 31.5 45.1 53.8 65.7 83.6 104 125.6
Water H2O 1.2 11.25 22.15 34.05 41.55 51.6 66.5 83 100
Cyclohexane C6H12 -45.3 -25.4 -15.9 -5 6.7 14.7 25.5 42 60.8 80.7
Benzene C6H6 -36.7 -19.6 -11.5 -2.6 7.6 15.4 26.1 42.2 60.6 80.1
Toluene C7H8 -26.7 -4.4 6.4 18.4 31.8 40.3 51.9 69.5 89.5 110.6
Ethylbenzene C8H10 -9.8 13.9 25.9 38.6 52.8 61.8 74.1 92.7 113.8 136.2
Methanol CH4O -44 -25.3 -16.2 -6 5 12.1 21.2 34.8 49.9 64.7
Ethanol C2H6O -31.3 -12 -2.3 8 19 26 34.9 48.4 63.5 78.4
1-Propanol C3H8O -15 5 14.7 25.3 36.4 43.5 52.8 66.8 82 97.8
1-Butanol C4H10O -1.2 20 30.2 41.5 53.4 60.3 70.1 84.3 100.8 117.5
1-Pentanol (n-Amyl alcohol) C5H12O 13.6 34.7 44.9 55.8 68 75.5 85.8 102 119.8 137.8
Acetone C3H6O -59.4 -40.5 -31.1 -20.8 -9.4 -2 7.7 22.7 39.5 56.5
Formic Acid CH2O2 -20 -5 2.1 10.3 24 32.4 43.8 61.4 80.3 100.6
Acetic Acid C2H4O2 -17.2 6.3 17.5 29.9 43 51.7 63 80 99 118.1
Propionic Acid C3H6O2 4.6 28 39.7 52 65.8 74.1 85.8 102.5 122 141.1
Oxygen O2 -219.1 -213.4 -210.6 -207.5 -204.1 -201.9 -198.8 -194 -188.8 -183.1
Nitrogen N2 -226.1 -221.3 -219.1 -216.8 -214 -212.3 -209.7 -205.6 -200.9 -195.8
Ammonia NH3 -109.1 -97.5 -91.9 -85.8 -79.2 -74.3 -68.4 -57 -45.4 -33.6
PERRYS CHEMICAL ENGINEERS' HANDBOOK 1 1 Pvap en mm de Hg

SEVENTH EDITION T1 T log P 1 log P T en K
=
Section 2, Physical and Chemical data 1 1 log P 1 log P2

T1 T2
1 1

T1 T log P 1 log P
=
1 1 log P 1 log P2

Vapor pressures of pure subtances T1 T2

COMPONENTES Presin en atm
1 2 5 10 20 30 40 50 60
Temperatura C
Pentane C5H12 36.1 58 92.4 124.7 164.3 191.3
Hexane C6H14 68.7 93 131.7 166.6 209.4
Heptane C7H16 98.4 124.8 165.7 202.8 247.5
Octane C8H18 125.6 152.7 196.2 235.8 281.4
Water H2O 100 120.1 152.4 180.5 213.1 234.6 251.1 264.7 276.5
Cyclohexane C6H12 80.7 106 146.4 184 228.4 257.5
Benzene C6H6 80.1 103.8 142.5 178.8 221.5 249.5 272.3 290.3
Toluene C7H8 110.6 136.5 178 215.8 262.5 292.8 319
Ethylbenzene C8H10 136.2 163.5 207.5 246.3 294.5 326.5
Methanol CH4O 64.7 84 112.5 138 167.8 186.5 203.5 214 224
Ethanol C2H6O 78.4 97.5 126 151.8 183 203 218 230 242
1-Propanol C3H8O 97.8 117 149 117 210.8 232.3 250
1-Butanol C4H10O 117.5 139.8 172.5 203 237 259 277
1-Pentanol (n-Amyl alcohol) C5H12O
Acetone C3H6O 56.5 78.6 113 144.5 181 205 214.5
Formic Acid CH2O2
Acetic Acid C2H4O2 118.1 143.5 180.3 214 252 276.5 297 312.5
Propionic Acid C3H6O2 141.1 160 186 203.5 220 228 233 238
Oxygen O2 -183.1 -176 -164.5 -153.2 -140 -130.7 -124.1
Nitrogen N2 -195.8 -189.2 -179.1 -169.8 -157.6 -148.3
Ammonia NH3 -33.6 -18.7 4.7 25.7 50.1 66.1 78.9 89.3 98.3
PERRY Y CHILTON. MANUAL DEL INGENIERO QUIMICO

1 1 Pvap en mm de Hg

T1 T log P 1 log P
=
1 1 log P 1 log P2

T1 T2
1 1

QUINTA EDICION (Segunda edicin en espaol) T1 T log P 1 log P T en K
=
Seccin 3. Datos de Fsica y Qumica. 1 1 log P 1 log P2

Presiones de vapor de sustancias puras. T1 T2
COMPONENTES Presin en mm de Hg
1 5 10 20 40 60 100 200 400 760
Temperatura C
Pentane C5H12 -76.6 -62.5 -50.1 -40.2 -29.2 -22.2 -12.6 1.9 18.5 36.1
Hexane C6H14 -53.9 -34.5 -25 -14.1 -2.3 5.4 15.8 31.6 49.6 68.7
Water H2O 1.2 11.25 22.15 34.05 41.55 51.6 66.5 83 100
Ethylbenzene C8H10 -9.8 13.9 25.9 38.6 52.8 61.8 74.1 92.7 113.8 136.2

COMPONENTES Presin en atm
1 2 5 10 20 30 40 50 60
Temperatura C
Pentane C5H12 36.1 58 92.4 124.7 164.3 191.3
Hexane C6H14 68.7 93 131.7 166.6 209.4
Water H2O 100 120.1 152.4 180.5 213.1 234.6 251.1 264.7 276.5
Ethylbenzene C8H10 136.2 163.5 207.5 246.3 294.5 326.5
VAPOR-PRESSURE EQUATIONS. Presin de Vapor p en mm de Hg VAPOR-PRESSURE EQUATIONS. Presin de Vapor p en mm de Hg
ANTOINE EQUATIONS T temperatura absoluta en K ANTOINE EQUATIONS T temperatura absoluta en K
t temperatura en C t temperatura en C
B B B B B B
1) log p = A 2) log p = A 3) log p = A C log T 1) log p = A 2) log p = A 3) log p = A C log T
t +C T T t +C T T
Compound Formula State
EquationRange, C A B C tneb C % var Compound Formula State Equation Range, C A B C tneb C % var
Pentane C5H12 1 (-50) - 58 6.85296 1064.84 233.01 36.1 2.896065 787.164 3.574 Pentane C5H12 1 (-50) - 58 6.85296 1064.84 233.01 36.1 2.896065 787.164 3.574
Hexane C6H14 1 (-25) - 92 6.87601 1171.17 224.41 68.7 2.880343 759.177 -0.108 Hexane C6H14 1 (-25) - 92 6.87601 1171.17 224.41 68.7 2.880343 759.177 -0.108
Heptane C7H16 1 -2 to 124 6.89677 1264.9 216.54 98.4 2.880449 759.363 -0.084 Water H2O 1 0 to 60 8.1332 1762.39 235.66 100 2.882679 763.271 0.430
Octane C8H18 1 19 to 152 6.91868 1351.99 209.15 125.8 2.882287 762.582 0.340 1 60 to 120 7.97208 1668.84 227.7 100 2.879495 757.697 -0.303
Water H2O 1 0 to 60 8.1332 1762.39 235.66 100 2.882679 763.271 0.430 Ethylbenzene C8H10 1 26 - 164 6.95719 1424.255 213.21 136.2 2.881019 760.359 0.047
1 60 to 120 7.97208 1668.84 227.7 100 2.879495 757.697 -0.303
Cyclohexane C6H12 1 20 to 81 6.8413 1201.53 222.65 80.7 2.880430 759.329 -0.088
Benzene C6H6 1 8 to 103 6.90565 1211.033 220.79 80.1 2.880814 760.000 0.000
Toluene C7H8 1 -6 to 137 6.95464 1344.8 219.48 110.6 2.880476 759.410 -0.078
Ethylbenzene C8H10 1 26 - 164 6.95719 1424.255 213.21 136.2 2.881019 760.359 0.047
Methanol CH4O 1 64 to 110 7.97328 1515.14 232.85 64.7 2.881228 760.726 0.096
Ethanol C2H6O 1 (-2) - 100 8.32109 1718.1 237.52 78.4 2.882688 763.287 0.433
1-Propanol C3H8O 1 2 to 120 7.84767 1499.21 204.64 97.8 2.890621 777.357 2.284
1-Butanol C4H10O 1 15 - 131 7.476 1362.39 178.77 117.5 2.877526 754.268 -0.754
1-Pentanol ( C5H12O 1 37 to 138 7.17758 1314.56 168.11 137.8 2.880368 759.221 -0.102
Acetone C3H6O 1 liq 7.11714 1210.595 229.664 56.5 2.886716 770.400 1.368
Formic Acid CH2O2 1 37 to 101 7.5818 1699.2 260.7 100.6 2.878783 756.455 -0.466
Acetic Acid C2H4O2 1 liq 7.38782 1533.313 222.309 118.1 2.883494 764.706 0.619
Propionic Aci C3H6O2 1 56 to 139.5 6.403 950.2 130.3 141.1 2.901895 797.801 4.974
Oxygen O2 liq 1 6.69144 319.013 266.697 -183.1 2.875358 750.513 -1.248
Nitrogen N2 liq 1 6.49414 255.535 266.451 -195.8 2.877277 753.836 -0.811
Ammonia NH3 liq 1 7.3605 926.132 240.17 -33.6 2.877119 753.562 -0.847
LANGE'S HANDBOOK OF CHEMISTRY

John A. Dean
Fifteenth Edition 1999
McGRAW-HILL, INC.
Section 5, PHYSICAL PROPERTIES
TABLE 5.8 Vapor pressures of Various Inorganic Compounds
TABLE 5.9 Vapor pressures of Various Organic Compounds
Clculo del equilibrio vapor liquido para la mezcla Acetona-Acido actico 1 atm de
presin (Ideal P cte.)
Paso 1
Seleccionar el mtodo para determinar las presiones de vapor a diferentes temperaturas.
Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

B
1) log p = A T temperatura absoluta en K Pa*1.450377*10^-04=psia
t +C t temperatura en C Pa*0.00750062=mm de Hg
Compound Formula State Equation Range, C A B C tneb C

Acetona C3H6O 1 liq 7.11714 1210.595 229.664 56.5
HAC C2H4O2 1 liq 7.38782 1533.313 222.309 118.1
Paso 2
Determinar la temperatura normal de ebullicin de los componentes puros.
Name Tneb
C K
Acetona 56.5 329.65
HAC 118.1 391.25
Paso 3
Determinar las temperaturas a las cuales se calcular la presin de vapor, dividiendo el rango en
fracciones; establecer alrededor de 8 a 10 puntos de temperaturas.
Pt = 760 mm de Hg
Paso 4
Calcular las presiones de vapor como componentes puros para cada una de las temperaturas
y para ambos componentes.
Paso 5
Calcular la fraccin lquida y vapor en equilibrio para el componente ms voltil.
Paso 6
Determinar la volatilidad relativa de la mezcla, as como las presiones parciales.
t PA PB x y p*a p*'b
C mm Hg mm Hg fac. Mol frac. Mol mmHg mm Hg
56.5 770.40 77.32 0.9850 0.9985 9.963 759 1
60 866.63 90.47 0.8626 0.9836 9.579 748 12
65 1020.35 112.46 0.7132 0.9576 9.073 728 32
70 1194.81 138.77 0.5883 0.9248 8.610 703 57
75 1391.87 170.03 0.4829 0.8843 8.186 672 88
80 1613.46 206.93 0.3932 0.8348 7.797 634 126
85 1861.56 250.23 0.3164 0.7749 7.439 589 171
90 2138.23 300.76 0.2499 0.7032 7.109 534 226
95 2445.55 359.40 0.1920 0.6179 6.805 470 290
100 2785.68 427.11 0.1411 0.5173 6.522 393 367
110 3573.09 593.88 0.0558 0.2621 6.016 199 561
118.1 4325.72 764.71 -0.0013 -0.0075 5.657 -6 766
Paso 7
3000.00
2500.00
Construir los diagramas de equilibrio vap-liq
3000.00y vap-liq-temp, x-y y t-x-y respectivamente
y* fr a c c i n m o l de Be nc e n o e n la fa s e va po r
2500.00
x t y x
0.9850 56.5
2000.00 0.9985 0.9850
0.8626 60 0.9836 0.8626
0.7132 65 0.9576 0.7132
0.5883 70
1500.00 0.9248 0.5883
0.4829 75 0.8843 0.4829
0.3932 80 0.8348 0.3932
0.3164 85
1000.00 0.7749 0.3164
Diagrama de equilibrio vapor-lquido
0.2499 90 0.7032
sistema0.2499
Benceno - Etil benceno a 1 atm
0.1920 95 0.6179 0.1920
0.1411 1001.00000.5173
500.00 0.1411
0.0558 110 0.2621 0.0558
0.9000
-0.0013 118.1 -0.0075 -0.0013
0.8000
0.00
y 0.9985 0.0000
56.50.7000 0.2000 0.4000 0.6000 0.8000 1.0000
Column P
0.9836 600.6000
0.9576 65
0.5000
0.9248 70
0.8843 750.4000
0.8348 800.3000
0.7749 850.2000
0.7032 90
0.1000
0.6179 95
0.5173 1000.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.2621 110 0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
-0.0075 118.1 x fraccin mol de Benceno en la fase lquida
Diagrama de equilibrio vapor lquido
sistema Benceno-Etil benceno a 1 atm
Temperatura C
140
130
120
110
100
90
80
70
60
50
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de Benceno
60
50
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Acetona-Acido actico Clculo del equilibrio va
a 100 C (Ideal T cte.) presin (Ideal P cte.)
Paso 1 Paso 1
Seleccionar el mtodo para determinar las presiones de vapor a diferentes temperaturas. Seleccionar el mtodo
Pa*9.869233*10^-06=atm
B B
1) log p = A Pa*1.450377*10^-04=psia 1) log p = A
t +C Pa*0.00750062=mm de Hg t+
Compound Formula State Equation Range, C A B C tneb C Compound

Acetona C3H6O 1 liq 7.11714 1210.6 229.664 56.5 Benceno
HAC C2H4O2 1 liq 7.38782 1533.3 222.309 118.1 Et-Benceno
Paso 2 Paso 2
Determinar las presiones de vapor de los componentes puros a la T cte. Determinar la temperat
Name T P
C mm Hg
Acetona 100 2785.68
HAC 100 427.11
Paso 3 Paso 3
Establecer los puntos de concentracin de la fase lquida (frac. Mol) en cantidad de Determinar las tempera
8 a 10 puntos de concentracin. fracciones; establecer
Paso 4 Paso 4
Calcular las presiones parciales de las mezclas a las diferentes concentraciones. Calcular las presiones
y para ambos compone
Paso 5 Paso 5
Calcular la Presin total y la composicin de y* de la fase vapor. Calcular la fraccin lqu
Paso 6 Paso 6
Determinar la volatilidad relativa. Determinar la volatilida
x p*a p*b Pt y
fac. Mol mmHg mm Hg mm Hg frac. Mol
1.0000 2785.68 0.00 2785.68 1.0000
0.9000 2507.11 42.71 2549.82 0.9832
0.8000 2228.54 85.42 2313.97 0.9631
0.6000 1671.41 170.85 1842.25 0.9073
0.5000 1392.84 213.56 1606.40 0.8671
0.4000 1114.27 256.27 1370.54 0.8130
0.2000 557.14 341.69 898.83 0.6198
0.1000 278.57 384.40 662.97 0.4202
0.0000 0.00 427.11 427.11 0.0000
Paso 7
d e Be n ce n o e n la fas e vap o r
Paso 7 Construir los diagrama

Construir los diagramas de equilibrio vap-liq y vap-liq-temp, x-y y t-x-y respectivamente
y* fr acci n m o l d e Be n ce n o e n la fas e va
y* fr a c c in m o l d e Be nc e n o e n la fa s e va p or
x y x Pt
1.0000 1.0000 1.0000 2785.68
0.9000 0.9832 0.9000 2549.82
0.8000 0.9631 0.8000 2313.97
0.6000 0.9073 0.6000 1842.25 Diagrama de equilibrio v
sistema Benceno - Etil ben
0.5000 0.8671 0.5000 1606.40
Diagrama de
0.4000 0.8130 0.4000 1370.54
1.0000 siste ma Bence
0.2000 0.6198 0.2000 898.83
Presin en mm de Hg
0.1000 0.4202 0.1000 662.97 0.9000
0.0000 0.0000 0.0000 427.11 0.8000
3000.00
1.0000
0.7000 0.9000
uido 1.0000 2785.68
1 atm 0.9832 2549.82 0.6000 2500.00 0.8000
0.9631 2313.97 0.7000
0.5000
0.9073 1842.25
0.6000
0.8671 1606.40 0.4000 2000.00
0.5000
0.8130 1370.54 0.3000
0.6198 898.83 0.4000
0.8000 1.0000 0.4202 662.97 0.2000 1500.00 0.3000
0.0000 427.11 0.1000
0.2000
0.0000 0.1000
1000.00
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0
0.0000 e
x fraccin m ol de Benceno
0.0
500.00
0.00
000 0.9000
0.0000 0.1000 0.2000 0.30
0.8000 1.0000
e lquida
Temperatura C
180
170
160
150
140
130
120
110
100
0.0000
0.0000
Clculo del equilibrio vapor liquido para la mezcla Benceno - Etil benceno a 2 atm de Clculo del equilibrio vapor liqu
Paso 1
Seleccionar el mtodo para determinar las presiones de vapor a diferentes temperaturas. Seleccionar el mtodo para det

B B
1) log p = A T temperatura absoluta en K Pa*1.450377*10^-04=psia 1) log p = A
t +C t temperatura en C Pa*0.00750062=mm de Hg t +C
Formula State Equation Range, C A B C tneb C Compound

C6H6 1 64 to 110 6.90565 1211.033 220.79 80.1 Benceno
C8H10 1 (-2) - 100 6.95719 1424.255 213.21 136.2 Et-Benceno
Paso 2
Determinar la temperatura normal de ebullicin de los componentes puros. Determinar las presiones de va
Name Tneb Presin cte

C K
Benceno 104.42 377.57374 1520
Et-Bencen 164.04 437.19147 1520
Paso 3
Determinar las temperaturas a las cuales se calcular la presin de vapor, dividiendo el rango en Establecer los puntos de conce
fracciones; establecer alrededor de 8 a 10 puntos de temperaturas. 8 a 10 puntos de concentracin
Pt = 1520 mm de Hg
Paso 4
Calcular las presiones de vapor como componentes puros para cada una de las temperaturas Calcular las presiones parciales
Paso 5
Calcular la fraccin lquida y vapor en equilibrio para el componente ms voltil. Calcular la Presin total y la co
Paso 6
Determinar la volatilidad relativa de la mezcla, as como las presiones parciales. Determinar la volatilidad relativ
104.42 1520 297 1.0000 1.0000 5.112 1520 0
116.00 2041 427 0.6771 0.9092 4.775 1382 138
125.00 2532 557 0.4876 0.8121 4.544 1234 286
135.00 3176 736 0.3213 0.6713 4.314 1020 500
145.00 3935 958 0.1889 0.4891 4.109 743 777
150.00 4361 1086 0.1325 0.3801 4.015 578 942
160.00 5313 1383 0.0348 0.1215 3.840 185 1335
164.04 5738 1520 0.0000 0.0000 3.775 0 1520
Construir los diagramas de equilibrio vap-liq y vap-liq-temp, x-y y t-x-y respectivamente Paso 7
Construir los diagramas de equ
x t y x
1.0000 104.4237 1.0000 1.0000
0.6771 116 0.9092 0.6771
0.4876 125 0.8121 0.4876
ama de equilibrio vapor lquido
0.3213 135 0.6713 0.3213
a Benceno - Etil benceno a 100 C
0.1889 145 0.4891 0.1889
Diagrama de e quilibrio v apor lquido
0.1325 150 0.3801 0.1325
siste ma Benceno - Diagrama
Etil be ncedeno equilibrio
a 100 C vapor-lquido
0.0348 160
sistema Benceno - 0.1215 0.0348
Etil benceno a 2 atm
0.0000 164.0415 0.0000 0.0000
0.00
1.0000
y 1.0000 104.4237
0.9000
0.9092 116
0.00 0.8000 0.8121 125
0.7000 0.6713 135
0.4891 145
0.6000
0.00 0.3801 150
0.5000
0.1215 160
0.4000 0.0000 164.0415
0.00 0.3000
0.2000
0.00 0.1000
2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
0.0000 en la fase lquida
accin m ol de Benceno
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.00
x fraccin mol de Benceno en la fase lquida
0.00
Diagrama
0.0000 0.1000 0.2000 0.3000 0.4000 de equilibrio
0.5000 0.6000 0.7000 0.8000vapor lquido
0.9000 1.0000
sistema
x - y* frac. molBenceno
Benceno - Etil Benceno a 2 atm
Temperatura C
180
170
160
150
140
130
120
110
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Benceno - Etil benceno a 50 C (Ideal T cte.) EFECTO DE LA PRESION
1 ATM
Seleccionar el mtodo para determinar las presiones de vapor a diferentes temperaturas. x
fac. Mol
Pa*9.869233*10^-06=atm 1.00149467
B
1) log p = A Pa*1.450377*10^-04=psia 0.8705197
t +C Pa*0.00750062=mm de Hg 0.68753226
0.48601337
Formula State Equation Range, C A B C tneb C 0.30986645
C6H6 1 64 to 110 6.90565 1211 220.79 80.1 0.15482712
C8H10 1 (-2) - 100 6.95719 1424.3 213.21 136.2 0.07046544
-0.00311346
1.0000
Determinar las presiones de vapor de los componentes puros a la T cte. 0.8175
0.6521
Name T P 0.5019
C mm Hg 0.3648
Benceno 50 271.29 0.2393
Et-Bence 50 35.16 0.1240
0.0000
Establecer los puntos de concentracin de la fase lquida (frac. Mol) en cantidad de 1.00065526
8 a 10 puntos de concentracin. 0.93820956
160
0.83055575
0.6744655
0.49193197
Calcular las presiones parciales de las mezclas a las diferentes concentraciones. 0.28006615
150
0.13759363
-0.00652131
140
Calcular la Presin total y la composicin de y* de la fase vapor. 1.0000
0.9028
0.7936
130
Determinar la volatilidad relativa. 0.6715
0.5355
x p*a p*b Pt y 0.3846
fac. Mol mmHg mm Hg mm Hg frac. Mol 0.2178
120
1.0000 271.29 0.00 271.29 1.0000 0.0000

0.9000 244.16 3.52 247.67 0.9858
0.8000 217.03 7.03 224.06 0.9686 110
0.6000 162.77 14.07 176.84 0.9205

0.5000 135.64 17.58 153.22 0.8853
0.4000 108.51 21.10 129.61 0.8372
100
0.2000 54.26 28.13 82.39 0.6586
0.1000 27.13 31.65 58.78 0.4616
0.0000 0.00 35.16 35.16 0.0000
90

80
0 0.1 0.2 0.3
y* fr a c c i n m o l d e H e p ta n o e n la fa s e va p o r
80
0 0.1 0.2 0.3
x y x
1.0000 1.0000 1.0000 271.29
0.9000 0.9858 0.9000 247.67
0.8000 0.9686 0.8000 224.06
0.6000 0.9205 0.6000 176.84
0.5000 0.8853 0.5000 153.22
0.4000Diagrama
0.8372 de equilibrio
0.4000 129.61
vapor lquido
0.2000 sistema
0.6586 Heptano-Octano
0.2000 82.39
a 50 C
0.1000 0.4616 0.1000 58.78
0.0000
1.0000 0.0000 0.0000 35.16
0.9000
1.0000 271.29
0.8000
0.9582 247.67
0.9107
0.7000 224.06
0.7926
0.6000 176.84
0.7182 153.22
0.5000
0.6295 129.61
0.3891
0.4000 82.39
0.2207
0.3000 58.78
0.0000
0.2000
35.16
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x fraccin mol de Heptano en la fase lquida

sistema Heptano-Octano a 50 C
Presin en mm de Hg
300.00
250.00
200.00
150.00
100.00
50.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol Heptano
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
FECTO DE LA PRESION
y t t x y
frac. Mol C C fac. Mol frac. Mol
1
1.00065526 1.00149467 98.4 123.95 1.0000 1.0000
0.93820956 0.8705197 101 127.95 0.8175 0.9028
0.83055575 0.68753226 105 131.95 0.6521 0.7936 0.9
0.6744655 0.48601337 110 135.95 0.5019 0.6715
0.49193197 0.30986645 115 139.95 0.3648 0.5355
0.8
0.28006615 0.15482712 120 143.95 0.2393 0.3846
0.13759363 0.07046544 123 147.95 0.1240 0.2178
-0.00652131 -0.00311346 125.8 152.65 0.0000 0.0000 0.7
1.0000 1.0000 123.95 0.6

0.9028 0.8175 127.95
0.7936 0.6521 131.95
0.6715 0.5019 135.95 0.5
0.5355 0.3648 139.95
0.3846 0.2393 143.95 0.4
0.2178 0.1240 147.95
0.0000 0.0000 152.65
0.3
98.4
160
101 0.2
105
110
115 0.1
150
120
123 0
125.8 0 0.1
140
123.95
127.95
131.95
130
135.95
139.95
143.95
120
147.95
152.65
110
100
90
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Clculo del equilibrio vapor liquido para la mezcla Benceno - Etil benceno 1 atm de
Paso 1

B

Benceno C6H6 1 64 to 110 6.90565 1211.033 220.79 80.1
Et-Benceno C8H10 1 (-2) - 100 6.95719 1424.255 213.21 136.2
Paso 2
Name Tneb
C K
Benceno 80.1 353.25
Et-Bencen 136.2 409.35
Paso 3
Pt = 760 mm de Hg
Paso 4
Paso 5
Paso 6
80.1 760.00 126.30 1.0000 1.0000 6.018 760 0
85 881.67 151.77 0.8333 0.9667 5.809 735 25
90 1020.99 181.94 0.6889 0.9255 5.612 703 57
95 1176.84 216.84 0.5658 0.8761 5.427 666 94
100 1350.49 256.98 0.4600 0.8174 5.255 621 139
105 1543.23 302.94 0.3685 0.7483 5.094 569 191
110 1756.38 355.30 0.2888 0.6675 4.943 507 253
115 1991.27 414.69 0.2190 0.5739 4.802 436 324
120 2249.29 481.77 0.1574 0.4659 4.669 354 406
125 2531.80 557.23 0.1027 0.3421 4.544 260 500
130 2840.19 641.78 0.0538 0.2010 4.426 153 607
136.2 3260.66 760.36 -0.0001 -0.0006 4.288 0 760
Paso 7
y* fr a c c i n m o l d e Be nc e no e n la fa s e va po r
x t y x
1.0000 80.1 1.0000 1.0000
0.8333 85 0.9667 0.8333
0.6889 90 0.9255 0.6889
0.5658 95 0.8761 0.5658
0.4600 100 0.8174 0.4600
0.3685 105 0.7483 0.3685
0.2888 110 0.6675 0.2888
sistema Benceno - Etil benceno a 1 atm
0.2190 115 0.5739 0.2190
1.0000 0.1574 120 0.4659 0.1574
0.9000
0.1027 125 0.3421 0.1027
0.0538 130 0.2010 0.0538
0.8000
-0.0001 136.2 -0.0006 -0.0001
0.7000
0.6000
y 1.0000 80.1
0.9667 85
0.5000
0.9255 90
0.4000 0.8761 95
0.3000 0.8174 100
0.7483 105
0.2000
0.6675 110
0.1000 0.5739 115
0.0000 0.4659 120
0.10000.34210.3000 125 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.2010 130
-0.0006 136.2
sistema Benceno-Etil benceno a 1 atm
140
Temperatura C
130
120
110
100
90
80
70
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
80
70
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Benceno - Etil benceno Clculo del equilibrio va
a 100 C (Ideal T cte.) presin (Ideal P cte.)
Paso 1 Paso 1
Pa*9.869233*10^-06=atm
B B
t +C Pa*0.00750062=mm de Hg t+

Benceno C6H6 1 64 to 110 6.90565 1211 220.79 80.1 Benceno
Et-Benceno C8H10 1 (-2) - 100 6.95719 1424.3 213.21 136.2 Et-Benceno
Paso 2 Paso 2
Name T P
C mm Hg
Benceno 100 1350.49
Et-Bence 100 256.98
Paso 3 Paso 3
Paso 4 Paso 4
Paso 5 Paso 5
Paso 6 Paso 6
x p*a p*b Pt y
1.0000 1350.49 0.00 1350.49 1.0000
0.9000 1215.44 25.70 1241.14 0.9793
0.8000 1080.39 51.40 1131.79 0.9546
0.6000 810.29 102.79 913.09 0.8874
0.5000 675.25 128.49 803.74 0.8401
0.4000 540.20 154.19 694.39 0.7779
0.2000 270.10 205.59 475.69 0.5678
0.1000 135.05 231.29 366.33 0.3686
0.0000 0.00 256.98 256.98 0.0000
Paso 7
d e Be n c e n o e n la fas e va p o r

y* fr acci n m o l d e Be n c e n o e n la fas e va p
x y x Pt
1.0000 1.0000 1.0000 1350.49
0.9000 0.9793 0.9000 1241.14
0.8000 0.9546 0.8000 1131.79
0.6000Diagrama
0.6000 913.09
v apor lquido
0.5000 0.8401 0.5000 803.74 a 100 C
sistema Benceno - Etil benceno
0.4000 0.7779 0.4000 694.39
1.0000
0.2000 0.5678 0.2000 475.69
0.90000.1000 0.3686 0.1000 366.33
0.0000 0.0000 0.0000 256.98 1.0000
0.8000
0.9000
0.70001.0000 1350.49
0.9793 1241.14 0.8000
0.6000
0.9546 1131.79 0.7000
0.50000.8874 913.09 0.6000
0.8401 803.74
0.4000 0.5000
0.7779 694.39
0.30000.5678 475.69 0.4000
0.2000
0.3686 366.33 0.3000
0.0000 256.98
0.1000 0.2000
0.1000
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
0.0000
x fraccin m ol de Benceno en la fase lquida
0.0

siste ma Benceno - Etil be nce no a 100 C
Presin en mm de Hg
1600.00
180
Temperatura C
1400.00
170
1200.00
160
1000.00
150
800.00
140
600.00
130
400.00
120
200.00 110
0.00 100
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
x - y* frac. mol Benceno 0.0000
100
0.0000
Clculo del equilibrio vapor liquido para la mezcla Benceno - Etil benceno a 2 atm de Clculo del equilibrio vapor liqu
Paso 1

B B

C6H6 1 64 to 110 6.90565 1211.033 220.79 80.1 Benceno
C8H10 1 (-2) - 100 6.95719 1424.255 213.21 136.2 Et-Benceno
Paso 2

C K
Benceno 104.42 377.57374 1520
Et-Bencen 164.04 437.19147 1520
Paso 3
Pt = 1520 mm de Hg
Paso 4
Paso 5
Paso 6
104.42 1520 297 1.0000 1.0000 5.112 1520 0
116.00 2041 427 0.6771 0.9092 4.775 1382 138
125.00 2532 557 0.4876 0.8121 4.544 1234 286
135.00 3176 736 0.3213 0.6713 4.314 1020 500
145.00 3935 958 0.1889 0.4891 4.109 743 777
150.00 4361 1086 0.1325 0.3801 4.015 578 942
160.00 5313 1383 0.0348 0.1215 3.840 185 1335
164.04 5738 1520 0.0000 0.0000 3.775 0 1520
x t y x
1.0000 104.4237 1.0000 1.0000
0.6771 116 0.9092 0.6771
0.4876 125 0.8121 0.4876
0.3213 135 0.6713 0.3213
0.1889 145 0.4891 0.1889
0.1325 150 0.3801 0.1325
0.0348 160
sistema Benceno - 0.1215
Etil benceno0.0348
a 2 atm
0.0000 164.0415 0.0000 0.0000
1.0000
y 1.0000 104.4237
0.9000
0.9092 116
0.8000 0.8121 125
0.7000 0.6713 135
0.6000
0.4891 145
0.3801 150
0.5000
0.1215 160
0.4000 0.0000 164.0415
0.3000
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

sistema Benceno - Etil Benceno a 2 atm
180
Temperatura C
170
160
150
140
130
120
110
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Benceno - Etil benceno a 50 C (Ideal T cte.) EFECTO DE LA PRESION
1 ATM
fac. Mol
Pa*9.869233*10^-06=atm 1.00149467
B
1) log p = A Pa*1.450377*10^-04=psia 0.8705197
t +C Pa*0.00750062=mm de Hg 0.68753226
0.48601337
C6H6 1 64 to 110 6.90565 1211 220.79 80.1 0.15482712
C8H10 1 (-2) - 100 6.95719 1424.3 213.21 136.2 0.07046544
-0.00311346
1.0000
0.6521
Name T P 0.5019
C mm Hg 0.3648
Benceno 50 271.29 0.2393
Et-Bence 50 35.16 0.1240
0.0000
160
0.83055575
0.6744655
0.49193197
150
0.13759363
-0.00652131
140

0.9028
0.7936
130
0.5355
x p*a p*b Pt y 0.3846
120
1.0000 271.29 0.00 271.29 1.0000 0.0000
0.9000 244.16 3.52 247.67 0.9858
0.8000 217.03 7.03 224.06 0.9686 110
0.6000 162.77 14.07 176.84 0.9205

0.5000 135.64 17.58 153.22 0.8853
0.4000 108.51 21.10 129.61 0.8372
100
0.2000 54.26 28.13 82.39 0.6586
0.1000 27.13 31.65 58.78 0.4616
0.0000 0.00 35.16 35.16 0.0000
90

80
0 0.1 0.2 0.3
80
0 0.1 0.2 0.3
x y x
1.0000 1.0000 1.0000 271.29
0.9000 0.9858 0.9000 247.67
0.8000 0.9686 0.8000 224.06
0.6000 0.9205 0.6000 176.84
0.5000 0.8853 0.5000 153.22
0.4000Diagrama
0.4000 129.61
vapor lquido
0.2000 sistema
0.2000 82.39
a 50 C
0.1000 0.4616 0.1000 58.78
0.0000
1.0000 0.0000 0.0000 35.16
0.9000
1.0000 271.29
0.8000
0.9582 247.67
0.9107
0.7000 224.06
0.7926
0.6000 176.84
0.7182 153.22
0.5000
0.6295 129.61
0.3891
0.4000 82.39
0.2207
0.3000 58.78
0.0000 35.16
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Presin en mm de Hg
300.00
250.00
200.00
150.00
100.00
50.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
FECTO DE LA PRESION
y t t x y
1
1.00065526 1.00149467 98.4 123.95 1.0000 1.0000
0.93820956 0.8705197 101 127.95 0.8175 0.9028
0.83055575 0.68753226 105 131.95 0.6521 0.7936 0.9
0.6744655 0.48601337 110 135.95 0.5019 0.6715
0.49193197 0.30986645 115 139.95 0.3648 0.5355
0.8
0.28006615 0.15482712 120 143.95 0.2393 0.3846
0.13759363 0.07046544 123 147.95 0.1240 0.2178
-0.00652131 -0.00311346 125.8 152.65 0.0000 0.0000 0.7
1.0000 1.0000 123.95

0.6
0.9028 0.8175 127.95
0.7936 0.6521 131.95
0.6715 0.5019 135.95 0.5
0.5355 0.3648 139.95
0.3846 0.2393 143.95
0.4
0.2178 0.1240 147.95
0.0000 0.0000 152.65
0.3
98.4
101
160 0.2
105
110
115 0.1
150
120
123
0
125.8
0 0.1
140
123.95
127.95
131.95
130
135.95
139.95
143.95
120
147.95
152.65
110
100
90
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Clculo del equilibrio vapor liquido para la mezcla Metano-Etanol 1 atm de presin (Ideal P cte.)
Paso 1

B

Methanol CH4O 1 64 to 110 7.97328 1515.14 232.85 64.7
Ethanol C2H6O 1 (-2) - 100 8.32109 1718.1 237.52 78.4
Paso 2
Name Tneb
C K
Methanol 64.7 337.85
Ethanol 78.4 351.55
Paso 3
Pt = 760 mm de Hg
Paso 4
Paso 5
Paso 6
64.7 760.73 432.67 0.9978 0.9987 1.758 759 1
66.7 822.67 471.55 0.8215 0.8893 1.745 676 84
68.7 888.74 513.36 0.6571 0.7683 1.731 584 176
70.7 959.13 558.25 0.5033 0.6351 1.718 483 277
72.7 1034.07 606.40 0.3591 0.4887 1.705 371 389
74.7 1113.77 658.02 0.2238 0.3279 1.693 249 511
76.7 1198.47 713.29 0.0963 0.1518 1.680 115 645
78.4 1274.56 763.29 -0.0064 -0.0108 1.670 -8 768
Paso 7
y* fr a c c i n m o l d e M e ta no l e n la fa s e va p or
x t y x
0.9978 64.7 0.9987 0.9978
0.8215 66.7 0.8893 0.8215
0.6571 68.7 0.7683 0.6571
0.5033 70.7 0.6351 0.5033
0.3591 72.7 0.4887 0.3591
0.2238 74.7 0.3279 0.2238
0.0963 76.7 0.1518 0.0963
sistema Metanol-Etanol a 1 atm
-0.0064 78.4 -0.0108 -0.0064
1.0000
y 0.9987 64.7
0.9000
0.8893 66.7
0.8000 0.7683 68.7
0.7000 0.6351 70.7
0.4887 72.7
0.6000
0.3279 74.7
0.5000 0.1518 76.7
0.4000 -0.0108 78.4
0.3000
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x fraccin mol de Metanol en la fase lquida

sistema Metanol-Etanol a 1 atm
90
Temperatura C
85
80
75
70
65
60
55
50
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de Metanol
50
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de Metanol
Clculo del equilibrio vapor liquido para la mezcla Metanol Etanol60 C (Ideal T cte.) Clculo del equilibrio va
Paso 1 Paso 1
Pa*9.869233*10^-06=atm
B B
t +C Pa*0.00750062=mm de Hg t+

Methanol CH4O 1 64 to 110 7.97328 1515.14 232.85 64.7 Methanol
Ethanol C2H6O 1 (-2) - 100 8.32109 1718.1 237.52 78.4 Ethanol
Paso 2 Paso 2
Name T P
C mm Hg
Methanol 60 630.24
Ethanol 60 351.85
Paso 3 Paso 3
Paso 4 Paso 4
Paso 5 Paso 5
Paso 6 Paso 6
x p*a p*b Pt y
1.0000 630.24 0.00 630.24 1.0000
0.9000 567.21 35.18 602.40 0.9416
0.8000 504.19 70.37 574.56 0.8775
0.6000 378.14 140.74 518.88 0.7288
0.5000 315.12 175.92 491.04 0.6417
0.4000 252.10 211.11 463.20 0.5442
0.2000 126.05 281.48 407.52 0.3093
0.1000 63.02 316.66 379.68 0.1660
0.0000 0.00 351.85 351.85 0.0000
Paso 7
y* fr a c c in m o l d e He pta no e n la fa s e va po r
y* fr acci n m o l d e M e tan o l e n la fas e va p o r
x y x
1.0000 1.0000 1.0000 630.24
0.9000 0.9416 0.9000 602.40
0.8000 0.8775 0.8000 574.56
0.6000 0.7288 0.6000 518.88
0.5000 0.6417 0.5000 491.04
0.4000 0.5442
Diagrama de 0.4000
equilibrio 463.20
vapor lquido
0.2000 sistema
0.3093 Metanol-Etanol
0.2000 407.52C
a 60
0.1000
1.0000
0.1660 0.1000 379.68
0.0000 0.0000 0.0000 351.85 1.0000
0.9000
0.9000
1.0000
0.8000 630.24
0.8000
0.9582 602.40
0.7000
0.9107 574.56 0.7000
0.7926
0.6000 518.88 0.6000
0.7182 491.04
0.5000 0.5000
0.6295 463.20
0.3891
0.4000 407.52 0.4000
0.2207 379.68 0.3000
0.3000
0.0000 351.85
0.2000
0.2000
0.1000
0.1000
0.0000
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 0.0
x fraccin mol de Metanol en la fase lquida

siste ma M etanol-Etanol a 60 C
Presin en mm de Hg
160
Temperatura C
700.00
600.00 150
500.00 140
400.00
130
300.00
120
200.00
110
100.00
100
0.00
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
x - y* frac. mol Metanol
100.00
100
0.00
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
x - y* frac. mol Metanol
Clculo del equilibrio vapor liquido para la mezcla Heptano-Octano a 2 atm de presin (Ideal P cte.) Clculo del equilibrio vapor liqu
Paso 1

B B

CH4O 1 64 to 110 7.97328 1515.14 232.85 64.7 Methanol
C2H6O 1 (-2) - 100 8.32109 1718.1 237.52 78.4 Ethanol
Paso 2

C K
Methanol 83.37 356.51833 1520
Ethanol 96.79 369.93971 1520
Paso 3
Pt = 1520 mm de Hg
Paso 4
Paso 5
Paso 6
83.37 1520 927 1.0000 1.0000 1.640 1520 0
87.37 1745 1078 0.6628 0.7608 1.618 1156 364
91.37 1996 1251 0.3616 0.4747 1.596 722 798
95.37 2275 1445 0.0902 0.1350 1.574 205 1315
99.37 2586 1664 -0.1563 -0.2660 1.554 -404 1924
103.37 2930 1910 -0.3823 -0.7369 1.534 -1120 2640
107.37 3310 2185 -0.5912 -1.2875 1.515 -1957 3477
96.79 2382 1520 0.0000 0.0000 1.567 0 1520
x t y x
1.0000 83.36833 1.0000 1.0000
0.6628 87.36833 0.7608 0.6628
0.3616 91.36833 0.4747 0.3616
0.0902 95.36833 0.1350 0.0902
-0.1563 99.36833 -0.2660 -0.1563
-0.3823 103.3683 -0.7369 -0.3823
-0.5912 107.3683
sistema -1.2875 a 2-0.5912
Heptano-Octano atm
0.0000 96.78971 0.0000 0.0000
1.0000
y 0.9000
1.0000 83.36833
0.7608 87.36833
0.8000
0.4747 91.36833
0.7000 0.1350 95.36833
0.6000
-0.2660 99.36833
-0.7369 103.3683
0.5000
-1.2875 107.3683
0.4000 0.0000 96.78971
0.3000
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

sistema Heptano-Octano a 2 atm
160
Temperatura C
150
140
130
120
110
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de Heptano
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Heptano-Octano a 50 C (Ideal T cte.) EFECTO DE LA PRESION
1 ATM
fac. Mol
Pa*9.869233*10^-06=atm 1.00149467
B
1) log p = A Pa*1.450377*10^-04=psia 0.8705197
t +C Pa*0.00750062=mm de Hg 0.68753226
0.48601337
CH4O 1 64 to 110 7.97328 1515.14 232.85 64.7 0.15482712
C2H6O 1 (-2) - 100 8.32109 1718.1 237.52 78.4 0.07046544
-0.00311346
1.0000
0.6521
Name T P 0.5019
C mm Hg 0.3648
Methanol 50 413.61 0.2393
Ethanol 50 221.57 0.1240
0.0000
160
0.83055575
0.6744655
0.49193197
150
0.13759363
-0.00652131
140

0.9028
0.7936
130
0.5355
x p*a p*b Pt y 0.3846
120
1.0000 413.61 0.00 413.61 1.0000 0.0000

0.9000 372.25 22.16 394.40 0.9438
0.8000 330.89 44.31 375.20 0.8819 110
0.6000 248.16 88.63 336.79 0.7368
0.5000 206.80 110.78 317.59 0.6512
0.4000 165.44 132.94 298.38 0.5545
100
0.2000 82.72 177.25 259.98 0.3182
0.1000 41.36 199.41 240.77 0.1718
0.0000 0.00 221.57 221.57 0.0000
90

80
0 0.1 0.2 0.3
90
80
0 0.1 0.2 0.3
x y x
1.0000 1.0000 1.0000 413.61
0.9000 0.9438 0.9000 394.40
0.8000 0.8819 0.8000 375.20
0.6000 0.7368 0.6000 336.79
0.5000 0.6512 0.5000 317.59
0.4000Diagrama
0.4000 298.38
vapor lquido
0.2000 sistema
0.2000 259.98
a 50 C
0.1000 0.1718 0.1000 240.77
0.0000
1.0000 0.0000 0.0000 221.57
0.9000
1.0000 413.61
0.8000
0.9582 394.40
0.9107
0.7000 375.20
0.7926
0.6000 336.79
0.7182 317.59
0.5000
0.6295 298.38
0.3891
0.4000 259.98
0.2207
0.3000 240.77
0.0000 221.57
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Presin en mm de Hg
450.00
400.00
350.00
300.00
250.00
200.00
150.00
100.00
50.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
50.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
FECTO DE LA PRESION
y t t x y
1
1.00065526 1.00149467 98.4 123.95 1.0000 1.0000
0.93820956 0.8705197 101 127.95 0.8175 0.9028
0.83055575 0.68753226 105 131.95 0.6521 0.7936 0.9
0.6744655 0.48601337 110 135.95 0.5019 0.6715
0.49193197 0.30986645 115 139.95 0.3648 0.5355
0.8
0.28006615 0.15482712 120 143.95 0.2393 0.3846
0.13759363 0.07046544 123 147.95 0.1240 0.2178
0.7
-0.00652131 -0.00311346 125.8 152.65 0.0000 0.0000
1.0000 1.0000 123.95 0.6

0.9028 0.8175 127.95
0.7936 0.6521 131.95
0.6715 0.5019 135.95 0.5
0.5355 0.3648 139.95
0.3846 0.2393 143.95 0.4
0.2178 0.1240 147.95
0.0000 0.0000 152.65
0.3
98.4
160
101 0.2
105
110
115 0.1
150
120
123
0
125.8
0 0.1
140
123.95
127.95
131.95
130
135.95
139.95
143.95
120
147.95
152.65
110
100
90
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
90
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Clculo del equilibrio vapor liquido para la mezcla Hexano-Heptano a 1 atm de presin (Ideal P cte.)
Paso 1
Pa*9.869233*10^-06=atm
Pvap=10
[ ( )
C1 +
C2
T
+ C 3 ln( T) + C 4 T C 5
] Pa*1.450377*10^-04=psia
Pa*0.00750062=mm de Hg
Name Formula C1 C2 C3 C4 C5 Tneb

C K
Hexane C6H14 104.65 -6995.5 -12.702 1.23810E-05 2 68.7 341.85
Heptane C7H16 87.829 -6996.4 -9.8802 7.20990E-06 2 98.4 371.55
Paso 2
Name Tneb
C K
Hexane 68.7 341.85
Heptane 98.4 371.55
Paso 3
Pt = 760 mm de Hg
Paso 4
Paso 5
Paso 6
68.7 759.18 289.38 1.0017 1.0007 2.623 761 -1
70 790.43 303.14 0.9375 0.9751 2.607 741 19
75 920.03 361.05 0.7137 0.8640 2.548 657 103
80 1065.49 427.49 0.5212 0.7307 2.492 555 205
85 1228.06 503.33 0.3542 0.5723 2.440 435 325
90 1409.05 589.47 0.2081 0.3858 2.390 293 467
95 1609.81 686.87 0.0792 0.1678 2.344 128 632
98.4 1758.33 760.03 0.0000 -0.0001 2.314 0 760
Paso 7
y* fr a c c i n m o l d e H e x a n o e n la fa s e va p o r
x
Diagrama t equilibrio
de y vapor-lquido
x
1.0017 68.7 1.00066
sistema Hexano-Heptano a 11.0017
atm
0.9375 70 0.97509 0.9375
1
0.7137 75 0.86399 0.7137
0.5212 80 0.73067 0.5212
0.9
0.3542 85 0.57228 0.3542
0.8 0.2081 90 0.38576 0.2081
0.7 0.0792 95 0.16784 0.0792
0.0000 98.4 -6E-005 0.0000
0.6
y 0.5 1.000661 68.7

0.4 0.975088 70
0.863993 75
0.3
0.73067 80
0.2
0.572279 85
0.1 0.385761 90
0 0.167839 95
-6E-005
0.1000 98.4
0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x fraccin mol de Hexano en la fase lquida

sistema Hexano-Heptano a 1 atm
110
Temperatura C
100
90
80
70
60
50
40
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de Hexano
40
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de Hexano
Clculo del equilibrio vapor liquido para la mezcla Hexano-Heptano a 75 C (Ideal T cte.)
Paso 1
Pa*9.869233*10^-06=atm
Pvap=10
[ ()
C1 +
C2
T
+ C 3 ln(T) + C 4 T C 5
] Pa*1.450377*10^-04=psia
Pa*0.00750062=mm de Hg
Name Formula C1 C2 C3 C4 C5 Tneb

C K
Hexane C6H14 104.65 -6995.5 -12.702 1.23810E-05 2 68.7 341.85
Heptane C7H16 87.829 -6996.4 -9.8802 7.20990E-06 2 98.4 371.55
Paso 2
Determinar las presiones de vapor de los componentes puros a la T cte.
Name T P
C mm Hg
Hexane 75 920.03
Heptane 75 361.05
Paso 3
Establecer los puntos de concentracin de la fase lquida (frac. Mol) en cantidad de
8 a 10 puntos de concentracin.
Paso 4
Calcular las presiones parciales de las mezclas a las diferentes concentraciones.
Paso 5
Calcular la Presin total y la composicin de y* de la fase vapor.
Paso 6
Determinar la volatilidad relativa.
x p*a p*b Pt y
1.0000 920.03 0.00 920.03 1.0000
0.9000 828.03 36.10 864.14 0.9582
0.8000 736.03 72.21 808.24 0.9107
0.6000 552.02 144.42 696.44 0.7926
0.5000 460.02 180.52 640.54 0.7182
0.4000 368.01 216.63 584.64 0.6295
0.2000 184.01 288.84 472.84 0.3891
0.1000 92.00 324.94 416.95 0.2207
0.0000 0.00 361.05 361.05 0.0000
Paso 7
y* fr a c c i n m o l d e H e x a n o e n la fa s e va p o r
x y
Diagrama dex equilibrio vapor lquido
1.0000 sistema
1.0000 Hexano-Heptano
1.0000 a 75 C
920.03
0.9000 0.9582 0.9000 864.14
0.8000
1.0000 0.9107 0.8000 808.24
0.6000
0.9000
0.7926 0.6000 696.44
0.5000 0.7182 0.5000 640.54
0.8000
0.4000 0.6295 0.4000 584.64
0.2000
0.7000 0.3891 0.2000 472.84
0.1000
0.6000 0.2207 0.1000 416.95
0.0000 0.0000 0.0000 361.05
0.5000
1.0000
0.4000 920.03
0.9582
0.3000 864.14
0.9107 808.24
0.2000
0.7926 696.44
0.1000
0.7182 640.54
0.6295
0.0000 584.64
0.3891 0.1000 0.3000 0.5000
472.84 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.2207 416.95
x fraccin mol de Hexano en la fase lquida
0.0000 361.05

sistema Hexano-Heptano a 75 C
Presin en mm de Hg
1000.00
900.00
800.00
700.00
600.00
500.00
400.00
300.00
200.00
100.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol Hexano
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol Hexano
1000.00
900.00
800.00
700.00
600.00
500.00
400.00
300.00
200.00
100.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
110
100
90
80
70
60
50
40
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
1.0000
0.9000
40
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
1.0000
0.9000
0.8000
0.7000
0.6000
0.5000
0.4000
0.3000
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Benceno y Tolueno a 1 atm de presin (Ideal P cte.)
Paso 1

Presin en mm de Hg
1 5 10 20 40 60 100 200 400 760
Temperatura C
Benzene C6H6 -36.7 -19.6 -11.5 -2.6 7.6 15.4 26.1 42.2 60.6 80.1
Toluene C7H8 -26.7 -4.4 6.4 18.4 31.8 40.3 51.9 69.5 89.5 110.6
PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS ARRIBA DE 1 atm.

Presin en atm
1 2 5 10 20 30 40 50 60
Temperatura C
Benzene C6H6 80.1 103.8 142.5 178.8 221.5 249.5 272.3 290.3
Toluene C7H8 110.6 136.5 178 215.8 262.5 292.8 319
Paso 2
Name Tneb 1 1 Pvap en mm de Hg

C K T en K
T1 T log P 1log P
Benzene 80.1 353.25 =
Toluene 110.6 383.75 1 1 log P 1log P2
T1 T2
Paso 3
Pt = 760 mm de Hg
Paso 4
Paso 5
Paso 6
Benceno Tolueno
t T1 T2 P1 P2 PA T1 T2 P1 P2 PB x y p'a p'b
C C C mm Hg mm Hg mm Hg C C mm Hg mm Hg mm Hg fac. Mol frac. Mol mmHg mm Hg
80.1 760.0 69.5 89.5 200 400 291.6 1.0000 1.0000 2.606 760.00 0.00
82 80.1 103.8 760 1520 806.2 69.5 89.5 200 400 311.3 0.9067 0.9618 2.590 730.96 29.04
84 80.1 103.8 760 1520 857.2 69.5 89.5 200 400 333.1 0.8145 0.9187 2.573 698.19 61.81
88 80.1 103.8 760 1520 967.3 69.5 89.5 200 400 380.7 0.6466 0.8230 2.540 625.45 134.55
92 80.1 103.8 760 1520 1088.5 89.5 110.6 400 760 433.3 0.4986 0.7142 2.512 542.75 217.25
96 80.1 103.8 760 1520 1221.9 89.5 110.6 400 760 491.3 0.3678 0.5913 2.487 449.41 310.59
100 80.1 103.8 760 1520 1368.2 89.5 110.6 400 760 555.5 0.2516 0.4529 2.463 344.23 415.77
104 103.8 142.5 1520 3800 1528.0 89.5 110.6 400 760 626.6 0.1480 0.2976 2.439 226.17 533.83
108 103.8 142.5 1520 3800 1694.1 89.5 110.6 400 760 704.9 0.0557 0.1241 2.403 94.35 665.65
110.6 103.8 142.5 1520 3800 1809.6 760.0 0.0000 0.0000 2.381 0.00 760.00
y* fr a c c i n m o l d e B e n c e n o e n la fa s e va p o r
Paso 7

x t y x sistema Benceno-Tolueno a 1 atm
1.0000 80.1 1.0000 1.0000
0.9067 82 0.9618 0.9067 120
0.8145 84 0.9187 0.8145
Temperatura C
0.6466 88 0.8230 0.6466
Diagrama de equilibrio vapor-lquido 110
0.4986 92 0.7142a 10.4986
sistema Benceno-Tolueno atm
0.3678 96 0.5913 0.3678
1.0000 0.2516 100 0.4529 0.2516
100
0.1480 104 0.2976 0.1480
0.9000
0.0557 108 0.1241 0.0557
0.8000
0.0000 110.6 0.0000 0.0000
90
0.7000
0.6000
0.5000 80
1.0000 80.1
0.4000 0.9618 82
0.3000 0.9187 84 70
0.8230 88
0.2000
0.7142 92
0.1000 0.5913 96 60
0.0000 0.4529 100 0.1000 0.3000 0.5000 0.7000 0.9000
y 0.29760.3000 104 0.5000
0.1000 0.7000 0.9000 0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.1241 108 x - y* frac. mol de Benceno
0.0000 110.6
Clculo del equilibrio vapor liquido para la mezcla Benceno y Tolueno a 95 C (Ideal T cte.)
Paso 1

Presin en mm de Hg
1 5 10 20 40 60 100 200 400 760
Temperatura C
Benzene C6H6 -36.7 -19.6 -11.5 -2.6 7.6 15.4 26.1 42.2 60.6 80.1
Toluene C7H8 -26.7 -4.4 6.4 18.4 31.8 40.3 51.9 69.5 89.5 110.6
PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS ARRIBA DE 1 atm.

Presin en atm
1 2 5 10 20 30 40 50 60
Temperatura C
Benzene C6H6 80.1 103.8 142.5 178.8 221.5 249.5 272.3 290.3
Toluene C7H8 110.6 136.5 178 215.8 262.5 292.8 319
Paso 2
Determinar las presiones de vapor de los componentes puros a la T cte.
t t1 t2 P1 P2 p
Benceno 95 80.1 103.8 760 1520 1187.39
Tolueno 95 89.5 110.6 400 760 476.211
Paso 3
Establecer los puntos de concentracin de la fase lquida (frac. Mol) en cantidad de
8 a 10 puntos de concentracin.
Paso 4
Calcular las presiones parciales de las mezclas a las diferentes concentraciones.
Paso 5
Calcular la Presin total y la composicin de y* de la fase vapor.
Paso 6
Determinar la volatilidad relativa.
x p*a p*b Pt y
1.0000 1187.4 0.00 1187.39 1.0000
0.9000 1068.6 47.62 1116.27 0.9573
0.8000 949.9 95.24 1045.15 0.9089
0.6000 712.4 190.48 902.92 0.7890
0.5000 593.7 238.11 831.80 0.7137
0.4000 475.0 285.73 760.68 0.6244
0.2000 237.5 380.97 618.45 0.3840
0.1000 118.7 428.59 547.33 0.2169
0.0000 0.0 476.21 476.21 0.0000
y * f r a c c i n m o l d e Be n c e n o e n la f a s e v a p o r
Paso 7
x y x
1.0000 1.0000 1.0000 1187.39 Diagrama de equilibrio vapor lquido
sistema Benceno-Tolueno a 75 C
0.9000 0.9573 0.9000 1116.27
Pre sin e n m m de Hg
0.8000 0.9089 0.8000 1045.15
0.6000 0.7890 0.6000 902.92 1400.00
0.5000 0.7137 0.5000 831.80
0.4000 0.6244 0.4000 760.68 1200.00
Diagrama de e quilibrio v apor lquido
0.2000
siste ma Be nce no-Tolue no618.45
0.3840 0.2000 a 95 C
0.1000 0.2169 0.1000 547.33
1.0000 0.0000 0.0000 0.0000 476.21 1000.00
0.9000
0.8000
800.00
0.7000
600.00
0.6000
1.0000 1187.39
0.5000 0.9582 1116.27 400.00
0.4000
0.9107 1045.15
0.7926 902.92
0.3000
0.7182 831.80 200.00
0.2000 0.6295 760.68
0.3891 618.45
0.1000 0.00
0.2207 547.33 0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.0000 476.21 0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.0000 0.10000.2000 0.30000.4000 0.5000 0.60000.70000.80000.9000 1.0000
x fraccin m ol de Be nce no en la fas e lquida x - y* frac. m ol Benceno
Clculo del equilibrio vapor liquido para la mezcla Heptano-Octano a 1 atm de presin (Ideal P cte.)
Paso 1

B

Heptane C7H16 1 -2 to 124 6.89677 1264.9 216.54 98.4
Octane C8H18 1 19 to 152 6.91868 1351.99 209.15 125.8
Paso 2
Name Tneb
C K
Heptane 98.4 371.55
Octane 125.8 398.95
Paso 3
Pt = 760 mm de Hg
Paso 4
Paso 5
Paso 6
98.4 759.36 333.18 1.0015 1.0007 2.279 760 0
101 819.10 362.69 0.8705 0.9382 2.258 713 47
105 918.10 412.13 0.6875 0.8306 2.228 631 129
110 1054.69 481.35 0.4860 0.6745 2.191 513 247
115 1206.55 559.50 0.3099 0.4919 2.156 374 386
120 1374.76 647.38 0.1548 0.2801 2.124 213 547
123 1484.01 705.12 0.0705 0.1376 2.105 105 655
125.8 1591.86 762.58 -0.0031 -0.0065 2.087 -5 765
Paso 7
y* fr a c c i n m o l d e He p ta n o e n la fa s e va p or
x t y x
1.0015 98.4 1.0007 1.0015
0.8705 101 0.9382 0.8705
0.6875 105 0.8306 0.6875
0.4860 110 0.6745 0.4860
0.3099 115 0.4919 0.3099
0.1548 120 0.2801 0.1548
Diagrama de123
0.0705 equilibrio vapor-lquido
0.1376 0.0705
-0.0031 125.8 -0.0065 -0.0031
1.0000
y 1.0007 98.4
0.9000 0.9382 101
0.8000 0.8306 105
0.7000
0.6745 110
0.4919 115
0.6000
0.2801 120
0.5000 0.1376 123
0.4000 -0.0065 125.8
0.3000
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Temperatura C
130
125
120
115
110
105
100
95
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
95
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Heptano-Octano a 100 C (Ideal T cte.) Clculo del equilibrio va
Paso 1 Paso 1
Pa*9.869233*10^-06=atm
B B
t +C Pa*0.00750062=mm de Hg t+

Heptane C7H16 1 -2 to 124 6.89677 1264.9 216.54 98.4 Heptane
Octane C8H18 1 19 to 152 6.91868 1351.99 209.15 125.8 Octane
Paso 2 Paso 2
Name T P
C mm Hg
Heptane 100 795.70
Octane 100 351.10
Paso 3 Paso 3
Paso 4 Paso 4
Paso 5 Paso 5
Paso 6 Paso 6
x p*a p*b Pt y
1.0000 795.70 0.00 795.70 1.0000
0.9000 716.13 35.11 751.24 0.9533
0.8000 636.56 70.22 706.78 0.9006
0.6000 477.42 140.44 617.86 0.7727
0.5000 397.85 175.55 573.40 0.6938
0.4000 318.28 210.66 528.94 0.6017
0.2000 159.14 280.88 440.02 0.3617
0.1000 79.57 315.99 395.56 0.2012
0.0000 0.00 351.10 351.10 0.0000
Paso 7
y* fr acci n m o l d e He p tan o e n la fa s e vap o r
x y x
1.0000 1.0000 1.0000 795.70
0.9000 0.9533 0.9000 751.24
0.8000 0.9006 0.8000 706.78
0.6000 0.7727 0.6000 617.86
0.5000 0.6938 0.5000 573.40
0.4000 0.6017de e quilibrio
Diagrama 0.4000 vapor
528.94
lquido
0.2000 sistema
0.2000 a 75 C
440.02
0.1000 0.2012 0.1000 395.56
1.0000
0.0000 0.0000 0.0000 351.10 1.0000
0.9000
0.9000
1.0000
0.8000
795.70
0.9582 751.24 0.8000
0.9107
0.7000 706.78 0.7000
0.7926
0.6000 617.86 0.6000
0.7182 573.40
0.5000 0.5000
0.6295 528.94
0.3891
0.4000 440.02 0.4000
0.2207 395.56 0.3000
0.3000
0.0000 351.10
0.2000
0.2000
0.1000
0.1000
0.0000
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000 0.0

siste ma He ptano-Octano a 75 C
Presin en mm de Hg
Temperatura C
900.00 160
800.00
150
700.00
140
600.00
500.00 130
400.00
120
300.00
200.00 110
100.00
100
0.00
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
100.00
100
0.00
0.0000
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Heptano-Octano a 2 atm de presin (Ideal P cte.) Clculo del equilibrio vapor liqu
Paso 1

B B

C7H16 1 -2 to 124 6.89677 1264.9 216.54 98.4 Heptane
C8H18 1 19 to 152 6.91868 1351.99 209.15 125.8 Octane
Paso 2

C K
Heptane 123.95 397.10127 1520
Octane 152.65 425.80069 1520
Paso 3
Pt = 1520 mm de Hg
Paso 4
Paso 5
Paso 6
123.95 1520 724 1.0000 1.0000 2.099 1520 0
127.95 1679 809 0.8175 0.9028 2.075 1372 148
131.95 1850 902 0.6521 0.7936 2.051 1206 314
135.95 2034 1002 0.5019 0.6715 2.029 1021 499
139.95 2231 1111 0.3648 0.5355 2.008 814 706
143.95 2443 1230 0.2393 0.3846 1.987 585 935
147.95 2670 1357 0.1240 0.2178 1.967 331 1189
152.65 2955 1520 0.0000 0.0000 1.944 0 1520
x t y x
1.0000 123.9513 1.0000 1.0000
0.8175 127.9513 0.9028 0.8175
0.6521 131.9513 0.7936 0.6521
0.5019 135.9513 0.6715 0.5019
0.3648 139.9513 0.5355 0.3648
0.2393 143.9513 0.3846 0.2393
0.1240
sistema Heptano-Octano a 2 0.1240
147.9513 0.2178 atm
0.0000 152.6507 0.0000 0.0000
1.0000
y 1.0000 123.9513
0.9000
0.9028 127.9513
0.8000 0.7936 131.9513
0.7000 0.6715 135.9513
0.6000
0.5355 139.9513
0.3846 143.9513
0.5000
0.2178 147.9513
0.4000 0.0000 152.6507
0.3000
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Temperatura C
160
150
140
130
120
110
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
100
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
Clculo del equilibrio vapor liquido para la mezcla Heptano-Octano a 50 C (Ideal T cte.) EFECTO DE LA PRESION
1 ATM
fac. Mol
Pa*9.869233*10^-06=atm 1.00149467
B
1) log p = A Pa*1.450377*10^-04=psia 0.8705197
t +C Pa*0.00750062=mm de Hg 0.68753226
0.48601337
C7H16 1 -2 to 124 6.89677 1264.9 216.54 98.4 0.15482712
C8H18 1 19 to 152 6.91868 1351.99 209.15 125.8 0.07046544
-0.00311346
1.0000
0.6521
Name T P 0.5019
C mm Hg 0.3648
Heptane 50 141.63 0.2393
Octane 50 50.31 0.1240
0.0000
160
0.83055575
0.6744655
0.49193197
150
0.13759363
-0.00652131
140
0.9028
0.7936
130
0.5355
x p*a p*b Pt y 0.3846
120
1.0000 141.63 0.00 141.63 1.0000 0.0000

0.9000 127.46 5.03 132.49 0.9620
0.8000 113.30 10.06 123.36 0.9184 110
0.6000 84.98 20.12 105.10 0.8085
0.5000 70.81 25.16 95.97 0.7379
0.4000 56.65 30.19 86.84 0.6524
100
0.2000 28.33 40.25 68.57 0.4131
0.1000 14.16 45.28 59.44 0.2383
0.0000 0.00 50.31 50.31 0.0000
90

80
0 0.1 0.2 0.3
90
80
0 0.1 0.2 0.3
x y x
1.0000 1.0000 1.0000 141.63
0.9000 0.9620 0.9000 132.49
0.8000 0.9184 0.8000 123.36
0.6000 0.8085 0.6000 105.10
0.5000 0.7379 0.5000 95.97
0.4000Diagrama
0.4000 86.84
vapor lquido
0.2000 sistema
0.2000 68.57
a 50 C
0.1000 0.2383 0.1000 59.44
0.0000
1.0000 0.0000 0.0000 50.31
0.9000
1.0000 141.63
0.8000
0.9582 132.49
0.9107
0.7000 123.36
0.7926
0.6000 105.10
0.7182 95.97
0.5000
0.6295 86.84
0.3891
0.4000 68.57
0.2207
0.3000 59.44
0.0000 50.31
0.2000
0.1000
0.0000
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

Presin en mm de Hg
160.00
140.00
120.00
100.00
80.00
60.00
40.00
20.00
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
0.00
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
FECTO DE LA PRESION
y t t x y
1
1.00065526 1.00149467 98.4 123.95 1.0000 1.0000
0.93820956 0.8705197 101 127.95 0.8175 0.9028
0.83055575 0.68753226 105 131.95 0.6521 0.7936 0.9
0.6744655 0.48601337 110 135.95 0.5019 0.6715
0.49193197 0.30986645 115 139.95 0.3648 0.5355
0.8
0.28006615 0.15482712 120 143.95 0.2393 0.3846
0.13759363 0.07046544 123 147.95 0.1240 0.2178
-0.00652131 -0.00311346 125.8 152.65 0.0000 0.0000 0.7
1.0000 1.0000 123.95 0.6

0.9028 0.8175 127.95
0.7936 0.6521 131.95
0.6715 0.5019 135.95 0.5
0.5355 0.3648 139.95
0.3846 0.2393 143.95 0.4
0.2178 0.1240 147.95
0.0000 0.0000 152.65
0.3
98.4
160
101 0.2
105
110
115 0.1
150
120
123 0
125.8 0 0.1
140
123.95
127.95
131.95
130
135.95
139.95
143.95
120
147.95
152.65
110
100
90
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
90
80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Clculo del equilibrio vapor liquido para la mezcla etanol - 1 propanol a 1 atm de presin (Ideal P cte.)
Paso 1

B

Etanol C2H6O 1 (-2) - 100 8.32109 1718.1 237.52 78.4
1 propanol C3H8O 1 2 to 120 7.84767 1499.21 204.64 97.8
Paso 2
Name Tneb
C K
Etanol 78.4 351.55
1 propanol 97.8 370.95
Paso 3
Pt = 760 mm de Hg
Paso 4
Paso 5
Paso 6
78.4 760.00 355.51 1.0000 1.0000 2.138 760 0
80.4 825.85 387.28 0.8499 0.9235 2.132 702 58
82.4 892.66 421.38 0.7185 0.8439 2.118 641 119
84.4 963.94 457.94 0.5970 0.7571 2.105 575 185
86.4 1039.93 497.11 0.4843 0.6627 2.092 504 256
88.4 1120.86 539.03 0.3798 0.5601 2.079 426 334
90.4 1206.99 583.84 0.2827 0.4490 2.067 341 419
92.4 1298.57 631.69 0.1924 0.3287 2.056 250 510
94.4 1395.86 682.75 0.1083 0.1990 2.044 151 609
96.4 1499.15 737.17 0.0300 0.0591 2.034 45 715
97.8 1575.17 760.00 0.0000 0.0000 2.073 0 760
Paso 7
y* fr a c c in m ol de e ta nol e n la fa s e va por
x t y x
1.0000 78.4 1.0000 1.0000
0.8499 80.4 0.9235 0.8499
0.7185 82.4 0.8439 0.7185
sistema etanol - 1 propanol a 1 atm0.5970
0.5970 84.4 0.7571
0.4843 86.4 0.6627 0.4843
1.0000 0.3798 88.4 0.5601 0.3798
0.2827 90.4 0.4490 0.2827
0.9000
0.1924 92.4 0.3287 0.1924
0.8000 0.1083 94.4 0.1990 0.1083
0.0300 96.4 0.0591 0.0300
0.7000
0.0000 97.8 0.0000 0.0000
0.6000
0.5000 1.0000 78.4

0.9235 80.4
0.4000
0.8439 82.4
0.3000 0.7571 84.4
0.6627 86.4
0.2000
0.5601 88.4
0.1000 0.4490 90.4
0.0000 0.3287 92.4
0.1990 0.300094.4 0.5000
0.1000 0.7000 0.9000
0.0000 0.2000
0.0591 0.4000
96.4 0.6000 0.8000 1.0000
x fraccin mol de etanol en la fase lquida
0.0000 97.8

sistema etanol - 1 propanol a 1 atm
Temperatura C
100
95
90
85
80
75
70
0.1000 0.3000 0.5000 0.7000 0.9000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x - y* frac. mol de etanol
DESTILACIN POR ARRASTRE DE VAPOR
B
1) log p = A
Mezcla Agua-Tolueno t +C
Compound Formula Range, C A B C tneb C

Water H2O 0 to 60 8.1332 1762.39 235.66 100.0
60 to 120 7.97208 1668.84 227.7 100.0
Octano C8H18 -6 to 137 6.91868 1351.99 209.15 110.6
Temperatura PA PB Pt dif a 760

C mm Hg mm Hg
80.00 353.57829 174.9608 528.53909 231.461
81.00 368.17537 181.57484 549.75021 210.250
82.00 383.27493 188.39088 571.66581 188.334
83.00 398.89054 195.41348 594.30402 165.696
84.00 415.03601 202.64725 617.68326 142.317
85.00 431.7254 210.09687 641.82227 118.178
86.00 448.97304 217.76707 666.74011 93.260
87.00 466.7935 225.66264 692.45615 67.544
88.00 485.20163 233.78844 718.99007 41.010
89.00 504.21252 242.14936 746.36188 13.638
89.10 506.14735 242.99857 749.14592 10.854
89.20 508.08838 243.85019 751.93857 8.061
89.30 510.03562 244.70422 754.73984 5.260
89.40 511.98908 245.56067 757.54975 2.450
89.50 513.94879 246.41954 760.36833 -0.368
89.47 513.26218 246.11866 759.38084 0.619
89.49 513.65444 246.29056 759.94499 0.055
89.50 513.85066 246.37654 760.2272 -0.227
89.51 514.04694 246.46255 760.50949 -0.509
89.52 514.24329 246.54858 760.79187 -0.792
y*=PA/Pt = 0.67591 gr mol de Agua en la fase vapor ("Heteroazeotropo")
1-y* = 0.32409 gr mol de Tolueno (Destilan a 84.4 C)
Si se ponen 20 gr de agua y 80 gr de Tolueno, describir el fenmeno que ocurre
800 gr H2O gr mol = 44.414835 gr mol de agua

18 gr
500 gr octano gr mol = 4.3859649 gr mol de Tol

114 gr
44.41483 gr mol Agua 0.32408998 gr mol Tol = 21.29633 gr mol Tol necesarios para que el agua arras
0.67591002 gr mol Agua solo hay 4.38596491
4.38596 gr mol de Tol 0.67591002 gr mol Agua = 9.1472055 gr mol de agua que se llevarn todo el tol y q
0.32408998 gr mol Tol al final 35.2676291
roazeotropo")
cesarios para que el agua arrastre, pero

por lo tanto.
a que se llevarn todo el tol y quedarn
gr mol de Agua que ebullirn a 100 C
B
1) log p = A
Mezcla Agua-Tolueno t +C

Water H2O 0 to 60 8.1332 1762.39 235.66 100.0
60 to 120 7.97208 1668.84 227.7 100.0
Toluene C7H8 -6 to 137 6.95464 1344.8 219.48 110.6

C mm Hg mm Hg
80.00 353.57829 291.199 644.77729 115.223
81.00 368.17537 301.39368 669.56905 90.431
82.00 383.27493 311.87406 695.149 64.851
83.00 398.89054 322.64595 721.53649 38.464
84.00 415.03601 333.71521 748.75121 11.249
84.05 415.85744 334.27658 750.13402 9.866
84.10 416.68023 334.83871 751.51895 8.481
84.15 417.50439 335.40161 752.906 7.094
84.20 418.32992 335.96526 754.29518 5.705
84.25 419.15681 336.52968 755.68648 4.314
84.30 419.98506 337.09485 757.07992 2.920
84.35 420.81469 337.66079 758.47549 1.525
84.36 420.98078 337.77407 758.75486 1.245
84.37 421.14693 337.88738 759.03431 0.966
84.38 421.31313 338.00072 759.31385 0.686
84.39 421.47938 338.11409 759.59348 0.407
84.40 421.6457 338.22749 759.87319 0.127
84.41 421.81206 338.34093 760.15299 -0.153
84.42 421.97848 338.45439 760.43287 -0.433
84.43 422.14496 338.56788 760.71284 -0.713
1-y* = 0.4451104 gr mol de Tolueno (Destilan a 84.4 C)
20 gr H2O gr mol = 1.1103709 gr mol de agua

18 gr
80 gr Tolueno gr mol = 0.8695652 gr mol de Tol

92 gr
1.11037 gr mol Agua 0.44511045 gr mol Tol = 0.8906956 gr mol Tol necesarios para que el agua arras
0.55488955 gr mol Agua solo hay 0.86956522
0.86957 gr mol de Tol 0.55488955 gr mol Agua = 1.0840291 gr mol de agua que se llevarn todo el tol y q
0.44511045 gr mol Tol al final 0.02634181
roazeotropo")
C7H8 92
cesarios para que el agua arrastre, pero

por lo tanto.
a que se llevarn todo el tol y quedarn
gr mol de Agua que ebullirn a 100 C
B
1) log p = A
Mezcla Agua-Etil benceno t +C

Water H2O 0 to 60 8.1332 1762.39 235.66 100
60 to 120 7.97208 1668.84 227.7 100
Etil benceno C8H10 26 - 164 6.95719 1424.255 213.21 136.2

C mm Hg mm Hg
75.00 287.67269 103.62475 391.29744 368.70256
77.00 312.67002 112.07782 424.74784 335.25216
78.00 325.83856 116.51246 442.35102 317.64898
79.00 339.47037 121.0904 460.56077 299.43923
80.00 353.57829 125.81513 479.39342 280.60658
81.00 368.17537 130.69021 498.86558 261.13442
82.00 383.27493 135.71923 518.99416 241.00584
83.00 398.89054 140.90583 539.79637 220.20363
84.00 415.03601 146.25373 561.28974 198.71026
85.00 431.7254 151.76669 583.49208 176.50792
86.00 448.97304 157.4485 606.42154 153.57846
86.50 457.81075 160.35394 618.16468 141.83532
86.75 462.28388 161.823 624.10688 135.89312
91.85 561.83773 194.27634 756.11408 3.8859233
91.90 562.8957 194.6189 757.51461 2.4853929
91.95 563.95534 194.96195 758.91729 1.0827108
91.99 564.80424 195.23675 760.04099 -0.0409859
1-y* = 0.2568766 gr mol de Etil benceno (Destilan a 91.99 C)
PM moles gr
AGUA 18 0.7431 13.3762 246 500
Etil benceno 106 0.2569 27.2289 500 1017.8106
1.0000 40.6051
Relacin Agua/Etil Benceno gr/gr = 0.4913

EJEMPLO COCON-TOJO
Una mezcla lquida de hexano y benceno que contiene 40 % en moles de hexano
se somete a destilacin cerradaa la presin atmosfrica y temperatura constante
75
hasta que el 40 % del lquido inicial pasa a la fase vapor. Determnese la temperatura
a que ha de realizarse la operacin y las composiciones del lquido residual en el vapor.
separado.
74.5
los datos de equilibrio para el hexano-benceno a 1 atm son los siguientes (expresadas
las composiciones en fraccin molar):
74
x y t
0 0 80.1 L yxo
0.05 0.111 78.5 =
0.1 0.191 77.1
V xox 73.5
0.15 0.258 76 Si V= 0.4 frac. de F

0.2 0.317 75.1 L= 0.6 frac. de F
0.25 0.371 74.4 entonces 73
0.3 0.422 73.7 L/V= 1.5
0.35 0.47 72.7
72.5
0.4 0.518 72.2 L yxo
0.45 0.563 71.5 = =1. 5
0.5 0.602 71
V xox
0.55 0.64 70.6 La y* ser mayor que 0.4 frac. mol 72
0.6 0.676 70.3 y x menor que 0.4 frac. mol
0.65 0.71 69.9
0.7 0.744 69.5 Por lo tanto la temperatura estara entre 71.5
0.75 0.782 69.3 72.2 C y 74 C
0.8 0.822 69.1
0.85 0.862 68.9 71
0.9 0.906 68.8 Si xo= 0.4 frac. mol hexano 0.2 0.25
0.95 0.952 68.7
0.97 0.971 68.7
1 1 68.7
Graficamente L/V
t C x y
72.5 0.37 0.498 3.3
72.9 0.347 0.472 1.4
72.8 0.35 0.478 1.6
72.85 0.348 0.475 1.4
72.83 0.349 0.476 1.5
1
f(x) = 0.9119824367x^3 - 1.7346092365x^2 + 1.8100718139x + 0.0154348436
R = 0.9995850705
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x y t
75
0 0 80.1 0
0.05 0.111 78.5 0.05
0.1 0.191 77.1 0.1
74.5
0.15 0.258 76 0.15
0.2 0.317 75.1 0.2
0.25 0.371 74.4 0.25
74
0.3 0.422 73.7 0.3
0.3584 0.47 72.7 0.35
0.397 0.518 72.2 0.4
73.5
0.45 0.563 71.5 0.45
0.5 0.602 71 0.5
0.55 0.64 70.6 0.55
73 0.6 0.676 70.3 0.6
0.65 0.71 69.9 0.65
0.7 0.744 69.5 0.7
72.5 0.75 0.782 69.3 0.75
0.8 0.822 69.1 0.8
0.85 0.862 68.9 0.85
72 0.9 0.906 68.8 0.9
0.95 0.952 68.7 0.95
0.97 0.971 68.7 0.97
71.5 1 1 68.7 1
0 80.1
71 0.111 78.5
0.2 0.25 0.3 0.35 0.4
0.191 0.45 0.5 0.55
77.1 0.6
0.258 76
0.317 75.1
0.371 74.4
0.422 73.7
0.484 72.7
0.518 72.2
0.563 71.5
0.602 71
0.64 70.6
0.676 70.3
0.71 69.9
0.744 69.5
0.782 69.3
0.822 69.1
0.862 68.9
0.906 68.8
0.952 68.7
0.971 68.7
1 68.7
PROBLEMA 5.4 OCON TOJO
En una caldera cerrada est contenida una mezcla benceno-tolueno de composicin 0.35
fraccin molar de benceno. La caldera tiene capacidad suficiente para que en el equilibrio
a una atm el 20 % de los moles contenidos en la carga inicial se encuentren en la fase vapor.
Determinese el volumen de la caldera por mol de carga.
F= 1 mol xo= 0.35 f mol bz

V= 0.2 mol
L= 0.8 mol
Datos del equilibrio
t x y La temperatura estara entre los 96.6 C

C fac. Mol frac. Mol y los 102.7 C
80.1 1.0000 1.0000 2.606
82 0.9067 0.9618 2.590 L/V= 4
84 0.8145 0.9187 2.573
88 0.6466 0.8230 2.540 L yxo
92 0.4986 0.7142 2.512 =
96 0.3678 0.5913 2.487 V xox
100 0.2516 0.4529 2.463
104 0.1480 0.2976 2.439
108 0.0557 0.1241 2.403 PV=nRT
110.6 0.0000 0.0000 2.381
P= 1 atm
T x y L/V T= 371.05 K
R= 0.08205784 lt atm / K mol
100 0.2516 0.4529 1.04573 n= 0.2
99 0.28 0.49 2
98.5 0.29 0.507 2.61667 R= 8.3145107 J/K mol
98.2 0.303 0.518 3.57447 J* 0.00986923 lt atm
98.1 0.305 0.52 3.77778
98.05 0.307 0.523 4.02326 V= 6.08951256 lt/mol de F
98 0.309 0.526 4.29268
106
105
104
103
102
101
100
99
98
97
96
0.1500 0.2000 0.2500 0.3000 0.3500 0.4000 0.4500 0.5000 0.5500 0.6000
t
1.0000 x y
C fac. Mol frac. Mol
0.9000
80.1 1.0000 1.0000 2.606 1.0000
0.8000 82 0.9067 0.9618 2.590 0.9067
84 0.8145 0.9187 2.573 0.8145
0.7000
88 0.6466 0.8230 2.540 0.6466
0.6000
92 0.4986 0.7142 2.512 0.4986
96 0.3678 0.5913 2.487 0.3678
0.5000 100 0.2516 0.4529 2.463 0.2516
104 0.1480 0.2976 2.439 0.1480
0.4000
108 0.0557 0.1241 2.403 0.0557
0.3000 110.6 0.0000 0.0000 2.381 0.0000
0.2000
0.1000
1.0000 80.1
0.9067
0.0000 82
0.0000 0.1000 0.2000 0.3000 0.4000 0.5000 0.6000 0.7000 0.8000 0.9000 1.0000
0.8145 84
0.6466 88
0.4986 92
0.3678 96
0.2516 100
0.1480 104
0.0557 108
0.0000 110.6
1.0000 80.1
0.9618 82
0.9187 84
0.8230 88
0.7142 92
0.5913 96
0.4529 100
0.2976 104
0.1241 108
0.0000 110.6
10 kg de una mezcla metanol-agua de composicin 50% en peso, se destila en operacin
abierta hasta que la ltima gota del vapor condensado tenga igual composicin que la
mezcla de partida. Determinese el destilado y su composicin global.
F= 10 kg 0.43403 kg mol
xo= 50 % w 36 % mol
% peso=kg PM mol % mol

metanol 50 32 1.5625 36
agua 50 18 2.7778 64
100 23.04 4.3403
x y 1/(y-x) alfa 0.8

0 0 0
0.100 0.417 0.100 3.1546 6.4374
0.200 0.579 0.200 2.6385 5.5012 0.7
0.300 0.669 0.300 2.7100 4.7160
0.400 0.729 0.400 3.0395 4.0351
0.500 0.780 0.500 3.5714 3.5455 0.6
0.600 0.825 0.600 4.4444 3.1429
0.700 0.871 0.700 5.8480 2.8937
0.800 0.915 0.800 8.6957 2.6912 0.5
0.900 0.959 0.900 16.9492 2.5989

1.000 1.000 1.000
0.4
alfa prom 3.6666
alfa-1 2.6666
0.3
Fo= 0.43403 kg mol

xo= 0.360 frac. mol 0.2
x= 0.082

Fo 1 xo 1x
y*= 0.36
16.47822
L
=
x 1xo ( ) 0.1
Fo/L= 2.85990
L= 0.15176 kg mol 0
V= 0.28226 kg mol 0 0.0
y*= 0.50947061
PM
metanol 0.50947061 32 16.3030595 64.86820677
agua 0.49052939 18 8.82952904 35.13179323
1 25.1326 25.1325885 100
V= 7.09403427
12
4
16
32
6.1 kg
74 % w metanol
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5
Se pretende recuperar por destilacin diferencial el 80% del etanol contenido en una disolucin acuosa
cuya composicin es 30% en peso de etanol. Calclese la composicin del lquido residual.
los datos de equilibrio para esta mezcla son:
x y alfa
0.01 0.103 0.01 11.3679
0.03 0.235 0.03 9.9325
0.05 0.325 0.05 9.1481
0.1 0.444 0.1 7.1871
0.15 0.496 0.15 5.5767
0.2 0.529 0.2 4.4926
0.25 0.552 0.25 3.6964
0.3 0.573 0.3 3.1311 7.3430
0.35 0.592 0.35 2.6947
0.4 0.613 0.4 2.3760
0.45 0.632 0.45 2.0990
0.5 0.652 0.5 1.8736
0.55 0.673 0.55 1.6839
0.6 0.697 0.6 1.5336
0.65 0.723 0.65 1.4054
0.7 0.753 0.7 1.3065
0.75 0.783 0.75 1.2028
0.8 0.818 0.8 1.1236
0.85 0.856 0.85 1.0490
0.87 0.873 0.87 1.0272
0.8943 0.8943 0.8943 1.0000 3.5670
Base Fo= 100 kg 4.5410628 kg mol= Fo

xo= 30 % peso
kg PM kg mol % mol
etanol 30 46 0.652174 14.3617 =xo
agua 70 18 3.888889 85.6383
100 22.0213 4.541063 100.0000
Fo(xo)= 0.65217391 mol de etanol que entran

80 % de etanol que entra y se destila
V(y*)= 0.52173913 mol de etanol en el destilado
L(x)= 0.13043478 mol de etanol en el lquido residual

Lo=
V=
x y alfa 1(y-x) dx*(1/(x-x)

0.01 0.103 0.01 11.3679 10.753 0.2150538
0.03 0.235 0.03 9.9325 4.878 0.0975610 0.15630737
0.05 0.325 0.05 9.1481 3.636 0.1818182 0.13968958
0.1 0.444 0.1 7.1871 2.907 0.1453488 0.16358351
0.15 0.496 0.15 5.5767 2.890 0.1445087 0.14492875
0.2 0.529 0.2 4.4926 3.040 0.1519757 0.14824218
0.25 0.552 0.25 3.6964 3.311 0.1655629 0.1587693
0.3 0.573 0.3 3.1311 3.663 0.1831502 0.17435655
0.35 0.592 0.35 2.6947 4.132 0.2066116 0.19488088
0.4 0.613 0.4 2.3760 4.695 0.2347418 0.22067668
0.45 0.632 0.45 2.0990 5.495
0.5 0.652 0.5 1.8736 6.579
0.55 0.673 0.55 1.6839 8.130
0.6 0.697 0.6 1.5336 10.309
0.65 0.723 0.65 1.4054 13.699
0.7 0.753 0.7 1.3065 18.868
0.75 0.783 0.75 1.2028 30.303
0.8 0.818 0.8 1.1236 55.556
0.85 0.856 0.85 1.0490 166.667
0.87 0.873 0.87 1.0272 333.333
0.8943 0.8943 0.8943 1.0000 #DIV/0!
solucin acuosa
1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
100 L
Area
1.08587724
0.92956987
0.78988029
0.62629678
0.48136802
0.33312585
0.17435655

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Table 2-6.

Vapor Pressure of Inorganic and Organic Liquids

PERRYS CHEMICAL ENGINEERS' HANDBOOK T en K Pa*9.869233*10^-06=atm

PERRYS CHEMICAL ENGINEERS' HANDBOOK 1 1 Pvap en mm de Hg

PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS HASTA 1 atm.

PERRY Y CHILTON. MANUAL DEL INGENIERO QUIMICO

PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS HASTA 1 atm.

LANGE'S HANDBOOK OF CHEMISTRY

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Compound Formula State Equation Range, C A B C tneb C

Compound Formula State Equation Range, C A B C tneb C Compound

Paso 7 Construir los diagrama

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Formula State Equation Range, C A B C tneb C Compound

Name Tneb Presin cte

1.0000 271.29 0.00 271.29 1.0000 0.0000

0.6000 162.77 14.07 176.84 0.9205

Construir los diagramas de equilibrio vap-liq y vap-liq-temp, x-y y t-x-y respectivamente

Diagrama de equilibrio vapor lquido

1.0000 1.0000 123.95 0.6

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Compound Formula State Equation Range, C A B C tneb C

Compound Formula State Equation Range, C A B C tneb C Compound

Paso 7 Construir los diagrama

Diagrama de equilibrio vapor lquido

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Formula State Equation Range, C A B C tneb C Compound

Name Tneb Presin cte

Diagrama de equilibrio vapor lquido

Calcular la Presin total y la composicin de y* de la fase vapor. 1.0000

0.6000 162.77 14.07 176.84 0.9205

Construir los diagramas de equilibrio vap-liq y vap-liq-temp, x-y y t-x-y respectivamente

Diagrama de equilibrio vapor lquido

1.0000 1.0000 123.95

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Compound Formula State Equation Range, C A B C tneb C

Diagrama de equilibrio vapor lquido

Compound Formula State Equation Range, C A B C tneb C Compound

Diagrama de equilibrio vapor lquido

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Formula State Equation Range, C A B C tneb C Compound

Name Tneb Presin cte

Diagrama de equilibrio vapor lquido

Calcular la Presin total y la composicin de y* de la fase vapor. 1.0000

1.0000 413.61 0.00 413.61 1.0000 0.0000

Construir los diagramas de equilibrio vap-liq y vap-liq-temp, x-y y t-x-y respectivamente

Diagrama de equilibrio vapor lquido

1.0000 1.0000 123.95 0.6

Name Formula C1 C2 C3 C4 C5 Tneb

y 0.5 1.000661 68.7

Diagrama de equilibrio vapor lquido

Name Formula C1 C2 C3 C4 C5 Tneb

Diagrama de equilibrio vapor lquido

PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS HASTA 1 atm.

PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS ARRIBA DE 1 atm.

Name Tneb 1 1 Pvap en mm de Hg

Diagrama de equilibrio vapor lquido

PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS HASTA 1 atm.

PRESIONES DE VAPOR DE COMPUESTOS ORGANICOS E INORGANICOS ARRIBA DE 1 atm.

Presin de Vapor p en mm de Hg Pa*9.869233*10^-06=atm

Compound Formula State Equation Range, C A B C tneb C

Diagrama de equilibrio vapor lquido

Compound Formula State Equation Range, C A B C tneb C Compound

PERRYS CHEMICAL ENGINEERS' HANDBOOK T en K Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm

Presin de Vapor p en mm de Hg Pa9.86923310^-06=atm