Chemistry Marking scheme

Delhi - 2016
Set 56/1/2/D
Q.No VALUE POINTS MARKS
1 2,4,6-Tribromoaniline / 2,4,6-Tribromobenzenamine 1
2 Like Charged particles cause repulsion/ Brownian motion/ solvation 1
3 CH3CH2CH(Cl)CH3 ; secondary halide/ 20 carbocation is more ,
stable
4 NH3 1
5 Ferromagnetism 1
6 (i) zero order , bimolecular/ unimolecular ,
(ii) mol L-1 s-1 1
7

8 (i) Mercury cell

(ii) Fuel cell
(iii) Lead storage battery
(iv) Dry cell
9 A-Na2CrO4
B-Na2Cr2O7
C-K2Cr2O7
Use- strong oxidising agent / as a primary standard in
volumetric analysis
OR
9 8MnO4 + 3S2O32 + H2O > 8MnO2 + 6SO42 + 2OH 1

Cr2O72- + 14 H+ + 3 Sn2+ 2 Cr3+ + 3 Sn4+ + 7 H2O 1

10 (i) [Cr(H2O)5Cl]Cl2.H2O 1
(ii) pentaaquachloridoChromium(III) chloride monohydrate (or 1
chloride hydrate)
(no deduction for not writing hydrate)
11 (i)
Adsorption Absorption
Surface phenomena Bulk phenomena
The accumulation of The substance is uniformly
molecular species distributed throughout
at the surface rather than in the bulk of the solid
the bulk of a solid or liquid is essentially a bulk
termed adsorption. phenomenon.
(any one difference) 1
 c. Buna-S<polystyrene<Terylene 1

OR
17
1

18 (i) -D glucose and -D-galactose / glucose and galactose ,

(ii) water soluble ,excreted out of the body 1
(iii)In nucleotide , phosphoric acid/phosphate group attached to
the nucleoside / structures of both nucleotide and nucleoside / 1
nucleotide= base +sugar + phosphate group, nucleoside= base
+sugar.
19 d2sp3 , Paramagnetic, low spin 1, ,

20 (i) ability of oxygen to form multiple bond/ p-d bond. 1

(ii) Partially filled d orbitals / due to comparable energies of ns 1
and (n-1) d orbitals
(iii) due to relative stabilities of the f0, f7 and f14 occupancies of
1
the 5f orbitals/ Comparable energies of 7s,6d,5f orbitals.
21 (i) CH3 OH , (CH3)3 C-I 1
(ii) CH3 CH2CH2OH
1
1
(iii)
22 (i) C6H5NH2, C6H5N2+Cl- , C6H5I ++
++
(ii) CH3CN, CH3CH2NH2, CH3 CH2NC
23 (i)Aware, concerned or any other correct two values. +
(ii) Side effects, unknown health problems 1
(iii) Neurologically active drugs/ stress relievers 1
Example- valium, equanil +
(or any other correct two example)
24 a) Tf = i Kf wb x1000 1
M b x wa
1
Tf = 3 ( 1.861.9/9550) 1000
= 2.23K
Tf -Tf = 273.15- 2.23 / 273- 2.23
 1
Tf = 270.92 K or 270.77K

b)
i)2M glucose ; More Number of particles / less vapour pressure +
ii)Reverse Osmosis 1

OR
24

a)
Tf = Kf wb x1000
Mb x wa 1

0.383 =( 3.832.56/M100) 1000 1

M=256
S x = 256
32 x= 256
x=8 1
b)
i)Shrinks 1
ii)swells 1
25 a)
i. Endothermic compound / decomposition of ozone is exothermic 1
in nature and G is negative / decomposition of ozone is
spontaneous.
ii. Exists as [PCl4]+[PCl6]- 1
iii. Shows only -1 oxidation state / most electronegative element/ 1
absence of d-orbitals

b)
i) ii)
1,1

OR
25 (i)
F2 is the stronger oxidising agent than chlorine 4=2
(a) low enthalpy of dissociation of F-F bond
(b) less negative electron gain enthalpy of F
(c) high hydration enthalpy of F- ion

ii) low temperature, high pressure and presence of catalyst

iii) 1
a) H3PO4< H3PO3< H3PO2 1
b) BiH3< SbH3< AsH3< PH3< NH3 1
26 A -C6H5COCH3 1
B-C6H5 CH2 CH3 1
C-C6H5COOH 1
D ,E -C6H5COONa , CHI3 1+1

OR
26 a)HCHO + HCHO conc NaOH HCOONa +CH3OH 1
(or any other example)
b)CH3CH=N-NHCONH2 1
c) Stronger -I effect of fluorine ,stronger acid less pka / strong 1
electron withdrawing power of fluorine.
d)CH3CH=CHCH2 CHO 1
e)Silver mirror formed on adding ammonical silver nitrate to 1
propanal and not with propanone (or any other correct test)