Advanced Chemistry Final Assessment

30 perguntas

1
point

1. Determine G for the following reaction at 25 C.

AgCl(s) Ag(aq) + Cl(aq) Ksp = 1.77 105

27.1 kJ

253 kJ

1840 kJ

48.1 kJ

1
point

2. For the reaction A + B 2C, the activation energy is 145 kJ/mol. If the rate constant is
0.0012 M1s1 at 450 C, determine the rate constant at 650 C.
0.22 M1s1

190 M1s1

0.0019 M1s1

2.5 M1s1

1
point

3. What is S univ given Ssys = 192 J/K and Ssurr = 284 J/K?

92 J/K

476 J/K

476 J/K

92 J/K

1
point

4. For the reaction A products, a plot of ln[A] versus time gives a straight line with slope
= 6.5 102 s1. Starting with 0.11 M of A, determine the half-life for the reaction and the
quantity of A that remains after 3 half-lives.
 11 s; 0.014 M

11 s; 0.023 M

150 s, 0.023 M

150 s, 0.014 M

1
point

5. Given the following information, what is the equilibrium constant for this reaction?
2A + 3D 3B + 2C

A B + C Kc = 1.56

B 3D Kc = 2.13 10-3

1.14 103

3.32 10-3

732

5.36 105

1
point

6. The reaction A + B 2C is second-order with respect to A and zeroth-order with

respect to B. What is the effect on the rate of the reaction if the concentration of A is
doubled and the concentration of B is doubled?
The rate will be quadrupled (increased by a factor of 4).

The rate will be the same.

The rate will be doubled.

The rate will be increased by a factor of 16.

1
point

7. Which of the following acid/base titrations will have a pH < 7 at the equivalence point?
HCl and CH3NH2

HBr and KOH

HF and Ba(OH)2
 HNO3 and LiOH

1
point

8. Consider the following reaction:

2H2O2(aq) 2H2O(l) + O2(g)

At some point in the reaction, the rate of disappearance for hydrogen peroxide, H2O2, is
0.250 M/s. What is the rate of appearance of oxygen gas?

0.125 M/s

0.250 M/s

0.500 M/s

0.750 M/s

1
point

9. Calculate the pH of a solution formed by the addition of 0.0010 moles of HCl to 100.0
mL of

0.150 M CH3NH2 / 0.100 M CH3NH3Cl, where Kb(CH3NH2) = 4.4 104.

10.75

4.40

10.60

10.32

1
point

10. The following reaction is allowed to proceed until equilibrium is established. Which
statement is false?

C3H8(g) + 5O2(g) 3CO2(g) + 4H2O(g) G = 2074.2 kJ

When equilibrium is established, G = 0.0 kJ

When equilibrium is established, the partial pressures of CO2 and H2O will both be

greater than the partial pressures of C3H8 and O2.

When equilibrium is established, G = 0.0 kJ
 If the reaction initially has one mole of each gas present in the reaction chamber, the

reaction will proceed toward the products to reach equilibrium.

1
point

11. Which of the following statements is true?

The concentrations of the products are always greater than the concentrations of the

reactants for a system at chemical equilibrium.

In a system at chemical equilibrium, the rates of the forward and reverse reactions are

equal.
A system at chemical equilibrium has equal concentrations of all reactants and

products.
In a system at chemical equilibrium, the rate of the forward reaction is greater than the

rate of the reverse reaction.

1
point

12. Identify the conjugate acid of NH . 3

NH3(aq) + H2O(l) NH4+(aq) + OH-(aq)

NH4+

NH3

H2O

OH-

1
point

13. A sample of 1.50 M NO (g) is placed in a reaction vessel and allowed to reach
2

equilibrium. What is the concentration of O2(g) at equilibrium?

2NO2(g) 2NO(g) + O2(g) Kc = 3.33 10-7

5.72 10-3 M

0.135 M

4.33 10-4 M

3.53 10-4 M

1
point
14. Calculate the pH of a solution prepared by the addition of 10.0 mL of 0.20 M
CH3COOH and 15.0 mL of 0.065 M NaOH. Ka(CH3COOH) = 1.8 105.
4.71

4.74

4.85

5.18

1
point

15. Find G sys at 20 C when H = 203 kJ and S = 325 J/K.

298 kJ

67.0 kJ

108 kJ

95.4 kJ

1
point

16. Identify the Lewis base in the reaction.

N(CH3)3

BF3

BF3N(CH3)3

There is not a Lewis base in the reaction.

1
point

17. Select the solution that would resist a change in pH upon the addition of a small
amount of acid or base.
A solution containing 0.05 M NH3 and 0.10 M NH4Cl.

A solution containing 0.10 M NaCl and 0.10 M HCl.

 A solution containing 0.10 M HCl and 0.05 M NaOH.

A solution containing 0.10 M NaOH and 0.75 M NaCl.

1
point

18. What is the pH of a 0.250 M solution that is 2.31% ionized?

2.24

1.64

0.602

0.238

1
point

19. If [SO ] = 0.250 M, [O ] = 0.100 M, and [SO ] = 1.50M, which way will the reaction
2 2 3

proceed?

SO2(g) + O2(g) SO3(g) Kc = 12.5

The reaction will proceed to the left because Q > K.

The reaction will proceed to the left because Q < K.

The reaction will proceed to the right because Q > K.

The reaction will proceed to the right because Q < K.

1
point

20. For which reaction is K p > Kc at 125 C? Assume that Kc is greater than 1 for all of the
reactions.
H2O(l) H2O(g)

CO2(g) + H2O(g) CO(g) + H2O(l)

N2(g) + 3H2(g) 2NH3(g)

H2(g) + Cl2(g) 2HCl(g)

1
point

21. What changes will result in a loss of color for the following reaction?
N2O4(g) 2NO2(g) H > 0
colorless brown

I. Increasing temperature

II. Decreasing volume

III. Addition of N2

Only II

Only I

Only III

Both I and II

1
point

22. What is the pH of a 0.350 M NH Cl solution? K

4 b (NH3) = 1.8 10-5

4.86

9.71

5.20

3.10

1
point

23. Which of the following lists the acids in order of decreasing acidic strength (strongest
to weakest)?
HI, HBr, HCl, HF

HClO, HClO2, HClO3, HClO4

HOI, HOBr, HOCl, HOF

H2O, H2S, H2Se, H2Te

1
point

24. Which statement is true concerning the addition of NaCl to a saturated solution of
AgCl?

Ksp(AgCl) = 1.77 1010.

The molar solubility of AgCl will decrease.

 The molar solubility of AgCl will increase.

The solubility product, Ksp, will increase.

The solubility product, Ksp, will decrease.

1
point

25. Calculate the standard entropy change (S) for the reaction using the standard
entropy values provided in the table below.

2NH3(g) + 2O2(g) N2O(g) + 3H2O(g)

Substance S(J/mol.K)
NH3(g) 192.8
O2(g) 205.2
N2O(g) 220.0
H2O(g) 188.8
9.6 J/K

839.6 J/K

11.0 J/K

12.6 J/K

1
point

26. Calculate the value of K sp for a salt, MX2, given that the molar solubility is 1.9 10
2
M.
2.7 105 M

3.5 104 M

7.4 104 M

1.7 105 M

1
point

27. Consider the following two-step mechanism:

Step 1: A + B C

Step 2: A + C B + D
Select the false statement:

There are two intermediates in the mechanism.

The overall reaction is 2A D.

B is a catalyst.

Both elementary steps are bimolecular.

1
point

28. The reaction

X+YZ

is catalyzed by substance K. Determine the rate law given the following experimental data.

Initial rate (M/s) [X] (M) [Y] (M) [K] (M)

0.062 0.10 0.10 0.0001

0.248 0.10 0.40 0.0001

0.52 0.20 0.40 0.0001

0.062 0.20 0.40 0.0002

0.062 0.30 0.20 0.0003

Rate = k[X][Y]

Rate = k[X][Y]2

Rate = k[X]2[Y]

Rate = k[X][Y][K]

1
point

29. Which pair first lists a basic salt followed by an acidic salt?
LiF, NH4Cl

KF, KCl

NaBr, NH4Cl
 NaCl, KBr

1
point

30. Which process will result in an increase in entropy?

NaCl(s) NaCl(aq)

H2O(l) H2O(s)

2NO2(g) N2O4(g)

CO2(g) CO2(s)