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SUB : CHEMISTRY
I. Volumetric Analysis 10 Marks
1. Simple procedure
Pipette solution : 20 ml of standard FAS
Burette solution : Potassium permanganate
Medium : Equal volume of 4 N sulphuric acid
Temperature : Room temperature
Indicator : Self (Potassium permanganate)
End point : Appearance permanent pale pink colour
N-factor
i. FAS (a) :1
ii. KMnO4 (b) :5
Molecular weight of KMnO4 : 158
2. (a) Calculation of molarity of standard FAS solution
Weight of FAS : _____________
w
Molarity of Std. FAS =
M v
= ______________M
3. Principle
Reduction half
MnO-4 + 8H+ + 5e- Mn2+ + 4H2O
Oxidation half
Fe2+ Fe3 + + e- 5
Over all reaction
MnO-4 + 5Fe2+ + 8H+ 5Fe3 + + Mn2 + + 4H2O
4. Tabular column
5. Calculation of Molarity
Volume of Std. FAS (V1) : 20 ml
Molarity of std. FAS (M1) : ____M
Volume of KMnO4 (V2) : ____ml
Molarity of KMnO4 (M2) :?
According to law of volumetric analysis
V1 x a x M1 = V2 x b x M2
V1 a M 1
M2 =
V2 b
= ______________M.
Molarity of KMnO4 = ________________M.
6. Calculation of strength
Strength of the given KMnO4 solution = Molarity x Molecular weight
= ____________ gram/litre
7. Result
i. Molarity of given KMnO4 solution = ___________ M.
ii. Strength of the given KMnO4 solution = ___________ g.
1. Simple procedure
Pipette solution : 20 ml of standard Oxalic acid
Burette solution : Potassium permanganate
Medium : Equal volume of 4 N sulphuric acid
Temperature : 60 to 70 C
Indicator : Self (Potassium permanganate)
End point : Appearance permanent pale pink colour
N-factor
i.Oxalic acid (a) :2
ii. KMnO4 (b) :5
Molecular weight of KMnO4 : 158