30 Daily Tutorial Sheet

Choose the correct alternative. Only One choice is Correct. However, questions marked with '*' may have More than One
Correct option.
1. Which carbocation is most stabilized?

(A) (B) (C) (D)

2. A fluoride of Xenon reacts with excess of hydrogen to give 22.4 ml of Xenon at STP and liberated certain amount of HF,
which is trapped in water. This hydrofluoric acid solution requires 60 ml of 0.1 M NaOH to neutralize it completely. The formula of
Xenon fluoride will be:
(A) XeF2 (B) XeF4 (C) XeF6 (D) XeF8
3. What is the total number of radial and angular nodes present in 5f orbital ?

4. MATCH THE FOLLOWING : (For an ideal gas)

Column 1 Column 2

(A) If temperature of given gas is increased (p) Average speed of gas will increase

If pressure of a given gas is increased at Root mean square speed of gas molecules will
(B) (q)
constant temperature increase

If the density of a given gas is lowered at Must probable speed of gas molecules will
(C) (r)
constant temperature increase
If the volume of a given gas is increased at
(D) (s) Speed of gas molecules will not change.
constant temperature

Paragraph for Questions 5 - 7

Hydrogen bonding is said to be formed, when slightly acidic hydrogen atom attached to a strongly, electronegative fluorine,
oxygen or nitrogen atom, is held with weak electrostatic forces by the non-bonded pair of electrons of another atom. The co-
ordination number of hydrogen in such cases is two. It acts as a bridge between two atoms, to one of which it is covalently
bonded and to other attached through electrostatic forces, also called Hydrogen bond.
Though the hydrogen atoms in a methyl group are not polarised, if an electronegative group like chloro, carbonyl, nitro or cyano
(in order to increase electronengativity) is attached to it, the C H bond gets polarised due to the inductive effect and the
hydrogen atom becomes slightly acidic resulting in the formation of weak hydrogen bonds.
Though a weak bond, the H-bond effect a large number of the physical properties of compounds some of which are:
- Boiling point of liquids.
- Solubility of polar compounds in polar solvents (containing H attached with strong electronegative atom).
- Viscosity of liquids.
- Acidity

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 Daily Tutorial Sheet 31

5. Which of the following combination can involve hydrogen bonding?

I. Mixture of KF and HF II. Mixture of CH3COCH3 and CHCl3
III. Mixture of NH4Cl and H2O IV. Mixture of CH3OCH3 and H2O
The correct choice is :
(A) I, II and IV (B) I and II (C) I, II and III (D) I, II, III and IV
6. For which of the following interamolecular H-bonding is not responsible?
CHCOO CHCOO
||
(A) High value of pKa2 for maleate acid ion || as compared to fumarate ion
CHCOOH CHCOOH

(B) High viscosity of H3PO4 compared with (CH3)3PO4
(C) High volatility of ortho-nitrophenol compared with para-isomer
(D) Stability of chloral hydrate [CCl3CH(OH)2] compared with CH3CH(OH)2

7. Which of the following is incorrectly matched?

(A) H 2 O HF - (Enthalpy of vaporistaion)
(B) SbH3 NH3 AsH3 PH3 - (Boiling point)
(C) CH 2 OHCHOHCH 2OH CH 2OHCH 2OH - (Viscosity)
(D) - (Basicity of starred nitrogen)

8. MATCH THE FOLLOWING :

Column 1 Column 2
(A) CN (p) B.O. of corresponding cation 2
(B) N2 (q) B.O. increasing when converted to corresponding (monopositive) cation

(C) O2 (r) B.O. decreases when converted to corresponding anion (mononegative)

(D) NO (s) Paramagnetic in both cationic (monopositive) as well as anionic (mononegative) form

9. PCl5 dissociates into PCl3 and Cl2 : PCl5(g) PCl3(g) + Cl2(g)

The total pressure of the system is P at a density and temperature T. If the vapour density of the gas mixture at
equilibrium has the value of 62 when the temperature is 230C, what is the value of P
(A) atm/gm/l (B) atm/gm/l (C) atm/gm/l (D) None of these
10. Following is the titration curve of two acids HA and HB (5 milli-moles each) titrated against strong base NaOH (0.1 M)

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 32 Daily Tutorial Sheet

What is pKa for HB acid?

(A) 3 (B) 4 (C) 5 (D) 6

*11. Select the irreversible process(s)?

(A) Mixing of two gases by diffusion (B) Evaporation of water at 373 K and 0.1 atm pressure
(C) Free expansion of gases (D) None of these

12. Column-1 and column-2 contains four entries each. Entries of column-1 are to be matched with some entries of
column-2. One or more than one entries of column-I may have the matching with the same entries of column-II and one
entry of column-1 may have one or more than one matching with entries of column-2.
Column 1 Column 2
(A) For the process H2O(l) H2O(s), H & S are (p) ve, +ve

(B) For the endothermic reaction +ve, ve

(q)
2A(s) + 1/2O2(g) A2O(s) at 298 K S & G are

(C) C(diamond) C(graphite), favourable conditions for formation of +ve, +ve

diamond are high pressure and high temperature then H for formation of (r)
diamond and S for formation of graphite from diamond are
(D) For the given reaction N2O4 (g) 2NO2 (g), Ea(forward)= 57.2 kJ and ve, ve
Ea(backward) = 3.2 kJ, H for the given reaction & S for the reverse (s)
reaction

*13. Which of the following are true for the first order reaction?
(A) t 3 / 4 2t1/ 2 (B) t15 /16 4t1/ 2 (C) t15 /16 3t 3 / 4 (D) t 7 / 8 2t 3 / 4

*14. Which of the following statements is/are correct about azeotropic mixture?
(A) Azeotropic mixture are non-ideal solutions
(B) The components of azeotropic mixture cannot be separated by fractional distillation
(C) Azeotropes obey Raoults law
(D) Solutions with positive deviation from Raoults law, forms minimum boiling azeotrope

15. HNO3 (aq) is titrated with NaOH(aq) conductometrically, graphical representation of the titration as :

(A) (B) (C) (D)

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 Daily Tutorial Sheet 33

16. Which of the following may be represented by atleast one alternative resonance structure in which all the six-membered
rings correspond to kekule forms of benzene?

(A) Only I (B) I and II (C) I, IV (D) I, II, III, IV

*17. In which of the following reactions product is an aromatic compound?

(A) (B)

Red hot
(C) CH3 C C CH 3
(D)
Fe tube

Paragraph for Questions 18 - 20

Packing referes to the arrangement of constituent units in such a way that the forces of attraction among the constituent particles
is maximum and the constituents occupy the maximum available space and the remaining is the void space. Different voids are
present in close packing viz trigonal, tetrahedral, octahedral and cubic void. In three dimensions there are hexagonal close
packing and cubic close pacing. HCP has AB AB AB .... layer arrangement and CCP has ABC ABC ABC layer
arrangement of constituent spheres.
18. The volume of HCP unit cell is : (r is radius of constituent spheres)
64
(A) 24 2 r 3 (B) 16 2 r 3 (C) 12 2 r 3 (D) r3
3 3
19. Which of the following is not common between HCP and CCP arrangements ?
(A) Both have same packing efficiency (B) Both have same coordination number
(C) Both contain octahedral voids
(D) Both contain same number of tetrahedral voids per unit cell

20. Distance between two adjacent most closely packed layers in CCP will be equal to (r = radius of atom)
2 2 3
(A) 2r (B) r (C) 2 r (D) 2 r
3 3 2

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 34 Daily Tutorial Sheet

Choose the correct alternative. Only One choice is Correct. However, questions marked with '*' may have More than One
Correct option.
1. A particle is moving on a circular path of radius R with uniform angular speed . The magnitude of average linear
velocity of particle during time t is
2R t 2R t 2R t
(A) R (B) sin (C) cos (D) sin 2
t 2 t 2 t 2

2. A rectangular block weighing 150 N, is lying on a rough inclined plane with

inclination angle 45 as shown in the figure. The block is tied up by a horizontal
string which has a tension of 50 N to keep the block just in equilibrium, then the
coefficient of friction between the block and the inclined surface is :
(A) Zero (B) 0.33
(C) 0.5 (D) 0.7
P0t02
3. A machine delivers power given by P = Where P0 and t0 are constants. The machine starts at t = 0 and runs
(t t0 ) 2
forever. What is maximum work that the machine can perform?
(A) Infinite (B) zero
(C) P0t0 (D) Cannot be predicted, data insufficient

4. A heavy homogeneous sphere is suspended from a string whose end is attached to a vertical wall. The point at which the
string is attached to the sphere lies on the same vertical line as the center of sphere. If radius of sphere is R and length of
thread is R / 3 , then the minimum value of coefficient of friction between wall and sphere for which sphere remains
stationary will be:
(A) 1 3 (B) 2 3 (C) 3 2 (D) 1
5. 10 gm of ice at 0C is kept in a calorimeter of water equivalent 10 gm. How much heat should be supplied to the
apparatus to evaporate the water thus formed? (Neglect loss of heat)
(A) 6200 cal (B) 7200 cal (C) 13600 cal (D) 8200 cal
6. An insulated container is divided into two equal portions. One portion contains an ideal monoatomic gas at pressure P
and temperature T, while the other portion is a perfect vacuum. If a hole is opened between the two portions, the change
in internal energy of the gas is
(A) zero. (B) equal to work done by the gas
(C) equal to work done on the gas. (D) 3RT/2

*7. A rectangular vessel of dimension l b h and mass M contains a liquid of

density . The vessel has an orifice at its bottom at a distance c from the rear
wall as shown in the figure.
(A) The maximum volume of the water that can be stored when the vessel is
accelerated in hcb/2
(B) The maximum volume of the water that can be stored when the vessel is
accelerated is hlb/2

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 Daily Tutorial Sheet 35

hcb hg
(C) Force F that must be applied when maximum water stored is M
2 c
hcb lg
(D) Force F that must be applied when maximum water stored is M
2 c
*8. If a simple harmonic motion is given by y = sin t + cos t, where y is in cm. Which of the following statement(s)
is(are) correct ?
(A) the amplitude is 1 cm. (B) the amplitude is 2 cm.
(C) initial phase is /6 (D) initial phase is /4

*9. An air column in a pipe, which is closed at one end will be in resonance with a vibrating tuning fork of frequency
264 Hz, if the length of the pipe in cm is :
(A) 31.25 (B) 62.5 (C) 93.75 (D) 125
Speed of sound in air = 330 m/s

*10. A spherical conductor of radius 2R has a spherical

R
cavity of radius . The cavity does not enclose the
2
centre of sphere. Charges Q1 and Q2 are placed as
shown in figure. Q2 is at the center of cavity. An
additional charge Q3 is given to the sphere.
KQ1 K (Q2 Q3 )
(A) The potential of the sphere is
3R 2R
The potential inside the cavity at a distance r r from the center of cavity is
R KQ2 5KQ1 3KQ2
(B)
2 r 6R 2R
k (Q2 Q3 ) kQ1
(C) The value of potential outside the sphere at a distance r from the center of sphere is where r
r r'
is the distance from Q1
2Q
(D) The charge that will flow into ground if the sphere is grounded Q2 Q3 1
3

11. In the given circuit, find the potential difference between A and B
(in volts). Round off your answer to the nearest integer.

12. Assume linear parts to be very long

and the curved has the radius R.
Current in wire is i. If i = 10 A and
R = 10 cm then magnitude of the z
component of magnetic field
a
strength at O in tesla is 10 . Find a.

13. A student is standing on a train travelling along a straight horizontal track at a speed of 10 m/s. The student throws a
ball into the air along a path, that makes an initial angle of 60 with the horizontal along the track as observed by the
student. The professor standing on the ground observes the ball to rise vertically. What will be the maximum height
(in m) reached by the ball?

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 36 Daily Tutorial Sheet

14. In the given figure, coefficient of friction between the 2kg and
3kg blocks are S = 0.3 and K = 0.2, between the 5kg and
surface are S = K = 0.1 and between 3 kg and surface is
S = K = 0, (g = 10 m/s2) .
Column 1 Column 2
(A) For F1 = 0, F2 = 15 N (p) acceleration of all blocks will be same
(B) For F1 = 25/4N, F2 = 0 (q) acceleration of any two blocks will be
different
(C) For F1 = 8 N, F2 = 10 N (r) frictional force between 2kg and 3kg block
is less than maximum static friction
(D) For F1 = 16 N, F2 = 9 N (s) contact force between 3kg and 5kg block is
less than 10 N.

15. Assume that 2 bodies collide head on. The graph of their velocities with time are shown in column-1 match them with
appropriate situation in column-2
Column 1 Column 2
(A) v (1) (2) (p)
m1 m2

m1 < m2 0 < e < 1

t
(B) v (1) (q) 2nd body is large
wall
m1
(2)
t
2
(C) v (1) (r)
(2)
putty ball
t

(D) v (1) (s) v1 v2

(2)
t m1 = m 2 e=1
v1 > v2
m1 m2

m1 > m2 e=1

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 Daily Tutorial Sheet 37

Choose the correct alternative. Only One choice is Correct.

1. If x 2 xy 12 and 2 xy 3 y 2 5 0 then x 4 y is equal to :

(A) 0 (B) 1 (C) 2 (D) 3
2. Two rays are drawn through a point A at an angle of 30. A point B is taken on one of them at a distance a from the
point A. A perpendicular is drawn from the point B to the other ray and another perpendicular is drawn from its foot to
AB to meet AB at another point from where the similar process is repeated indefinitely. The length of the resulting
infinite polygon line is :
(A)
a 2 3 (B)
a 2 3 (C) a (D) None of these

3. Suppose that a ray of light leaves the point (3, 4), reflects off the y-axis towards the
x-axis, reflects off the x-axis, and finally arrives at the point (8, 2). The value of x is :
1 1
(A) x4 (B) x4
2 3
2 1
(C) x4 (D) x5
3 3
4. In a circle with centre O PA and PB are two chords. PC is the chord that bisects the angle APB. The tangent to the
circle at C is drawn meeting PA and PB extended at Q and R respectively. If QC = 3, QA = 2 and RC = 4, then length of
RB equals:
(A) 2 (B) 8/3 (C) 10/3 (D) 11/3

5. The number of positive integers x that satisfy 3x x3 3 x 2 2 x 1 is :

(A) 0 (B) 1 (C) 2 (D) 4
2 64
6. The number of solution(s) of the equation z 2 z z 5
0 is ____________.
z
7. The function f x x x , where [.] denotes the greatest integer function and {.} denotes the fractional part
function respectively, is discontinuous at :
(A) all x (B) all integer points (C) no x (D) x which is not an integer.
8. The function f : [a, ) R where R denotes the range corresponding to the given domain, with rule
f (x) = 2x3 3x2 + 6, will have an inverse provided :
(A) a1 (B) a0 (C) a0 (D) a1

sin 3/ 2

cos3 / 2 d
9. If sin 3 cos3 sin
a cos tan sin b cos sin cot c then :

(A) a 2sec , b 2cosec , c R (B) a 2sec , b 2cosec , c R

(C) a 2sec , b 2cosec , c R (D) a 2cosec , b 2sec , c R
x2 y2
10. There are exactly two points on the ellipse 1 whose distance from its centre is same and is equal to
a2 b2
a 2 2b 2
. Then the eccentricity of the ellipse is :
2
(A) 1/2 (B) 1 2 (C) 1/3 (D) 13 2

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