Sei sulla pagina 1di 6

S E PA R AT I O N S

Designing vacuum units

When designing vacuum units for processing heavy Canadian crudes, reliability
costs can be high if the feedstocks thermal instability is not fully appreciated.
Process design considerations affecting VGO yield and quality are discussed
Scott W Golden and Tony Barletta
Process Consulting Services Inc

N
ew vacuum unit capacity is production or whether there is sufficient crude will dictate whether metallurgy
currently being added at several blendstock for the bitumen. upgrades will pay off.
North American refineries to Applying conventional design
process higher amounts of heavy practices to new units that will process Crude composition variability
Canadian crude. Many other refiners are heavy Canadian crudes will result in Conventional and oil sands heavy
evaluating revamps or new units. many unwanted surprises. Oil sands- Canadian crudes are blends of
Ultimately, coker unit capacity will based crude oils are generally less condensate or upgrader products and
determine the maximum amount of thermally stable than conventional very heavy crude or bitumen. Many are
heavy Canadian crude refiners can crudes, some are very unstable, most have currently produced in limited volumes.
process. Nonetheless, maintaining a high volatile vanadium and nickel Thus, it is prudent to assume crude
high vacuum gas oil (VGO) yield content in the VGO boiling range, many composition will likely be different than
throughout the run will reduce the coker have high solids content and several have the current assays when commercial
charge rate, decrease the amount of coke very high total acid number (TAN) in the production begins. The same has been
produced per barrel of crude, and permit VGO boiling range. Rapid equipment true of extra-heavy Venezuelan blends;
maximum processing of heavy crudes. coking and asphaltene precipitation are there have been significant variations in
Heavy Canadian crude oil properties major problems facing refiners. In some compositions. Lower API gravity crude
influence vacuum unit reliability, VGO instances, heater outlet temperatures forces a higher heater outlet
yield, gas oil quality and run length. Few have been reduced below 700F to obtain temperature to achieve the same VGO
refiners currently process high reasonable heater run lengths at the product cutpoint. Even though the
percentages of these crudes in their expense of a low gas oil cutpoint. crude source is the same, gravity
crude blend. Furthermore, oil sands- Crude processing flexibility will variability requires operating flexibility
based crudes are less thermally stable largely depend on equipment to achieve the same distillate cutpoint.
than conventional crudes, with metallurgy. Some oil sands-based crude In addition, laboratory data show
asphaltene precipitation and vacuum oils produce heavy vacuum gas oil that a 10F change in temperature in the
heater tube coking just two of the many (HVGO) product with TAN values of 68. laboratory distillation device dramat-
challenges. Operating at a low gas oil Processing high percentages requires ically alters the rate of thermal cracking
cutpoint is one solution, but this 317L SS in many of the circuits. Since the on some of these crudes. Even though
approach reduces the VGO yield, crude supply situation is still developing, laboratory devices do not reflect true
increases the coker charge rate and raises metallurgical selection may be the cracking tendencies in the vacuum
coke production per barrel of crude. difference between processing low-cost heater, they do show directionally that
crudes and having to compete with other there is an important stability difference
Heavy Canadian crude oils refiners for the low-TAN feedstocks. If between conventional heavy crude oils
The implications of crude source on most new units are built to process only like Cold Lake and some of the oil
vacuum unit design cannot be low-TAN crudes to minimise investment, sands-based crudes.
overstated. Heavy Canadian oils consist crude flexibility will be limited or high Typical vacuum unit design assumes
of conventional heavy and oil sands- corrosion rates in some circuits will be crude quality is fixed based on a given
based crude oils. Cold Lake and Western the consequence of processing high-TAN assay. An alternate approach assumes
Canadian Select are examples of crudes. Price differentials between low- large quality variability during the
conventional heavy crude. Oil sands- and high-TAN heavy sour Canadian design phase and determines the
based crudes include Albian Heavy, operating flexibility and capital cost to
Christina Lake, McKay River and others maintain product yield, quality and run
that have not yet come into production. Maintaining a high VGO length. Evaluating critical operating
Total conventional heavy Canadian yield throughout the run will variables and estimating the VGO yield
crude production today is approximately over a range of feedstock qualities is
500Mbpd, which is expected to drop reduce the coker charge rate, prudent. Refiners processing heavy and
slowly until 2010 and then sharply decrease the amount of coke extra-heavy Venezuelan and Maya crude
decline. Conversely, oil sands-based oils have experienced significant
production will increase from about produced per barrel of crude, performance differences between the
1000Mbpd today to about 2500Mbpd or and permit maximum design and actual operation. Many of
more by 2015, depending on how many these early heavy oil projects were
of the planned upgrader projects are processing of heavy crudes designed at a benchmark 1050F TPB
actually built, when they reach full cutpoint, yet several achieved less than

105
P T Q Q2 2006
w w w. e p t q . c o m
SEPARATIONS

decisions based solely on a design case


heat and material balance and low
Atmospheric
column initial investment cost, ignoring the
need for operating flexibility. While
initial cost is important, building units
that actually meet their design gas oil
yield, quality and run length should be
part of the investment decisions. Yet,
Low
many cost/performance decisions are
Consequence much more complicated and involve
Steam pressure
high P
drop many more unknowns than looking at
only initial cost. It is easy to eliminate
Vacuum equipment or purchase the lowest-cost
tower vacuum heater. However, these low-cost
Transfer line
units will have a much lower return over
High head Vacuum the life of the unit than one that has
pump heater been designed properly.
Coil
steam Many difficult questions must be
answered. Is there a run length benefit
to installing a well-designed heater vs a
Figure 1 Vacuum unit charge system low-cost one when asphaltene
precipitation and poor thermal stability
are known problems? Is it prudent to
design a double-fired heater with
$ISTILLATE $ISTILLATE balanced-pass heat flux, low oil
FROM FROM residence time and high oil mass
HEATER STRIPPER
velocity, and pay 20% more for the
heater? Should the vacuum ejector
(EATER OUTLET system be designed for 7mmHg absolute
TEMPERATURE pressure or 10mmHg, and what effects
will this have on product yield and run
length as well as cost? Should vacuum
column wash zone internals be designed
6ACUUM for high efficiency to reduce VGO
HEATER vanadium content, knowing this
-AXIMISE STRIPPING increases the coking tendency? True
MINIMISES HEATER value engineering should be performed
OUTLET TEMPERATURE continuously as part of the process
3TEAM
design effort and should encompass all
critical decisions influencing perfor-
mance and cost, not simply initial cost.
During value engineering, someone
will generally ask why a dry vacuum
6ACUUM unit design is not being used. Dry units
RESIDUE
have much smaller vacuum ejectors, use
less cooling water and steam, have a
Figure 2 Minimising heater outlet temperature lower heater pressure drop and require a
lower charge pump head, but they also
1000F when commissioned. These Canadian crude oils. And these few produce less VGO product and more
units produced 3 vol% less VGO and operate at TBP cutpoints below 950F. In coker charge. First and foremost,
higher coker feed rates than design. In some instances, major equipment vacuum units processing heavy oils
some cases, the actual crude charge rate design changes were needed to reliably must be designed with steam. Designing
was reduced by 810% to stay in balance produce high volumes of acceptable- heaters without steam dramatically
with coker capacities. quality VGO for four-to-five-year run increases the rate of coke formation and
Reducing crude oil cost is the major lengths. In several cases, vacuum heater decreases the run length. Those refiners
incentive driving these new crude and and column wash sections coked in less who have dry units have had to reduce
vacuum unit projects. Yet the reality is than one year. One refiner had less than their heater outlet temperature to
that higher capital cost designs are one years run on the gas oil maintain a reasonable run length when
needed to process these crudes reliably hydrotreater due to HVGO product processing heavy crude oils. A lower
over a four-to-five-year run length. vanadium content of 10ppmw or more. heater outlet temperature reduces the
Designing a low-cost unit will reduce Additional reactors were added to VGO yield. There are places to reduce
project revenues, because product yields remove the high metals prior to the initial investment costs; however,
are lower and run lengths are shorter desulphurisation reactors so that building a dry vacuum unit is a poor
between turnarounds. reasonable run lengths were achieved in economic decision. Past experience is
the hydrotreater. being ignored.
Vacuum unit reliability During the design phase, it is Fundamental principles drive process
Few refiners have experience of common to perform value engineering. and equipment design. For example,
processing high volumes of either Typical value engineering approaches because many of these crudes are
conventional or oil sands-based heavy make design and equipment selection thermally unstable, equipment must be

106
P T Q Q2 2006
SEPARATIONS

designed for minimum temperature and


minimum oil residence time. Figure 1
shows major components of the feed
system. Lowering the oil residence time
and minimising the oil temperature Pass #1 Pass #3
requires relatively high rates of coil steam Pass #2 Pass #4
injection and minimum heater tube size.
This increases the system pressure drop,
dictating a high charge pump head. Outlet Outlet
These systems should be designed with tubes Double tubes
overall performance in mind. Common Serpentine fired Double
tubes tubes fired
practice is to send out a heater bid
specification document with the
maximum pressure drop based on charge
pump hydraulics. Heater vendors base
the heater tube size on allowable pressure
drop. Vendors minimise the number of
passes and make other compromises,
because equipment is often purchased
solely on low initial cost. This is not the
vendors fault. If the buying decision is
based on price, what choice do they Figure 3 Double-fired serpentine tube layout
have? When designing vacuum units,
the charge pump head is a consequence Vacuum heater designed vacuum heater will dictate a
of the heater design; it should never Fired heaters processing unstable oils or lower outlet temperature and produce
determine the heater design. those operating at a very high less VGO product yield, because the oil
temperature must be designed to avoid film temperature and oil residence time
Vacuum unit operating rapid coke formation rates. Controlling are both high. Properly designed heaters
variables the oil film temperature and residence allow much higher heater outlet
Process and equipment design will time is essential to minimise coking. temperatures, producing more VGO
determine the product yield, product Nevertheless, most vacuum unit fired product for the same heater run length.
contaminants and unit run length. heaters are designed by the vendors Critical oil film and oil residence time
Since there is little commercial according to the process data given to variables are controlled through heater
experience with many of these crudes, them on an API 560 data sheet. As long design and coil steam injection.
the process engineers should be cautious as the vendors comply with the API Large single-cell vacuum heaters have
when evaluating key operating guidelines, such as minimum burner four to six tube passes. A well-designed
variables. Since many of these crudes are spacing from the tubes, their bids are heater minimises heater flux variation,
less thermally stable, the heater outlet considered technically acceptable. This although heat flux always varies from
temperature should be balanced against approach ensures a substandard heater the combustion zone, where the fuel/air
other variables used to meet the targeted is installed when the primary selection mixture is burned, to the flue gas outlet
VGO yield. Flash zone pressure, coil criterion is low initial costs. Vacuum from the radiant section. It is lowest at
steam rate and column stripping section heater designs should be specified in the floor of the heater, highest where
performance all influence the VGO detail, including tube passes, tube size, the greatest amount of combustion
yield. Reducing the column operating tube configuration, burner layout, coil occurs, and decreases in the top of the
pressure, decreasing the flash zone oil steam injection location and all other radiant section. Each heater pass must
partial pressure by adding coil steam, or factors influencing the oil film be designed so the average heat flux is
increasing the stripping section temperature and oil residence time. the same for each pass. Low-cost heaters
efficiency will all increase the VGO Heater outlet temperature is only one are designed such that heat absorbed per
product yield. Adjusting these variables of the variables affecting coke pass varies significantly. The result is a
also affects capital investment and formation, and it is a relatively higher heat flux and higher oil film
operating costs. unimportant variable. However, many temperatures in some of the passes.
Meeting VGO product TBP cutpoints designers assume a low heater outlet Several factors including the number
of 950970F or higher requires steam in temperature will ensure a heater will not of burners, burner layout, burner flame
the heater, and meeting cutpoints at or coke. Bulk oil temperature certainly length, burner-to-tube spacing, firebox
above 1000F requires a stripping contributes to heater coking, but oil height-to-width (L/D) and non-ideal
section on the column. Figure 2 shows cracking occurs in the oil film flowing flue gas flow patterns influence heat flux
the total vacuum distillate, which on the inside of the tube. A poorly variability from the floor of the heater
includes both the heater and stripping to the outlet. Since heat flux always
section contributions. Increasing the varies, the amount of radiant section
yield from the stripping section When designing vacuum surface area in the low- and high-flux
decreases the heater outlet temperature zones must be equal. One approach is to
needed to meet a targeted VGO product
units, the charge pump use multiple external jump-overs so the
yield. Determining the most cost- head is a consequence of surface area in each pass is the same in
effective combination of column the low- and high-flux zones. However,
operating pressure, heater outlet
the heater design; it should the designer must be able to predict the
temperature, coil and stripping steam never determine the location of high- and low-heat flux
flow rates is critical for heavy crude zones. Since many factors, including
processing, especially at high gas oil
heater design burner operation (as to opposed to
cutpoints. design), influence the location of the

107
P T Q Q2 2006
SEPARATIONS

Single fired tube Double fired tube

Peak heat flux


equals 1.8 average Peak heat flux
equals 1.15 average

Figure 4 Single-fired tube high peak


heat flux Figure 5 Double-fired tube much lower peak heat flux

High mass flux reduces


oil film temperature   

Mass flux
/PTIMISE TUBE TRANSITION SIZE
Coil steam LOCATION TO AVOID LOW MASS VELOCITY
AND HIGH OIL RESIDENCE TIME
Coil steam controls
oil residence time

Figure 6 Oil mass flux and coil steam function Figure 7 Heater tube size transition location

high- and low-flux zones, using external itf = Temperature drop across the oil film the tube facing the burners has a high
jump-overs does not ensure each pass = Qlocal Do/Di h i heat flux, while the side facing the
absorbs an equal amount of heat. A = F (1) refractory is much lower. For a single-
better solution is to use a serpentine pass fired tube (Figure 4) on two-to-one
layout that guarantees each pass gets the Equation 1 shows how temperature spacing, the peak flux is approximately
same amount of heat in spite of heat drop across the oil film is calculated. 1.8 times the average for the tube. A
flux variation (Figure 3). The Do and Di are the outside and few vacuum heaters and most modern
Coke forms inside the radiant section inside tube diameters respectively. coker heaters use double-fired tubes
tubes, because the oil film flowing along Combustion zone flame radiation, flue (Figure 5) that greatly reduce the
the inside of the tube exceeds the gas temperature and single or double peak flux to about 1.151.2 times the
temperature and residence time needed firing determine the amount of heat tube average.
to initiate thermal cracking. Oil film transferred locally (Qlocal). For a given Vacuum units processing low-stability
temperature depends on heat flux and localised heat flux (Qlocal), the crudes should use a double-fired design
oil mass velocity. Increasing the heat temperature drop through the oil film is to reduce the peak heat flux and the
flux raises the oil film temperature at a controlled by process fluid inside the peak oil film temperature. For example, a
fixed mass flux, while a higher mass flux film coefficient (h i). Reducing the tube single-fired heater tube with an average
2
lowers the film temperature at a given size increases the oil mass flux (Equation heat flux of 10 000btu/hr-ft -F will have
2
heat flux. Oil residence time depends on 2) and heat-transfer coefficient a peak heat flux of 18 000btu/hr-ft -F,
oil mass velocity, the quantity of coil (Equation 3), decreasing the oil film whereas the double-fired design having
steam and the radiant section tube temperature and thereby reducing the the same average heat flux will have a
2
surface area. While increasing the rate of coke formation. peak heat flux of only 12 000btu/hr-ft -
radiant section surface area decreases F. Hence, peak film temperatures are
the heat flux, it also raises the oil G (mass flux) = Mass rate of oil/inside cross- significantly reduced.
residence time. sectional area of heater tube Minimising oil residence time in the
Bulk oil temperature plus a = lb/sec-ft2 (2) radiant section reduces the rate of coke
temperature rise across the oil film sets formation. Oil residence time depends
the film temperature. Cracking occurs Inside tube heat (h i) = (0.023) k/D (DG/e)0.8 on the oil mass flux and coil steam rate
where the oil film reaches its highest (cpe/k)0.33 (e/ew)0.14 (Figure 6). Increasing the oil mass flux
(peak) temperature. Peak oil film Transfer coefficient = Btu/hr-ft2-F (3) and injecting the coil steam reduces the
temperature depends on the peak heat oil residence time, but it also
flux and oil mass flux. Designs that Most vacuum heaters are single fired. dramatically increases the heater
reduce the localised peak heat flux lower One side-to-tube faces the burners pressure drop, requiring a much higher
the oil film temperature, allowing and the other sees only the refractory. pump head.
higher heater outlet temperatures Since the fire is on one side, the heat Coking in the heater outlet is a
without excessive cracking and high flux around the circumference of the common problem. Outlet tubes have
rates of coke formation. tube varies greatly. The portion of several sizes to control the pressure

108
P T Q Q2 2006
SEPARATIONS

drop, as the oil vapourises to minimise


the bulk oil temperature. In addition,
two-phase mixed velocity must be kept 3TEAM
below critical to avoid a higher
operating pressure, further raising the
bulk oil temperature. But a larger tube /PTIMISE
size decreases the oil mass flux, causing OVERHEAD
a higher temperature drop across the oil PRESSURE
film. Oil vapourisation in the larger
tubes increases the fluid velocity as long
as the tube transition location is correct. 6ACUUM DIESEL
The increased fluid velocity dramatically
reduces the oil residence time, thus
avoiding rapid coke formation.
However, if the tube size is increased
before oil vapourisation begins, the -INIMISE
mass flux decreases, oil velocity 0
-6'/ PRODUCT
decreases, oil residence time increases
and oil film temperature increases,
causing rapid coke formation. Tube size
transition location must be selected so (6'/ PRODUCT
that the coking in the larger tube sizes is
not a problem (Figure 7).

Column operating pressure


Column flash zone pressure, column
diameter and ejector size should be -INIMISE
TEMPERATURE -AXIMISE
optimised to meet the vacuum gas yield STRIPPING
target while minimising the heater 3TEAM
outlet temperature. Operating pressure,
VGO yield and total steam rate set
the vacuum column diameter. Since
vessel diameter is a large cost issue,
optimising the operating pressure is 6ACUUM RESIDUE
essential. Ultimately, column top
pressure is selected so that the design
flash zone pressure allows the unit to Figure 8 Optimise column operating pressure
meets its design VGO yield at an
acceptable heater outlet temperature to VGO. If the design operating pressure is
avoid rapid coking. The coil and lower than necessary, the ejector system
stripping steam rate and design column and column diameter are larger than
top pressure determine the ejector necessary, raising capital costs. Motive steam
system size. These variables must be Conversely, a high operating pressure
carefully selected to minimise overall can increase the heater outlet
investment. temperature above the thermal cracking
Column flash zone pressure depends limit of these crude oils. Coil steam
on the design ejector inlet pressure
and the pressure drop through the Conclusions Stripping steam
column internals (Figure 8). Internals Lessons learned processing heavy
should be designed for a minimum Venezuelan crudes should be applied to
pressure drop. Since stripping section these new projects that will process
performance has a large influence on heavy sour Canadian crude oils. These
the heater outlet temperature, its units should not be designed with
efficiency should be optimised so that conventional practices used for light
the stripping steam rate is minimum. crudes. Heavy oil properties are very
Furthermore, the total coil steam and different, and design requirements will
stripping steam rate should be raise initial costs. These higher initial
optimised so that the booster ejector costs will pay out over the life of the
size is minimised (Figure 9). project through increased VGO product
Optimising the column operating yield, lower maintenance cost, reduced
pressure has major reliability, product vanadium content gas oil and longer Figure 9 Booster ejector steam load
yield, product quality and cost run length between decokings.
implications. Ideally, column diameter
should be minimum. However, if it is Email: sgolden@revamps.com
too small, the heavy vacuum gas Scott W Golden is a chemical engineer Tony Barletta is a chemical engineer with
product will be of poor quality due to with Process Consulting Services Inc in Process Consulting Services Inc in Houston,
residue entrainment. Since volatile Houston, Texas, USA. He holds a BS Texas, USA. He holds a BS degree in
metals are already high in these crudes, degree in chemical engineering from the chemical engineering from Lehigh
any entrainment results in poor-quality University of Maine. University. Email: tbarletta@revamps.com

110
P T Q Q2 2006

Potrebbero piacerti anche