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1.
(d )
11.
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21.
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31.
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41.
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51.
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61.
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71.
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53.
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63.
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73.
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83.
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4.
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14.
(c )
24.
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34.
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44.
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54.
(b )
64.
(b )
74.
(d )
84.
(c )
5.
(c )
15.
(b )
25.
(c )
35.
(d )
45.
(d )
55.
(c )
65.
(b )
75.
(a )
85.
(c )
6.
(c )
16.
(d )
26.
(a )
36.
(d )
46.
(c )
56.
(c )
66.
(c )
76.
(d )
86.
(b )
7.
(b )
17.
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27.
(a )
37.
(c )
47.
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57.
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67.
(a )
77.
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87.
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8.
(d )
18.
(d )
28.
(a )
38.
(b )
48.
(b )
58.
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68.
(a )
78.
(c )
88.
(d )
9.
(c )
19.
(c )
29.
(d )
39.
(a )
49.
(c )
59.
(c )
69.
(c )
79.
(a )
89.
(a )
10.
(d )
20.
(c )
30.
(b )
40.
(a )
50.
(d )
60.
(c )
70.
(d )
80.
(d )
90.
(b )
4.
3.
here x =h
and, R = 2a
s h
1
2e0 a
f o 150
=
= 30
fe
5
s
2e 0
50
1
rad
=
1000 20
b = q = MP a = 30
h s
1 2a 2e
Hence, c =
1
3
= = 1.5 rad
20 2
b = 1.5
p
; x (t) = a and y (t) = 0
2w
Hence trajectory of particle will look like as (c).
At t =
s h
1
2e0 2a
180
; 84
p
(c) At t = 0, x (t) = 0 ; y (t) = 0
x (t) is a sinusoidal function
or,
h
s
1
2e 0
4a2 + h2
q Q qV = 1 mv 2
2mV
(c) Magnifying power of telescope,
a=
R 2 + x 2
x
2a
sin a = Bd
Also, MP =
E1 =
dqB
mv
sin a =
MP =
s
1
2e 0
mv 2
And we know,
= qvB
R
mv
R=
qB
2.
E1 =
R
a
5.
h
sh
1 a =
4e0 a
s
4ae 0
h
h
h
=
=
mv
2mqV
P
or, l =
6.6 10 34
2 9.1 10 31 1.6 10 19 50
= 1.7
2
6.
v2 u2 = 2as
0 u2 = 2as
u2 = 2as
0.05v
= 2 0.5 2
10.05
10 cm
15 cm
7.
8.
1
1
1
+
=
f = 30 cm
15 (-10) f
Therefore radius of curvature,
R = 2f = 60 cm
(b) In VT graph
ab-process : Isobaric, temperature increases.
bc process : Adiabatic, pressure decreases.
cd process : Isobaric, volume decreases.
da process : Adiabatic, pressure increases.
The above processes correctly represented in P-V
diagram (b).
(d) Pressure, P =
11.
9.
Mass = m
mR 2
a = fR
2
a
mR 2 a
= fR Q a =
R
2 R
P=
Rt
For inductor circuit, i = i0 1 e L
ma
= f
...(ii)
2
Put this value in equation (i),
12.
V2
r
ra = constant
Hence graph (c) correctly describes relation between
acceleration and radius.
a=
f
( M + m) g
=
= g
M +m
( M + m)
= 0.05 10 = 0.5 ms2
ma
3ma
or F =
2
2
(c) Speed, V = constant (from question)
Centripetal acceleration,
ma = F
a=
And, torque t = Ia
1 mN 2
V rm s
3 V
m = 50g
V0 =
....(i)
a
( mN )T
V
If the gas mass and temperature are constant then
P (Vrms)2 T
So, force (Vrms)2 T
i.e., Value of q = 1
or,
201 2
= 2 10 H
10
H = 40 m = 0.04 km
(c) From figure,
ma = F f
13.
M = 10 kg
Pexcess =
V0
14.
T
R
T T
+
r1 r2
r = R
Q1
r2 = O
3
15. (b) Applying momentum conservation
m1u1 + m2u2 = m1v1 + m2v2
0.1u + m(0) = 0.1(0) + m(3)
0.1u = 3m
20.
(c)
qVB =
qBnh
= m2v 2
2p
1 2 1 x 1
kx = K + (0.1)32
2
2 2
2
3 1 2
kx = 0.9
2 2
1 2
Kx = 0.6 J (total initial energy of the spring)
2
(d) According to Faradays law of electromagnetic
induction,
16.
Induced emf, e =
21.
Ldi
dt
50 0.1 5
= = 1.67 H
3
3
(d) Electrons in an unbiased p-n junction, diffuse from
n -region i.e. higher electron concentration to pregion i.e. low electron concentration region.
(d) For a thin uniform square sheet
L=
17.
18.
I1 = I2 = I3 =
22.
\ B ( x, t ) = (9 10 8 T )k sin[2p(1.5 10 6 2 104 t )]
(d) Let unit u related with e, a0, h and c as follows.
[u] = [e]a [a0]b [h]c [C]d
Using dimensional method,
[M1L2T+4A+2] = [A1T1]a[L]b[ML2T1]c[LT1]d
[M1L2T+4A+2] = [Mc Lb+2c+d Tacd Aa]
a = 2, b = 1, c = 1, d = 1
e 2 a0
hc
(c) As we know,
F = ma a F
or, a sin t
I1
I3
u=
dv
sin t
dt
19. (c) As the two cells oppose each other hence, the
effective emf in closed circuit is 15 10 = 5 V and
net resistance is 1 + 0.6 = 1.6 W (because in the
closed circuit the internal resistance of two cells are
in series.
Current in the circuit,
dV sin t dt
V cos t + 1
x
dx = (- cos t + 1) dt
effective emf
5
=
A
I=
total resistance 1.6
5
0.6 = 13.1 V
= 15
1.6
E0
27
=
= 9 10 8 tesla
C 3 108
ur
ma 2
12
qBh 1 2
= mv
4pm 2
23.
I2
1
,
2m
qBh
i.e. KE = n
4pm
(d) As we know,
B0 =
52
50 = L
0.1sec
....(i)
nh
= mvr
....(ii)
2p
Multiplying equation (i) and (ii),
1
1
0.1u 2 = m(3)2
2
2
Solving we get, u = 3
3 2
kx = 0.9
4
mv 2
r
x = sin t
24.
(c)
1
sin 2t
2
r
NiA
M (mag. moment/volume) =
Al
=
Ni
(500)15
=
= 30000 Am1
l
25 10 2
4
25. (c) i = neAVd and Vd E (Given)
Reynolds number, Re =
or, i E
103 0.5
i2 E
i2 V
Hence graph (c) correctly dipicts the V-I graph for a
wire made of such type of material.
26. (a)
F=
2p
Qv = r w and w = T
V - (-V0 )
V + V0
V + 10
=
f
f=
f=
V
- 10
V
V
V
V
CHEMISTRY
31. (b) Total V.P. of solution = PA x A + PB x B
Given, PA = 74.7 torr, PB = 22.3 torr
nbenzene = 1.5 mol, ntoluene = 3.5 mol
nsolution = 1.5 + 3.5 = 5 mol
n
1.5
x A = benzene =
nsolution
5
320 + 10
=
8000 = 8516 Hz
320 - 10
28. (a) From Braggs equation
d sin q = l
l
<1
d
l<d
sin q =
\
h
<d
| py |
3.5
1.5
74.7 +
22.3 torr
=
5
5
h
Q l =
| p y |
h < | py | d
Radius, r =
1
p
2
p
cm
10-2 m
dm
= rAV
V
dt
2
15
1
-4
= 10 3 p
10 V
5 60
p
V = 0.05 m/s
34. (c)
@ 5500
0.1
= 0.01 cm
10
d1 = 0.5 + 8 0.01 + 0.03 = 0.61 cm
d2 = 0.5 + 4 0.01 + 0.03 = 0.57 cm
d3 = 0.5 + 6 0.01 + 0.03 = 0.59 cm
0.61 + 0.57 + 0.59
Mean diameter =
3
= 0.59 cm
30.
mv 2 2GM
2GM
=
m
m or,
r
Lr
Lr
2GMm
2p
mr =
Lr
T
T r
27. (a) Reflected frequency
10-3
2
10 -2
p
r Vr
n
22.4
= 0.589
38
Compound A reacts with alc.KOH to give compound B which on further ozonolysis gives C (does not contains a- H atom)
and D (contains a-H atom).This reaction sequence can be achieved by compounds in option (a) and (c). Since compound
A gives white ppt. with AgNO3 preferable option will be (c) as tert alkyl reacts with AgNO3 more quickly.
CH3
C6H5 CH2 C
CH3
alc. KOH
CH3
Cl
(A)
(it gives white ppt with AgNO3)
C6H5 CH = C
CH3
(i) O3
(ii) Zn/H2O
40. (a)
41. (a)
9
= 0.5
18
Grass molecular let of BaCl2 = 208
5
The donor atoms, molecules or anions which donate a
pair of electrons to the metal atom or ion and form a
coordinate bond with it are called ligands. In methane
there is no electrons for donation to central metal atom/
ion it is stable with complete octet configuration.
Rate law for first order reaction = k[N2O5]
Moles of H2O =
2N 2O5 ( g )
4NO2 ( g ) + O 2 ( g )
9
100 = 14.75%
61
18x
100 on solving x = 2
208 + 18x
This percentage is present in BaCl2.2H2O
36. (d) Hell-Volhard-Zelinsky Reaction :
It is a-substitution when a carboxylic acid having ahydrogens is treated with chlorine or bromine in
presence of small amount of red phosphorous.
t = 0 min
50
0
(Pressure in mm Hg)
t = 30 min
50 2p
4p
(Pressure in mm Hg)
Total pressure 50 2p + 4p + p = 50 + 3p
= 87.5 mm Hg
\ P = 12.5 mm Hg
\ P0 = 50 & P (t = 30 min)
= 25 for N2O5 reactant
X
|
37. (c)
42. (c)
Malachite
2CO2
39. (a)
M2
= 12
10
toluene 3.5
=
5
solution
45. (d) The optically inactive compound must contains achiral
carbon atom(s). Option (d) contains achiral carbon
atom
xB =
Cl
Cl
|
M
=2
10
Mili equivalent of NH3 = 12 2 = 10
1.4 10
= 10
1.4
44. (c)
% of nitrogen =
Calcium
oxide
D
Electrolysis
CaO + CO 2
Limestone
43. (c)
COOK
2.303
50 2.303
50
log =
log
30 min
25
60
min
x
On solving x = 12.5 mm Hg = 50 2p
\ P = 18.75 mm Hg
\ Total pressure = 50 + 3P = 106.25 mm Hg
Calcination is the process of converting an ore into its
oxide by heating it strongly below its melting point
either in absence or limited supply of air. It is usually
done to convert metal carbonates and hydroxides to
their respective oxides.
CaCO 3
38. (b)
\ k=
R - CH 2 COOH + X 2
1.4 ( N V ) NH3
2- chloropropanol
2-chlorobutane (chiral)
Cl
|
CH3 - CH 2 - CH 2 - C - CH 3
|
CH3
|
CH3 - CH 2 - C - CH 3
|
H
2-chloropentane
(chiral)
Cl
2-chloro-2-methylbutane
(achiral)
HCO3-
46. (c)
6
Tellurium (Te) has 5s25p4 valence shell configuration.
It belongs to group 16 and present in period 5 of the
periodic table.
50. (d) Stability of ionic compounds decreases with decrease
in lattice enthalpy. Thus stability of alkaline earth metal
hydroxides decreases with decrease in lattice enthalpy
as the size of alkali earth metal cations increases down
the group.
49. (c)
OH2
H2O
OH2
H3N
OH2
H3N
Cis
Trans
NH2
NO2
Now, E =
\l=
55. (c)
80 103
6.023 10 23
J/molecule
hc
l
80 10
\ l = 1.49 103 nm
Co+2 ion is precipitated by H2S in presence of NH4OH
which is a group reagent of group IV in cationic
analysis.
(1 - a ) M N2O4 + 2a M NO2
(1 + a )
(1 - 0.2 ) 92 + 2 0.2 46
= 76.66
(1 + 0.2 )
PM mix
1 76.66
=
= 3.11g / L
RT
0.0821 300
Drugs which relieve pain are called analgesics.
Analgesics are of two types (i) Narcotics and (ii) Nonnarcotics. Aspirin (acetylsalicylic acid) is a nonnarcotic analgesic.
Starch is a mixture of amylose & amylopectin
polysaccharides and monomer is glucose. Thus on
complete hydrolysis it gives only glucose.
Flourine is the most electronegative element & has
least tendency to form double bonds.
In XeOF4, Xe is sp3d2, hybridised having 6 bond pairs
and 1 lone pair.
\d =
57. (a)
58. (a)
59. (c)
60. (c)
OCH3
Meridional
56. (c)
53. (c)
\ BE(C C) =
OH2
Facial
NH2
CH3 NH
N H3
H3N
N H3
Ni
OH2
H3N
N H3
OH2
OH2
H3N
Ni
N H3
H2O
N H3
OH2
H3N
Ni
Ni
52. (c)
OH2
N H3
F
F
O
Xe
F
F
XeOF4
Square pyramidal
(sp3d2)
MATHEMATICS
an = 44.5 + 1.5 + 3 = 49
61. (d) x2 y + 6 = 0
2x
dy
dy
=0
= 2x
dx
dx
67. (a)
dy
=4
dx ( x, y )= (2,10)
68. (a)
x y
+ =1
2 4
2x + y = 4
equation of tangent
y 10 = 4(x z)
4x y + z = 0
tangent passes through (a, b)
4a b + z = 0 b = 4a + z ...(1)
and 2x + 2yy' + 8 2y' = 0
2 x + 8 2a + 8
=
=4
2 - 2 y 2 - 2b
from (1) and (2)
y =
63. (c)
(1, 2)
8
2
a=
,b =
17
17
For line
x 2y = 4
...(2)
solving equation (1) and (2); we get poin t of
intersection
-8 2
,
17 17
12
4 / 5,
5
( r 2 - r - 6 ) = 7780
r =16
n(P) = 25%
n(C) = 15%
n ( P C ) =65%
Cr n C r +1 n Cr + 2
=
=
1
7
42
By solving we get r = 6
so, it is 7th term.
70. (d) Required probability is
69. (c)
n(P C) = 65%
20
n ( P C) = n ( P ) + n (C) - n ( P C)
25 + 15 35 = 5%
x 5% = 2000
x = 40,000
64. (b) |3 + 4 12l + 13| = | 9 + 0 12 + 13|
| 12l + 20| = |8|
|3l 5| = 2
9l2+ 25 30l = 4
9l2 30l+ 21 = 0
3l2 10l+ 7 = 0
65. (b) a = 2 + 3i; b = 2 3i, g = ?
abg =
d
13
since product of roots = a
2
13
1
g=
2
2
a1 + a2 + a3 = 39
a1 + (a1 + d) + (a1 + 2d) = 39
3a1 + 3d = 39
[ Q a1 = 10]
d=3
Sum of last four term = 178
( 4 + 9) g =
Their mean =
178
= 44.5
4
+ ....... +
( 10C10 )
210
n ( P C ) = 35%
66. (c)
...(1)
...(2)
20
62. (d)
10 + 49 59
=
= 29.5
2
2
Let average wage of Night shift worker is x
70 54 + 30 x = 60 100
x = 74
Equation of line L
Median =
71. (a)
C10
220
Given that
0 -1
A =
1 0
-1 0
2
A2 =
A = -I
0 -1
0 1
A3 =
-1 0
1 0
A4 =
=I
0 1
A2 + I = A3 A
I + I = A3 A
A3 A
72. (d) Number of ways of selecting a man and a woman for a
team from 15 men and 15 women
= 15 15 = (15)2
Number of ways of selecting a man and a woman for
next team out of the remaining 14 men and 14 women.
= 14 14 = (14)2
8
Similarly for other teams
Hence required number of ways
= (15)2 + (14)2 + .... + (1)2 =
73. (a)
OP =
4
sin q
OB =
4
cos q
15 16 31
= 1240
6
77. (a)
P (o, h)
4
A
1
3
So, lies on same line
Plane passing through x + y + z + 1 = 0 and 2x y + z + 3 = 0
is x + y + z + 1 + l (2x y + z + 3) = 0
(2l + 1)x + (1 l)y + (1 + l)z + 3l + 1 = 0
Parallel to the given line if
a(2l + 1) 1(1 l) + 1(1 + l) = 0
Slope of BC =
a=
q
B
r
c=
r2
r2
r
r r
r
2
a + 4 b + 2.2 a cos 60n1 + 3 a b sin 60n 2
r r
r
+3 a b sin 60.n 2
r
r
n1 ^ r n 2
r2
3
c = (1 + 4 + 2 ) + 9
4
r2
c = 7 + 27 / 4 = 55 / 4
r
2 c = 55
76. (d)
8
A 0, B (1, 3) C (89,30 )
3
1
Slope of AB =
3
(2l + 1) + (1 - l ) + (1 + l)
1
3
32
32
; a = 0 or a =
102
19
Equation of hyperbola is
l = 0,
Area = OP OB =
4
=4 2
So, h =
sin 45
74. (d) Given that y + 3x = 0 is the equation of a chord of the
circle then
y = 3x
....(i)
(x2) + ( 3x)2 30x = 0
10x2 30x = 0
10x(x 3) = 0
x = 0, y = 0
so the equation of the circle is
(x 3) (x 0) + (y + 9) (y 0) = 0
x2 3x + y2 + 9y = 0
x2 + y2 3x + 9y = 0
r r
75. (a) a + b = 3
r
r
angle between a and b is 60.
r r
r
r
r
a b is ^ to plane containing a and b
r r
r
r r
c = a + 2b + 3 a b
...(i)
2l + 1 (1 - l ) + 0 + 3l + 1
Also,
16
32
=
sin q cos q sin 2q
least value sin2q = 1; q = 45
2l
2l + 1
78. (c)
x2 y2
=1
4
9
13
2
If e, be the eccentricity of the ellipse, then
e=
1
13 1
=
e1 =
13
2
2
Equation of ellipse is
e1
x2
a2
y2
b2
=1
x 2 y2
+
=1
13 12
13 3
,
Now putting the coordinate of the point
2
2
in the equation of the ellipse, we get
13
3
+
=1
4 13 4 12
1 1
+ = 1 , which is not true,
4 16
13 3
Hence the point 2 , 2 does not lie on the
ellipse.
9
79. (a)
dy
= x 2 + 4x - 9 x -2
dx
( x + 2)
dy x 2 + 4x - 9
=
dx
x+2
dy =
C(4, 1)
x + 4x - 9
dx
x+2
dy =
x 2 + 4x - 9
dx
x+2
(0, 0)
y = (x + 2) dx - 13
x+
(0, 1)
13
y = x + 2 dx
x+2
(1, 0)
y=
1
dx
x+2
1
and f = 0
2
x
+ 2x 13 log | x + 2 | + c
2
Given that y = (0) = 0
0 = 13 log 2 + c
y=
c = 2 and b =
2b + c = 1
x
+ 2x 13 log |x + 2| + 13 log 2
2
y(4) = 8 8 13 log 2 + 13 log
2= 0
80. (d) Solving
y = 2x2 = 0
y = 3x2 = 1
1
2
x 1 1
y=
83. (d)
y 1 0
1 1 z
xyz x y z + 2 0
xyz + 2 x + y + z > 3 (xyz)1/3
xyz + 2 3(xyz)1/3 0
ut(xyz) = t3
t3 3t + 2 0
(t + 2) (t 1)2 0
[t = 2] t3 = 8
2
84. (c)
1 3
x x2 1 1
Lim
e +
= 1+ =
x 0 sin x
2 cos x
2 2
(1, 2)
( 1, 2)
2xe x + sin x
Lim
x 0 2sin x cos x
1/x
85. (c)
1
f =
x
((
))
) (
2
2
Area = 2 1 - 3x - -2x dx
0
3 1
x
4
2 1 - x 2 dx = 2 x - =
0 3
0
81. (c)
Radius
CP =
1
z
1
z2
dz
ln z
f(x) = z z + 1 dz
( )
1
x
1
2
2
dt = -
ln x
1
f ( x) + f =
dz
x
z
4 +1
5
Let t =
ln t
1+t dt
5
2
2
( ln z ) 2
( ln x ) 2
=
= 2
2
10
86. (b)
sin A
= 2+ 3
sin B
sin (105)
sin (15 )
= 2 + 3 cos15 = 2 + 3
sin15
2x
f(x) = 2 tan1 x + sin1
1 + x2
f(x) = 2 tan 1x + p 2 tan1x
f(x) = p
f(5) = p
88. (d) The centre positive of the statement is If i will come,
then it is not raining.
89. (a) Given that
x = 2 cos t + 2t sin t
y- 2+
dx
= -2 sin t + 2 [ t cos t + sin t ]
dt
dy
= 2 cos t - 2 [ - t sin t + cos t ]
dt
dy
= 2t sin t
dx
2+
p
2 2
( (
2 2
( x + 1)
( x - 2 )5/ 4
dx
x +1
x-2
3/ 4
( x - 2 )2
x +1
=t
x-2
-3
( x - 2)
dx
2
dt
dx
=-
dt
3
-1 dt
1 -3
= - t lt
3/
4
3 t
3
4
-3 +1
1t 4
=
3 -3
+1
4
1/ 4
and
-4 x + 1
=
3 x - 2
+c
y = 2 - p/ 2 2
))
2 + p / 2 2
= -x + 2 + p / 2 2
dx
put
dy
=1
dx t =p / 4
3/ 4
( x - 2)
dy
= tan t
dx
At t = p /4x =
90. (b)
...(ii)
dy 2t sin t
=
dx 2t cos t
2 - p / 2 2 = -1 x
87. (c)
so,