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Hydrogen
iodide
was
found
to
be
22.3%
dissociated
at
730.8K.
Calculate Kc for
2 HI(g) H2(g) + I2 .
2. Phosgene (COCl2) is a poisonous gas that dissociates at high temperature into two other
poisonous gases, carbon monoxide and chlorine. The equilibrium constant
Kp = 0.0041 at 600K. Find the equilibrium composition of the system after 0.124 atm of
COCl2 is allowed to reach equilibrium at this temperature.
3. The gas-phase dissociation of phosphorus pentachloride to the trichloride has
540C:
Kp = 3.60 at
14. 2.00mL of 0.0150M HCL solution is added to 10.00mL of 0.150 HOAC solution. Calculate the
5
15. Calculate the pH of a buffer solution that initially consists of 0.0500 M NH 3 and 0.0350 M NH4+.
(Note: Ka for NH4+ is 5.6 x 10-10). The equation for the reaction is as follows:
NH4+ <-> H+ + NH3
16. A saturated solution of Mg(OH) 2 is prepared. The pH of the solution is 10.17. What is the K sp for
this compound?
Mg(OH)2 <-> Mg2+ + 2OH
17. A liter of a buffer is composed of 0.200 mol NH3 and 0.150 mol of NH4Cl
(Ka=5.70x10-10). What is the pH of this buffer solution?
18. Use the following reversible reaction to calculate the equilibrium concentration of each species.
Assume
K c =9.23 103
PCl5
PCl3
Cl2
19. A vessel initially contains 4M hydrogen and 3M iodine. It is allowed to reach equilibrium where
the concentration of hydrigen iodide is found to be 2M. Calculate Kc.
20. A mixture of 0.100mol of NO, 0.050mol of
H 2 , and 0.10mol of
H2O
is placed in a 1.0L
N2 + 2 H2O
H2 ,
N2 ,
and
H2O .
21. Three moles of pure SO 3 are placed in an 800 L flask at 1150 K. At equilibrium, 0.58 mol of O 2
has formed. Calculate Kc for the reaction at 1150 K.
2SO3 (g) 2SO2 (g) + O2 (g)
22. Determine the pH of .30 M acetic acid (HC 2H3O2) with the Ka of 1.8x10-5.
HC2H3O2 H+ + C2H3O2
23. The Kw value that we normally use is for room temperature (25C). Calculate the equilibrium H+
concentration and pH of pure, neutral water at 0.0C (Kw = 1.14 x 10 15 at 0.0C)
24. Methylamine (CH3NH2) is a derivative of the weak base ammonia. Write the equation for the
ionization of methylamine in water, and use the I.C.E. method to find the pH of a 3.75 M CH 3NH2
solution. (Kb = 4.37 x 104 at 25C)
25. Find the pH of a 0.325 M acetic acid solution, Ka = 1.8 x 10-5
HC2H3O2 (aq) + H2O (l) C2H3O2- (aq) + H3O+ (aq)
26. Calculate the pOH and the pH for 0.25 mol/L ammonia solution. Kb = 1.8 x 10 -5
NH3 (aq) + H2O (l) NH4 + (aq) + OH- (aq)
27. Calculate the hydronium and hydroxide ion concentrations and the pH and pOH of 0.200 M
aqueous NaOH at 25C.
28. Find the pH of a solution that contains 0.0034 M lactic acid (HC 3H5O3). Ka =1.4 x 10-4
HC3H5O3 (aq) + H2O (l) C3H5O3- (aq) + H3O+ (aq)
29. GIVEN THE CHEMICAL EQUATION: H2 + I2 2 HI
Calculate all three equilibrium concentrations when [H2] = [I2] = 0.200 M and K = 64.0.
30. In an experiment, hydrogen iodide was found to be 22.3% dissociated at 730.8K.
Calculate K for 2 HI H2 + I2 .
31. Benzoic acid (C6H3COOH) has a Ka of 6.3x10-5. Calculate the pH of a 0.120 M sodium benzoate
(NaC6H3COO).
32. An NH3 solution has a pH of 11.00. Calculate the analytical molarity of NH 3 in the solution. Kb =
1.8 x 105
33. Calculate the concentrations for each species present in a 0.1000 M aqueous solution of ammonia
(Kb = 1.8 x 10-5).
NH3(aq) + H2O(l) NH4+(aq) + OH-(aq)
34. Calculate the pH of the buffer solution that is 0.15 M HF and 0.15 M F-. (Ka = 6.8 x 10-4)
HF(aq) + H2O(l) H3O+(aq) + F-(aq)
35. The equilibrium constant for the following reaction at 600C is 3.5. Initially, three moles of CO
and 2 moles of H2O were mixed in a 2.5 liter container. Determine the pressure of all species at
equilibrium.
CO(g) + H2O(g) CO2(g) + H2(g)
36. Calculate the pH of a weak acid solution of 0.2 M HOBr, given:
HOBr + H2O(l) H3O+ + OBr 37. Find the equilibrium concentration of HC 7H5O2 from a 0.43 M solution of Benzoic
Acid, HC7H5O2. Ka of HC7H5O2= 6.4 x 10-5
38. 2.00mL of 0.015M HCl solution is added to 10.00mL of 0.150M HOAc, calculate the pH of the
resulting mixture. Ka=1.75x10-5
HOAc + H2O H3O+(aq) + OAc 39. Calculate the pH of 0.35M Sodium formate solution (NaHCOO). Ka= 1.8x10 -4
HCOO- + H2O OH- + HCOOH
40. Find the pH of a 0.0372 M solution of the commonly encountered weak base cocaine.
( Kb
= 2.6 x 10
41. Calculate the pH of a solution that is 0.200 M in NH3 and 0.300 M in NH4Cl.
+
++ H 2 O NH 3 + H 3 O
NH 4
Ka = 5.70 10-10
42. Given this equation:
H 2+ I 2 2 HI
Calculate all three equilibrium concentrations when [H2] = [I2] = 0.200 M initially and
Kc = 64.0
43.
C6 H 5 COONa . The
is 1.55 1010
k b for C6 H 5 CO O .
44. Find the pH of a 0.20M solution of sodium propionate,
5
2 NO ( g )+ 2 H 2 ( g ) N 2 ( g)+ 2 H 2 O(g)
Determine the value of the equilibrium constant, Kc, for the reaction. Initially, a mixture of 0.100
M NO, 0.050 M H2, 0.100 M H2O was allowed to reach equilibrium (initially there was no N2).
At equilibrium the concentration of NO was found to be 0.062 M.
46. Consider the following reaction
C2 H 4 ( g ) + H 2 ( g ) C2 H 6 (g) K c =0.99
What is the concentration for each substance at equilibrium if the initial concentration of ethene,
C2H4 (g) , is 0.335 M and that of hydrogen is 0.526 M?
47. What mass (in grams) of Ba(IO3)2 (487 g/mol) can be dissolved in 500 mL of water at 25oC?
48. Calculate the solubility of Ba(IO3)2 in a solution prepared by mmixing 200 mL of 0.100 M
Ba(NO3)2 with 100 mL of 0.100 M NaIO3.
49. What is the Kb for the equilibrium:
+ H 2 O HCN +OH
CN
Ka= 6.2 x 10-10
50. Calculate the hydroxide ion concentration in a 0.0100 M sodium hypochlorite solution.
++ NO 2
HNO2+ H 2 O H 3 O
Ka = 7.1 x 10-4