MOCK TEST PAPER 6

FIITJEE

KK Nagar Centre

Time: 3 Hours

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 2

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 3

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 4

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 5

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 6

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 7

23 rd May, 2015

PCM

CHEMISTRY

PART - II

Single Answer Questions

Which
one
of
the
following
is
more
reactive
towards electrophilic addition reaction
1.
(a) Ethylene
(b) Propylene
(c) 2 Butene
(d) 2, 3-dimethyl 2- Butene
Phenyl acetylene on hydration in the presence of H 2 SO4 / HgSO4 gives
(a) Phenyl acetaldehyde (b) Benzaldehyde
Acetophenone
(d) Benzophenone
2.

3.

A major product of the following reaction is H 3C CH CH 2 HBr

(a)
H3C

4.

(b) H3C

CH

Peroxide

Br

Br

CH 3 CH 2 CH 2 Br

(c)

CH3

(c)

H 2C

CH

CH2

(d)

Br

CH3
OH

(a)
(a)

(b)

Major product is

(c)

.
.

(d)

5.

Arrange the following alkene reactivity towards with HBr

(a)
(a) a b c

H3CO

H3CO

(c)

(b)
(b) b a c

(c) c b a

(d) b c a

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VVIT46X01 MOCK TEST -6 8

6.

CH3

C
C

CH3 C

18
O O Hx
H3 O

CH3

23 rd May, 2015

PCM

x
The probable structure for

CH3 18
OH

OH

HO

CH3

CH3 18
OH
H

CH3

is

CH3
H

OH

OH

CH3

CH3 18
OH
18
OH
CH3

(a)
(b)
(c)
(d)
The
no
of
structural
and
configurational
isomers
of
a
bromo
compound
formed by the
C
H
Br
5 9
7.
addition of HBr
on 2 Pentyne
(a) 1 and 2
(b) 2 and 4
(c) 4 and 2
(d) 2 and 1

8.

To prepare pure n Decane by wurtz reaction which of the alkyl halides gives more yield
(a) n Hexyl chloride + n Butyl chloride
(b) n Heptylchloride + n propyl chloride
(c) n octyl chloride + Ethyl chloride
(d) n Pentyl chloride + n Pentyl chloride
One or more than one option correct

9.

Which of the following statement is/are correct

(a) n Butane gives 3 compounds on mono chlorination
(b) When cis 2 butene undergoes bromination racemic dibromo compounds will be formed
(c) 2-methyl propene is more stable compared to trans 2-butene
(d) 1-chloro-4-bromo cyclo butane is optically inactive.

10.

A compound C5 H 8 Reacts with ammonical AgNO3 to give a white ppt and reacts with Excess of
KMnO4 solution to give CH 3 2 CH COOH The compound is
(a) H 2C CH CH CH CH 3
(c) CH 3 CH 2 2 C CH

(b) CH 3 2 CH C CH
(d)

H 3C 2 C C CH 2
11.

Resonance structures of a molecule should have

(a) identical arrangement of atoms
(c) The same number of paired electrons

(b) nearly the same energy content

(d) identical bonding

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 9

23 rd May, 2015

PCM

CH3

12.

Br

+ Br2

CH2

300C

CH3

CH2

Which of the following compound will be obtained in the above

reaction?
CH3

CH3

CH3

Br

Br

Br

Br

CH2

CH2

CH3

(a)

Br
CH2

H
CH3

Br

CH3
Br

Br

CH3

(b)

(c)

Match the following

M1.
COLUMN I
A
CH 3

Br2
CCl 4

Racemic mixture

Br 2
CCl 4

Meso compound

Br 2
CCl 4

Diastereomers

Vicinal dihalide

B
CH 3

COLUMN II

C
CH3

H3 C
H

H
CH3

Br2
CCl 4

M2.
Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

CH2

(d)

CH3

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23 rd May, 2015

PCM

COLUMN I
F

H
F

COLUMN II
C

H
F
H

Polar Molecule

Optically active

Optically inactive

Plane of symmetry

C
F

D
H

H
H

N1.

Numerical
How many distinct monochlorinated products (Including stereo isomrs) may be obtained when
the cycloalkane shown below is heated in the presence of Cl2 ?

N2.

H2(Excess)/pt

KMnO 4

COOH

+
COOH

COOH
COOH

Double bond equivalence of A is

CH2

N3.

Br2
CCl 4

alCKOH
NaNH2
C
NaNH2 B CH3-Cl

How many asymmetric Carbon atoms are present in the product (c) ?

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 11

N4.

OH

23 rd May, 2015

PCM

Possible products (x)

Br2/CCI4

(y) products what is the value of X

+Y
The number of isomers are possible for the molecular formula C2HIClF is
N5.
N6. How many correct statements in the following
(i) 2 Butene on reaction with cold KMnO4 to form cis diol.
(ii) trans 2 Butene on reaction with Br2 / CCl4 to form a reacemic mixture
(iii) 2, 2, 4 Tri methyl pentane is called isooctane
(iv) Sulphonation of benzene is reversible reaction
(v) Tropylium cation is aromatic compound
(vi) For the nitration of benzene

KH
KD

is equal to one.

(vii) Higher the Octane number of gasoline better is its quality.

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 12

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 13

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 14

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 15

PCM

23 rd May, 2015

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 16

PCM

23 rd May, 2015

VVIT46X01 - MOCK TEST - PAPER 6

ANSWER KEY

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8

VVIT46X01 MOCK TEST -6 17

PCM

23 rd May, 2015

VVIT46X01 - MOCK TEST - PAPER 6

ANSWER KEY

Fiitjee Towers , No : 51 Dr. Ramasamy Salai K K Nagar Chennai 600078 . Ph : 044 64690557/8