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Course Contents for Subjects with Code: CHEM

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CenterforUndergraduateStudies,UniversityofthePunjab
Code
SubjectTitle
Cr.Hrs
Semester
CHEM101 ChemistryI(PhysicalChemistry)
3
I
Year
Discipline
1
Botany,Zoology,ChemistryI,II
STATES OF MATTER
A. Gases:
Law of equipartition of energy, Collision diameter, collision number, collision frequency
and mean free path; Viscosities of gases, measurements, effect of temperature and
pressure on viscosities of gasses; Critical phenomenon of gases and experimental
determination of Pc, Vc and Tc; Concept of molecular velocities of gasses according to
Maxwells distribution law and comparison of various velocities.
B. Liquids:
The properties of liquids like surface tension, viscosity, refractive index and dipole
moment; Parachor, reheochor and molar refraction as additive and constitutive properties;
Measurement of refractive index and dipole moment; Magnetic susceptibility and its
measurement by Gouys balance.
C. Solids:
Symmetry operations and Bravis lattices; Concept of X-Ray diffraction, Braggs equation
and crystal structure analysis; Powder method of crystal structure analysis; X-ray
crystallography of sodium chloride crystal; Heat capacities of solids.
CHEMICAL THERMODYNAMICS:
Heat capacity as Cp and Vc; Difference in Cp and Cv and ration of Cp and Cv towards
atomicity; Temperature dependence of heat capacities; Quantitative effect of temperature
over enthalpy change and internal energy change; Types of thermodynamical processes;
Isothermal reversible expansion of ideal gases; Adiabatic process of ideal gasses; Second law
of thermodynamics, Carnot cycle, efficiency of heat engine and concept of entropy;
Thermodynamics scale of temperature entropy for phase transition, spontaneity and
reversibility; Entropy change in reversible and irreversible processes; Temperature
dependence of entropy, Variation of entropy with pressure and volume; Concept of free
energy; Derivation of Gibbs and Helmholtz equation; standard free energy of formation;
Partial molar quantities, Chemical potential, variation of chemical potential with pressure and
temperature fugacity; Thermodynamic of equilibrium, Reaction isohore; Calusius-Clapeyron
equation; Molecular basis of entropy and probability.
CHEMICAL KINETICS:
Derivation of kinetic expression of zero order, first order, second order (with same and
different concentration) and third order reactions (with same concentrations) with suitable
examples; Equation for half life periods and determination of rate constants; Methods of
measurements of order of reactions giving examples with different techniques; Derivation of
Arrhenius equation and measurements of Arrhenius parameters, Measurement of slopes of
Arrhenius plots for some important reactions Bimolecular collision theory of reaction rates
and its failures; Collision theory of uni-molecular, gas phase reactions (Lindeman
mechanism); Introduction transition state theory of reaction rates.
SOLUTION:
Thermodynamics derivation of colligates properties as lowering of vapor pressure, elevation
of boiling point, depression of freezing point; Relationship between lowering of vapor
pressure with Tb and Tf; Osmotic pressure an their determination; Concept of semi
permeable membrane, Isotonic solution, theory of osmotic pressure,

relationship between vapor pressure and osmotic pressure, Abnormal colligative properties
describing association and disassociation of solutes; Fractional distillation and idea of
azotropes in detail; Concept of colloids; Classification of Colloids; their properties with
reference to dialysis, electro dialysis, sedimentation, precipitation, ultra filtrations,
Suspensions and gels; Tyndal cone effect; Macromolecules and micelles.
SURFACE CHEMISTRY:
Introduction to adsorption; Difference between physical and chemical adsorption; Adsorption
of gases by solids; Different types of adsorption isotherms with special reference to Langmuir
adsorption isotherm and its applications; Freundlich adsorption isotherm giving some
important applications; Brief introduction to catalysis; Theories of Catalysis; Activation
energy for catalyzed reactions; Kinetics of enzyme catalysis; Theories of catalysis; Activation
energy for catalyzed reactions; Kinetics of enzyme catalysis.
Recommended Books:
rd
1. Adamson A. W. Understanding Physical Chemistry 3 Ed., Benjamin Cummings
Publishing Company Inc.
2. Akhtar M.N.& Ghulam Nabi, Textbook of Physical Chemistry, ilmi Kutab Khana,
Lahore.
3. Bhatti H.N. and K.Hussain, Principles of Physical Chemistry; Carwan Book House,
Lahore.
4. Maron S.H. & B. Jerome, Fundamentals of Physical Chemistry, Macruthan Publishing
Co., Inc. New York. (Also published by National Book Foundation).
5. Atikins P.W.& M.J.Clugston, Principles of Physical Chemistry Pitman Publishing
Company (1988).
th
6. Moore W.J. Physical Chemistry, 5 Ed. Longmans Publishers.
7. Jones M. Elements of Physical Chemistry Addison-Sesky Publishing Company.
8. G.M.Barrow, International six Edition Physical Chemistry.
9. IRA. N. Levine fourth edition Physical Chemistry
10. Alberty and Danials, Physical Chemistry
11. Castallon, Physical Chemistry
12. Laidler & Meiser Physical Chemistry
13. Friemental Chemistry in Action
Code
SubjectTitle
Cr.Hrs
Semester
CHEM102 ChemistryLabI(PhysicalChemistry)
1
I
Year
Discipline
1
1. Determination of percentage composition by surface tension, viscosity and refractive
index method.
2. Determination of heat of solution for solids and liquids.
3. Quantitative measurement of colored salt of KMnO4, K2Cr2O7 in colorimeter.
4. Study of first order reaction:
a) Study of hydrolysis of methylacetate
b) Measurement of rate constant
5. Measurement of molecular weight by; Depression of freezing point.
6. Determination of transition temperature of Na2SO4 10 H2O ; Na2CO3 10 H2O; MgSO4 7
H 2O
Recommended Books:
Crocleford H.D., H.W.Biard, F.W. Getzen & J.W. Nowell, Laboratory Manual of
Physical Chemistry, 2nd Ed., John Wiley & Sons London.
2.
Das R.C. and B. Behera, Experimental Physical Chemistry, Tata McGraw Hill
Publishing Company Limited.
3.
Levitt B.P., Findlays Practical Physical Chemistry, 9th Ed., Longman Group
Limited.
1.
Code
SubjectTitle
Cr.Hrs
Semester
CHEM103 ChemistryII(InorganicChemistry)
3
II
Year
Discipline
1
Periodicity
Modern periodic table; Similarities and differences in first row elements, their diagonal and
vertical relationship with other elements; Electro negativity of elements (Pauling and
Mullikan scales); Polarizability and polarizing power of ions; Periodicity in the properties of
transition and inner transition elements.
Theories of Chemical Bonding
Nature and types of chemical bonding; Modern concept of valence bond theory (VBT),
molecular orbital theory (MOT) and their applications to homo and hetero di-and polyatomic
inorganic molecules, explaining the conventional and modified MO diagrams; Valence shell
electron pair repulsion theory (VSEPR), explaining the shapes of inorganic molecules (i.e.
AB2, AB3, AB2E, AB4, AB3E, AB2E2, AB5, AB4E, AB3E2, AB2E3, AB6, AB5E, AB4E2) and
directed valence theory (Hybridization), Metallic bonds (detailed concept).
Acid-Base Concept
General concept of acids and bases. Detail of Lewis concept of acids and bases; Soft and hard
acid-base (SHAB) concept and its applications. Relative strength of acids and bases based on
Pk values. Reactions of acids and bases. Relationship between redox reactions and acid base
reactions. Indicators and theory of indicators.
Chemistry of d-Block Elements
Electronic configuration and oxidation states of transition elements. Metallurgy of chromium,
nickel and copper. Theories of coordination compounds, valence bond theory (VBT),
molecular orbital theory (MOT) and crystal field theory (CFT) for tetrahedral and octahedral
complexes. Nomenclature and Isomerism in coordination compounds. Chelates. Application
of coordination compounds.
Nuclear Chemistry
Phenomena of radioactivity; Natural radioactivity, Radioactive disintegration series, rate of
disintegration and half life period, Mass defect and binding energy, nuclear stability;
measurement of nuclear radiation, Wilson cloud chamber and Geiger-Muller counter, Carbon
dating; Artificial radioactivity and nuclear transformations, Nuclear reactions (fission and
fusion), Uses of radioactive isotopes; Biological effect of nuclear radiation.
Chemical Industries
Glass, Soda ash and Soap.
Recommended Books:
1.
Cotton, F, Albert, Goeffrey Wilkinson and Paul L. Gaus, Basic Inorganic
Chemistry, John, Wiley & Sons Ine, 3rd Edition (1995).
2.
Lee, J.D., Modem Inorganic Chemistry, Champan & Hall, 5th Edition (1996).
3.
Jolly, William, L., Modem Inorganic Chemistry, McGraw Hill, 2nd Edition (1991).
4.
5.
6.
7.
Shriver, D.F., P.W. Atkins and C.H. Langford, Inorganic Chemistry,

Oxford, 2nd Edition (1996).
Sharp, A.G. Inorganic Chemistry, Longman, 3rd Edition (1992).
Rayner Canham, Geiof., Descriptive Inorganic Chemistry & Co. (1995).
Jefferey, G.H., j. bassett, J.Mendham and R.C. Denney, Vogels text book of
Quantitave Chemical analysis, 5th Education, Benjamin Cummings, (1989).
Code
SubjectTitle
Cr.Hrs
Semester
CHEM104 ChemistryII(InorganicChemistry)
3
II
Year
Discipline
1
PAPER CHROMATOGRAPHY
Separation & identification of cations/basic radicals of group I, II.A, II.B & III. Also
calculate their Rf values.
ARGENTOMETRY
MOHRS METHOD
1) Determine the %age purity of NaCl (rock salt)
2) Determine the amount of NaCl in the commercial sample of soda ash.
VOLHARDS METHOD
1) Determination of %age purity of HCl.
2) Determination of silver in the given sample, using KSCN or NH4SCN.
REDOX TITRATIONS (By using both internal and external indicators)
3
1) Determination of amount/dm of FeSO4.7H2O with K2Cr2O7.
2) Determination of %age purity of K2Cr2O7 by using standard solution of Mohrs salt.
3) Determination of number of water molecules (x) in FeSO4. xH2O using K2Cr2O7.
2+
4) Determination of Ca by KMnO4.
5) Determination of %age of iron in ferric alum (NH4)2SO4.Fe2(SO4)3.24H2O using
K2Cr2O7.
COMPLEXOMETRY
1) Standardization of EDTA solution by magnesium/zinc sulfate solution.
2+
2) Find out the amount of Ca in the given sample of marble (lime stone).
2+
2+
3) Determination of Ca and Mg in the sample by using EDTA.
Books Recommended:
Vogel, A.I.A. Text Book of Macro and Semi micro-qualitative Inorganic Analysis,
Longamn Green & Co., (1995).
2.
Skoog, D.A., D.M. West and F.J. Holler, Analytical Chemistry, 6th Edition,
Saunders College Publications, (1994).
3.
Javed Iqbal, Amin, Theory and Practice of chromatography, Higher Education
Commission, Islamabad, (2002).
1.
Code
SubjectTitle
Cr.Hrs
Semester
CHEM111 FundamentalsofChemistry
3
I
Year
Discipline
1
Physics
Atomic structure, Periodic table and Atomic properties, Types of Chemical Bonding,
Gaseous, and Liquid states of matter.
Nature of covalent bond, Lewis structure, bond length. bond angles and bond
energies. localized and delocalized bonding resonance valence bond theory and molecular
orbital concepts. Hybridizations. Sp3. Sp2, and Sp orbital. Dipole moments, inductive and
resonance effects, rules for relative contribution from different resonance structures.
Modern concepts using mathematics for understanding the principles, Fundamental
laws, Atomic molecular structure, states of matter. Equilibrium, Kinetic, and elementary
inorganic, organic, and nuclear chemistry. Physical chemistry
Recommended Books:
1. Physical Chemistry by W.J. Moore, Prentice Hall College Div: 4th edition. tune 1972.
2. Basic Inorganic Chemistry by Cotton Wilkinson LeGain 3rd Ed. 1995.
3. Organic Chemistry by T.R. Morrison and R N. Boyd Allyn and Bacon Inc.
Longman Higher Education Division (a Pearson Education company); January 1,
1979.
4. Organic Chemistry by Khairat & Rahman. The Caravan Book House.
Code
SubjectTitle
Cr.Hrs
Semester
CHEM201 ChemistryIII(OrganicChemistry)
3
III
Year
Discipline
2
Basic Concepts in Organic Chemistry
Hybridization of orbitals of carbon atoms in alkanes, alkenes, alkynes and arenes.
Hybridization of orbitals of nitrogen, oxygen and sulfur atoms in various functional groups,
Localized and delocalized chemical bonding; Conjugation and hyper conjugation; Resonance,
rules of resonance, resonance energy, resonance hybrid, factor effecting the resonance;
Inductive effect, applications of inductive effect and resonance on various properties of
organic compounds; Steric effect and its applications, Hydrogen bonding and its effects on
various properties of organic compounds, Tautomerism.
Nomenclature of Organic Compounds
Nomenclature of alkanes, alkenes, alkynes, cycloalkanes, bicycycloalkanes, spiroalkanes,
Monofunctional and polyfunctional derivatives of open chain and cyclic compounds;
Polysubstituted benzenes; Polycyclic hydrocarbons such as naphthalene, anthracene,
phenanthrene and their derivatives; Heterocyclic compounds.
Hydrocarbons
a) Alkanes and Cycloalkanes
Preparation of alkanes from alkyl halides, coupling of alkyl halide and alkylboranes,
reduction of carbonyl compounds, Kolbes electro synthesis, Corey-house-synthesis,
hydrogenation of alkenes and alkynes.
Reactions of alkanes with halogens, their mechanism and comparison of reactivities of
halogens; combustion, isomerization, nitration and sulfonation.
Preparations of cycloalkanes by Freund synthesis, Hydrogenation of cyclic alkenes,;
Structure and stability of cycloalkanes; Reaction of cycloalkanes.
b) Alkenes and Alkynes
Preparation of alkenes from elimination reaction of alkyl halides and alcohols;
Mechanism and orientation of eliminations; Dehalogenation of vicinal dihalides with
mechanism; Pyrolytic eliminations.
Reactions of alkene; relative stability and reactivity; Addition of halogens, additions of
halogen acids and the rules governing these reactions, hydration reactions, oxidation
reactions including epoxidation and hydroxylation, polymerization; Simon-Smith and
Diels-Alder reactions.
Preparation of alkynes by carbide process, dehydrohalogenation of dihalides and
alkylation of terminal alkynes.
Reactions of alkynes: addition reactions with mechanisms, hydration reactions, oxidation,
reduction, hydroboration, formation of metal acetylides, polymerization (linear and closed
chain).
c) Aromatic Hydrocarbons
Structure of benzene, Resonance energy of benzene, Aromaticity, criteria for aromaticity,
Evidences of aomaticity; Natural sources of aromatic hydrocarbons; Preparation of
aromatic hydrocarbons by different methods.
Reaction of aromatic hydrocarbons: electrophilic aromatic substitution reactions i.e.
nitration, halogenation, Friedel-Crafts reaction and its limitations, sulfonation;
Orientation and reactivity of substituted benzenes;
Nucleophilic aromatic substitution reactions; reaction such as addition,

hydrogenation, Birch reduction, and oxidation reactions of side chains.
Polycyclic aromatic hydrocarbons like naphthalene, anthracence and phenantharene, their
resonance structures and relative stabilities; Synthesis of naphthalene; Electrophilic
substitution reactions of naphthalene; Oxidation and reduction reactions; Brief description
of orientation and reactivity of naphthalene
Isomerism
Conformational isomerism: conformational analysis of ethane, n-butane,
cyclohexane, mono- and di-substituted cyclohexanes.
Optical isomerism: optical activity; chirality and optical activity; enantiomers,
diastreomers; racemates and their resolution; D, L and R, S conventions; Optical
Isomerism in cyclohexanes, biphenyls and allenes
Geometrical Isomerism: cis and trans isomers; E-Z convention; Determination of
configuration of the isomers; Inter-conversion of geometrical isomers; Geometrical
isomerism in cyclic compounds.
Alkyl halides
Preparation of alkyl halides from alcohols and carboxylic acids;
Chemical reactions: Aliphatic nucleophilic substitution reactions, SN1 and SN2 mechanism,
effects of the nature of substrate, attacking nuclophile, leaving group and the nature of
solvent. Elimination reactions, E1 and E2, mechanisms, orientation of elimination ( Hoffmann
and Sytzeff rules).
Grignard Reagents; synthesis, structure, and reactions with active hydrogen compounds,
carbonyl compounds such as aldehydes, ketones, esters, acid halides and CO2; Reactions with
nitriles, ethylene oxide, sulphur and oxygen.
Chemistry of Hydroxyl Group containing Compounds and Ethers
Alcohols: Physical properties; Preparation of alcohols by the reduction of carbonyl
compound,; Reactions of alcohol with metals, organic and inorganic acids; Oxidation of
alcohols; Distinction between primary, secondary and tertiary alcohols; Preparation of diols,
triols and their important reactions and uses.
Phenols: Physical properties; Synthesis of phenols; Reactions of phenols such as acylation,
Friedel-Crafts reaction, nitration, sulfonation, carbonation, formylation and diazo coupling.
Ethers: Physical properties; Preparation of ethers from alcohols, alkyl halides and alkenes;
Reactions of ethers; Brief introduction of crown ethers and polyethers.
Recommended Books:
C.K. Ingold, Structure and mechanism in organic chemsitry, C.B.S.
I.L.Finar, Organic Chemistry, Vol. I, Pearson Education, L.P.E.
I.L.Finar, Organic Chemistry, Vol. II, 5th Edition, L.P.E.
Jerry March, Advanced Organic Chemistry, Reaction, Mechanism and Structure, 5th
Edition, Wiley Inter Science.
5.
Morison and Boyd, Organic Chemistry, 6th Edition, Prentice Hall.
6.
Seyhan N. Ege, Organic Chemistry Structure and Reactivity, 3rd Edition, The
University of Michigan, A.I.T.B.S. Publishers & Distributors (Regd.).
7.
Thomas H. Lowry, Kathleen Schueller Richardson Mechanism and Theory in
Organic Chemistry, 3rd Edition, Harper and Row Publishers, New York.
8.
Alder, Baker, Brown, Mechanism in Organic Chemistry, Wiley Publishers.
9.
Atkins Carey, Organic Chemistry, A Brief Course, 2nd Edition.
10.
Peter Sykes, A guide book to mechanism in organic chemistry, 6th Edition, Pearson
Education, Singapore.
1.
2.
3.
4.
10
11.
12.
13.
14.
15.
Carruthers, Modern Methods of Organic Synthesis, Cambridge low

Priced Edition, Cambridge.
Harris, Wamser, Fundamentals of Organic Reaction Mechanism, Wiley Publishers.
G. Malcolm, Dyson, A Manual of Organic Chemistry, Vol. I.
Canant Blat, The Chemistry of Organic Compound, 5th Edition.
R. Panico, W.H.Powell, Jean-Claude Richer, A guide to IUPAC Nomenclature of
Organic Compounds, Blackwell Sci. Publication, 1993.
11
Code
SubjectTitle
Cr.Hrs
Semester
CHEM202 ChemistryLabIII(OrganicChemistry)
1
III
Year
Discipline
2
1) Compound Analysis
Identification of organic compounds containing only one functional group with special
emphasis on compounds containing following functional groups.
-COOH, -OH, C=O, -NH2, and CONH2
2) Basic Experimental techniques used in organic chemistry
1) Filtration
2) Simple and fractional distillation
3) Solvent extraction
4) Sublimation
5) Re-crystallization
6) Column Chromatography
3) Estimations (volumetric)
1) Determination of molecular weight of a carboxylic acid.
2) Estimation of amide group and glucose.
Recommended Books:
K.M.Ibne Raza, M.A. Rehman, Abdur Rehman, Organic Chemistry, The Carvan
Book House, Lahore.
2.
B.S. Furniss, Vogels T.B of Practical Organic Chemistry, Addison Wesley
Longman, Inc. 1989.
3.
Frederick George Mann and Saunder, Practical Organic Chemistry, The English
Language Book Society, 1960.
4.
Daniel R. Palleras, Experimental Organic Chemistry , John Willey & Sons Inc.,
2000.
5.
James A. Moore, Experimental methods in Organic Chemistry, Holt-Saunders Int.,
1983.
6.
R.L. Shriner, R.C Fuson, D.V. Curtin and T.C Morrill The systematic identification
of organic compounds, 6th ed. John Willey & sons, 1979.
1.
12
Code
SubjectTitle
Cr.Hrs
Semester
CHEM203 ChemistryIV(GeneralChemistry)
3
IV
Year
Discipline
2
Quantum Mechanics and Atomic Structure:
Elementary treatment of Compton effect and photoelectric effect; Brief discussion of result of
Bohrs Model and its defects; Somerfields modification and evolution of azimuthal quantum
number; Dual nature of matter; Verification of dual nature by Davisson and Germers
experiment; Detail of Heisenbergs uncertainty principle; Postulates of quantum mechanics;
Brief introduction of operators; Derivation of time independent Schrodinger wave equation in
terms of polar coordinates and derivation of principle quantum number; Energy equation for
free motion of particle in one-dimensional box; Eigen values and Eigen functions;
normalization of wave function; Probability functions; radial distribution, probability density
functions.
Electrochemistry:
Electrolytic conduction and its measurement; Specific, equivalent and molar conductance,
Determination of resistance; Cell content, conductance ratio, conduction of strong and weak
electrolytes; Ionic motilities and their determination; Kohlrauschs law and its applications;
Faradays law (first and second) and their significance; Transport number; Hittorts rule;
Determination of transference number by Hittorts method. Applications of conductance
measurement; EMF of the chemical cells; Electrode potential and its measurement with
reference to Weston standard, glass electrode, calomel electrode and quinhydrone electrode;
Nerst equation; Thermodynamics of cells; Concentration of cells with liquid junction and
without liquid junction.
Evaluation of Analytical Data and Essentials of Chemical Analysis:
Some fundamental concepts like mole, activity and activity co-efficient; Concepts of mean,
median, accuracy, precision, significant figures; Various types of errors, their detection and
elimination; Standard deviation; Relative standard deviation; Confidence limits; Rounding
off the analytical data. Law of mass action and its applications; precipitation and solubility
product; common ion effect; Co-precipitation, fractional precipitation, concept of pH, buffers,
working of indicators.
Spectroscopy:
Electromagnetic radiation and its interaction with matter; Nature of different transitions
possible in atoms and molecules; Electronic, vibrational, rotational and other possible
transitions by absorption of radiation by molecules and atoms. Development of spectroscopic
analytical techniques employing various transitions.
Classification of spectroscopic
techniques on the basis of type of radiation, phenomenon occurring and the nature of the
matter. Basic introduction to atomic and molecular spectroscopic techniques including flame
emission, spectrophotometry, UV, IR spectroscopy.
Chemistry of Carbonyl Compounds:
Preparation of aldehydes and ketones by pyrolysis of calcium salts of acids, acylation of
alkenes and arenas, reduction of acid halides and nitriles. Physical properties of aldehydes
and ketones; Structure and reactivity of carbonyl group; Comparison of the reactivity of
aldelydes and ketones; Nucleophilic additions of water, alcohols, ammonia and its
derivatives, hydrogen cyanide, bisulfite, reduction and oxidation reactions; Aldol
condensation and related reaction; Cannizaros reaction; Witting reaction; Oxidation
reactions, Chemical tests of aldehydes and ketones.
13
Chemistry of Carboxylic Acids and Their Derivatives:

Physical properties of carboxylic acids; Effects of different parameters on the acid strengths
of aliphatic and aromatic carboxylic acids. Chemical properties like salt formation
nucleophilic acylt substitution, reduction of carboxylic acids, decarbonylation, Hunsdicker
reaction, Kochi reaction, substitution at a-carbon. Preparations, properties and reactions of
acids chlorides, acids anhydrides, amides, cyanides, and esters; Malonic and acetoacetic
esters syntheses.
Recommended Books:
1.
Adamson A. W. Understanding Physical Chemistry 3rd Ed. Benjamin Cummings
publishing company Inc.
2.
Akhtar M.N. & Ghulam Nabi, Textbook of Physical Chemistry ilmi kutab khana,
Lahore.
3.
Bhatti H.N. and K. Hussain, Principles of Physical Chemistry; Carwan Book
House, Lahore.
4.
Shriver, D.F., P.W. Atkins and C.H. Langford, Inorganic Chemistry; Oxford, 2nd
Ed. (1996).
5.
Snarp, A.G. Inorganic Chemistry, Longman, 3rd Edition (1992).
6.
Rayner Canham, Gelof, Descriptive Inorganic Chemistry & Co. (1995).
7.
Daniel R. Pallers, Experimental Organic Chemistry, John Willey & Sons Inc., 2009.
8.
James A. Moore, Experimental methods in Organic Chemistry Holt-Saunders Int.
1983.
9.
R.L. Shriner, R.C. Fuson, D.lV. Curtin and T.C. Morrill The systematic
Identification of organic compounds, 6th ed. John Willey & sons, 1979.
14
Code
SubjectTitle
Cr.Hrs
Semester
CHEM204 ChemistryLabIV(GeneralChemistry)
1
IV
Year
Discipline
2
1) Verification of first law of Faraday by electroplating of CuSO4, NiSO4, Cr2 (SO4)3, Ag+
CN and Au+ CN.
2) Conductometeric and potentiometric titration using conductivity bridge and pH meter.
3) Measurement of reduction potential using of Zn, Cu, Ag, Al etc. by using calomel
electrode.
4) Verification of Langmuir Isotherm.
5) Thin layer chromatography.
Preparations:
1) Ferric Alum
2) Potassium tri-oxalato aluminate
3) Sodium Thiosulfate
4) Amm. Coppr (II) Sulphate
Iodometry:
1) Determination of iodide and Kl in the given sample solution.
2) Standardization of Na2S2O3. 5H2O solution.
3
3) Determination of amount/dm of Cu2+ in CuSO4. 5H2O using Na2S2O3 and Kl.
4) Determination of number water molecules (x) in CuSo4 xH2O.
Preparation of Organic Compounds:
Preparation and techniques of purification of tribrmophenol, nitrobenzene, aspirin, ethyl
benzoate and benzoic acid from toluene, butyl chloride, acetanilide.
Estimations (volumetric):
1) Determination of molecular weight of a carboxylic acid.
2) Estimation of amide group and glucose.
Recommended Books:
1.
Crocleford H.D. H.W. Biard F.W. Getzen & J.W. Nowell, Laboratory Maual of
Physical Chemistry 2nd Eddition John Wiley & Sons London.
2.
Skoog, D.A., D.M. West and F.J. Holler, Analytical Chemistry 6th Ed. Saunders
College Publications (1994).
3.
Javed Iqbal Amin, Theory and Practice of Chromatography, Higher Education
Commission, Islamabad. (2002).
4.
James A. Moore, Experimental methods in Organic Chemistry, Holt-Saunders
Int.,1983.
5.
R.L. Shriner, R.C., Fuson D.V. Curtin and T.C. Morrill The systematic identification
of organic compounds, 6th Ed. John Willey & Sons 1979.
15
Code
SubjectTitle
CHEM301 PhysicalChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
V
1. Electrochemistry:
Idea of conductance of electrolytes, Deby-Huckle equation and limiting law, ionic
strength, weak electrolyte and Deby-Huckle theory, Activity and activity coefficients of
electrolytic solution, determination of activities, concentration cells, Types of
concentration cells, derivation of E.M.F of concentration cells with and without
transference, Fuel cells and hydrocarbon cells.
2. Quantum Chemistry:
Postulates of quantum theory, Eigen functions, operators, Schrdingers wave equation,
particle in one dimensional box, Normalized wave function and orthogonality, Quantum
mechanical tunneling, motion of particle in three dimensional box and idea of
degeneracy, separation of variables and derivation of quantum numbers, Mathematical
treatment of rigid rotator and calculation of bond length of simple molecules, harmonic
oscillator and calculation of bond length of simple molecules, harmonic oscillator and
calculation of vibrational frequencies, formation of covalent bond, Mathematical
treatment of He2+ and H2 molecules, discussion of overlapping integrals, molecular
orbital theory and formation of H2 and O2 molecules.
3. Chemical kinetics:
Concept of rate law and order of reaction, Kinetics of 3rd order reaction with different
concentrations and molecular identity, kinetics of opposing, parallel and consecutive
reactions, basic experimental methods, Kinetics of thermally excited chain reactions like
reaction of H2 and Br2, kinetics of thermal decomposition of ozone, N2O5 and CH3CHO.
RECOMMENDED BOOKS:
1. Physical Chemistry, Samuel Glasstone, 1995. Macmillan and Co. Ltd. St. marlins Street,
London.
2. Principles of Physical chemistry, Maron and Prutton, 1965 the Macmillan Company,
Collier Macmillan Ltd. London.
3. Physical Chemistry, Barrow, 1973, McGraw Hill, Tokyo.
4. Physical Chemistry, Moore, 1972, Rentice Hall, Englewood cliffs, Jersey.
5. Physical Chemistry, Alberty and Daniels, 1962, McGraw Hill Book Company Ltd
London.
6. Physical chemistry, Alkins, 1989, Oxford University Press, Walton Street, Oxford.
Physical Chemistry, Castallan, 1972, Addson Westey Publishing Company, Menla Park,
California, London.
16
Code
SubjectTitle
CHEM302 PhysicalChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
V
1. Basic Concepts:
Preparation of standard molar and Normal solutions and percentage.
compositions of different compounds
2. Chemical Kinetics:
To investigate the kinetics of hydrolysis of ethyl in the presence of an acid.
To determine the relative strength of acids (HCl and H2SO4) studying the hydrolysis of an
ester.
3. Electric conductance of electrolytes:
To determine the cell constant of given cell.
To determine the equivalence conductance of solution of weak electrolyte.
At a no. of dilution at room temperature and from this result to verify Oswalds law.
To determine the solubility of sparingly soluble salt.
To determine the solubility of weak base of NH4 OH by titrating it against Standard
solution of HCl by using conductivity method.
To determine the strength of given base by titrating it against standard Acetic acid
solution and HCl solution using conductivity meter.
To determine the strength of HCl and CH3 COOH in the given mixture of both by
titrating it against NaOH conductometrically.
To determine the equivalent conductance of a weak electrolyte at infinite dilution using
Kohlraush law.
4. Phase Equilibria:
To determine the partition coefficient of benzoic acid and iodine between CCl4 and H2O.
RECOMMENDED BOOKS:
1. Advanced Experimental Physical Chemistry by Ayodhya Sing.
2. Experimental Physical Chemistry by Daniel
3. Experimental Physical Chemistry by G.Peter Mattews.
4. Experiments in Physical Chemistry by Shoemaker.
17
Code
SubjectTitle
CHEM303 InorganicChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
V
1. Pi- acceptor Ligands:

Transition metal carbonyls (Mononuclear, Binuclear, Poylnuclear), synthesis, bonding
situation based on spectroscopic evidences; Theoretical rationalization of molecular
structures, (close, nido, erachno), Synthesis. Characteristics and reactivity of derivatives of
metal carbonyls (carbonylate anions, carbonyl hydrides and carbonyl halides); Metal nitrosyls
including halonitrosyl and their derivatives.
2. Chemical bonding:
Metallic bond on the basis of band model, X-ray spectra and N(E) curves, n(E) curves.
Binding energy in metals, conductors, semi-conductors and insulators. Effect of temperature
and impurities on conductivity.
3. Coordination Compounds:
(Structure & Bonding)
Development of coordination compounds, Rules of inorganic nomenclature for acids, salts,
radicals, ions, iso and heteropoly anions & compounds. Hybridization in coordination
compounds with coordination number from 2 to 9. MO diagrams for metal complexes of
common geometry. Important features of CFT, d-orbitals splitting for various common
geometries, measurement of 10 Dq., factors effecting 10 Dq. CFSE, factors influencing
magnitude of variation in lattice and hydration energy for ions of first transition series.
RECOMMENDED BOOKS:
1. J H Huheey, Inorganic Chemisry - Principles, structure and reactivity, Harper
and Row Publisher, Inc. New York (2008)
2. 3) J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London
3. Chemical Bonds, and introduction to atomic and molecular structure by H.B. Gray 1973,
W.A. Benjamin, Inc., London
4. Advanced Inorganic Chemistry F.A. Cotton and G.Wilkineon 6th Ed. 2001, Interscience,
Publishers, London.
5. Coordination Compounds by S.F.A. Kettle, 1999, Nelson , (Nauohi Kenya).
18
Code
SubjectTitle
CHEM304 InorganicChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
V
1. Chromatographic Techniques:
(a) Separation of metal ions by paper chromatography and their identification with the
help of locating agents and comparison of Rf values.
(b) Separation of anions by paper chromatography and their identification.
2. Aqueous acid-base Titrations:
(a) Estimation of SO2 and SO3 in air and discharged from an industrial process.
(b) Estimation of CO2
(c) Estimation of oxalic acid and H2SO4 in a mixture.
(d) Estimation of H3BO3 and NaH2BO3 in a mixture.
(e) Determination of %age composition of a mixture containing H3BO3 and
CH3COOH.
3. Precipitation Titrations:
Estimation of following anions with the help of adsorption indicators:
(i) Chloride (ii) Bromide (iii) Sulphate (iv) Chloride and Iodide in a mixture.
RECOMMENDED BOOKS:
1. J. Bassett, R. C. Denny, G. H. Jeffery and J. Mendham, Vogels Text Book of qualitative
Inorganic Analysis, the English Language Book Society and Longman, New York, (2008)
2. Quantitative Analysis Chemistry, James S. Pritz, George H. Sehenk, 2001 Alby and
Becon Inc. London.
3. Theory and practice of chromatography by Prof. Dr. Javed Iqbal (2002).
4. Instrumental analysis by Gary D. Christian and James E.O., Reilly, 2007, Allyn and
bacon Inc., London.
5. Hand Book of Organic reagents in Inorganic Analysis by ZAVIX Holzbecher and other
1976 Ellis Hurwod Limited, London.
19
Code
SubjectTitle
Cr.Hrs
Semester
CHEM305 OrganicChemistry
4
V
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
1. Acid-base strength:
pKa and Ka values, electronic effects (Inductive and resonance effects), field effect,
solvent effect, hyper-conjugation, hydrogen bonding, steric and stereo-chemical effects,
and hybridization.
2. Stereochemistry:
(a) Conformation Analysis
The concept of conformational analysis in ethane, propane, n-butane, pentane,
cyclopentane, cyclohexane, substituted alkanes, substituted cycloalkanes and
decalins.
(b) Optical isomerism:
Configuration, Chirality and symmetry, optical isomerism upto three chiral carbon
atoms, enantiomers and diastereomers, R and S nomenclature, Racemates,
Racemization and Resolution of Racemates, epimerization. Walden inversion,
Stereoisomerism in biphenyls, allenes and spiro-compounds
(c) Geometrical isomerism
Cis & Trans, and Z & E conventions, Determination of configuration, Geometrical
isomerism in cyclic compounds.
3. Active Methylene Compounds:
Alkylation, arylation, and acylation of active methylene compounds, Acid and base
catalysed aldol condensation. Conditions, mechanism and synthetic applications of the
following reactions; Claisen, Claisen Schmidt, Knoevenagel, Perkin, Reformatsky, and
Stobbes condensations, Darzens glycosidic ester synthesis, Mannich and Wittig
reactions.
RECOMMENDED BOOKS:
1. Organic Chemistry, Volume I (6th ed.) & II (5th ed.) by I.L. Finar, Pearson Education
(singapore) Pte Ltd, 2008.
2. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed.
by Michael B. Smith, Jerry March, Wiley, 2007
3. Organic Chemistry, 5th ed.; by S. H. Pine, McGraw Hill: New York,1987
4. Organic Chemistry 6th ed. by Francis A. Carey, McGraw Hill, 2005.
5. Organic Chemistry 6th ed, by R. T. Morrison, R. N. Boyd, and R. K. Boyd, Benjamin
Cummings, 1992,.
6. Modern Synthetic Reactions 2nd ed. by H.O.House , W.A. Benjamin Inc., Menlo Park,
CA
7. Principles in Organic Synthesis by R.O.C Norman & J. M. Coxon, Chapman and Hall,
1993
8. Organic Chemistry by Jonathan Clayden, Nick Geeves, Stuart Warren, Oxford
University Press 2000.
20
Code
SubjectTitle
CHEM306 OrganicChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
V
1. Organic Preparations:
Benzyl alcohol; Ethyl benzene; benzilic acid, p-Nitrophenol, acetophenone oxime,
acetophenone arylHydrazone.
2. Quantitative and Qualitative Analysis of Organic compounds:
Estimation of glucose, and Number of acetyl groups, two component mixture analysis.
RECOMMENDED BOOKS:
1. Practical Organic Chemistry by F. G. Mann and B. C. Saunders, Longman, UK, 1978.
2. Vogel's Textbook of Practical Organic Chemistry (5th ed.) by A.I. Vogel, A.R.
Tatchell, B.S. Furnis, A.J. Hannaford, P.W.G. Smith, 1989, Longman UK, 1989.
3. The Systematic Identification of Organic Compounds, (8th ed.) by Ralph L. Shriner et al.,
Wiley, 2003.
4. Advanced Practical Organic Chemistry, by J. Leonard, B. Lygo, G. Procter, CRC, 1994.
5. Advanced Practical Organic Chemistry (2nd ed.) by N. K. Vishnoi, Vikas Publishing
House Pvt Ltd, India, 1996.
21
Code
SubjectTitle
CHEM307 AnalyticalChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
V
1. Introduction / Assessment of Analytical Data

Introduction and scope of Analytical Chemistry: Analytical problems and their solutions; The
nature of analytical methods; trends in analytical methods; Different units of concentration
and their conversion; Definition and basic concepts: nature and origin of errors, Classification
of errors; Accuracy and Precision; Limits of detection, Confidence limits; Deviation,
Standard deviation, Application of statistical tests; Rounding off analytical data; Quality
control charts; Computation of analytical data. Significance of sampling, weighing and
measuring in Analytical chemistry.
2. Basic Chromatography Techniques
Classifications of Chromatographic Techniques, Paper and Thin Layer Chromatographic
Techniques; their instrumentation, applications and limitations,
Column Adsorption Chromatography,
3. Introduction to Spectroscopy / Spectrophotometry
Introduction to Molecular spectroscopy, absorption in UV and Visible range; Basic principle
of Spectrophotometry; Beer-Lamberts law; Deviations; Instrumentation and application.
RECOMMENDED BOOKS:
1. Analytical Chemistry by J.D. Dick, McGraw Hill, 1973, N.Y. also available in
International students edition McGraw Hill, Mogakusha, 1973.
2. Instrumental Methods by W.Ewing, Mc Graw Hill Book Co. N.Y. (Third/Fourth Edition)
also available in International students edition.
3. Chromatography by R.K Sharma , Gogel publishing home meerret
4. Introduction to chromatography by Nasir-ud-din, Published by author
5. Paper chromatography by Dr.Friedrich Cramer, London Macmillan and Co Ltd
6. Thin- layer chromatography by Marini, Elservier publisher
7. Modern analytical chemistry by David Harvey, Roohani-art press, Islamabad
8. Principle and Practice of analytical chemistry by Fillfield, Blackwell Science Ltd
9. Spectroscopy by Browing, Mcgram Hill London
10. Fundamentals of Chromatography by H.G. Cassidy, Inter Science Publisher,
London, N.Y.
11. Fundamentals of Analytical Chemistry by Doughlas Skoog and Donals M. W. West, Holt
Reinchart and Inc, London.
22
Code
SubjectTitle
CHEM308 AnalyticalChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
V
1. Calibration
Calibration of glassware (pipette, burette and flask) used for volumetric analysis. Use of
analytical balance and calculation of standard deviation. Calibration of pH meter and
determination of pH of various acidic and basic solution.
Calibration of conductometer and determination of conductance of tap water, distilled water,
conductivity water and canal water.
Calculation of dissociation constants of various acids.
Calculation of variance, mean, median, coefficient of variance of the data.
2. Basic Chromatography
Separation of ink components by paper chromatography.
Separation of amino acids by thin layer chromatography.
Separation of dyes by column chromatography.
Separation of mixtures by circular paper chromatography.
RECOMMENDED BOOKS:
1. Vogels, s text book of quantitative inorganic analysis by J. Bassett. The English language
book Society and Longman.
2. Introduction to chromatography by Nasir-ud-din, Published by author.
3. Paper chromatography by Dr.Friedrich Cramer, London Macmillan and Co Ltd.
4. Thin- layer chromatography by Marini, Elservier publisher.
23
Code
SubjectTitle
CHEM309 AppliedChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
V
1. Chemical Industrial Unit Operations:

Brief introduction to Chemical Industry with reference to Pakistan, Elementary treatment
of general unit operations commonly used in Industry such as heat transfer; Evaporation;
size Reduction; Screening; Filtration and Distillation.
2. Industrial Inorganic Synthesis:
Raw materials; Chemical processes involved; flow sheet diagrams with all the important
parameters concerned with the manufacturing of Sulphuric acid; Hydrochloric acid;
caustic Soda; Washing soda; Applications of these chemicals in industry.
3. Cement Industries:
Cement raw materials used for cement manufacturing, dry process, wet process, semi wet
process, special cement, chemistry involved in hydration of cement, setting of cement,
setting time.
4. Water Softening and Scale Removing:
Water hardness; its measurement and removal; methods used for water softening
including ion-exchange and reverse osmosis, distillation and precipitation. Types of boiler
scales. Chemical and mechanical methods to eliminate the scaling.
RECOMMENDED BOOKS:
1. Industrial Organic Chemicals, by H.A.Witcoff and B.J.Reuben, John Wiley & Sons Inc.
New York.
2. Water Supply and Sewerage, T.J.McGhee, McGraw Hill Book Co. New York.(1991)
3. Unit operations in Chemical Engineering, Chattopadhyay, Khanna Publishers, Delhi6.(1993).
4. Chemical Process Design, Robin Smith, McGraw Hill Book Co. New York.(1995).
5. Hand Book of Industrial Chemicals, By SIRI Board of Consultants and Engineers,
6. Small Industries Research Institute, New Delhi (1995)
7. Small Medium and large Scale Industries, A.K. Sirivastawa, Small Industries Research
Institute, New Delhi (1996).
8. The Chemistry of Cement, H.F.W. Taylor, Academic Press, London, 1964.
9. Shereves Chemical Process Industries, 5th Ed.1975 by G.T.Austin McGraw Hill Book
Co. New York.
10. Industrial chemistry, B. K. Sharma Krishna Prakashan Media (P) Ltd., Ed-15 (2006)
24
Code
SubjectTitle
CHEM310 AppliedChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
V
1. Preparations:
Detergent and cosmetics (Cold cream, shampoo and vanishing cream)
2. Titrimetery:
Estimation of water hardness by complexometery
Estimation of acetic acid contents in the vinegar sample
Determine the acidity of the sulphuric acid and its normality.
Determination of acidity, alkalinity, Free CO2 in water
Assay of bleaching powder by free chlorine method.
Determine the %age purity of the Commercial sample of sodium chloride.
3. Flamephotometery:
Estimation of Potassium in the tap water.
Estimation of Sodium in the Commercial Sodium Chloride.
Estimation of Calcium in milk.
4. Spectorphotometery:
Determination of the of KMnO4, K2Cr2O7 and CoCl4
5. Chromatography:
Separation of mixture of ink by circular paper chromatography.
Separation of mixture of metal ions by paper chromatography.
Coating of TLC plates and separation of mixture of dyes.
Separation of different pigments of plant extract by TLC chromatography.
RECOMMENDED BOOKS:
1. Perfumes Cosmetics and Soaps, W.A. Poucher, chapmann and Hall 7th Ed. (1974).
2. Applied Chemistry Theory and Practice O.P. Vermani & A.K. Narula, Wiley Eastern
Limited (1989).
3. T. B. of Quantitative Inorganic Analysis, Vogals Ed-4th, Longman Group Limited
(1978).
4. Practical Statistics for the Analytical Scientist, A Bench Guide, RSC Publishing, LGC
Ltd 2009
25
Code
SubjectTitle
CHEM311 BioChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
V
1. Introductory Biochemistry:
Scope of Biochemistry. The molecular logic of life. Structure and Functions of Cells. Cell
wall Composition. A brief description on the isolation of cellular components.
2. Water:
Weak interactions in aqueous system. Ionization of water. Weak acids and weak bases.
pH and buffer systems. Different buffering agents. Importance of buffers in biological
systems.
3. Carbohydrates:
Nature, Structure and Classification of Carbohydrates. Aldoses and Ketoses Cyclic
structure of monosaccarides Hawarth configurations, D and L configuration of
monosaccharides, Optical isomerism and Mutarotation in glucose. Formation of
Glycosidic bonds. Reducing and non reducing sugars. Important monosaccharide and
their derivatives. Invert sugars. Biological significance of Glucose. Structures and
functions of common Disaccharides and Polysaccharides: Succrose, Lactose, Maltose
Amylose and Amylopectins. , Cellulose, Chitin, Glycogen, Starch and Dextran. Derived
carbohydrates and hexose derivatives present in microorganisms. Sensory properties of
monosaccharides. Proteoglycan and glycoproteins: their Structure and function.
Hyluronic acid Chondroitin Sulphate and related compounds.
4. Nucleic acids:
Purines, Pyrimidines and nucleotides. Structure and functions of DNA, different type of
RNA. Nucleic acid hydrolysis. Determination of Primary structure of Nucleic acids.
Chemical synthesis of oligonucleotides.
RECOMMENDED BOOKS:
1. Principles of Biochemistry by Lehninger AL, Nelson DL and Cox MN, 2000 Pub:
worth Publishers
2. Biochemistry by Lubert Stryer 2006 Pub: Freeman and Company
3. Biochemistry by Voet, and Pratt, 2004, John wiley and sons Inc.
4. Lippincotts Biochemistry by Champe.P C; Harvey. R. A and Ferrier. D. R. 3rd ed.,
2004 Pub: J. b. Lippincott Company
5. Harpers Biochemistry, 27th ed. 2006 Pub: McGraw Hill Inc.
26
Code
SubjectTitle
CHEM312 BioChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
V
1. Carbohydrates:
Qualitative tests for Carbohydrates. Distinction between pentoses and hexoses, aldoses
and Ketoses, reducing and non reducing sugars mono and polysaccharides.
Chromatography of sugars. Preparation of glycogen from liver. Acid and enzymic
hydrolysis of glycogen.
2. Nucleic Acids:
Isolation of RNA from beef liver. Isolation of DNA from Calf Spleen. UV absorption of
nucleic acids.
RECOMMENDED BOOKS:
1. Practical clinical Biochemistry by Varley. Pub: CBS publishers
2. An Introduction to Practical Biochemistry By D. T. Plummer Pub: McGraw Hill
27
Code
SubjectTitle
CHEM313 PhysicalChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
VI
1. Kinetics of bimolecular reactions:

Mathematical treatment of collision and transition state theory of bimolecular reactions,
effect of temperature on reaction rates, the interpretation of bimolecular reactions in
solution, ionic reaction in solution, unimolecular gas phase reactions, fast reactions and
their methods of study.
2. Classical Thermodynamics:
Maxwells relations and thermodynamics formula, second law of thermodynamics,
Clausius inequality, the entropy of non ideality of a gas, Nerst heat theorem, its
applications to solid and gases, Nerst approximation formula, third law of
thermodynamics and determination of entropy by third law, Experimental verification of
third law. Adiabatic demagnetization.
3. Statistical Thermodynamics:
Sterlings approximation, statistical treatment of entropy, partition function and its
physical significance, absolute entropy and partition functions, interpretation of
thermodynamic functions in terms of translational, rotational vibrational and electronic
partition functions, Free energy and equilibrium constant from partition function.
4. Kinetic theory of Gases:
Introduction, Maxwell distribution of molecular velocities and energies, Derivation of
average velocity and most probable velocity, Barometric formula, effect of altitude, molar
mass and temperature on vertical distribution of particles.
Note Suggested out lines for Mathematics Course:
Basic Mathematics for Chemistry (1 Credit Course):
Review of basic algebra and trigonometry, concept of function,
Differentiation, concept of maxima and minima, integration, Differential
Equations, equations of straight lines, partial fraction, Applications of
Calculus in Chemistry and data handling.
RECOMMENDED BOOKS:
1. Physical Chemistry by Kundu, N and Jain, S.K.,S. Chand and Company Ltd. 1984.
2. Fundamentals of Chemical kinetics by Logan, S.R., Longman Group Ltd. 1996.
3. Elementry reaction kinetics by Latham. J.L. and burgess, A.E., 3rd Ed., Butterworths,
London, 1997.
4. Physical Chemistry by Atkins, P.W., 5th Ed., W.H. Freeman and Company, New Yark,
1994.
5. Physical Chemistry by Alberty, R.A. and Silbey, R.J., John Wiley, New York, 1995.
6. Physical Chemistry by Engel, T. and Ried, P., 1st Ed,. Pearson education, Inc. 2006.
28
7. Electrochemical Methods and applications by bard, A. and Faulkner, L.R.,

John Wiley, New York, 1980.
8. Principles of Physical Chemistry by Maron and Prutton, Macmillan and Co. Ltd. 1965.
9. Physical Chemistry by Glasstone, S. Macmillan and Co. Ltd., London, 195.
10. Elements of classical and statistical thermodynamics by Nash, L.K. Addison Wesley Co.
Ltd., 1979.
11. Mathematics for Chemists.
29
Code
SubjectTitle
CHEM314 PhysicalChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
VI
1. Refractrometery:
To determine the unknown concentration of sucrose solution and ethanol solution.
2. Molar mass determination (Colligative properties):
To determine the molecular weight of a substance by cryoscopic method and
Ebullioscopic method.
3. Spectrophotometery:
To determine the wavelength of maximum absorption of compounds using
spectrophotometer.
To determine the unknown concentration of a compound using spectrophotometer.
4. Phase Equilibrium:
To determine the phase diagram of Naphthalene and diphenyl system.
To determine the phase diagram of urea and phenol.
To determine the phase diagram of Benzoic acid and Naphthalene.
5. Optical activity measurement:
To determine the unknown percentage composition of the following by using polarimeter
(Sucrose, glucose).
To determine the specific and molar rotation of optically active compound (sucrose,
glucose).
RECOMMENDED BOOKS:
1. Advanced Experimental Physical Chemistry by Ayodhya Sing.
2. Experimental Physical Chemistry by Daniel
3. Experimental Physical Chemistry by G.Peter Mattews.
4. Experiments in Physical Chemistry by Shoemaker.
30
Code
SubjectTitle
CHEM315 InorganicChemistry
Year
Discipline
3
ChemistryI,II
Cr.Hrs
4
Semester
VI
SYLLABUS OUTLINE:
1. The Covalent Bond (Structure & Reactivity):
(a) VSEPR model followed by VB theory (Hybridization, Resonance etc.,) explanation
of the structure of AB2, AB3, AB2E, AB4, AB3E, AB2E2, AB5, AB3E3, AB6, AB5E,
AB4E2, AB7, AB6E, AB8 and AB9 type molecules.
(b) Discussion of molecular orbitals and molecular structures of homonuclear molecules
and ions, heteronuclear diatomic and polyatomic molecules and ions.
(c) Bent bond, bridge bond, four electrons-three centre bond.
(d) Shielding effect and effective nuclear charge, Factors affecting the magnitude of
and Zeff and their variation in the period table, Applications of Slaters rules,
Polarization of ions, Fajans rules and its applications.
(synthesis and properties)
2. Co-ordination compounds:
Preparative methods. Techniques of studying complexes, stability constants. The
spectrochemical series and colour of metal complexes. Diamagnetism and Para
magnetism, stereochemistry, John-Teller Theorem, Isomerism. Role of metal complexes
in analytical chemistry, industry and nature.
3. Chemistry of the Lanthanides and Actinides
Nomenclature, Position in periodic table, occurrence, Separation, and electronic
configuration, oxidation States, Complex Formation, shapes of f-orbitals, applications.
RECOMMENDED BOOKS:
1. J H Huheey, Inorganic Chemisry - Principles, structure and reactivity, Harper and Row
Publisher, Inc. New York (2008)
2. J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London (2007).
3. Advanced Inorganic Chemistry F.A. Cotton and G.Wilkineon 6th Ed. 2001, Interscience,
Publishers, London.
4. Coordination Compounds by S.F.A. Kettle, 1999, Nelson , (Nauohi Kenya).
5. Coordination Chemistry by B.A. Basallo and R. Johnson 1972 W.A. Benhamen, London.
31
Code
SubjectTitle
CHEM316 InorganicChemistryLab
Year
Discipline
3
ChemistryI,II
Cr.Hrs
2
Semester
VI
SYLLABUS OUTLINE:
1. Complexometric Tritrations:
(a) Estimation of Mg+2 Zn+2 with EDTA (Direct titration).
(b) Estimation of Ni+2 with EDTA (Back titration).
(c) Determination of Ca+2 and Zn+2 in mixture (Masking)
(d) Determination of Cd2+ and Zn+2 in a mixture (Demasking).
(e) Determination of SO42- and PO4-3 with EDTA (Indirect titration).
2. Redox Titrations:
(a) Use of Ceric sulphate solution for the estimation of the following:i). Determination of iron in an iron ore.
ii). Determination of nitrites.
(b) Use of potassium iodate for the determination of the followings:
(i) Copper (ii) H2O2
(iii) Commercial Hypochlorite
3. Preparations:
(a) Tris (ethylenediamine ) nickle (II) Chloride 2-hydrate.
(b) Sodium Cobaltinitrite.
(c) Pot. Trioxalato Aluminate.
(d) Ammonium sulphate Nickel (II) Sulphate.
(e) Hexa aqua Chromium (III) Chloride.
(f) Ammonium Sulphate Copper (II) Sulphate Pentahydrate.
RECOMMENDED BOOKS:
1. J. Bassett, R. C. Denny, G. H. Jeffery and J. Mendham, Vogels Text Book of qualitative
Inorganic Analysis, the English Language Book Society and Longman, New York, (2008)
2. Quantitative Analysis Chemistry, James S. Pritz, George H. Sehenk, 2001 Alby and
Becon Inc. London.
3. Theory and practice of chromatography by Prof. Dr. Javed Iqbal (2002).
4. Instrumental analysis by Gary D. Christian and James E.O., Reilly, 2007, Allyn and
bacon Inc., London.
5. Hand Book of Organic reagents in Inorganic Analysis by ZAVIX Holzbecher and other
1976 Ellis Hurwod Limited, London.
6. Experimental Inorganic Chemistry - W. G. Palmer, 2005.
7. The analysis of minerals and ores of the rarer elements W. R. Schoeller,and A. R.
Powell, Charles, Griffin and Company Limited,2004.
32
Code
SubjectTitle
CHEM317 OrganicChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
VI
1. Free radical Reactions:

Introduction, generation methods, relative stability, structure, free radical reactions and
industrial applications.
2. Oxidation and Reduction reactions:
(a) Oxidation Reactions:
Introduction, Oxidation of saturated hydrocarbons, olefinic double bonds, aromatic
rings, systems containing oxygen such as alcohols, aldehydes, ketones, oxidative
decarboxylation, of acids, oxidation of systems containing nitrogen such as amines,
hydrazines etc..
(b) Reduction Reactions:
Introduction, Reduction of alkenes, alkynes, and aromatic rings, hydrogenolysis,
reduction of benzylic and allylic systems, aldehydes and ketones, alcohols, pinacols,
epoxides, acids and their derivatives, Reduction of system containing nitrogen such
as imines, oximes and nitro compounds
3. Spectroscopy:
(a) IR Spectroscopy:
Electromagnetic radiations: IR; modes of vibration, sampling techniques, factors
influencing the vibration frequencies and industrial applications
(b) UV Spectroscopy:
Ultraviolet (UV) or electronic spectroscopy: electronic transition; factors
influencing the max. value.
RECOMMENDED BOOKS:
1. Organic Chemistry, Volume I (6th ed.) & II (5th ed.) by I.L. Finar, Pearson Education
(singapore) Pte Ltd, 2008.
2. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed. by
Michael B. Smith, Jerry March, Wiley, 2007.
3. Organic Chemistry, eth Ed.; by S. H. Pine, McGraw Hill: New York, 1987.
4. Organic Chemistry 6th ed. by Francis A. Carey, McGraw Hill, 2005.
5. Organic Chemistry 6th d, by R. T. Morrison, R. N. Boyd, and R. K. Boyd, Benjamin
Cummings, 1992.
6. Modern Synthetic Reactions 2nd ed. by H.O.House , W.A. Benjamin Inc., Menlo Park,
CA
7. Principles in Organic Synthesis by R.O.C Norman & J. M. Coxon,1993, Chapman and
Hall, 1993.
8. Organic Chemistry by Jonathan Clayden, Nick Geeves, Stuart Warren, Oxford University
Press 2000.
33
9. Spectroscopic Methods in Organic Chemistry 6th ed. by D. Williams and I.

Fleming. Wiley-VCH, 1991.
10. Spectrometric identification of Organic Compounds 6th ed. by R. M. Silverstein and F.
X. Webster, Wiley, 2007.
11. Organic Spectroscopy and Chromatography by M Younas, ILMI, Pakistan, 2007.
34
Code
SubjectTitle
CHEM318 OrganicChemistryLab
Year
Discipline
3
ChemistryI,II
Cr.Hrs
2
Semester
VI
SYLLABUS OUTLINE:
1. Organic Preparations:
Synthesis of compounds containing nitro, halogeno, amino, carboxylic and carbonyl
functionalities (depends upon the availability of chemicals).
2. Quantitative and Qualitative Analysis of Organic compounds:
Physical/ Chemical separation of mixture containing two compounds, identification and
derivitization.
RECOMMENDED BOOKS:
1. Practical Organic Chemistry by F. G. Mann and B. C. Saunders, Longman, UK., 1978.
2. Vogel's Textbook of Practical Organic Chemistry (5th ed.) by A.I. Vogel, A.R.
Tatchell, B.S. Furnis, A.J. Hannaford, P.W.G. Smith, Longman UK, 1989.
3. The Systematic Identification of Organic Compounds, (8th ed.) by Ralph L. Shriner et al.,
Wiley, 2003.
4. Advanced Practical Organic Chemistry, by J. Leonard, B. Lygo, G. Procter, CRC., 1994.
5. Advanced Practical Organic Chemistry (2nd ed.) by N. K. Vishnoi, Vikas Publishing
House Pvt Ltd , India., 1996.
35
Code
SubjectTitle
CHEM319 AnalyticalChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
VI
Ion Exchange Chromatography:

Cation Exchange resin, Anion Exchange resin, Cross-linkage, Effect of pH-separation of
Amino Acids, Separation of metal ions on Anions Exchange Columns, Applications of ion
Exchange Chromatography.
Solvent Extraction:
Basic principle of solvent extraction, The Distribution Coefficient, The Distribution Ratio,
The Percent Extracted Solvent Extraction of Metals, Analytical Separations, Multiple Batch
Extractions, Countercurrent Distribution, Solid-Phase Extraction, Solvent Extraction by Flow
Injection Analysis.
Electrophoresis:
Capillary Zone Electrophoresis, Application of traditional Electrophoresis
Gel Chromatography.
Flame Emission:
Basic principle of atomic spectroscopy; Use of atomic spectra for detection and determination
of elements; flame as a source of atomization and excitation; Instrumentation involved in
FES; applications and limitations.
Atomic Absorption Spectroscopy:
Basic Principle of AAS; Flameless AA spectroscopy including graphite furnace and hydride
generation.
RECOMMENDED BOOKS:
1. Vogels, text book of Quantitative chemical analysis byJ.mendham, RCDenny, JDBarnes,
MJ KTHomas, Pearson education Ltd.
2. Advances in electrophoresis by Andrea Chrmambach , Wiiley- VCH.
3. Ion-Exchange Chromatography by Helfferich, McGraw Hill Book Co., Inc. N.Y. London.
4. Solvent Extraction by Gorge H. & Morrison Hener, John Wiley and sons, London, N.Y.
5. Chromatographic Methods of Analysis by Stock & Rice, Elsevier Co. Amsterdam.
6. Flow injection analysis by Ruzicke hassen, wiley interscience.
36
Code
SubjectTitle
CHEM320 AnalyticalChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
VI
Flame Emission / Spectrophotometry:

Determination of Sodium in tap water by using Flame Photometer.
Determination of Potassium in tap water by using Flame Photometer.
Find out the calcium in chalk sample by flame photometry.
Determination of Ba by flame photometry.
Estimation of purity of various compounds on the base of flame emission Spectrophotometry.
Indirect determination of various compounds by flame photometric techniques.
Determination of max of KMNO4 and K2Cr2O7 by using spectrophotometer.
Verification of Beer and Lambert Law.
Ultraviolet spectrophotometric determination of Aspirin, Phenacetion and Caffeine in APC
tablet using Solvent Extraction.
RECOMMENDED BOOKS:
1. Vogels, s text book of quantitative inorganic analysis by J. Bassett. The English language
book Society and Longman
2. Flame spectrometry in environmental chemical analysis. A practical guide (RSc)
analytical spectroscopy series by Malcolms Cresser alfreds sanz medel ,http// www.
Amazon.co.uk
37
Code
SubjectTitle
CHEM321 AppliedChemistry
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
4
Semester
VI
1. Chemical unit processes:

Elementary treatment of general unit Chemical unit processes, Nitration; Halogenation;
Sulphonation; Hydration and Hydrogenation and Oxidation with real examples from
Industry.
2. Industrial Organic Synthesis:
Raw materials; Chemical processes involved; flow sheet diagrams with all the important
parameters concerned with the manufacturing of Oxalic acid; Pthalic anhydride; Acetic
acid; Phenol; Ethyl Acetate; Butadiene and Styrene
3. Glass Industries:
History of glass, raw materials used for glass, methods of manufacturing, various types of
furnaces and crucibles used for the manufacture of glass, special types of glass, their
manufacture and properties.
4. Soap and Detergent Industries:
Processes involved in soap manufacturing, methods used for manufacture of laundary
soap, typical soaps. Recovery of glycerine. Detergents or surface active agents, cationic,
anionic and non-ionic agents.
RECOMMENDED BOOKS:
1. Shereves Chemical Process Industries, 5th Ed.1975 by G.T.Austin, McGraw Hill Book
Co. New York.
2. Industrial Organic Chemicals, by H.A.Witcoff and B.J.Reuben, John Wiley & Sons Inc.
New York.
3. Riegals handbook of Industrial Chemistry, Ed. J.A.Kent, CBS Publkishers and
Distributors, New Delhi.(1997).
4. Chemical Process Design, Robin Smith, McGraw Hill Book Co. New York.(1995).
5. Hand Book of Industrial Chemicals, by SIRI Board of Consultants and Engineers, Small
Industries Research Institute, New Delhi (1995).
6. Chemistry of glass manufacturing, F.W.Hunter, Dower Publications, New York, 1950.
7. Industrial chemistry, B. K. Sharma, Krishna Prakashan Media (P) Ltd., Ed-15 (2006).
38
Code
SubjectTitle
CHEM322 AppliedChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
VI
1. Preparations:
Dentrifrice, Thermosetting and thermoplastic resins (alkyd and urea formaldehyde)
2. Chromatography:
Coating of TLC plates and separation of mixture of dyes.
Separation of different pigments of plant extract by TLC chromatography Packing of
chromatographic column and separation of a mixture of dyes. Separation of -carotene from
the pulp of tomato and carrot by column chromatography.
3. Titrimetery:
Analysis of soda ash and caustic soda in a mixture. Determine the active material in the
commercial sample of detergent by cationic titration. Determining the %age purity of sodium
bicarbonate and sodium carbonte. Determination of Residual Chlorine in water. 5age of
reducing sugars. Soap anlalysis for free and combined alkali.
4. Spectorphotometery:
Estimation of nickel in vanaspati ghee.
Estimation of chloride in the tannery effluent.
Estimation of Iron in Pharmaceutical Products.
Estimation of Phosphates in fertilizers.
RECOMMENDED BOOKS:
1. Perfumes Cosmetics and Soaps, W.A. Poucher, chapmann and Hall 7th Ed. (1974).
2. Applied Chemistry Theory and Practice, O.P. Vermani & A.K. Narula, Wiley Eastern
Limited (1989).
3. T. B. of Quantitative Inorganic Analysis, Vogals Ed-4th, Longman Group Limited
(1978).
4. Practical Statistics for the Analytical Scientist, A Bench Guide, RSC Publishing, LGC
Ltd 2009.
39
Code
SubjectTitle
Cr.Hrs
Semester
CHEM323 BioChemistry
4
VI
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
1. LIPIDS:
Lipid Classification, Structures and functions. Chemical Properties of triglycerides.
Phospholipids. Sterol/steroids. Lipid with specific biological activities. Prostaglandins:
Structure and function. Properties of lipid aggregates: Micelles and Bilayers. Biological
membranes. Membrane proteins, Membrane structure and Assembly. Fluid Mosaic
model. The erythrocyte membrane.
2. PROTEINS:
Amino acids: their Structure, Chiral Center, and stereoisomerism. Classification of amino
acids. Acid base properties, their titration curve and its importance. . Amino acid
sequence. Peptides and their biological importance. Proteins: classification, Covalent
structure and biological significance including Primary. Secondary, Tertiary and
Quaternary structure of proteins, as Keratins, Collagens and elastin. Conformation and
function of globular proteins with special reference to structure and function of
Hemoglobin and Myoglobin. Biological significance of Proteins.
3. ENZYMES:
Chemical nature, nomenclature and classification of enzymes. Cofactors and Coenzymes.
Concepts of Active site. Substrate specificity. Affect of different factors on enzyme
activity. Kinetics of single substrate reactions. Quantitative assay of enzymatic activity.
Enzyme inhibition: Competitive, non-competitive and irreversible inhibition. Regulatory
enzymes, allosteric enzymes, Multienzyme system, Zymogons, isoenzyme. Immobilized
enzymes.
4. NUTRITION:
Introduction to the science of nutrition: Nutrients and their functions Biological
evaluation of proteins, carbohydrates and lipids. Sources and forms of Energy. Energy
value of foods. Energy requirements under different living and physiological conditions.
Direct and indirect Calorimetry. Basal metabolic Rate, Respiratory quotient and their
measurements. Assessment of nutritional status in Pakistan. Thermogenic effects of food.
RECOMMENDED BOOKS:
1. Principles of Biochemistry by Lehninger AL, Nelson DL and Cox MN, 2000
Pub:
worth Publishers
2. Biochemistry by Lubert Stryer(2006) Pub: Freeman and Company
3. Lippincotts Biochemistry by Champe.P C; Harvey. R. A and Ferrier. D. R. 3rd ed., 2004
Pub: J. b. Lippincott Company
4. Nutritional biochemistry by T. Brody 1994, Pub: Acadmic Press
5. Harpers Biochemistry, 27th ed. 2006 Pub: McGraw Hill Inc.
40
Code
SubjectTitle
CHEM324 BioChemistryLab
Year
Discipline
3
ChemistryI,II
SYLLABUS OUTLINE:
Cr.Hrs
2
Semester
VI
1. Lipids:
Qualitative tests for lipids including fatty acids, sterols and phospholipids. Lipids
separation from Calf brain tissue. Acid value, Saponification Value and Iodine Value of
fats. Extraction and TLC of Wheat Lipids.
2. Amino Acids and Proteins:
Qualitative tests of amino acids, determination of isoelectric Point. Isolation and
solubilization of proteins from plant and animal origin.Hydrolysis of proteins. Estimation
of proteins by Kjeldahl method. Isolation of enzyme amylase, a study on its properties
and catalytic activity.
RECOMMENDED BOOKS:
1. Practical clinical Biochemistry by Varley. Pub: CBS publisher
2. An Introduction to Practical Biochemistry By D. T. Plummer 3rd ed. (1987) Pub:
McGraw Hill
41
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4401
Yeear
4
Subjectt Title
Environmentaal Chemistryy
Cr. Hrs
2
Sem
mester
V
VII
Discipline
D
Chemistry
C
SYLLAB
BUS OUTLIN
NE:
1. Introduction:
Historry and sign
nificance of environmenttal degradatiion, impact of the moddern life-stylle on
enviroonmental quaality, resourcee dep} at envvironmental conservation
c
and sustainaability povertyy and
enviroonmental deg
gradation, envvironmental education
e
, innstitutions forr the protectioon of environnment,
inter-ddisc nature off environmenntal studies, ennvironmental segments.
2. Atmoospheric pollu
ution:
Imporrtance of air, nature and coomposition of
o atmospheree, temperaturee and pressuree profi of diffferent
layerss of the atmossphere, comm
mon air polluttants and theiir sources, oxxides of C, N, and S hydroologic
cycle,, green housee effect and global warm
ming, stratosphheric ozone depletion, veehicular emissions,
particculate matter and aerosols, airborne lead, acid rain
r
and its impats, phootochemical smog,
s
photoochemistry of the atmospheere, role of hyydroradicals, indoor
i
air quaality.
3. Wateer pollution and

a water treeatment:
Imporrtance of watter, physical and chem. Properties
P
of water, criteria for water quality, BOD
D and
COD,, sources off water polllution (indusstrial, agriculltural, municcipal and naatural), fertillizers,
pesticcides, detergeents, heaw metals,
m
bio-acccumulation and bio-implliflcat primarry, secondaryy and
advannced treatmen
nt of water.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
7.
Kumaar. Environmeental Chemisttry, Wiley Eaastern, New Delhi.

D
J.W. Moore
M
& EM
M. Moore, Envvironmental Chemistry,
C
Accademic Presss, New York.
S. K. Banerji, Enviironmental Chhemistry, Preentice Hafl, Delhi.
D
nmental Chem
mistry, Tata Publisher,
P
Delhi.
K. Baanerji, Environ
Staneley E. Manah
han, Environm
mental Chemiistry, Brooks, California.
Neil, P.O. Environ
nmental Chem
mistry, Chapm
mann, Londonn.
Bairdd, C. Environm
mental Chemiistry, Freemann, New York.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4402
Yeear
4
Subjectt Title
Environmentaal Chemistryy
Cr. Hrs
2
Sem
mester
VIIII
Discipline
D
Chemistry
C
SYLLAB
BUS OUTLIN
NE:
1. Land
d pollution:
Imporrtance of soil, nature and composition
c
o soil, macroo and micro-nnutrients in soil, soil erosioon, pH
of
of sooil and nutrrients availabbility, on-exxchange in soil,
s
sourcess of soil poollution (inddustry,
agrochemicals, min
ning, munioppal waste, litteering), reclam
mation of soil.
2. Chem
micals in the Environmen
E
nt and their im
mpact:
Chem
mical speciatio
on, heavy meetals, persisteent organic pollutants,
p
afllatoxins, PCB
Bs, pesticidees and
deterggents, house hold chemiicals, solventts. Impact of chemicals on human health, cropss and
vegetaation, buildin
ngs and monuments, aquatiic life, biodivversity, visibillity, concept of
o green chem
mistry.
3. Moniitoring of En
nvironmentall Pollution an
nd Legislatioon:
Princiiple, applicatiions of analyytical techniquues for monittoring of polllution with sppecial referennce to
OC, HPLC.
H
UV
V and IR speectrometry, Atomic
A
absorrption spectroscopy. Legiislation aspeccts of
enviroonmental polllution, internaational standaards regardingg environmenntal pollution.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
7.
Kumaar. Environmeental Chemisttry, Wiley Eaastern, New Delhi.

D
J.W. Moore
M
& EM
M. Moore, Envvironmental Chemistry,
C
Accademic Presss, New York.
S. K. Banerji, Enviironmental Chhemistry, Preentice Hafl, Delhi.
D
nmental Chem
mistry, Tata Publisher,
P
Delhi.
K. Baanerji, Environ
Staneley E. Manah
han, Environm
mental Chemiistry, Brooks, California.
Neil, P.O. Environ
nmental Chem
mistry, Chapm
mann, Londonn.
Bairdd, C. Environm
mental Chemiistry, Freemann, New York.
BS(4Ye
ears)forA
AffiliatedCo
olleges
Code
Subjeect Title
CHEM-4403
Physsical Chemisstry (Sp. Theeory-I)
Yeear
4
Cr. Hrs
C
4
Sem
mester
V
VII
Discipline
D
Chemistry
C
SYLLAB
BUS OUTLIN
NE:
1. Collooids and Surffactants:
Colloids, Colloidal disspersions, solss and their prreparation, prooperties of suspensions, Optional
O
propperties
of sols, determination
d
of particle size,
s
kinetic properties
p
of sols, sedimenntion of susppensions, elecctrical
propertiess of sols, eleectrophoresis and electro osmosis, stabbility of susppensoids, preecipitation off sols,
associatedd colloids, maacromolecularr properties inn solutions annd molecular weight determ
minations.
2. Advaance approacch to homogeenous and heterogeneous kinetics:
Adsorptioon isotherms, single system
m, double sysstem, study off gas reactionns on solid surfaces, retarddation,
the Eley--Rideal mech
hanism and the
t Langmuirr-Hinshelwoood mechanism
m to study some
s
organicc and
inorganic reactions, Caatalysis, Autoocatalysis, enzzyme catalysis and enzymee inhibition.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
7.
8.
Physical Chemistry
y by Kundu, N and Jain, S.K.S. Chand and Companyy Ltd. 1984.
Fundaamentals of ch
hemical kinettics by Logann, S.R, Longm
man Group Lttd. 1996.
Elemeentry reaction
n kinetics by Latham.J.L.
L
A Burgess, A.E.3rd Ed.,, Butterworthss, London, 19977.
And
Physical chemistry
y by Atkins, P.W.
P
5th Ed., W.H.Freemaan and Compaany, New Yorrk, 1994.
Physical Chemistry
y by Alberty, R.A. and Silbbey. R.J., Johhn Wiley, New
w York, 19955.
Physical chemistry
y by Engel, T.. and Ried, P.., 1st Ed., Peaarson Educatioon, Inc. 2006.
Hand book of surfaace and Collooid Chemistryy by Birdi, K.S., CRC Presss, 1997.
Heterrogeneous Caatalysis: Princciples and appplications byy Bond, G.C
C., 2nd Ed., Oxford,
O
Clareendon
press,, 1987.
9. Surfacctants and intterfacial Phennomena by Roosen, Milton J.,
J John Wileyy, New York,, 1978.
BS(4Years)forrAffiliatedColleges
Codee
CHEM- 404
4
Yeear
4
Subjecct Title
Physiccal Chemistrry (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Rotattional and Viibrational Sp
pectroscopy
Special reegions and claassification of spectroscoppy; Rotationall energies of diatomic mollecules, popuulation
of Rotatioonal energy leevel. Rotationnal spectra of rigid linear molecules
m
andd determinatioon of bond lenngths.
The Starkk effect.
Viberationnal spectroscopy: energy of an atomicc molecule, haarmonic and harmonic oscillator molecules,
relative poopulation of energy
e
levels and intensitiees of transitioon, types of viibrational modes.
Vibratinall of polyatom
mic moleculess, interpretatiion of IR speectra of simplle molecules,, Fermi resonnance,
applicatioons and samplling techniquees.
2. Photoo Chemistry::
Laws of photochemistr
p
ry, quantum efficiency
e
andd its determinnation Photocchemical reactions, excitedd state
symbols; photosensitizzed reactions, phosphorescence, fluoresccence, chemilluminescencee, Lasers.
3. Advaanced Treatm
ment of Soluttions:
The therm
modynamic properties
p
of solution. Thhe solution process.
p
Condditions of equuilibrium bettween
phases. Theoretical
T
baasis of Raoullts equation. Deviation
D
from ideal behaavior. Compouund formatioon and
associatioon. Separation
n of solid soluutions.
RECOMMENDED BOOKS:
B
Physical Chemistry
Fundaamentals of ch
Elemeentry reaction
L
And
Physical chemistry
y by Atkins, P.W.
P
Physical Chemistry
w York, 19955.
Physical chemistry
O
Clareendon
press,, 1987.
1.
2.
3.
4.
5.
6.
7.
8.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4405
Yeear
4
Subject Title
Physiccal Chemistrry (Sp. Practtical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
V
VII
BUS OUTLIN
NE:
SYLLAB
1. Moleccular Mass Determinatio

D
on of differen
nt Polymers by
b Visosity measurement
m
t.
2. Therm
mo-chemicall measuremeents
(i) Heat
H of solutio
on of a salt byy solubility methods.
(ii) Heat
H of precipiitation.
3. Collooidal State:
Prepaaration of As2
2 S3 sol, and comparison
c
o precipitatinng powers of different
of
d
catioons.
4. Specttrophotometrry:
(i) Detemination
D
of
o percentagee compositionn of two colouured componeents in solutioon.
(ii) Sttudy of kinetiics of iodinatiion of acetonee and decompposition of beenzene diazonnium chloride.
(iii) Prredicting norm
mal modes off vibration forr simple moleecules and intterpretation off their IR Speectra.
B
RECOMMENDED BOOKS:
1.
2.
3.
4.
mental Physiccal Chemistryy by Ayodhyaa Sing.

Advaanced Experim
Experrimental Physsical Chemisttry by Daniel
Experrimental Physsical Chemisttry by G.Peterr Mattews.
Experriments in Ph
hysical Chemiistry by Shoem
maker
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4422
Yeear
4
Subjectt Title
Physiccal Chemistrry (Sp. Theorry-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
BUS OUTLIN
NE:
SYLLAB
1. Nucleear Chemistrry:
Compposition of th
he nucleus, natural
n
and artificial
a
radiooactivity, ratee of radioacttive disintegrration,
radioaactive equilib
brium, transformation off elements cyclotron
c
and linear acccelerators; nuuclear
processes; nuclearr fission, atomic bomb, nuclear
n
reactor, nuclear fusion,
f
hydroogen bomb, steller
s
h
use of
o tracers in chhemistry.
energy, radiation hazards,
2. Advaance Approacch to Osmosiis and Osmottic Pressure::

Semi Permeable membranes.
m
The cause of
o semi-permeeability. Meechanism of osmotic pressure.
Dilutee solutions and
a the Gas Laws. The Bombardmennt theory. Obbjections to the Bombarddment
theoryy. Review of the theories. Determinatioon of the moleecular weightt by Osmomeetry.
3. Gels and
a Emulsio
ons:
Introdductions, Metthods of Prepaaration of Em
mulsions. Em
mulsifiers, Breaking of emuulsions. Orienntation
Theorry. Emulsificcation and wetting, Significcance.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
7.
8.
Physical Chemistry
Fundaamentals of ch
Elemeentry reaction
L
And
Physical chemistry
y by Atkins, P.W.
P
w York, 19955.
Physical Chemistry
Physical chemistry
O
Clareendon
press,, 1987.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4423
Yeear
4
Subject Title
Physiccal Chemistry (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
1. Polym
mers:
Classiification of polymers; kiinetics of coondensation, addition andd co-polymerisaiton reacctions;
Moleccular mass distribution,
d
d
determination
n of molecullar masses by
b different methods.
m
Annalysis
techniiques.
2. Electrronic and Ra
aman Spectrroscopy:
Princiiples of electtronic transitiion. Types of electronic transition. Energies
E
of atomic
a
orbitall-with
refereence of H-atom
m spectrum electronic
e
anggular momentuum fine struccture of H-atom spectrum.
Ramaan Spectra-ideea of Raman scattering, Rayleigh
R
scatttering Molecuular poparazaability. Rotaational
Ramaan Spectra of
o linear Moolecules. Symmetric topp molecules and sphericcal top moleecules
Vibraational Raman
n spectra.
B
RECOMMENDED BOOKS:
Physical Chemistry
Fundaamentals of ch
Elemeentry reaction
L
And
Physical chemistry
y by Atkins, P.W.
P
Physical Chemistry
w York, 19955.
Physical chemistry
O
Clareendon
press,, 1987.
1.
2.
3.
4.
5.
6.
7.
8.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4424
Yeear
4
Subjectt Title
Phyysical Chemisstry (Sp. Praactical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
VIIII
BUS OUTLIN
NE:
SYLLAB
1. Polarrimetric Stud
dy of Reactioon Kinetics:
Inverssion of cane sugar;
s
salt efffects on inverssion of cane sugar.
s
2. Equillibrium constant for the reaction:
r
I2 +
I3
Calcuulation of G for the formaation of I3 reaaction.
3. Adsorrption measu
urements:
Verifiication of Freeundlich and Langmuir
L
adssorption isothherms for Adssorption of acetic acid on active
a
charcooal
4. Poten
ntiometric measurementss:
A.
Potentiomeetric Titrationns
(i)
B.
Acid
A base (ii))
Oxidatioon-reduction
Equilibrium
m constant deetermination.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
Advaanced Experim
mental Physiccal Chemistryy by Ayodhyaa Sing.
Experrimental Physsical Chemisttry by Daniel
Experrimental Physsical Chemisttry by G.Peterr Mattews.
Experriments in Ph
hysical Chemiistry by Shoem
make.
BS (4 Years)
Y
for Affiliated
d Colleges
Codee
CHEM-4406
Yeear
4
Subjecct Title
Inorgaanic Chemisttry (Sp. Theoory-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Stereochemistry and
a bonding in main grou
up compoun
nds:
Introdduction, direccted valence theory,
t
three center bond model, correelation diagraam approach, some
qualittative failuress of the simplee theories critticism and com
mparison of simple
s
modells, d-P bonds.
2. Perioodicity:
First and second row anomallies. The usee of d-orbitaals by non-m
metals, reactivvity and d-oorbital
particcipation. The use of p-orbbitals in Pi-boonding, perioodic anomaliees of the nonn-metals and posttransition metals.
3. Organic Reagentss used in Inorganic Analyysis:
Classiification of organic reagennts, their selecctivity and sppecificity, meethods of prepparation of sppecific
compounds and th
heir studies with
w
UV, Visible and IR. Typical reaagents used in
i complexom
metric
titratioons involving
g the use of EDTA. Chellates, classificcation, stability, preparatiion and propeerties.
Role of
o organic Reeagents in diff
fferent analytical techniquees.
B
RECOMMENDED BOOKS:
1. Organnotransition metal
m
Chemiistry by Akiin Yamamto,, 1996, A. Wiley
W
Intersccience Publiccation
Londoon.
2. Hand Book of Org
ganic reagentts in Inorganiic Analysis by
b ZAVIX Holzbecher
H
annd other 19766 Ellis
Hurw
wod Limited, London.
L
3. Structtural Inorganiic Chemistry by Wells, A.F
F. 1975, Charrenden Press, London.
4. Stereoochemistry an
nd bonding inn Inorganic Chemistry
C
by by J.E. Fergguson 1974, Prentice
P
Hall,, New
Jersy..
5. J H Huheey,
H
Inorganic Chemisrry - Principless, structure annd reactivity, Harper and Row
R Publisherr, Inc.
New York
Y
(2008)
6. Cullenn Dolphin and James, Biollogical aspectts of Inorganiic Chemistry, 2005.
7. Williaams, An Intro
oduction to Biioinorganic Chemistry,
C
2003.
BS (4 Years)
Y
for Affiliated
d Colleges
Codee
CHEM-4407
Yeear
4
Subjecct Title
Inoorganic Chem
mistry (Sp. Theory-II)
T
Cr. Hrs
4
Sem
mester
V
VII
Discipline
D
Chemistry
C
BUS OUTLIN
NE:
SYLLAB
1. Chem
mistry of Oxides:
Physical states and
d structures of oxides of thhe elements, covalent
c
oxiddes, periodic trends in struucture
p
state,, acidity, soluubility, practiccal uses, and environmenttal chemistry of volatile oxxides,
and physical
close packed anio
ons, metal oxides,
o
electrrical conducctivity of sollid lonic com
mpounds, sppinels,
perovvskites, high teemperature suuperconductoors, magnetic properties in mixed metal oxides.
2. Reacttions in aqueous and non-aqueous sollvents:
Classiification of so
olvents, typess of reactions,, the dielectricc constant, solubilities, electrode
e
pottential
and ellectromotive forces. Reacttions in waterr and molten salts.
s
Reactioons in non-aquueous solventts, i.e.
ammoonia, sulphur dioxide, brom
mine trifluoridde and hydroffluoric acid.
3.
Radiooactivity:
Naturral radioactiv
vity, Artificiaal radioactivitty, types of radioactive rays,
r
Saddy-F
Fajans and Russel
R
groupp displacemen
nt law, Halff life period of a radioacctive substannce, Disintegrration constaant K,
Averaage life periiod, Radioacttive equilibrium, Law of
o successive disintegratioon, Activity of a
radioaactive substaance, Transm
mutation of elements,
e
Arttificial transm
mutation reacctions induceed by
differrent bombard
ding projectilles, Applicattions of artifficial transmuutation reacttions, Naturaal and
artificcial radioactiv
ve series.
B
RECOMMENDED BOOKS:
1. J H Huheey,
H
R Publisherr, Inc.
New York
Y
(2008)
2. Cullenn Dolphin and James, Biollogical aspectts of Inorganiic Chemistry, 2005.
oduction to Biioinorganic Chemistry,200
C
03
m
Chemiistry by Akiin Yamamto,, 1996, A. Wiley
W
Intersccience Publiccation
Londoon.
5. Hand Book of Org
b ZAVIX Holzbecher
H
Hurw
L
C
P
Hall,, New
Jersy..
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4408
Yeear
4
Subjectt Title
Inorgaanic Chemisttry (Sp. Practical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
V
VII
BUS OUTLIN
NE:
SYLLAB
1. Use of
o organic rea
agents for the estimation of various metal
m
ions;
(At leeast any fourr of the follow
wing):
(a)
(b)
(c)
(d)
(e)
3
8-Hydroxyqu
uinoline (A13+
), Ti3+), Fe3++)
3+
Pyrogallol (B
Bi )
Nitron (NO31-)
Salicyladoxiime (Ni2+ in presence of Cuu2+)
Anthranilic acid
a (Cd2+, Znn2+, Co2+)
umental metthods of anallysis:

2. Instru
(a) Conductomeetry:
i).
Titration of HCl and acetic acid with a strongg base.
ii). Precip
pitation titratioon of AgNO3
iii). Determ
mination of Ka
K for acetic acid.
a
(b)
Colorimetry
y:
i).
Micro determinatioon of chromiuum by diphenyyl Carbazide.
ii). Determ
e.
mination of irron by 1, 10 Phenanthrolin
P
iii). Determ
mination of niickel by rubeaanic acid
RECOMMENDED BOOKS:
B
1. Hand Book of Org
b ZAVIX Holzbecher
H
Hurw
L
2. J. Basssett, R. C. Denny,
D
G. H. Jeffery and J.
J Mendham, Vogels Texxt Book of quualitative Inorrganic
Analyysis, the Engliish Languagee Book Societty and Longm
man, New Yorrk, (2008)
3. Quanttitative Analy
ysis Chemisttry, James S.. Pritz, Georrge H. Sehennk, 2001 Albby and Beconn Inc.
Londoon.
4. Theorry and practicce of chromatography by Prof.
P
Dr. Javedd Iqbal (20022).
5. Instruumental analy
ysis by Gary D. Christiann and James E.O., Reillyy, 2007, Allyyn and baconn Inc.,
Londoon.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4425
Yeear
4
Subjectt Title
Inorgaanic Chemisttry (Sp. Theoory-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
BUS OUTLIN
NE:
SYLLAB
1. Advan
nces in Atom
mic Spectrosccopy and Rad
dio Chemistrry:
Varioous forms off interaction of electromaagnetic radiattion with maatter, absorpttion and emiission
spectrra. Flame ph
hotometer. Atomic
A
absorrption spectrrophotometer, Inductivelyy coupled plasma
emisssion, Applicattions in cliniccal chemistry,, industry, geeochemistry, soil
s sciences and environm
mental
studiees.
2. Some Thermodyn
namic aspectss of Inorganiic Chemistryy:
Therm
modynamic and
a
kinetic stability, Intterpretation of stability, Role of thhermodynamics in
interppretative chem
mistry, The latttice energy as
a a criterion of bond type,, Quantitativee uses of the lattice
l
energy, The Kapu
ustunskii equuations, The stabilization of high oxidation statess by fluorinee and
oxygeen, The stabilization of loow oxidation states by larrge anions, Halogen
H
exchaange reactionn, The
stabiliity of halides containing protonated basses.
3. Polym
meric Inorga
anic Compou
unds (Chains,, Rings and Cages):
C
(a) Chains: Cateenatin, Homoocatenotion, Heterocatenati
H
ion, Siliconess, Silicates, Zeolites,
Z
talc, mica,
clay.
c
(b) Rings: (i) Heterocyclicc systems of borazines,
b
Phosphazenes, S-N
S rings.
(ii) Homocyclicc system of suulphur and seelenium.
ounds of phosphorus, and boron
(c) Cages compo
olymers as Coonductors.
(d) Inorganic Po
RECOMMENDED BOOKS:
B
C
P
Hall,, New
Jersy..
3. J H Huheey,
H
R Publisherr, Inc.
New York
Y
(2008)
4. Analytiical chemistry
y,G.D Christiian 2005
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4426
Yeear
4
Subjectt Title
Inorganic Chemistrry (Sp. Theory-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
BUS OUTLIN
NE:
SYLLAB
1. Inorgganic Chemisstry in Biologgical systemss:
Energgy sources fo
or life, metallloporphyrins. Photosynthhesis and resppiration. Nitrrogen fixationn, the
biochhemistry of Iro
on essential and
a trace elem
ments in bioloogical systemss biochemistrry of the nonm
metals
mediccinal chemistrry organomettallic in bio Innorganic Chem
mistry.
2. Kinettics and mech
hanisms of Reaction
R
of Coordination Compoundss:
Introdduction of reaaction rate law
w and mechannism of statioonary state appproximation. Type of reacctions,
nucleoophilic displaacements, efffective collisions. Dis-plaacement in sqquare planar complexes, transeffectt, replacemen
nt in octahedrral complexes, inert and labile
l
compleexes, (VBT, CFT explanaation),
Inner and outer sph
here exchangee reactions.
3.
Orgaano Metallic Compounds:

(Syntthesis, Structture, Bondingg & Reaction
n Pathways)
Naturre of carbon-m
metal bond, classificationn, synthesis annd propertiess of organom
metallic compoounds
(cn2-bbonded oleffin, n3-allylic, n4-cycllopentadienyll, n6-organoometallic compounds)
c
and
characcterization off organometaallic compounnds with the help of IR, NMR, mass spectrometryy etc.
Experrimental tech
hniques in Organometalli
O
ic chemistry oxidative-adddition, reduuctive eliminnation,
inserttion and de-in
nsertion reactiions, fluxionaal behaviour. Applicationss of organomeetallic compounds.
RECOMMENDED BOOKS:
B
1. Cullenn Dolphin and James, Biollogical aspectts of Inorganiic Chemistry,2005
oduction to Biioinorganic Chemistry,200
C
03
m
Chemisttry by Akin Yamamto,
Y
19996, A. Wiley Interscience Publication
P
Londoon.
4. Hand Book of Org
ganic reagentss in Inorganic Analysis by ZAVIX Holzzbecher and other
o
1976 Elllis
Hurw
L
nd bonding inn Inorganic Chhemistry by by
b J.E. Fergusson 1974, Preentice Hall, New
N
Jersy..
7. J H Huheey,
H
Inorganic Chemisrry - Principless, structure annd reactivity, Harper
8. and Row
R Publisherr, Inc. New York
Y
(2008)
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4427
Yeear
4
Subjectt Title
Inorgaanic Chemisttry (Sp. Practical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
VIIII
BUS OUTLIN
NE:
SYLLAB
1. Chromatographicc Techniquess:
(a) Column and thin layer tecchniques for the
t qualitativee analysis of inorganic
i
com
mpounds.
(b) Applicationss of solvent exxtraction and ion exchangeers technique.
2. Instru
umental Metthods of Anaalysis:
(a) Potentiometeery:
i).
Determ
mination of K1, K2 and K3 for H3PO4
ii). Determ
mination of Cobalt
C
(II)
iii). Determ
mination of irron (II)
iv). Determ
mination of chhloride in preesence of iodidde and evaluaation of Ksp for
f AgI and AgCl.
A
(b) Thermal anaalysis
Decompositiion studies off the followingg substances:
(c)
i). Copper su
ulphate penta hydrate
ii).Calcium oxalate
o
monoohydrate
Atomic abso
orption spectrooscopy
Estimation of
o following:
Mg2+ Zn2+, Al
A 3+
B
RECOMMENDED BOOKS:
1. J. Basssett, R. C. Denny,
D
G. H. Mendham, Vogels
V
Textt Book of quaalitative Inorgganic Analysiis, the
English Language Book Societyy and Longmaan, New Yorkk, (2008).
2. Quanttitative Analy
ysis Chemisttry, James S.. Pritz, Georrge H. Sehennk, 2001 Albby and Beconn Inc.
Londoon.
3. Theorry and practicce of chromatography by Prof.
P
Dr. Javedd Iqbal (20022).
4. Instruumental analy
ysis by Gary D. Christiann and James E.O., Reillyy, 2007, Allyyn and baconn Inc.,
Londoon.
5. Hand Book of Org
b ZAVIX Holzbecher
H
Hurw
L
6. Experrimental Inorg
ganic Chemisstry - W. G. Palmer,
P
2005.
7. The analysis
a
of miinerals and orres of the rareer elements W. R. Schoeeller,and A. R.
R Powell, Chharles,
Griffiin and Compaany Limited, 2004.
2
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4409
Yeear
4
Subjectt Title
Organ
nic Chemistrry (Sp. Theorry-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Deterrmination of Reaction Meechanism:

Deterrmination of reaction
r
mechhanism, kinetiics, stereocheemical, interm
mediate formation, spectrosscopic
and issotopic labelin
ng methods
2. Aliph
hatic Nucleop
philic substitution:
Mechhanism of SN
N1, SN2, SNii, SN1, SN2 and SNi reactions, kinetics, stereocchemical and other
evidennce; effects of
o other substrate structuree, attacking nuucleophile, leeaving group and solvent effect,
e
and neighbouring group
g
particippation.
3. Elimiination Reactions:
Mechhanism of E1, E2, and E1cb eliminnation reactiions; kineticss and stereoochemical stuudies;
appliccations of th
hermodynamically and kiinetically conntrolled reacttions (Saytzeeff and Hofffmann
reactions), Effects of substrates,, solvent, base, leaving grooup and temperature on kinnetics, compeetition
betweeen eliminatiion and substitution reacctions; pyrollytic eliminaation reactionn mechanism
m and
syntheetic applicatio
ons.
RECOMMENDED BOOKS:
B
1. Organnic Chemistry
y, Volume I (6
( th ed.) & II (5th d.) by I.L. Finar, Peaarson Educatiion (singaporee) Pte
Ltd, 2008.
2
2. Marchh's Advanced
d Organic Cheemistry: Reacctions, Mechaanisms, and Structure,
S
6th ed. by Michaael B.
Smithh, Jerry March
h, Wiley, 20007.
y, 5th ed.; by S. H. Pine, McGraw
M
Hill: New York,19987.
y 6th ed. by Francis
F
A. Carrey, McGraw Hill, 2005.
y 6th ed, by R. T. Morrison, R. N. Booyd, and R. K.
K Boyd, Bennjamin Cumm
mings,
1992,.
6. Modeern Synthetic Reactions 2nnd ed. by H.O.House , W.A
A. Benjamin Inc., Menlo Paark, CA
7. Princiiples in Organ
nic Synthesis by R.O.C Noorman & J. M.
M Coxon, Chaapman and Hall, 1993.
y by Jonathann Clayden, Nick Geeves, Sttuart Warren,, Oxford Univversity Press 2000.
2
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM- 410
4
Yeear
4
Subjectt Title
Organ
nic Chemistryy (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Arom
matic Substitu
ution reactioons:
(a) Electrophilicc substitution:
General mechanism (kinnetic, isotopiic and spectrroscopic eviddences), nitraation, sulfonnation,
n, Friedel-Craafts alkylation and formyylation, structture and reacctivity, orienttation;
halogenation
polysubstituttion reations of
o aromatic compounds
(b)
Nucleophilicc Substitutionn reactions:

SN1, SN2 (ad
ddition and eliimination), annd Benzyne mechanism
m
2. Moleccular Rearra
angements:
Classiification of molecular rearrangemen
r
nts: mechanissm of intram
molecular 1,2-shifts invoolving
migraation of a gro
oup from carbbon to carbonn, carbon to nitrogen,
n
andd carbon to oxxygen, mechaanism
and synthetic
s
app
plications of Wagner-Meeerwein, Pinaccol-pinacolonne, benzidine, benzyl, bennzylic
acid, Favorski, Wo
olff, Beckmaann, Hoffmannn, Curtius, Lossen
L
and Scchmidt; Baeyyer-Villiger, Dakin
D
and Fries
F
rearrangeements.
3. Heterrocyclic Chem
mistry:
Five and six mem
mbered hetroocycles with one and seeveral identiccal hetro-atoms, Five annd six
ycles with twoo different hettro-atoms.
membbered hetrocy
RECOMMENDED BOOKS:
B
y, Volume I (6
( th ed.) & II (5th ed.) by I..L. Finar, Peaarson Educatiion (singaporee) Pte
Ltd, 2008.
2
2. Marchh's Advanced
d Organic Cheemistry: Reacctions, Mechaanisms, and Structure,
S
6th ed. by Michaael B.
Smithh, Jerry March
h, Wiley, 20007.
y, 5th ed.; by S. H. Pine, McGraw
M
Hill: New York,19987.
y 6th ed. by Francis
F
A. Carrey, McGraw Hill, 2005.
y 6th ed, by R. T. Morrison, R. N. Booyd, and R. K.
mings,
1992,.
6. Heterrocyclic Cheemistry, 4th ed.

e by J. A. Joule,
J
K. Mills, Blackweell Publishing, 2000.
7. Heterrocyclic Cheemistry, 3rd ed. by T.L. Gilchrist,
G
Loongman, 19997.
8. Princiiples in Organ
nic Synthesis by R.O.C Noorman & J. M.
M Coxon, Chaapman and Hall, 1993.
y by Jonathann Clayden, Nick Geeves, Sttuart Warren,, Oxford Univversity Press 2000.
2
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4411
Yeear
4
Subjectt Title
Orgganic Chemisstry (Sp. Praactical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Qualiitative analyssis:
Threee componentt organic mixture
m
analyysis (separattion and iddentification of the unkknown
components)
2. Chromatography
y and Spectrooscopy:
Separration of mixttures by chrom
matography and
a identificattion by spectrroscopy
B
RECOMMENDED BOOKS:
1. Practiical Organic Chemistry
C
byy F. G. Mann and
a B. C. Sauunders, 1978, Longman, UK,
U 1978.
2. Vogell's Textbook
k of Practicaal Organic Chemistry (5th
(
ed.) byy A.I.Vogel, A.R.Tatchelll, B.S.
Furnis, A.J. Hannaaford, P.W.G. Smith, Longgman UK, 19889.
3. The Systematic
8th ed.) by Ralph
S
Id
dentification of Organic Compounds,(
C
R
L. Shrriner et al., Wiley,
W
2003.
4. Advannced Practicaal Organic Chhemistry, by J.
J Leonard, B. Lygo, G. Proocter, CRC, 1994.
1
5. Advannced Practicaal Organic Chhemistry (2ndd ed.) by N. K.
K Vishnoi, Vikas
V
Publishiing House Pvvt Ltd,
India,, 1996.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM- 428
4
Yeear
4
Subjectt Title
Organ
nic Chemistrry (Sp. Theorry-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
1. Nucleear Magneticc Resonance Spectroscop

py:
Nucleear magneticc resonance: Basic princciples, theorry, spin flippping, nucleaar precessionn and
absorpption of electtromagnetic radiation,
r
spinn relaxation, basic
b
introducction of 1-D (1H and 13C) NMR
spectrroscopy, chem
mical shifts annd integrationn curve, instrrumentation, spin-spin
s
spliitting and couupling
constaants. Structurre elucidation of small mollecules. Introdduction of 2-D
D NMR specttroscopy.
2. Mass Spectroscop
py:
Introdduction; typees, Isotopic abundance,
a
m
molecular
annd metastablee ions; fragm
mentation paattern,
appliccations of maass spectroscopy in differrent classes of
o organic chhemistry, interrpretation off mass
spectrra of small orrganic molecuules.
3. Naturral Products:
Introdduction, classsification, isolation,
i
biosynthesis and
a
general methods for
f
the struucture
determ
mination of alkaloids
a
(pipperine, Nocotene, Cocainee, Morphine, Quinine), steeroids (cholessterol,
progeesterone, estro
ogens, androggens, glucocoorticoids mineeralocorticoidds) and terpennoids (Triterppenes,
-amyyrin, -amyrin
n, Ursolic aciid, Oleanolic acid).
RECOMMENDED BOOKS:
B
y, Volume II by
b I.L. Finar; 5th ed. Longgman scientifi
fic, 1975.
2. Specttroscopic Metthods in Orgaanic Chemisttry 6th ed. byy D. William
ms and I. Flem
ming. Wiley-V
VCH,
1991.
3. Specttrometric iden
ntification of Organic Com
mpounds 6th ed. by R. M. Silverstein and
a F. X. Weebster,
Wileyy, 2007.
4. Organnic Spectrosco
opy and Chroomatography by M Younass, ILMI, Pakistan, 2007.
5. Specttroscopy by Pavia,
P
Lampm
man, Kriz, 2ndd ed., Harcourrt Brace Colleege Publisherrs, 1996.
6. Biosyynthesis of Naatural Productts, Paolo Mannito, John Willey & Sons, 1980.
1
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4429
Yeear
4
Subjectt Title
Organ
nic Chemistryy (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
1. Reacttive Intermed
diates:
Carbeenes, nitrenes, and Arynes, structure annd evidence foor formation, general reacttions and synnthetic
appliccations
2. Organic Synthesiss:
An ouutline of the recent developments in organic synttheses involving boron, phosphorus,
p
silicon
reagennts, reaction conditions annd methods; phase
p
transferr catalysis invvolving quateernary ammonium,
phospphonium salts and crownn ethers, solid phase synnthesis, Introoduction to protective
p
grroups,
protecction of hydroxyl, amino, carbonyl andd carboxylic groups, reacttions involvinng the introduuction
and removal
r
of some comm
mon protectivve groups annd synthetic applicationss. Introductioon to
disconnnection apprroach.
3. Pericyclic reaction
ns:
Introdduction, Woo
od-ward-Hoffm
fmann rules and
a molecularr orbital theoory; cycloaddiition, electroccyclic
and siigmatropic rearrangement and group traansfer reactionns.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
Orgganic Chemisttry, Volume I (6th ed.) & II (5th ed.) by

b I.L. Finar, Pearson Eduucation (singaapore)
Pte Ltd, 2008.
C
Reeactions, Mecchanisms, andd Structure, 6th
6 ed. by Miichael
Marrch's Advanced Organic Chemistry:
B. Smith,
S
Jerry March,
M
Wileyy, 2007.
Orgganic Chemisttry, 5th ed.; by
b S. H. Pine, McGraw Hilll: New York,,1987.
Orgganic Chemisttry 6th ed. byy Francis A. Carey,
C
McGraaw Hill, 2005..
Orgganic Chemisttry 6th ed, byy R. T. Morriison, R. N. Boyd, and R. K.
mings,
19992,.
Phaase-transfer catalysis: funddamentals, appplications, and industrial perspectivess by C. M. Starks,
S
C.L
L. Liotta and M.
M Halpern, Chapman
C
&H
Hall, 1994.
Prinnciples in Org
ganic Synthessis by R.O.C Norman
N
& J. M. Coxon, Chapman
C
and Hall, 1993.
Orgganic Chemisstry by Jonathhan Clayden,, Nick Geevees, Stuart Waarren, Oxfordd University Press
20000.
Elecctrocyclic Reeactions by F. L. Ansari, R. Qureshi, M.. L. Qureshi, 1999, Wiley-VCH.
Reaactive Intermeediates in Orgganic chemisttry, N. S. Isaaac, John Willey and Sons, 1974.
Woork book for Organic
O
Syntthersis, The discoinnection
d
n approach, Stuart
S
Warrenn, John Willeey and
Sonns, 1994,.
Orgganic Synthersis, The discooinnection appproach, Stuarrt Warren, 19993, John Willley and Sons 1993.
13.
14.
Designing Organic Synthesis, A Programmed Introduction to synthon approach, S. Warren, John

Willey and Son, 1992.
Guide book to Organic Syntheses, R. K. Mackie, D. M. Smith, Longman Group Limited, 1982.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4430
Yeear
4
Subjectt Title
Organ
nic Chemistrry (Sp. Practtical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
Organic Synthesis:
S
(a)
(b)
Mullti-step preparation and spectroscoppic characterrization: p-nnitroaniline from anilinee; pbrom

motoluene fro
om p-toluidine, o-Bromotooluene from o-toluidine
from
Prepparation, sepaaration and iddentification of regio-isom
mers: o-nitrotooluene and p-nitrotoluene
p
toluuene; o-nitroso
ophenol and p-nitrosophen
p
nol from phennol
RECOMMENDED BOOKS:
B
1. Practiical Organic Chemistry

C
byy F. G. Mann and
a B. C. Sauunders, 1978, Longman, UK,
U 1978.
2. Vogell's Textbookk of Practicaal Organic Chemistry
C
(5tth ed.) by A.I.
A Vogel, A.R.
A
Tatchelll, B.S.
Furnis, A.J. Hannaaford, P.W.G. Smith, Longgman UK, 19889.
3. Advannced Practicaal Organic Chhemistry, by J.

J Leonard, B. Lygo, G. Proocter, CRC. 1994.
1
4. Advannced Practicaal Organic Chhemistry (2ndd ed.) by N. K.
K Vishnoi, Vikas
V
Publishiing House Pvvt Ltd.
India,, 1996.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4412
Yeear
4
Subjectt Title
Analyttical Chemisttry (Sp. Theoory-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
Gas Liqu
uid Chromattography / Gas
G Solid Chrromatograph
hy:
Gas Chromatographs, Derivative Foormation, Gaas Chromatographic Colum
mns, Liquid Phases
P
and Coolumn
Selection,, Detectors for
f Gas Chrromatographyy, Optimizatiion of Experrimental Conndition, Gas--Solid
Chromatoography, Intterfacing Gaas Chromatoography witth Mass Sppectrometry, Interfacing Gas
Chromatoography with Infrared Specctrometry,
High Performance Liiquid Chrom
matography:
Optimizattion of Colu
umn Performaance, Gradient Elution and
a
Related P
Procedures, Derivation,
D
H
HPLC
Instrumenntation, Mob
bile-Phase Deelivery System
m, Sample Inntroduction, Separation
S
Coolumns, Deteectors,
Interfacinng HPLC with
h Mass Spectrrometry
Potentiom
metry:
Nernst eqquation; Electrode Potenntials; differeent referencee electrodes including glass
g
and caalomel
electrode;; working of a potentiometter and its appplications inccluding pH meeasurements and
a potentiom
metric
titrations; ion-selectivee electrode systems;
s
ion--exchange membrane
m
electrode; gas-ssensinig electtrode;
e
and bio membranne electrode.
solid-statee membrane electrode
Thermo gravimetric
g
Analysis
A
/ Diifferential Th
hermal Analyysis:
General Principle
P
of th
hermal, instrum
mentation, tyypes of measuurements; TGA
A (thermograavimetric anallysis),
DTA (diff
fferential therm
mal analysis), DSC (differrential scanninng calorimetrry), TT (therm
mometric titraations)
and EGD (evolved gas detection), Principles,
P
insstrumentation and applicatiions of these techniques.
t
RECOMMENDED BOOKS:
B
1. Electrro Analytical Chemistry byy J.J. Longane, Inter Sciennce Publisher Inc. N.Y. Lonndon.
2. Vogells, text book
k of Quantitative chemiical analysis byJ.mendhaam, RCDennny, JDBarness, MJ
KTHoomas, Pearson
n education Ltd.
L
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4413
Yeear
4
Subjectt Title
Analyticcal Chemistrry (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
FTIR / Raman
R
Spectrroscopy:
Origin off Infra Red Spectra;
S
Diffferent vibratioonal modes, Normal coordinate and normal
n
vibraations,
Symmetryy of normal vibrations annd selection rule, Raman Spectroscoppy, Metal-isottope spectrosscopy,
Vibrational Spectra in
n gaseous phhase and inerrt gas matricces; Compariison of ramaan with Infraa Red
spectroscoopy; Applicattions for quallitative and quuantitative chhemical analyysis; Instrumeentation detaills and
their function.
UV / Vis Spectroscopy
y:
The Natuure of Electrromagnetic Radiation,
R
Thhe Electromaagnetic Spectrum, Atomiic Energy Levels,
molecularr Electronic Energy
E
Levelss, Vibrationall Energy Leveels, Raman Efffect, Lasers,
Radiationn Sources, Wavelength
W
Seelection, Cellls and Samplling Devices,, Detectors, Readout
R
Moddules,
Instrumennts for Absorp
ption Photometry
Atomic / Mole Fluoreescence:
Atomic Flluorescence Spectroscopy;
S
; Instrumentaation, applicattions and limiitations of theese techniquess
Plasma Soource
Inductivelly coupled plasma
p
sourcees, special deetection systeems and readd out devicess used for IC
CPES;
multielem
ment analysis with
w plasma devices.
d
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
Chem
mical Applicattion of Spectrroscopy by West,
W
Inter Science Publisheer Inc. N.Y. London.
L
Kinettics in Analytiical Chemistrry by H.B. Maark Jr. & G.A
A. Rechnitz, Innterscience N.Y.
N (1968).
Analyytical Chemisstry by Gary D.
D Christian, John
J
Wiley annd Sons (19777).
Autom
mated Chemiccal Analysis by
b J.K. Forman Stockwell, John Wiley and Sons, N.Y. (1975).
Advannces in Infrarred Group Freequencies by L.J. Bellacy, Mathuen & Col.
C Amsterdaam (1968).
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4414
Yeear
4
Subjectt Title
Analyttical Chemisttry (Sp. Pracctical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
Moleculaar Spectrophotometry:
Determinaation of Iron (II) using 1, 10-phenanthro
1
oline method.
Determinaation of Iron (III) using thiiocyanate metthod.
Determinaation of chrom
mium by diphhenylcarbazidde method.
Determinaation of Fe, Pb,
P Cd, Zn andd Cu in soil samples by AA
AS techniquee.
Simple accid base titratiions using potentiometer.
Determinaation of F in
i water by ussing ion selecctive electrodees.
Preparatioon of standard
d calibration graphs
g
of Pb, Cd, Zn and Fe
F by AAS.
Determinaation of Ni by
y DMG methood spectrophootometricallyy.
with
Determinaation
of
mixtures
of
com
mplexes
o
of
Iron
1, 10, pheeranthroline.
Determinaation of max
x of Cr compllex with dipheenyl carbazidde.
Infrared Determination
D
n of a Mixturee of Xylene
Spectrophhotmetric deteermination off Lead or Leavves using Sollvent Extraction.
Thhiocyanide
and
B
RECOMMENDED BOOKS:
1. Vogells, s text boo
ok of quantittative inorgaanic analysis by J. Bassettt. The Engliish language book
Society and Longm
man.
2. Atom
mic and moleccular spectrooscopy. Basicc concepts annd practical application
a
b Sune Svannberg,
by
springgerlink Berlin
n Heidelberg.
BS (4 Years)
Y
for Affiliated
d Colleges
Codee
CHEM-4431
Yeear
4
Subjecct Title
Analytiical Chemistrry (Sp. Theoory-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
Voltrameetry:
Principle and applicatio
ons of anodicc stripping voltametry
Polarograaphy:
Introductiion and princciple of polaarography, baasic instrumeentation, worrking and advvantages of DME
(droppingg mercury electrode); lim
miting and residual currrent; half-waave potentiall; qualitativee and
quantitativve aspects of polarographiical analysis
Amperom
metry:
Conductoometry:
Conductannce in Solutio
ons; Specific conductance; molar conduuctance; factoors upon whicch the conducctance
of solution depends; Measurement
M
of conductannce; cell constant; Analyticcal applicatioons of conducctance
measurem
ment.
Arc / Spaark / Glow, Automation:
A
RECOMMENDED BOOKS:
B
1. Vogells, s text boo
ok of quantittative inorgaanic analysis by J. Bassettt. The Engliish language book
Society and Longm
man.
2. Vogels, text book off Quantitativee chemical anaalysis by J.meendham, RC Denny, JDBaarnes, MJ
ucation Ltd.
KTHomass, Pearson edu
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4432
Yeear
4
Subjectt Title
Analytiical Chemistry (Sp. Theoory-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
Laser Speectroscopy:
Principle of laser operation; Stimullated emissionn Population inversion, Siingle level annd multi-levell laser
systems, Properties
P
of laser light annd its general and analyticaal applicationss; ruby laser, nitrogen laser, dye
laser, Usee of laser radiaation in absorrption and fluuorescence speectroscopic methods.
m
Nuclear Magnetic
M
Resonance Spectroscopy:
Basic prinnciples; prop
perties of nucclei, Chemicaal shifts; Spinn-Spin couplling; Pulsed Fourier
F
Transform
NMR Speectrometry; Id
dentification of structural features; Use of NMR im
maging in meedicine; Anallytical
applicatioons of NMR spectroscopy.
Mass Speectrometry:
Principle of mass specctrometry; Intel system, ionnization, acceeleration, Drift Chamber, Detection
D
sysstems;
ments in equ
uipment in eqquipment; Annalytical uses of mass sppectrometry, Quadrupole mass
Advancem
spectromeetry; Interprettation of masss spectra. Corrrelation of mass
m spectra with
w Moleculaar structure.
RECOMMENDED BOOKS:
B
1. New Instrumental Methods in Electro
E
Chem
mistry by Fauul-Delabay, Innter Science Publisher,
P
Loondon,
N.Y.
2. Instruumental Meth
hods of Analyysis by Hobert H. Willart, Lyle L. Meerrit, D. Van Nosrant Com
mpany
Inc. N.Y.
N London.
3. Princiiples of Polarrography by J.
J Herosky & J.
J Kuta, Acaddemic Press N.Y.
N (1968).
4. Laserr spectroscopy
y by Wolfganng Demtroder, springerlinkk.
5. Analyytical chemisttry by Kellnerr, J.M. Merm
met, Wiley-VC
CH Verlag Gm
mbH & Co. KGaA.
K
6. A texxt book of an
nalytical chem
mistry by Y--Anjaneyulu, K-chamdaree khar, ValiM
Manickam, Phharma
book syndicate.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4433
Yeear
4
Subjectt Title
Analyticcal Chemistrry (Practical))
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
Conductoometry:
Determinee the amount of HCl conduuctometricallyy by using strrong base NaO
OH.
Determinee the amount of base NH4OH conductoometrically byy using strongg acid.
Determinee the amount of NH4OH by
b using weakk acid CH3CO
OOH conducttometrically.
Determinee the amount of NaOH connductometricaally by using weak acid CH
H3COOH.
Potentiom
metry:
Determinee the amount of HCl by ussing strong baase (NaOH) potentiometriccally.
Determinee the amount of HCl by ussing weak basse (NH4OH) potentiometri
p
ically.
Determinee the amount of CH3COOH by using sttrong base (naaoh).
Determinee the amount of HCl & CH
H3COOh condductometrically by using strong
s
base NaOH.
N
B
RECOMMENDED BOOKS:
1. V
Vogels, text book
b
of Quanntitative chem
mical analysiis byJ.mendhham, RCDennny, JDBarness, MJ
K
KTHomas,
Peaarson education Ltd.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4415
Yeear
4
Subjectt Title
Appliied Chemistrry (Sp. Theorry-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Proceessing of Cru
ude Oil:
Brief description of origin off petroleum, Migration, reeservoir, expploration andd drilling of crude
petrolleum; Variou
us unit processses involvedd petroleum processing
p
likke surface opperation, fractional
distilllation; refinin
ng, cracking; reforming, isomerizationn; Polymerization, alkylattion and finiishing
processes
2. Paperr and Pulp In
ndustries:
Historry and back ground, survvey of raw materials,
m
prooduction of pulp
p
by sodaa process, suulphite
process and Kraft (sulphate)
(
proocess, Manufa
facture of papeer environmental aspects of
o paper indusstry.
3. Fertillizer Industrries (Ammonia, Urea and
d other Fertilizers):
(a) Ammonia:
Raw materiaals, various sources
s
of hyydrogen and nitrogen,
n
mannufacture of ammonia
a
(Haabers
process), its use as fertilizzer and other applications.
(b)
Urea:
Raw materiaals, manufactuure of urea, asssimilation inn soil.
(c)
Calcium Ferrtilizers:
Calcium am
mmonium nitrrate, calcium
m cyanamide, calcium supper phosphatee and triple super
phosphate.
(d)
Potash Fertillizers:
Manufacturee and use of potash
p
fertilizeers.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
Pulp and
a Paper Tecchnology, Testing and Appplications, K..P. Rao (20033), CBS Publiishers.
Chem
mistry of Pulp and Paper making, Edwinn Sutermeisterr, Ed-3rd (19446)
Fertiliizers and Soill Fertility, U.S.Jones, Reston Publishinng Co. Virginiia,1979.
Petrolleum Refining
g Technologyy, Ram Parsadd (2002).
Industrial chemistrry, B. K. Sharrma, Krishna Prakashan Media
M
(P) Ltd., Ed-15 (20066).
Shereeves Chemical Process Inndustries, 5th Ed.1975, byy G.T.Austinn, McGraw Hill
H Book Co. New
York..
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4416
Yeear
4
Subjectt Title
Applieed Chemistryy (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Steel,, Metallurgiccal Products and Electrop
plating:
(a) Steel and Metallurgical
M
Products:
Manufacturee of cast iron and steel, wrought
w
iron, formation off alloys, heat treatment of steel,
classification
n of steel, passsivity, differeent theories of
o rusting of irron and its preevention.
(b)
Electroplatiing:
Principle off electroplatting, purposee of electrooplating, diff
fferent proceesses involveed in
electroplatin
ng, chrome plaating, nickel plating
p
and ellectroplating of
o plastics.
2. Textile Dyeing:
Colorr and chemicaal constitution, Important classes of chhromogens, Classification
C
and nomenclature
of dyyes, manufactturing of dyee intermediatees and dyes, Selection off dyes for woool, cellulosic and
syntheetic fibers, Th
heory of Colooration, Colorration of wooll, cellulosic and
a synthetic fibers.
3. Analyytical Techniiques and on
n-line analysiis in Industryy:
(a) Spectroscop
py:
Use of differrent spectrosccopic techniquues like FES, AAS and Sppectrophotometry for the quality
q
control of raw
w materials, intermediates
i
s and final prooducts in various industries.
(b)
Chromatogrraphy:
Use of Thin layer chromaatography, gas chromatogrraphy and HPLC in pharmaaceutical and other
industries.
(c)
nalysis and Automation:

A
On-Line An
Significancee of on-line analysis annd automatioon of analyytical techniqques in inddustry;
Classification of techniqques w.r.t. auutomation, Use
U of microprocessor in conjugationn with
automation and
a on-line annalysis, differrent types of automatic
a
anaalyzers.
B
RECOMMENDED BOOKS:
1. Chem
mistry of iron
n and Steel Manufacture,
M
C
C.Bodsworth
h, Longman Press,
P
Londoon, 1963.
2. Instruumental metho
od of Analysiis, Willar Merrritt Dean Setttle, Seventh Edition
E
(19866)
3. Grahaams Electro
oplating Enggineering Haand Book, Ed.
E
L.J. Duurney, CBS Publkisherss and
Distriibutors, New Delhi. (1997)).
4. Nickeel and Chrom
mium plating,, J.K.Dennis & T.E.Such,, Newness Buutterworth, London
L
(19722).
5. T. B. of Quantitativ
ve Inorganic Analysis, Voogals Ed-4th, Longman Grooup Limited (1978).
(
6. Instruumental Anallysis, Gary D.
D Christain, 1978, Introdduction to Insstrumental Analysis
A
by Braun,
B
McGrraw-Hill Book
k company, 1987.
1
7. Dyes and Dyeing, C.E. Pellow, Abhishek Publishers, 1998.

8. Textile Dyes and Pigments, H. Panda, NIIR Publishers.
9. The Chemistry of Synthetic Dyes and Pigments, H. A. Lubs, Reinhold Publishing Corporation, 1955.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4417
Yeear
4
Subjectt Title
Appliied Chemistrry (Sp. Practiical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Oil & Fats

Acid value;
v
Ester Value;
V
Sponiffication valuee and Iodine value
v
of differrent vegetablee oils
2. Wateer Pollution
(a) Dissolved Oxygen
(b) Biological Oxygen
O
Demaand
xygen Demannd
(c) Chemical Ox
3. Indusstrial Analyssis
Steel Analysis invo
olving volum
metry, spectrophotometry and
a solvent exxtraction.
mite; haemetite; chromitee and bauxitee ores involvving separatiion and anallytical
Analyysis of dolom
techniiques.
4. Textile
Dyingg of clothes in
n different shaades using Accid dyes
RECOMMENDED BOOKS:
B
1. Metalllurgical Anallysis, Lord (1893).
2. Appliied Chemistry
y Theory annd Practice, O.P.
O
Vermanni & A.K. Narula,
N
Wileyy Eastern Liimited
(19899).
(
4. Practiical Statistics for the Analyytical Scientisst, A Bench Guide,
G
RSC Publishing
P
LG
GC Ltd 2009.
5. Dyes and Dyeing, C. E. Pellew,, Abhishek Puublishers (19998).
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4434
Yeear
4
Subjectt Title
Appliied Chemistrry (Sp. Theorry-I)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
1. Leath
her Tanning
g Industries:
Introdduction, impo
ortant steps inn leather mannufacturing, thheory of leathher tanning, waste
w
disposaal and
polluttion aspects in
nvolved in tannning industries.
2. (a)
(b)
Oils and Fats:

Classification of oils andd fats, vegetaable oils, esseential oils, vaarious methodds of extractiion of
oils, refining
g and hydroggenation of oils,
o
Industriaal applicationns of oils in resins,
r
surfacctants,
lubricants an
nd paints.
Petrochemiccals:
Chemistry and
a importancce of the folllowing petroochemicals: Acetylene;
A
ethhylene; propyylene,
benzene, to
oluene, xyleene and napphthalene. Oxidation
O
haalogination and nitratioon of
petrochemicals of industrrial significance.
3. Textile Fibers:
Classiification of sy
ynthetic fiberrs, chemistry and manufacturing of visccose rayon, trrue synthetic fibers
includding nylons and
a polyester fibers. Finishhing processees for 100% cotton fibricss such as singgeing,
desiziing, scouring,, mercerizing and bleachinng.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
Food Oils and Fatss, H.Lawson, CBS Publkisshers and Disttributors, New
w Delhi.(19977).
Industrial chemistrry, B. K. Sharrma, Krishna Prakashan Media
M
(P) Ltd., Ed-15 (20066).
Leathher in life art and
a industry, John W. Watterer, 1927. Faber
F
and Faber Ltd.
Fibre to fabric, 4th Ed, Potter & Corban, McG
Graw Hill boook Company, 1959.
A Texxt on Petrocheemicals, Bhasskararsao, 2002.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4435
Yeear
4
Subjectt Title
Applieed Chemistryy (Sp. Theorry-II)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
1. Coal Chemicals fu
uel Gases:
The destructive distillation of
o coal, cokking of coaal distillationn of coal taar; Liquid Fuels:
F
Hydroogenelysis Naatural gas; Cooal Gas: Wateer Gas; Liqueffied Petroleum
m Gases.
2. Sugarr Industry an
nd Related Chemicals:
C
Extracction of juicee from sugarr cane, purificcation of juicce, clarification, concentraation, refining and
crystaallization. Beeet sugar. Gluccose and hydrrogenated gluucose syrups.
3. Polym
mers:
Generral classificattion of polym
mers, characterristics and siggnificance off polymers, vaarious mechannisms
of pollymerization process, Polyymer processiing like extruusion, injectioon, modeling and blow moolding
of plaastics.
Brief description and
a uses of thee following polymers:
p
ystyrene, epoxxy resins, polyyethylene tetrrapthalate.
Polyeethylene, poly
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
5.
6.
Shereeves Chemicaal Process Inddustries, 5th Ed.1975,

E
G.T.Austin, McG
Graw Hill Boook Co. New York.
Y
An Inntroduction to Polymer Cheemistry, W.R
R.Moor, Londoon Press, Lonndon.
Princiiples of Polym
mer Systems, Rodri-Guez, McGraw Hilll Book Co. New
N York.
Modeern Technolog
gy of Plastics and Polymerr Processing Industries,
I
NIIIR Board
Sugarr: Science and
d Technologyy, G. G. Birchh and K.. J. Paarker, Appliedd Science Pubblishers Ltd., 1979.
Princiiples of Sugarr Technologyy, Pieter Honigg Vol I, Elsevvier Publishinng Company, 1953.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4436
Yeear
4
Subjectt Title
Appliied Chemistrry (Sp. Practiical)
Discipline
D
Chemistry
C
Cr. Hrs
2
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
Petroleum
m:
Determinaation of dieseel index, Aniliine point and Pour point of lubricating oil.
o
Water Poollution:
Heavy meetals in industtrial effluents by AAS.
Industriaal Analysis:
Sucrose inn sugar cane juice
j
using poolarimetry.
Isolation and
a determinaation of casinne, lactose andd fat in milk.
Analysis of
o effluents frrom leather taanneries.
Assay of phamaceuticcal products like aspirin, paracetamol,, and chloram
mphenecol ussing spectrosscopic
techniquees.
metery:
Spectrom
Simultaneeous determin
nation of chroomium and maanganese in steel.
s
Determinaation of pK value
v
of indicaators (methyl orange and methyl
m
red).
Polymer::
Depolymeerization of polyethylene terephthalate.
t
Catalytic degradation of
o polythene.
RECOMMENDED BOOKS:
B
1. Metalllurgical Anallysis, Lord (1893).
2. Appliied Chemistry
y Theory annd Practice, O.P.
O
Vermanni & A.K. Narula,
N
Wileyy Eastern Liimited
(19899).
(
4. Practiical Statistics for the Analyytical Scientisst, A Bench Guide,
G
RSC Publishing,
P
LG
GC Ltd 2009.
5. Dyes and Dyeing, C. E. Pellew,, Abhishek Puublishers (19998).
ysical Chemistry, David P.
P Shoe Makerr, McGraw Hill
H Internationnal (1996).
6. Experriments in Phy
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4418
Yeear
4
Subjectt Title
Biocheemistry (Sp. Theory-I)
T
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Basis of Metabolism:
Methoods of metab
bolism studyy. Cell bioennergetics andd Role of ATP.
A
Biological oxidationn and
reduction. Electorn
n Carriers invvolved in thee oxidation off fuel molecuules. Oxidativve phosphoryylation
c
Uncouuplers of oxiddative
and regulation of ATP producction. Inhibitoors of electroon transport chain.
phospphorylation.
2. Metabolism of Ca
arbohydratess:
Digesstion, Absorpttion, and Trannsport of Carrbohydrates. Glycolysis,
G
Citric acid Cyccle. HMP pathhway.
Glycogenolyysis, Photosyynthesis and their
Uroniic acid pathw
way. Gluconneogenesis. Glycogenesis,
G
controol. Regulation
n of carbohyddrate metaboliism.
3. Metabolism of Lip
pids:
Digesstion and abso
orption of Lippids. Detailedd Synthesis and
a Oxidationn of fatty acidds, Involvingg Acyl
carrieer protein an
nd Carnitine carriers. Meetabolism of essentiall faatty acids annd their metaabolic
disordders. . Conttrol of fattyy acid Metaabolism. Kettone Bodies. Phospholippids, steroidss and
Prostaaglandins.
4. Endoocrine system
m:
Mechhanisms of acttion of hormoones. Chemisstry, Metaboliism and Bioloogical functioons of Pancreeateic,
Pituitaary, Gonadall, Adrenal, Thyroid,
T
Parathyroid, Inttestinal and Renal
R
harmoones. Pherom
mones.
Horm
monal control mechanisms.
m
RECOMMENDED BOOKS:
B
1. Princiiples of Bioch
hemistry by Lehninger
L
AL
L, Nelson DL and Cox MN
N, 2000 Pub: worth
w
Publishhers
2. Biochhemistry by Lubert
L
Stryer(22006) Pub: Freeman and Company
C
3. Lippinncotts Bioch
hemistry by Champe.P
C
C; Harvey. R. A and Ferrierr. D. R. 3rd ed.,
e 2004 Pub: J. b.
Lippinncott Compan
ny
of Cell signalling by Ernst J. Helmreichh 2001 Pub: Oxford
4. The Biochemistry
B
O
Univerrsity Press.
5. Harpeers Biochemisstry, 27th ed. 2006 Pub: McGraw
M
Hill Inc
I
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4419
Yeear
4
Subjectt Title
Bioochemistry (S
Sp. Theory- II)
I
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
V
VII
SYLLAB
BUS OUTLIN
NE:
1. Bioch
hemistry of Body
B
Fluids:
Generral composition of Blood, blood plasmaa, blood proteeins, formed elements
e
of blood.
b
Biosynnthesis
and metabolism
m
off Porphyrin annd Hemoglobbin. Gaseous transport.
t
Coagulation of blood.
b
Normaal and
Abnormal composition of Urinee and its Biocchemical effeccts. Composittion of CSF.
2. Immu
unochemistry
y:
The im
mmune systeem. Detailed structure,
s
cheemistry and syynthesis of im
mmunoglobullins. Myelom
ma and
hybriddoma immun
naglobulins. Immungenes.
I
Complemennt system. Infflammatory process.
p
Perippheral
leucoccytes and Maacrophages. Abnormalitites
A
s of the immuune system.
3. Vitam
mins in health
h and diseasee:
Waterr soluble and
d fat solublee vitamins. A discussion of the occurrrence, chem
mistry, metaboolism,
physioological funcctions, deficieency symptom
ms and requirrements of vitamins A. B--Complex, C,, D, E
and K.
K
4. Physiical Techniqu
ues used in Biochemistry
B
y:
Generral methods for extracction, fractioonation and purificationn of proteinns. Principlees of
chrom
matography, Gel
G filtrationn, ion-exchannge chromatoography, Affi
finity chromaatography andd gas
chrom
matography. HPLC. Poolyacrylamidee and agarrose gel electrophoresi
e
is, SDS PAGE,
Immuunoelectropho
oresis. Imunoological technniques includding RIA, ELISA,
E
Immuunohistochem
mistry,
Electrrofocussing. Gradient ceentrifugation. Ultra filtrattion. Lyphollization. Elecctron microsscopy.
Radiooisotopes and their applicattions in Biochhemistry. X-rray diffractionn
RECOMMENDED BOOKS:
B
1. Princiiples of Biocchemistry by Lehninger AL,
A Nelson DL
D and Cox MN,
M 2000
Pub: worth
w
Publisshers
L
C
3. A bioologists guidee to Principlees and Techniiques of Practtical Biochem
mistry by Bryan L William
ms and
Keithh Wilson Pub: Edward Arnold Ltd.
4. Immuunology by J. Kuby 2nd edd. 1996 Pub: W.
W H. freemann and Co.
5. Harpeers Biochemisstry, 27th ed. (2006) McGrraw Hill Inc.
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4421
Yeear
4
Subjectt Title
Bioochemistry (Sp. Practicall)
Cr. Hrs
2
Sem
mester
V
VII
Discipline
D
Chemistry
C
SYLLAB
BUS OUTLIN
NE:
1. Enzym
mes:
Isolattion of enzy
yme from diifferent sourcces, study of
o different factors like temperature. pH,
Conceentration of substrate
s
on thhe properties of Alkaline Phosphatase
P
a LDH. Deetermination of
and
o the
kinetiic parameterrs of thesee enzymes and their mode of inhibition using
u
UV/V
Visible
Specttrophotometerr.
2. Vitam
mins:
Estim
mation of Vitam
min A, B1, B2,
B C and D inn food materials by chemiccal methods and
a HPLC.
3. Urinee Analysis:
Analyysis of organic constituentss in normal annd abnormal human
h
urine.
4. Blood
d Analysis:
Analyysis of blood constituent liike, Calcium,, Phosphate, Sugar,Urea,
S
c
creatine,
Biliuuribin, Cholessterol,
Triglyycerides by ch
hemical methhods, flame phhotometry andd atomic absoorption spectrroscopy.
RECOMMENDED BOOKS:
B
1.
2.
3.
Modren Experim
mental Biocheemistry by R. F. Boyer 3rdd ed, 2000, Puub: Pearson Edducation Inc.
Pracctical clinicall Biochemistrry by Varley. Pub: CBS puublisher
An Introduction to Practical Biochemistry
B
By D. T. Plum
mmer 3rd ed.. (1987)
Pubb: McGraw Hill
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4437
Yeear
4
Subjectt Title
Bioochemistry (Sp. Theory-II)
Cr. Hrs
4
Sem
mester
VIIII
Discipline
D
Chemistry
C
SYLLAB
BUS OUTLIN
NE:
1. Metabolism of Am
mino acids an
nd Proteins:
Digesstion and Abssorption of Proteins. Biosyynthesis of essential
e
aminno acids. Deggradation of amino
a
acids,, Urea Cycle Decarboxylaation, transam
mination and deaminationn reactions off amino acidds and
their importance.
i
Creatine
C
and ccreatinine
c
syynthesis and secretion.
s
2. Metabolism of Nu
ucleic Acids:
Biosyynthesis and Catabolism of
o Purines annd Pyrimidinnes. Biosynthhesis of nuclleotides. Disoorders
linkedd to serum uraate levels. Synthesis of RN
NA and splicinng.
3. Indusstrial Biochemistry:
Use of
o Prokaryotees and Fungi in industry. Industrial prroduction of Ethyl
E
Alcohool, Vinegar, Lactic
L
acid and
a monosodiium Glutamatte (MSG) usinng microorgaanisms. Bacterial applicatioon in food inddustry
i.e. usse of bacteria in processingg and preservving of milk and
a meat. Baccterial use in other industrries as
washiing powders,
4. Minerals:
Discuussion of miccro, macro annd alien metaals; their occuurrence, physsiological funnctions, deficciency
sympttoms, daily reequirement annd their metabbolism.
RECOMMENDED BOOKS:
B
L
AL
N, 2000 Pub: worth
w
Publishhers
L
C
3. Princiiples of cell and Molecular Biology by
b Kleinsmithh.L. J. and Kish.
K
V. M. 2nd
2 ed. 1995,, Pub:
Harpeer Collins
4. Harpeers Biochemisstry, 27th ed. (2006) McGrraw Hill Inc
BS (4 Years)
Y
for Affiliated
d Colleges
Code
CHEM-4438
Yeear
4
Subjectt Title
Bioochemistry (S
Sp. Theory-III)
Discipline
D
Chemistry
C
Cr. Hrs
4
Sem
mester
VIIII
SYLLAB
BUS OUTLIN
NE:
1. Physiiological Cheemistry:
Structture and detoxification funnction of liverr. Structure of
o Kidney witth special refeerence of excrretion
and detoxification
d
n function. Muscular
M
conntraction andd relaxation. Nerve conduction and action
a
potenntial. Ionizatio
on of water,, weak Acidds and weakk Bases. Bufffering againsst pH changges in
Biological systemss. Water metaabolism and acid
a base balannce.
2. Moleccular Biology
y:
DNA as a geneticc material. Eukaryotic
E
chhromosomes. Genes and mutational units.
u
Repliccation,
transccription and translation. Protein
P
Syntheesis and Genetic code. DNA repair annd recombinantion.
Restriiction enzymees. Regulationn of gene exppression in Prrokaryotes & Eukaryotes and
a Operon model.
m
Consttitutive, repreessed and innduced enzym
mes. Plasmidds, bacteriopphages, cosm
mids. Methods of
recom
mbinant DNA, Viruses. RN
NA Processinng.
3. Drug Metabolism
m and chemottherapy:
Chem
mistry, metabo
olism and mechanism
m
off action of antimalarialss, antibacteriaals, antivirals and
antifuungal drugs. Drug
D
resistannce, Biochemiical transform
mation of druggs. Anticancerr drugs.
4. Microobial Biochem
mistry:
Microoorganisms and
a
their grross Classifiication, Bactterial growthh and cultivvation techniiques.
Identiification of Microorganism
M
ms, Factors for the grow
wth of microobes. Culture medias and their
composition. Meth
hods of Grow
wth measurem
ment, Growth under extrem
me environmeents. Mutation and
protopplast fusion in cultures and its beneefits. Gene transfer:
t
traansformation, transductionn and
conjuugation. Bacteeriophages.
RECOMMENDED BOOKS:
B
L
AL
N, 2000 Pub: worth
w
Publishhers
2. Moleccular Biology
y of the cell byy Albert. B annd Bray. D 3rrd ed. 1994 Pub:
P
Garland Publishing
P
Inc.
3. Princiiples of cell and Molecular Biology by
b Kleinsmithh.L. J. and Kish.
K
V. M. 2nd
2 ed. 1995,, Pub:
Harpeer Collins
4. Harpeers Biochemisstry, 27th ed. (2006) McGrraw Hill Inc
5. Humaan Physiology
y- From Cellss to Systems by
b Lauralee Sherwood
S
4thh ed. 2004 Puub: Cole Publiishing
Co.
M
by E. Alcamoo 1994 Pub: Benjamin
B
cum
mmings Co.
6. Fundaamentals of Microbiology
Y
for Affiliated
d Colleges
BS (4 Years)
Code
CHEM-4439
Yeear
4
Subjectt Title
Bioochemistry (Sp. Practicall)
Cr. Hrs
2
Sem
mester
VIIII
Discipline
D
Chemistry
C
SYLLAB
BUS OUTLIN
NE:
1. Urinee Analysis:
Analyysis of Inorgaanic constitueents in normal and abnorm
mal urine by atomic
a
absorpption spectrom
metry,
flamee photometry and titration method.
m
2. Blood
d Analysis:
Analyysis of inorg
ganic constituuents of bloood like , soddium, potassiium etc by flame
f
photom
metry.
Estim
mation of org
ganic constituuents like Urric acid, seruum proteins, haemoglobinn etc by cheemical
methoods.
Estim
mation of Clin
nically imporrtant enzymees like alkalinne phosphataase, acid phosphatase, SG
GPOT,
SGOT
T, creatine kin
nase, etc usinng their speciffic assay methhods.
(a)
Cell structurre:
Study of celll structure by light microsccope. Growthh of Bacteria and
a its growthh curve.
(b)
Separation teechniques:
Gel filtration
n of proteins, Separation off Blood proteeins by Polyaccrylamide gell electrophoreesis.
RECOMMENDED BOOKS:
B
1.
2.
3.
4.
Modrren Experimen
ntal Biochem
mistry by R. F.. Boyer 3rd edd, 2000, Pub: pearson Eduucation Inc.
Practiical clinical Biochemistry
B
b Varley. Puub: CBS publlisher
by
An Inntroduction to Practical Bioochemistry Byy D. T. Plumm
mer 3rd ed. (1987) Pub: McGraw
M
Hill
Fundaamentals of Microbiology.
M
. By E. Aicam
mo 1994 Publiisher; Benjam
min- Cummings Publishingg Co.

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Shriver, D.F., P.W. Atkins and C.H. Langford, Inorganic Chemistry,

Nucleophilic aromatic substitution reactions; reaction such as addition,

Carruthers, Modern Methods of Organic Synthesis, Cambridge low

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1. Pi- acceptor Ligands:

1. Introduction / Assessment of Analytical Data

1. Chemical Industrial Unit Operations:

1. Kinetics of bimolecular reactions:

7. Electrochemical Methods and applications by bard, A. and Faulkner, L.R.,

1. Free radical Reactions:

9. Spectroscopic Methods in Organic Chemistry 6th ed. by D. Williams and I.

Ion Exchange Chromatography:

Flame Emission / Spectrophotometry:

1. Chemical unit processes:

3. Wateer pollution and

Kumaar. Environmeental Chemisttry, Wiley Eaastern, New Delhi.

Kumaar. Environmeental Chemisttry, Wiley Eaastern, New Delhi.

Physsical Chemisstry (Sp. Theeory-I)

1. Moleccular Mass Determinatio

mental Physiccal Chemistryy by Ayodhyaa Sing.

2. Advaance Approacch to Osmosiis and Osmottic Pressure::

umental metthods of anallysis:

Orgaano Metallic Compounds:

1. Deterrmination of Reaction Meechanism:

Nucleophilicc Substitutionn reactions:

6. Heterrocyclic Cheemistry, 4th ed.

1. Nucleear Magneticc Resonance Spectroscop

Orgganic Chemisttry, Volume I (6th ed.) & II (5th ed.) by

Designing Organic Synthesis, A Programmed Introduction to synthon approach, S. Warren, John

Mullti-step preparation and spectroscoppic characterrization: p-nnitroaniline from anilinee; pbrom

1. Practiical Organic Chemistry

3. Advannced Practicaal Organic Chhemistry, by J.

nalysis and Automation:

7. Dyes and Dyeing, C.E. Pellow, Abhishek Publishers, 1998.

1. Oil & Fats

Oils and Fats:

Shereeves Chemicaal Process Inddustries, 5th Ed.1975,

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