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Sol.
(C).
2.
(B) H 2 I 2
2 NO
2 PCl3 Cl 2
(D) N 2 3 H
2 HI
2 NH 3
Sol.
3.
(C).
For the reaction, A B
C D , if active mass of A is kept constant and active mass of B is tripled, the rate of
Sol.
(D).
4.
The rate of
CO( g )
1
O2 ( g )
2
CO2 ( g ) is
(A) 1
(C)
RT
(B) RT
1/ 2
1/ 2
(D) RT
Sol.
(D).
5.
CaCO3 ( s )
g)
CaO( s ) CO2 (
in a closed container at equilibrium. What would be the effect of addition of CaCO3 on the equilibrium concentration of CO2?
Sol.
6.
(A) Increases
(B) Unpredictable
(C) Decreases
(D).
For the reaction, PCl5 (g)
(A)
(B)
(C)
(D)
Sol.
(C).
7.
A liquid is in equilibrium with its vapour at its boiling point. On an average, the molecules in the two phases have equal
(A) intermolecules forces
(B) potential energy
(C) kinetic energy
(D) both kinetic energy and potential energy
Sol.
(C).
8.
H2 I2
2 HI is
1
(A) Lmol
1
(C) molL
(B) L mol
(D) None of the above
Sol.
(D).
9.
If K1 and K2 are the equilibrium constants of the equilibrium (i) and (ii) respectively, what is the relationship between the two
constants?
1
(i) SO2 ( g ) O2 ( g )
SO3 ( g ); K1
(ii) 2 SO ( g )
3
(A) K 1
2
1
K2
2 SO2 ( g ) O2 ( g ); K 2
(B) K K 2
2
1
1
(C) K 1
(D) K1 = K2
2
Sol.
(A).
10.
It is found that equilibrium constant increase by a factor of four when the temperature is increased from 25C to 40C. The
value of H is
(A) 25.46 kJ
(B) 171.67 kJ
(C) 89.43 kJ
(D) 71.67 kJ
Sol.
(D).
11.
PbI2(s) + 2NaNO3
AgCl (s) +
Sol.
12.
(D).
Solubility of a substance which dissolves with decrease in volume and absorption of
(A) low temperature and low pressure
(B) low temperature and high pressure
(C) high temperature and high pressure
(D) high temperature and low pressure
Sol.
(C).
13.
Water
(A).
14.
Sol.
2NH3(g)
2HCl(g)
PCl5(g)
(C).
15.
Sol.
(A).
16.
(B) Q Kp
(D) Q = 2Kp
Sol.
(B).
17.
In a reaction 2A+B
A2B, the reactant (A) will disappear at
(A) half the rate at which B will decrease
(B) the same rate at which B will decrease
(C) the same rate at which A2B will form
(D) twice the rate at which B will decrease
Sol.
(D).
18.
Sol.
19.
(C).
A tenfold increase in pressure on the reaction, N2(g) + 3H2(g)
(A) tenfold increase
(C) no change
(D)
4
fold decrease
9
Sol.
(C).
20.
One mole each of A and B and 3 moles each of C and D are placed in 1 litre flask, if equilibrium constant is 2.25 for A + B
C + D, equilibrium constant of A and C will be in the ratio
(A) 2 : 3
(C) 1 : 2
(B) 3 : 2
(D) 2 : 1
Sol.
(A).
21.
The Kf = 5 10 mole/litre/seconds
2
and Kb = 3 10 litre/mole/seconds
the equilibrium concentration of M is
(A) 0.13 M
(C) 0.8 M
(B) 0.3 M
(D) cant be calculated
Sol.
(A).
22.
One mole each of CH 3CO2 H and CH 3CH 2OH are heated in presence of little conc.
following equilibrium,
CH 3CO2 H CH 3CH 2OH
CH 3CO2CH 2CH
Sol.
(D).
23.
H2 I2
at 444 C
is
2 HI
(A) 27.5
(C) 73.647
Sol.
(B) 37.647
(D) 57.25
24.
C D , is 1 10
(B) endothermic
(D) neither exothermic nor endothermic
Sol.
(B). K is increased on increasing temperature. This shows that forward reaction is favoured by increase in temperature. Thus,
forward reaction should be endothermic.
25.
C( s ) H 2O( g )
CO( g ) H 2 ( g )
Sol.
(B).
26.
The Kp value for a reaction is 0.9 atm at 300 K. The Kc value of the reaction is
(A) 0.9
(B) 0.0365
(C) 0.009
(D) cant be calculated
Sol.
(B).
27.
A cylinder fitted with movable piston contains liquid water in equilibrium with water vapour at 25C. Which operation would
result in a decrease in the equilibrium vapour pressure?
(A) Moving the piston downwards by a short distance
(B) Removing a small amount of vapour
(C) Removing a small amount of liquid water
(D) Dissolving salt in the water.
Sol.
28.
For 2A + B
(A)
(B)
(C)
(D)
Sol.
(B).
29.
2NH3 + X kcal, one mole of N2 reacts with three moles of H2. At equilibrium, the value of
(A).
30.
Sol.
(A).
31.
CO2(g) + H2(g) is 4. A mixture initially containing one mole of each of carbon monoxide and steam
is allowed to reach equilibrium. How many moles of carbon monoxide are now present?
(A) 1/4
(B) 1/3
(C) 1/2
(D) 2/3
Sol.
(B).
32.
For 3A + 2B
2C + D, initial mole of A is double of B. At equilibrium moles of A and D are equal. Hence percentage
dissociation of A is
(A) 50%
(C) 75%
(B) 25%
(D) none of the above
Sol.
(C).
33.
C(g)
Sol.
(C).
34.
2C(g) + R(g)
C(g) an equilibrium mixture consist of 3.0 moles of A, 0.80 moles of B, and 0.40
(C).
35.
The vapour density of N2O4 at a certain temperature is 30. The percentage dissociation of N2O4 at this temperature is
(A) 53.3
(B) 26.7
(C) 0.533
(D) 2.67
Sol.
(A).
36.
(C) 510
Sol.
37.
(B) 2.510
(D) 10
26
45
(C).
In the reaction X
nY, the initial vapour density of X is D and vapour density at equilibrium is d. If degree of dissociation
of X is , then is equal to
Dd
Dd
(B)
(A)
d n 1
n 1 D
(C)
Dd
n d 1
Sol.
18
(A).
(D)
d n 1
Dd
38.
Sol.
(D).
39.
CO2(g) + H2(g)
CO(g) + H2O(g)
The Kp for the above reaction is 0.11. If the reaction was started with 0.45 moles of CO2 and 0.45 moles of H2 at 700 K, the
concentration of CO2 when 0.34 moles of CO2 and 0.34 moles of H2 are added when the first equilibrium is attained, is
(A) 0.52 M
(B) 0.17 M
(C) 0.34 M
(D) 0.26 M
Sol.
(B).
40.
Sol.
(A). Q
K c 20
[C][D] 4 5
10 [ A]
[B]
12
Q Kc
Therefore, equilibrium will shift from left to right.
41.
The K p value for certain reaction is 0.5 atm at 300 K. Which of the following is incorrect about the reaction?
(A) K can be calculated.
c
(B) From this data, it is not possible to determine about the H value of the reaction.
(C) K p K c
(D) Neither possible to calculate K c nor the relation between K p and K c .
Sol.
(A).
42.
(B) 16
(C) 2
(D) 32
Sol.
(A).
43.
The K p of a reaction is 10 atm at 300 K and 4 atm at 400 K. The incorrect statement about the reaction is
(A) the reaction is exothermic.
(B) the E a of forward reaction is more than that of backward reaction.
(C) the rate of backward reaction increases more than that of forward reaction with increase of temperature.
(D) the difference between heat of reaction at constant pressure and that at constant volume is RT.
Sol.
(B). K p decreases with temperature. Hence, H must be ve as evident from the equation.
d nK p
H
2
dT
RT
H Ea (FR) Ea (BR)
Ea (FR) Ea (BR)
44.
The partial pressure of CH3OH, CO and H2 in the equilibrium mixture for the reaction, CO + 2H2
are 2.0, 1.0 and 0.1 atm. respectively. The value of Kp for the decomposition of CH3OH to CO and H2 is
2
2
1
(A) 1 10 atm
(B) 2 10 atm
CH3OH, at 427 C
(C) 50 atm
(D) 5 10 atm
Sol.
(B).
45.
Sol.
(A).
46.
2 SO2 ( g ) O2 ( g )
2 SO3 (
g)
is 5. If the equilibrium constant mixture contains equal moles of SO3 and SO2, the equilibrium partial pressure of O2 gas is
(A) 0.2 atm
(B) 2 atm
(C) 0.02 atm
(D) 0.04 atm
[SO ]
Sol.
(A). K p
47.
2SO2 + O2
2SO3. Starting with 2 moles of SO2 and 1 mol of O2 in 1 L flask, mixture required 0.4 moles of MnO4 in
acidic medium. Hence, Kc is
(A) 2
(B) 0.4
(C) 1.6
(D) 2.6
Sol.
(A).
48.
Haemoglobin (Hb) forms bond with oxygen and gives oxyHaemoglobin (HbO2). This process is partially regulated by the
[O2 ][SO2 ]2 5
[O2 ] 0.2
(A).
49.
PCl5 is 40% dissociated when pressure is 2 atm. It will be 80% dissociated when pressure is approximately
(A) 0.2 atm
(B) 0.5 atm
(C) 0.3 atm
(D) 0.6 atm
Sol.
(A).
50.
C+D, is studied in a one litre vessel at 250C. The initial concentration of A was 3n and that of B
was n. When equilibrium was attained, equilibrium concentration of C was found to be equal to the equilibrium concentration
of B. What is the concentration of D at equilibrium?
(A) n/2
(B) (3n 1/2)
(C) (nn/2)
(D) n
Sol.
(A).
51.
(B) 0.6 M
(D) 1.6 M
Sol.
(D).
52.
When a mixture of N2 and H2 in the volume ratio of 1 : 5 is allowed to react at 100 K and 10 atm. pressure, 0.426 mole
fraction of NH3 is formed at equilibrium. The Kp for the reaction is
4
4
(A) 2.8 10
(B) 6.6 10
4
4
(C) 3.0 10
(D) 6 10
Sol.
53.
(B).
For the given reaction
2A(s) + B(g)
C(g) + 2D(s) + E(s)
the degree of dissociation of B was found to be 20% at 300 K and 24% at 500 K, the rate of backward reaction
(A) increases with increase in pressure and temperature
(B) increases with increase in pressure and decrease in temperature
(C) depends on temperature only and decreases with increase in temperature
(D) increases with increasing the concentration of B and increasing the temperature
Sol.
(C).
54.
In
the
reaction
A2(g)
4B2
(g)
2AB4(g)
0.
The
decomposition
of
(C). 2AB4(g)
A2(g) + 4B2(g)
H = ve
It is an exothermic reaction and hence favoured at low temperature. n for the reaction is +3. Therefore, low pressure will
favour the forward reaction
55.
In 1918, Fritz Haber, a German chemist, received the Nobel Prize in chemistry for his work on developing a direct synthesis
of ammonia on a commercial scale. Ammonia, which is used heavily by farmers as a fertilizer, is produced commercially by
the Habers process:
N2 (g) + 3 H2 (g)
2 NH3 (g)
Commercially, this reaction is performed at high temperature and in the presence of a heterogeneous catalyst (iron oxide) to
increase the rate of the reaction. Which of the following "forms" of iron oxide would be the most effective for increasing the
rate of the reaction?
(A) 1 g of iron oxide pellets (10 small spherical pellets)
(B) 1 g of iron oxide pellets (1 large spherical pellet)
(C) 1 g of iron oxide powder
(D) 1 g of iron oxide kept on a table outside of the reaction vessel
Sol.
(C). Iron oxide powder has large surface area and hence would be most effective for increasing the rate of the reaction.
56.
For this reaction at equilibrium, which changes will increase the quantity of Fe(s)?
Fe3O4(s) + 4 H2(g)
3 Fe(s) + 4 H2O(g) H > 0
1. increasing temperature
2. decreasing temperature
3. adding Fe3O4(s)
(A) 1 only
(C) 2 and 3 only
Sol.
57.
(A). As H is positive, increasing the temperature will shift the reaction in forward direction.
The thermochemical equation representing the dissociation of AB2 is as follows:
2AB2(g)
2AB(g) + B2(g) H = +40 kcals
Incorrect statement about this reaction is
(A) The Kp of the reaction will decrease with increase of temperature
(B) Carrying out the reaction in a larger vessel (closed) will favour the equilibrium to proceed in forward direction.
(C) H and E are not equal
(D) Adding B2(g) in the reaction mixture will decrease the yield of AB
Sol.
(A).
58.
The Kc of a reaction is 300 mol L at 27C. Hence, the Kp of the reaction will be
1
1
(A) 24.63 atm
(B) 12.18 atm
1
(C) 4.04 atm
(D) None of the above
Sol.
= 12.18 atm
So, Kp =
RT 0.0821
300
59.
Sol.
8.03
10
k2 =
60.
A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite.
The value of Kp if the total pressure at equilibrium is 0.8 atm is
(A) 1.8 atm
(B) 3 atm
(B) 0.3 atm
(D) 0.18 atm
Sol.
(A).
CO2(g) + C(s)
At equilibrium (0.5 x)
Initially
pCO = 0.5 atm
2CO(g)
2x
2
0.3)
(pCO )
2
(0.5 0.3)
61.
The molecular weight of PCl5 is 208.32 but when heated to 230C, it is reduced to 124. The extent of dissociation of PCl5 at
this temperature will be
(A) 6.8%
(B) 68%
(C) 46%
(D) 64%
Sol.
(B).
62.
NO2 is involved in the formation of smog and acid rain. A reaction that is important in the formation of NO2 is
34
O3(g) + NO(g)
O2(g) + NO2(g) Kc = 6.0 10
6
5
4
3
If the air over a section of New Delhi contained 1.0 10 M of O3, 1.0 10 M of NO, 2.5 10 M of NO2 and 8.2 10 M
of O2, what can we conclude?
(D) There will be no tendency for change because the reaction is at equilibrium.
Sol.
6
5
(1.0 10 )(1.0 10 )
= 8.2 2.5 10
= 20.5 10
As Q Kc, the reaction will have a tendency to move forward.
63.
Sol.
(A). Increasing the concentration of the reactant makes Q K. So, the reaction moves forward.
64.
14
Sol.
(B).
65.
(B) 4 10
(C) 4 10
Sol.
-4
(B). When the reaction is carried out in presence of a catalyst, it will catalyse both the forward and backward reactions
equally. So, the equilibrium constant will remain same.
66.
Sol.
C2H6(g)
H = 32.7 kcal.
Concentration of C2H4 will increase as all the factors are favouring backward reaction. High temperature, low pressure,
decrease in concentration of H2 and increase in concentration of C2H6 will favour backward reaction.
67.
Kp for a reaction at 25C is 10 atm. The activation energy for forward and reverse reactions is 12 and 20 kJ/mol respectively.
The Kc for the reaction at 40C will be
1
(B) 3.33 10 M
(D) 4.33 10 M
(A) 4.33 10 M
(C) 3.33 10 M
Sol.
n = +1
Kc at 40C is given by
K c 40 H 1 1
log
K c 25 2.303R T1 T2
8 1000
15
= 0.06719
=
2.303 8.314
298
313
(Kc)40/(Kc)25 = 0.85
68.
Sol.
(C). NH2COONH4(s)
2NH3(g) + CO2(g)
1
2
1
5
3
Kp = 2.9 10 atm
If the P is the total pressure at equilibrium
2
2P P
Kp =
3 3
27 2.9
5
10
4
P =
P=
= 1.9575
1.9575 = 0.058
69.
Sol.
(C).
70.
NH2COONH4(s)
2NH3(g) + CO2(g) The equilibrium constant Kp is 3210 atm . What is the total pressure of gases
in equilibrium with NH2COONH4(s) at 30C?
6
(C).
71.
When sulphur in the form of S 8 is heated at 900 K, the initial pressure of one atom falls by 29% at equilibrium. The Kp is
3
(C).
Initially
At equilibrium
1
0
1 0.29 0.29 4
= 0.71
K p
[PS ]
2
[PS ]
8
72.
4S2 (g)
= 1.16
(1.16)
3
2.55 atm
0.71
Two moles of an equimolar mixture of two alcohols R1OH and R2OH are esterified with one mole of acetic acid. If 80% of
the acid is consumed and the quantities of ester formed under equilibrium are in the ratio of 3:2, what is the value of
equilibrium constant for the esterification of R1OH?
(A) ~ 3.7
(C) ~ 3.2
(B) ~ 2.9
(D) ~ 3.0
Sol.
(A).
LIST I
73.
(a)
Kp = 20 atm
(b)
(c)
(d)
H2(g) + I2(g)
N2 + 3H2
GP , T 0
Codes
a
(A) 2
(B) 2
(C) 3
(D) 2
b
1
3
2
4
(1)
2HI(g)
2NH3, H = ve
c
4
1
1
1
(2)
(3)
(4)
LIST II
No effect of pressure on the yield of
the product
H = E RT
Nonspontaneous process
Kp decreases with temperature
d
3
4
4
3
Sol.
(C).
74.
(C) 510 M
Sol.
(A).
75.
(D) 0.25 M
SO2(g) + Cl2(g) is attained at 25C in a closed vessel and He is introduced, which of the
(D).
76.
In the system LaCl3(s) + H2O(g) + heat LaClO(s) + 2HCl(g), more water vapour is added to reestablish the
equilibrium. The Pressure of water vapour is doubled. The factor by which pressure of HCl will change is
(A) 2
(B) 2
(C) 3
(D) 5
Sol.
77.
(B).
Liquid NH 3 ionizes to a slight extent. At 60C, its ionic product,
K NH 3 [ NH 4 ][ NH 2 ] 1036
(assuming that NA = 6 10 )
(A) 300 ions
(C) 600 ions
Sol.
(C).
78.
is
The standard state Gibbs free energy change for the isomerization reaction, cis 2 pentene
1
3.67 kJ mol at 400 K, if more trans 2pentene is added to the reaction vessel
(A) more cis 2pentene is formed
(B) equilibrium shifts in the forward direction
(C) equilibrium remains unaltered
(D) more trans 2pentene is produced
trans 2 pentene