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Overview
PVC stabilisation the change from
Pb-based to Ca-based
PVC Cables & Wires correct recipe
design for maximum performance
PVC Pipes & Fittings trend towards
highly filled pipe formulations
PVC Profiles outdoor weathering
performance is key
Toxic
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 4
Source: ESPA
...
HC
H
CH
Cl
...
heat
...
CH
CH
...
+ HCl
BAEROPAN
...
...
Zn
Cl
C17 H35
C17 H35
O
PVC
Zn stearate
O
...
...
O
C17 H35
O
C17 H35
Zn
Cl
ZnCl2
C17 H35
Zn
Cl
Ca stearate
ZnCl2
+ Ca(OCO-C17H35)2
Zn
C17 H35
C17 H35
- CaCl2
O
Asia
thermostability
mechanical properties
electrical properties
performance
influence on Ca/Zn stabiliser performance by additional
components: Ca stearate, CPE, CPW, stearic acid
heavy metal pigments have to be replaced completely to be
heavy-metal-free
shorter storage stability of Ca/Zn stabiliser and cable compound
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 16
Ca/Zn stabilisers
Cable
Operating
Temperature
[C]
BP MC 91535 KA
60 - 80
3-6
BP MC 90224 KA
80 - 90
4-8
BP MC 90827 KA
80 - 90
4-8
BP MC 8656 KA-ST
90 - 105
4-8
BP MC 225 KA/1
80 - 90
3-6
white cables
Dosage
Application Type
[phr]
Asia
Pressure
Pipes
Sewer
Pipes
Injection
Moulding
100 (k 68)
100 (k 68)
100 (k 57)
Coated Filler
max. 5
20 - 50
0-2
Ca-based Stabiliser
2.0 - 3.0
2.0 - 3.0
4.0 - 6.0
1.0
as desired
as desired
as desired
[phr]
S-PVC
Processing Aid
Pigment
Asia
Window
profile
Rain
gutter
Roller
shutter
Cable
duct
100
100
100
100
Coated Filler
10 - 18
5 - 10
10 - 20
15 - 45
Ca/Zn Stabiliser
3.5 - 4.0
2.5 - 4.0
2.5 - 4.0
2.5 - 4.0
Processing Aid
0.5 - 1.0
1.0
1.0
1.0
Impact Modifier
5.0 - 9.0
0 5.0
0 5.0
0 2.0
Pigment
min. 3.0
as desired
as desired
as desired
[phr]
S-PVC
Lead-based
Profile
Ca/Zn
Profile
S-PVC
100
100
Coated Filler
5.0
5.0
Pb-based Stabiliser
5.3
Ca/Zn Stabiliser
4.4
Impact Modifier
7.0
7.0
TiO2 Pigment
4.0
4.0
[phr]
Ca/Zn
Delta L*
0
0
10
15
20
25
30
35
40
45
-1
-2
-3
time [months]
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 31
Ca/Zn
Delta a*
0
0
10
15
20
25
30
35
40
45
-1
-2
-3
time [months]
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 32
Ca/Zn
Delta b*
0
0
10
15
20
25
30
35
40
45
-1
-2
-3
time [months]
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 33
Ca/Zn
60
Gloss [%]
50
40
30
20
10
0
0
10
15
20
25
30
35
40
45
time [months]
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 34
adjusted lubrication
specific one-pack design
for each purpose
Asian Technical Seminar, June 2013 Dr. Jrg Frhlich Slide 36
BAEROPAN R 91605 FP
BAEROPAN MC 91684 P