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(a)
List - II
(1) Rotation
period of earth
4.
(i) 10 5 s
2
3
(d)
3
2
Consider a cylinder of mass M resting on a rough horizontal
rug that is pulled out from under it with acceleration a
perpendicular to the axis of the cylinder. What is Ffriction at
point P? It is assumed that the cylinder does not slip.
w
th
2.
3.
1
A bullet looses of its velocity passing through one
n
plank. The number of such planks that are required to stop
the bullet can be:
n2
2n 2
(a)
(b)
2n - 1
n -1
(c) infinite
(d) n
A heavy box is to dragged along a rough horizontal floor.
To do so, person A pushes it at an angle 30 from the
horizontal and requires a minimum force FA, while person B
pulls the box at an angle 60 from the horizontal and needs
minimum force FB. If the coefficient of friction between the
FA
3
, the ratio F is
box and the floor is
5
B
O
P
(c)
(2) Revolution
(ii) 10 7 s
period of earth
(a)
(b)
(c)
(d)
(b)
a
F friction
(a) Mg
(b) Ma
Ma
Ma
(d)
3
2
A particle is released on a vertical smooth semicircular track
from point X so that OX makes angle q from the vertical (see
figure). The normal reaction of the track on the particle
vanishes at point Y where OY makes angle f with the
horizontal. Then:
(c)
5.
X
Y
q
f
O
sin f =
2
cos q
3
(b) sin f =
1
cos q
2
(d) sin f =
3
cos q
4
2
6.
7.
8.
9.
(b)
(c)
Ma
16
In
4pR s 3
2
Ma
16
In
16pR s 3
2
Ma
3
In
16pR s 2
12. A gas is compressed from a volume of 2m3 to a volume of
1m3 at a constant pressure of 100 N/m2. Then it is heated at
constant volume by supplying 150 J of energy. As a result,
the internal energy of the gas:
(a) increases by 250 J
(b) decreases by 250 J
(c) increases by 50 J
(d) decreases by 50 J
13. A gas molecule of mass M at the surface of the Earth has
kinetic energy equivalent to 0C. If it were to go up straight
without colliding with any other molecules, how high it would
rise? Assume that the height attained is much less than
radius of the earth. (kB is Boltzmann constant).
(d)
(a) 0
(b)
5 cm
10.
11.
T 1 1
r r R
(b)
2T 1 1
r r R
(c)
4T 1 1
r r R
(d)
6T 1 1
r r R
Ma
3
In
2
4pR s 2
819k B
546k B
(d)
2Mg
3Mg
14. A body is in simple harmonic motion with time period half
second (T = 0.5 s) and amplitude one cm (A = 1 cm). Find the
average velocity in the interval in which it moves form
equilibrium position to half of its amplitude.
(a) 4 cm/s
(b) 6 cm/s
(c) 12 cm/s
(d) 16 cm/s
15. The total length of a sonometer wire between fixed ends is
110 cm. Two bridges are placed to divide the length of wire
in ratio 6 : 3 : 2. The tension in the wire is 400 N and the mass
per unit length is 0.01 kg/m. What is the minimum common
frequency with which three parts can vibrate?
(a) 1100 Hz
(b) 1000 Hz
(c) 166 Hz
(d) 100 Hz
16. The electric field in a region of space is given by,
r
E = E i + 2E j where E = 100 N/C. The flux of the field
(c)
273k B
2Mg
(a)
0 (1 + 2 ) A / d
(b)
0 ( 2 + 1 ) A / 2d
(c)
0 A / d ln ( 2 / 1 )
(d)
0 ( 2 - 1 ) A / d ln ( 2 / 1 )
3
18. Four bulbs B1, B2, B3 and B4 of 100 W each are connected
to 220 V main as shown in the figure.
E
B2
B1
220 V
B3
B4
(b)
Ammeter
E
(c)
I = 1A
(d)
x
v
22.
10 cm
The e.m.f induced at the time the left arm of the frame is at x
= 10 cm from the wire is:
(a) 2 mV
(b) 1 mV
(c) 0.75 mV
(d) 0.5 mV
20. An example of a perfect diamagnet is a superconductor. This
implies that when a superconductor is put in a magnetic
field of intensity B, the magnetic field Bs inside the
superconductor will be such that:
(a) Bs = B
(b) Bs = 0
(c) Bs = B
(d) Bs < B but Bs 0
21. Figure shows a circular area of radius R
R
where a uniform magnetic field B is
going into the plane of paper and
increasing in magnitude at a constant
rate.
In that case, which of the following graphs, drawn
schematically, correctly shows the variation of the induced
electric field E(r)?
23.
24.
25.
E
(a)
r
26.
27.
List - II
(ii) Charge of an
electron
(3) Rutherford
experiment
(iii) Quantisation of
energy levels
(4) Franck-Hertz
experiment
(iv) Existence of
nucleus
50 W
4.0
VCC 6V
50 W
Vout
R = 10 kW
29.
30.
8.0
6.0
List - I
28.
T (in s )
2.0
0.5 1.0 1.5 2.0 L (in m)
What is the value of g at the place?
(a) 9.81 m/s2
(b) 9.87 m/s2
2
(c) 9.91 m/s
(d) 10.0 m/s2
PART B - CHEMISTRY
31. Ionization energy of gaseous Na atoms is 495.5 kJ mol1.
The lowest possible frequency of light that ionizes a sodium
atom is
(h = 6.626 1034 Js, NA = 6.022 1023 mol1)
(a) 7.50 104 s1
(b) 4.76 1014 s1
(c) 3.15 1015 s1
(d) 1.24 1015 s1
32. Choose the correct statement with respect to the vapour
pressure of a liquid among the following:
(a) Increases linearly with increasing temperature
(b) Increases non-linearly with increasing temperature
(c) Decreases linearly with increasing temperature
(d) Decreases non-linearly with increasing temperature
33. Which one of the following molecules is paramagnetic?
(a) N2
(b) NO
(c) CO
(d) O3
34. Zirconium phosphate [Zr 3(PO4)4] dissociates into three
zirconium cations of charge + 4 and four phosphate anions
of charge 3. If molar solubility of zirconium phosphate is
denoted by S and its solubility product by Ksp then which
of the following relationship between S and Ksp is correct?
(a) S = {Ksp/ (6912)1/7}
(b) S = {Ksp/ 144}1/7
(c) S = {Ksp/ 6912}1/7
(d) S = {Ksp/ 6912}7
35. For the decomposition of the compound, represented as
NH2COONH4(s) 2NH3(g) + CO2(g)
the Kp = 2.9 105 atm3.
1 d [ A ] d [C]
n
m
=
= k [ A ] [ B]
dt
3 dt
5
(b)
(c)
38.
39.
40.
41.
dt
d [ C]
dt
= k [ A ] [ B]
n
44.
d [C]
1 d [ A]
n
m
== k [ A ] [ B]
dt
3 dt
1 d [ A ] d [C]
n
m
=
= k [ A ] [ B]
3 dt
dt
Sulphur dioxide and oxygen were allowed to diffuse through
a porous partition. 20 dm3 of SO2 diffuses through the
porous partition in 60 seconds. The volume of O2 in dm3
which diffuses under the similar condition in 30 seconds will
be (atomic mass of sulphur = 32 u):
(a) 7.09
(b) 14.1
(c) 10.0
(d) 28.2
The observed osmotic pressure for a 0.10 M solution of
Fe(NH4)2(SO4)2 at 25C is 10.8 atm. The expected and
experimental (observed) values of vant Hoff factor (i) will
be respectively:
(R = 0.082 L atm k1 mol1)
(a) 5 and 4.42
(b) 4 and 4.00
(c) 5 and 3.42
(d) 3 and 5.42
The total number of octahedral void (s) per atom present in
a cubic close packed structure is:
(a) 2
(b) 4
(c) 1
(d) 3
For an ideal solution of two components A and B, which of
the following is true?
(a) DHmixing < 0 (zero)
(b) DHmixing > 0 (zero)
(c) A B interaction is stronger than A A and B B
interactions
(d) A A, B B and A B interactions are identical.
Consider the reaction:
(d)
37.
d [A]
(b)
O 22 -
(c) B3+
(d) F
43. An octahedral complex with molecular composition M.5
NH3.Cl.SO4 has two isomers, A and B. The solution of A
gives a white precipitate with AgNO3 solution and the
solution of B gives white precipitate with BaCl2 solution.
The type of isomerism exhibited by the complex is:
(a) Linkage isomerism
(b) Ionisation isomerism
45.
46.
47.
48.
49.
50.
51.
52.
53.
is:
(a) 4 - methyl - 3 - ethylhexane
(b) 3 - ethyl - 4 - methylhexane
54.
(c) 3, 4 - ethylmethylhexane
(d) 4 - ethyl - 3 - methylhexane
Which one of the following substituents at para-position is
O
55.
56.
57.
58.
59.
60.
ion?
(a) CH3
(b) OCH3
(c) COCH3
(d) CH2OH
The final product formed when Methyl amine is treated with
NaNO2 and HCl is:
(a) Diazomethane
(b) Methylalcohol
(c) Methylcyanide
(d) Nitromethane
Which one of the following compounds will not be soluble
in sodium bicarbonate?
(a) 2, 4, 6 - Trinitrophenol
(b) Benzoic acid
(c) o - Nitrophenol
(d) Benzene sulphonic acid
Williamson synthesis of ether is an example of:
(a) Nucleophilic addition
(b) Electrophilic addition
(c) Electrophilic substitution
(d) Nucleophilic substitution
The reason for double helical structure of DNA is the
operation of:
(a) Electrostatic attractions
(b) van der Waals forces
(c) Dipole - Dipole interactions
(d) Hydrogen bonding
Among the following organic acids, the acid present in rancid
butter is:
(a) Pyruvic acid
(b) Lactic acid
(c) Butyric acid
(d) Acetic acid
In a set of reactions p-nitrotoluene yielded a product E.
CH3
PART C - MATHEMATICS
x -1
61. Let f : R R be defined by f(x) = x + 1 then f is:
(a) both one-one and onto
(b) one-one but not onto
(c) onto but not one-one
(d) neither one-one nor onto.
62. For all complex numbers z of the form 1 + ia, a R , if z2 = x
+ iy, then
(a) y2 4x + 2 = 0
(b) y2 + 4x 4 = 0
(c) y2 4x 4 = 0
(d) y2 + 4x + 2 = 0
63. The equation 3x 2 + x + 5 = x - 3 , where x is real, has;
(a) no solution
(b) exactly one solution
(c) exactly two solution
(d) exactly four solution
64. Let A and B be any two 3 3 matrices. If A is symmetric and
B is skewsymmetric, then the matrix AB BA is:
(a) skewsymmetric
(b) symmetric
(c) neither symmetric nor skewsymmetric
(d) I or I, where I is an identity matrix.
65. If D r =
2r - 1
3r - 2
n
2
n -1
1
n(n - 1) (n - 1)2
2
n -1
FeBr3
NO2
CuBr
HCl
HBr
2 D E
CH3
Br
CH3
Br
Br
(b)
(a)
Br
Br
CH3
CH2 Br
Br
(c)
Dr
r =1
Sn/HCl
2 B
C
NaNO
1
(n - 1)(3n - 4)
2
(d)
Br
Br
1
, then the number of terms in
2
7
the A.P. is:
(a) 4
(c) 12
x 5m
(b) 8
(d) 16
(a)
1 3n
n , where [n] denotes the greatest
69. Let f ( n ) = +
3 100
(b)
f ( n) is equal to:
(b) 689
(d) 1399
(c)
2 + cos x - 1
,x p
f ( x ) = ( p - x)2
,x = p
k
is continuous at x = p, then k equals:
(a) 0
(b)
(c) 2
(d)
(d)
1
2
75.
1
4
(a)
1
6
(b)
1
1
(d)
36
24
If m is a non-zero number and
x 5m -1 + 2x 4m-1
(x
2m
+ x +1
(a)
e F ( x ) - F (1 + a )
(b)
e -a F ( x + a ) - F ( a )
(c)
ea F ( x + a ) - F (1 + a )
e -a F ( x + a ) - F (1 + a )
The area of the region above the x-axis bounded by the
(d)
76.
x=
77.
1
9
(c)
74.
e
dt, x > 0 then the
t
1 1
,
2 2
x t
curve y = tan x, 0 x
2
2,
(d)
2,
73. If the volume of a spherical ball is increasing at the rate of 4p
cc/sec, then the rate of increase of its radius (in cm/sec),
when the volume is 288 p cc,
(c)
c
then
lies in the interval:
b
(b)
x R . Then, at x = 0, f is:
(a) continuous but not differentiable.
(b) continuous as well as differentiable.
(c) neither continuous nor differentiable.
(d) differentiable but not continuous.
72. If non-zero real numbers b and c are such that min f(x) > max
g(x), where f(x) = x2 + 2bx + 2c2 and
g(x) = x2 2cx +
2
b (x R);
(a)
(
)
2m ( x 5m + x 4m )
2
( x 2m + xm + 1)
( x5m - x4m )
2
2m ( x 2m + x m + 1)
2m x 2m + x m + 1
1
0,
2
x 4m
56
n=1
(a) 56
(c) 1287
70. If the function
2m x 2m + x m + 1
78.
dx = f ( x ) + c ,
p
and the tangent to the curve at
2
p
is:
4
(a)
1
1
log 2 -
2
2
(b)
1
1
log 2 +
2
2
(c)
1
(1 - log 2 )
2
(d)
1
(1 + log 2 )
2
If
dy
+ y tan x = sin 2x and y(0) = 1, then y(p)
dx
is equal
to:
(a) 1
(b) 1
(c) 5
(d) 5
The circumcentre of a triangle lies at the origin and its
centroid is the mid point of the line segment joining the
points (a2 + 1, a2 + 1) and (2a, 2a), a 0. Then for any a, the
orthocentre of this triangle lies on the line:
(a) y 2ax = 0
(b) y (a2 + 1)x = 0
(c) y + x = 0
(d) (a 1)2x (a + 1)2y = 0
If a line L is perpendicular to the line 5x y = 1, and the area
of the triangle formed by the line L and the coordinate axes
8
is 5, then the distance of line L from the line x + 5y = 0 is:
(a)
(c)
80.
81.
(b)
5
7
5
13
5
, then its slope can be:
2
(a)
(c)
82.
5
2
2
(b)
3
2
2
(d)
5
3
The tangent at an extremity (in the first quadrant) of latus
x2 y2
= 1 , meet x-axis and y-axis
4
5
at A and B respectively. Then (OA)2 (OB)2, where O is the
origin, equals:
20
16
(a) (b)
9
9
4
(d) (c) 4
3
Equation of the line of the shortest distance between the
x -1 y +1 z
x
y z
=
= is:
= and
lines =
1
-2
0
1 -1 1
x
y
z
(a)
=
=
1 -1 -2
x -1 y +1 z
=
=
(b)
1
-1
-2
x -1 y +1 z
=
=
(c)
1
-1
1
y z
x
= =
(d)
-2 1 2
If the angle between the line 2(x + 1) = y = z + 4 and the plane
83.
84.
2x y +
(c)
(d)
13
7
The equation of circle described on the chord
3x + y + 5 = 0 of the circle x2 + y2 = 16 as diameter is:
(a) x2 + y2 + 3x + y 11 = 0
(b) x2 + y2 + 3x + y + 1 = 0
(c) x2 + y2 + 3x + y 2 = 0
(d) x2 + y2 + 3x + y 22 = 0
A chord is drawn through the focus of the parabola y2 = 6x
such that its distance from the vertex of this parabola is
p
l z + 4 = 0 is 6 , then the value of l is:
135
7
45
7
(a)
(b)
(d)
45
11
135
11
p
2
(d)
p
4
43p
-1
89. The principal value of tan cot
is:
4
(a)
3p
4
(b)
3p
4
p
p
(d)
4
4
90. The contrapositive of the statement if I am not feeling well,
then I will go to the doctor is
(a) If I am feeling well, then I will not go to the doctor
(b) If I will go to the doctor, then I am feeling well
(c) If I will not go to the doctor, then I am feeling well
(d) If I will go to the doctor, then I am not feeling well.
(c)
2.
FB =
mmg
sin q + m cos q
mmg
FA sin q - m cos q
=
mmg
FB
sin q + m cos q
1
C = f l and T =
f
Therefore period of light wave is 1015 s (approx)
(a) Let u be the initial velocity of the bullet of mass m.
After passing through a plank of width x, its velocity
decreases to v.
4
4 u(n - 1)
or, v = u - =
n
n
n
If F be the retarding force applied by each plank, then using
work energy theorem,
uv=
1
1
1
1
( n - 1)
Fx = mu2 mv2 = mu2 mu2
2
2
2
2
n2
3
cos30
5
=
3
sin 60 cos 60
5
1
3
3
+
2 5
2
=
3
3 1
2
5 2
1
2n - 1
mu 2
2
n2
1 3
1 8
1 +
2 5
= 2 5
=
3 1
34
1 -
5 5
10
1
F ( Px ) = mu 2 - 0
2
1
2 ( 2n - 1) 1
2
= mu
or, P ( Fx ) = P 2 mu
2
2
n
\ P=
3.
(d)
n2
2n - 1
FA(Push)
4.
(d)
q = 60
30
f
mg
8
10 = 8 = 2
34
34
3
10
mmg
FA =
sin q - m cos q
Similarly,
3
given
m =
5
sin 30 +
1
2 1 - ( n - 1)
mu
= 2
n2
Fx =
mmg
3
sin 60 cos 60
5
mmg
3
sin 30 +
cos 30
5
5.
6.
(c)
(c)
1
Ma sin 90
3
Ma
3
[ here q = 90]
Given : m = 0.160 kg
q = 60
v = 10 m/s
Angular momentum L = r m v
10
= H mv cos q
=
v2 sin 2 q
H =
2g
v2 sin 2 q
cos q
2g
10
8
Therefore the rate at which water flows through the tube
Solving we get v1 =
7.
(d)
2
3
2
6
2
3
v1 - ( v1 ) = 2 10 5 Q g = 10m / s = 10 cm / s
10
and h = 5 cm
10. (d)
dv
dr
1 1
Then energy released, E = 4pTR 3 -
r R
If this energy is converted into kinetic energy then
y
x
v = - I x dx + I y dy
0
1 2
1 1
mv = 4pR 3T -
2
r R
= I x .x + I y .y
1 4 3 2
1 1
pR r v = 4pR 3T -
2 3
r R
= 5 ( 7 - 0 ) + 12 ( -3 - 0 )
8.
(b)
= - 35 + ( -36 ) = 1 J / kg
i.e., change in gravitational potential 1 J/kg.
Hence change in gravitational potential energy 1 J
h = 102 poise
v = 18 km/h =
18000
= 5 m/s
3600
11. (c)
l =5m
Coefficient of viscosity, h =
shearing stress
strain rate
= 10
(a)
-2
\ v 22 - v12 = 2gh
...(1)
According to the equation of continuty
A1v1 = A 2 v2
A1
6 mm2
=
A 2 10 mm 2
A1 v 2 6
From equation (2), A = v = 10
2
1
v2 =
6
v1
10
6T 1 1
r r R
v=
6T 1 1
r r R
dT sA 4
4
=
T - Tsurr
dt McJ
1
1
P1 + rv12 = P2 + rv 22
2
2
or,
v2 =
dT = ( 3T0 - 2T0 ) = T0
v
Strain rate =
l
9.
6 10
= 7.5cc / s
8
When drops combine to form a single drop of radius R.
= A1v1 = A 2 v 2 =
...(2)
T0
s 4pR 2
=
( 3T )4 - ( T0 ) 4
dt Ma ( 3T )3 J 0
0
dt =
Ma 27T04 J
s 4 pR 2 80T04
Solving we get,
Time taken for the sphere to cool down temperature 2T 0,
Ma
16
ln
16pR s 3
12. (a) As we know,
DQ = D u + D w
DQ = D u + P D v
t=
or
150 = Du + 100 (1 - 2 )
11
= Du - 100
\
Du = 150 + 100 = 250J
Thus the internal energy of the gas increases by 250 J
13. (d) Kinetic energy of each molecule,
3
K.E. = K B T
2
In the given problem,
Temperature, T = 0C = 273 K
Height attained by the gas molecule, h = ?
1000
Hz
6
n2 =
1000
Hz
3
1000
Hz
2
Hence common frequency = 1000 Hz
n3 =
16. (a)
819K B
3
K.E. = K B ( 273) =
2
2
K.E. = P.E.
Similarly, n1 =
E = E 0 i + 2E 0 j
Given, E 0 = 100N / c
819K B
= Mgh
2
2
Area = pr =
819K B
or h =
2Mg
22
0.02 0.02
7
-3
= 100i + 200j .1.25 10 i cos q [q = 0]
= 0.125 Nm2/c
17. (d)
18. (c)
Power
Voltage
100
= 0.45A
220
Current through ammeter = 0.45 3 = 1.35 A
19. (b) In the given question,
Current flowing through the wire, I = 1A
Speed of the frame, v = 10 ms1
Side of square loop, l = 10 cm
Distance of square frame from current carrying wires x = 10 cm.
We have to find, e.m.f induced e = ?
According to Biot-Savarts law
O
Time taken to a displacement A/2 where A is the amplitude
of oscillation from the mean position O is
Therefore, time, t =
Displacement, s =
T
12
0.5
sec
12
A 1
= cm
2 2
A
1
2
\ Average velocity, v =
= 2 = 12 cm / s
0.5
t
12
1 T 1000
=
Hz
2l m
11
B=
m0 Idlsin q
4p x 2
4p10-7 1 10-1
2
4p
10-1
( )
= 106
Induced e.m.f. e = Blv
= 106 101 10
= 1 mv
20. (b) Magnetic field inside the superconductor is zero.
Diamagnetic substances are repelled in external
magnetic field.
21. (a) Inside the sphere field varies linearly i.e., E r with
12
distance and outside varies according to E
22. (c)
23. (c)
1
2
r
Hence the variation is shown by curve (a)
Gamma rays < X-rays < Ultra violet < Visible rays
< Infrared rays < Microwaves < Radio waves.
30. (b)
sin - qiB
2
24. (c)
28. (a)
29. (b)
= 19039 years
AND Gate
Frequency of radio waves for sky wave propagation is
2 MHZ to 30 MHZ.
From graph it is clear that when
L = 1m, T2 = 4s2
As we know,
T = 2p
g=
ic
g=
31. (d)
32. (b)
dN0
= 20 decays/min
dt
But
N0
= lt
N
N
1
Log 0
l
N
495.5 103 J
= 12.4 1014
6.023 1023 6.6 10-34
= 1.24 1015 s1.
If we plot a graph between the vapour pressure and
the temperature. We would get a curve that rises faster
as T increases, giving a curved line.
Temp (C)
33. (b)
2.303 T1/ 2
N
Log10 0
0.693
N
dN 0
dt = N0 = 20 = 10
dN
N
2
dt
2.303 5730
1
\ t=
0.693
Energy = NA hn
495.5 = 6.023 1023 6.6 1034 n
n=
N = N0 e -lt
t=
484
= 9.87m / s 2
49
Chemistry
dN
= 2 decays/min
dt
T1/2 = 5730 years
As we know,
Log
Vapour Pressure/mm Hg
27. (c)
T2
2
2n sin q
l
l = Wavelength of light used to illuminate the object
n = Refractive index of the medium between object and
objective
q = Angle
(2)
(3)
(4)
4 p2 L
22 1 22
= 4 =
7 4 7
R.P. =
25. (c)
26. (b)
L
g
34. (c)
4
3S
4S
13
= 6912 S 7.
\
35. (b)
K sp
S=
6912
38. (a)
1/7
KP
PNH 2COONH 4 ( s)
(PNH ) ( PCO )
2
39. (b)
2 P
3
PCO2 =
1 P
3
P
4 P3
2P
KP = =
3
3
27
40. (d)
4 P3
27
41. (c)
2.9 10-5 27
4
2.9 10 -5 27 3
P=
= 5.82 102 atm
1 d [ A] d [ C ]
n
m
=
= k [ A] [ B ]
3 dt
dt
According to Grahams Law Diffusion:
=37. (b)
42. (a)
43. (b)
44. (a)
r1
d
= 2
r2
d1
r1 V1 / t1
=
r2 V2 / t2
or
r1 V1 / t1
=
=
r2 V2 / t2
20 / 60
16 / 2
=
=
V2 / 30
32 / 2
Mol.wt
2
On calculating,
V2 = 14.1
d2
d1
Q Mol. wt = 2 V.D
+4
4+
H 2SO3 ( aq ) + Sn ( aq ) + H 2O ( l )
+6
36. (d)
2NH 3 ( g ) + CO 2 ( g )
NH 2 COONH 4 ( s )
( PNH ) ( PCO ) =
=
45. (b)
1
2
46. (a)
Sn 2+ ( aq ) + HSO4 - ( aq ) + 3H +
Hence H2 SO 3 is the reducing agent because it
undergoes oxidation.
On moving along a period ionic radii decreases due to
increase in effective nuclear charge.
The two possible isomers for the given octahedral
complex are [M(NH3)5 SO4] Cl and [M(NH3)5 Cl] SO4.
They respectively give chloride ion (indicated by
precipitation with BaCl2) and SO4 ion (indicated by
precipitation with AgNO3). Hence the type of isomerism
exhibited by the complex is ionization isomerism.
The reaction given is
Cr3+ + Fe3+ + CO2
Cr2O72 + Fe2+ + C2O42
Cr2O72
2Cr3+
On balancing
2Cr3+ + 7H2O ......(i)
14H+ + Cr 2O72 + 6e
Fe3+ + e
Fe2+
......(ii)
2
C2O4
.......(iii)
2CO2 + 2e
On adding all the three equations.
Cr2O72 + Fe2+ + C2O42 + 14H+ + 3e
Ni 2+ ( d 8 )
3d
4p
4s
\ V.D =
[NiL4 ]2
sp3
14
47. (a)
(b)
(c)
(d)
48. (c)
49. (a)
50. (a)
51. (d)
53. (b)
3-ethyl-4-methyl hexa ne
54. (c)
55. (b)
56. (b)
OH
O
N
O
57. (d)
heat
Cl3C - CH 2 CH 3 + KOH
52. (d)
CH3
|
CH3CH 2 - C H - C H - CH 2CH 3
|
CH2
|
CH 3
O
||
CH3CH 2 C - OH
Polymers which change irreversibly into hard and rigid
material on heating are known as thermosetting
polymers e.g bakelite.
CH3
CH3
58. (d)
59. (c)
60. (b)
CH3
Br
NO2
Br
Br2
NaNO2
FeBr3
HCl
NO2
N = NCl
CH3
Br
Br
HBr
CuBr
15
61. (c)
x -1
x +1
f ( x) =
64.
(b)
x1 - 1 x2 - 1
=
x1 + 1 x2 + 1
x1 x2 + x1 - x2 - 1 = x1 x2 - x1 + x2 - 1
x1 - x2 = x2 - x1
n -1
2 x1 = 2 x2
65.
(d)
x1 = x2
r =1
r =1
(3r - 2) = 1 + 4 + 7 + .. + (3n 3 2)
n -1
r =1
n -1
r =1
= 4a + 4 - 4a - 4
= 0 = R.H.S.
Hence, y2 + 4x 4 = 0
(n - 1)(3n - 4)
2
Sr
Dr =
n
2
n(n - 1)
2
S (2 r - 1)
S (3r - 2)
n -1
(n - 1)2
(n - 1)(3n - 4)
2
Consider 3 x 2 + x + 5 = x 3
Squaring both the sides, we get
3x2 + x + 5 = (x 3)2
n -1
3 x + x + 5 = x2 + 9 - 6 x
2
2x2 + 7 x - 4 = 0
2
2x + 8x - x - 4 = 0
2 x( x + 4) - 1( x + 4) = 0
r =1
Dr
n(n - 1)
2
n
=
2
n(n - 1)
2
(n - 1)2
(n - 1)(3n - 4)
2
n -1
(n - 1)2
(n - 1)(3n - 4)
2
=0
(Q R1 and R3 are identical)
1
or x = 4
2
n -1
Hence, value of
1
For x =
and x = 4
2
(2 r - 1) = 1 + 3 + 5 + ... + [2 (n 1) 2]
n -1
x=
n (n - 1)
2
= (n 1)2
2
2
LHS : y 2 + 4 x - 4 = (2a ) + 4(1 - a ) - 4
63. (a)
r = 1 + 2 + 3 + ... + (n 1) =
r =1
x -1
For onto : f ( x ) =
x +1
n -1
x1 = x2 , x1 = x2
here x1 has two values therefore function is many
one function.
62. (b)
r=1
3 x2 + x + 5 = x 3
66.
(b)
and 'n'.
Let no. of men = n
16
No. of women = 2
Total participants = n + 2
No. of games that M1 plays with all other men
= 2(n 1)
These games are played by all men M2, M3, ......, Mn.
So, total no. of games among men = n.2(n 1).
However, we must divide it by 2, since each game
is counted twice (for both players).
So, total no. of games among all men
= n(n 1)
....... (1)
Now, no. of games M1 plays with W1 and W2 = 4
(2 games with each)
Total no. of games that M1, M2, ....., Mn play with
W1 and W2 = 4n
....... (2)
Given : n(n 1) 4n = 66
n = 11, 6
As the number of men can't be negative.
So, n = 11
67.
(b)
26-
3
2
Putting value of d in equation (3)
62
=4
3
Total no. of terms = 2n = 2 4 = 8
n=
69. (d)
1 3n
n
Let f (n) = +
3 100
where [n] is greatest integer function,
3n
n
= 0.33 +
100
So,
n =1
33
[46 + 32] + 112
2
33
(78) + 112 = 1399.
2
=
68.
(b)
n
So = [2a + (n - 1)(2d )] = 24
2
n [a + (n 1) d ] = 24
Sum of even terms :
n
[ 2(a + d ) + (n - 1)2d ] = 30
2
n [a + d + (n 1) d] = 30
Subtracting equation (1) from (2), we get
nd = 6
70. (d)
21
2nd d =
2
lim
q 0
= lim
...(1)
q0
( p - x) 2
is
2 - cos q - 1
q2
(2 - cos q) - 1
q2
1
2 - cos q + 1
1 - cos q 1
= lim
.
q 0
2
q2
...(2)
=
...(3)
21
Also, given that last term exceeds the first term by
2
21
2
2 + cos x - 1
Since f (x) =
Continuous at x = p
\ L.H.L = R.H.L = f (p)
Let (p x) = q, q 0 when x p
Se =
a + (2n 1) d = a +
(Q nd = 6)
d=
21
=d
2
=
71. (b)
(Q cos 0 = 1)
2
1
2sin 2 q / 2
2 lim sin q / 2
lim
=
2 q0
2 q0 q 2
q2
.4
4
1
4
sin x
= 1
Q lim
x 0 x
17
f ( h ) - f (0)
f (h)
= lim
h-0
h 0
h 0 h
\ f (0) = lim
Now,
f (h)
|h|
h
- | h |
72. (d)
...(1)
74.
(b)
(Q | f ( x ) | x 2 )
75.
4 3
pr
3
dv
4
2 dr
= .3pr .
dt
3
dt
4p = 4pr2.
dr
dt
dr
2 =
dt
r
Since, V = 288p, therefore from (1), we have
4
288 3
p(r 3 )
= r3
3
4
216 = r3
r=6
288p =
Hence,
dr 1
=
.
dt 36
x5 m -1 + 2 x 4 m -1
( x 2 m + x m + 1)3
...(1)
dx =
1 -3
1
+C
t dt =
-m
2mt 2
1
2m(1 + x
-m
+ x -2 m ) 2
x 4m
2m( x 2 m + x m + 1) 2
f ( x) =
(d)
F(x) =
+C
+C
x 4m
2 m( x 2 m + x m + 1) 2
x
et
dt , x > 0
t
et
1 t + a dt
Put t + a = z t = z a; dt = dz
for t = 1, z = 1 + a
for t = x, z = x + a
x
Let I =
c
( 2, ) .
b
dx
(1 + x - m + x -2 m )3
dt
= ( x - m -1 + 2 x -2 m -1 ) dx
-m
2c 2 - b 2 > b 2 + c 2
c 2 > 2b 2
Volume of sphere V =
x - m -1 + 2 x -2 m -1
dx
2
2
2
and g(x) = -( x + c) + b + c
Now, fmin = 2c2 b2 and gmax = b2 + c2
Given : min f (x) > max g(x)
73. (c)
x 6 m (1 + x - m + x -2 m )3
dt
= - mx - m -1 - 2mx -2 m -1
dx
x5 m -1 + 2 x 4 m -1
|c|
c
> 2 > 2
|b|
b
dx
Put t = 1 + xm + x2m
|c| > | b | 2
( x 2 m + x m + 1)3
f (h)
0
lim
...(2)
h 0 h
(using sandwich Theorem)
\ from (1) and (2), we get f (0) = 0,
i.e. - f (x) is differentiable, at x = 0
Since, differentiability Continutity
\ | f (x) | x2, for all x R is continuous as well as
differentiable at x = 0.
We have
f (x) = x + 2bx + 2c
x 5m -1 + 2 x 4 m -1
f (h)
| h |
h
\I=
x+a
1+ a
-a
= e
x+a
1+ a
e z -a
dz
z
ez
x + a et
dz e - a
dt
1+ a
z
t
x + a et
et
-a 1
dt +
dt
I = e
1+ a t
1
t
1+ a et
x + a et
-a
dt +
dt
= e -
1
t
t
1
= e - a [ - F (1 + a) + F ( x + a)]
(By the definition of F(x))
= e - a [ F ( x + a) - F (1 + a)]
18
76.
(a)
...(1)
p
,y=1
4
Equation of tangent at P is
when x =
78. (d)
(a + 1)2 (a - 1)2
Centroid = 2 , 2
p
2 p
y 1 = sec x -
4
4
Y
y = 2x + 1
p
2
O
L
79. (b)
3(a + 1) 2 3( a - 1) 2
,
2
2
Now, these coordinates satisfies eqn given in option
(d)
Hence, required eqn of line is
(a 1)2 x (a + 1)2 y = 0
Let equation of line L, perpendicular to 5x y = 1 be
x + 5y = c
Coordinate of orthocentre =
y = tan x
p
or y = 2x + 1
2
Area of shaded region
= area of OPMO ar (DPLM)
HG
2
=
GO
1
Also,
p
P ,1
4
X
x + 5y = c
c
B 0,
5
...(2)
O (0, 0)
A(c, 0)
p
4
0
1 p p - 2
= [ log sec x ] - 1
24
4
=
77.
(c)
1
1
log 2 - sq unit
2
2
Let
area, A = [ x1( y2 - y3 ) + x2 ( y3 - y1 ) + x3 ( y1 - y2 ) ]
2
dy
+ y tan x = sin 2x
dx
I.F = e
= e
Required solution is
tan x dx
- log cos x
= sec x
y (sec x) =
sin 2 x sec x dx + c
y (sec x) =
5=
1 c
c
2 5
c
Q ( x1, y1 ) = (10,0), ( x3 , y3 ) = 0, 5
( x2 , y2 ) = (c, 0)
2sin x cos x
dx + c
cos x
c = 50
y (sec x) = 2 sin x dx + c
y (sec x) = 2cos x + c
Given y(0) = 1
\ put x = 0 and y = 1, we get
1 (sec 0) = 2 cos 0 + c
c=1+2c=3
\ from eqn (1), we have
y sec x = 2 cos x + 3
\ Equation of line L is x + 5y = 50
Distance between L and line x + 5y = 0 is
...(1)
d=
...(2)
80. (a)
50 - 0
12 + 52
50
=
26
5
13
Given circle is x2 + y2 16 = 0
19
Eqn of chord say AB of given circle is
3x + y + 5 = 0.
Equation of required circle is
4 2
c
5
Putting value of c from (2), we get
a2 + b2 =
x 2 + y 2 - 16 + l (3x + y + 5) = 0
2
x + y + (3l ) x + (l ) y + 5l - 16 = 0
...(1)
-3l -l
, .
Centre C =
2
2
b2 =
a2
9 2
4
a - a2 = a 2
5
5
5 a
5
, =
4 b
2
-3l -l
,
C
will lie on line AB.
2 2
-3l -l
i.e. 3
+ +5 = 0
2 2
Slope of chord,
82.
5
dy
a
5
= - = -
=m 2
b
2
dx
(a)
9l - l
+5=0l =1
2
Hence, required eqn of circle is
b2
ae,
a
b2
- ae,
a
x 2 + y 2 + 3x + y + 5 - 16 = 0
81. (a)
4 9 2
a
5 4
a2 + b2 =
x 2 + y 2 + 3x + y - 11 = 0
Equation of parabola, y2 = 6x
y2 = 4
(ae, 0)
3
x
2
3
\ Focus = , 0
2
e=
...(1)
3
a+c = 0
2
Here x1 = 3, y1 =
3
c= - a
2
...(2)
5
2
4+5 3
=
4
2
5
2
3x y
x
y
+
=1
=1
4 -2
4 2
3
4
3
y-intercept of the tangent, OB = 2
c
2
a + b2
16
20
-4 = 9
9
Let equation of the required line be
OA2 OB2 =
c2
5
= 2
4
a + b2
3
, y = 0 in eqn (1), we get
2
a (0) + b (0) + c
5
=
=
2
a2 + b2
a 2 + b2
3 5
5
L = 2 , = 3,
2 2
2
3
Since chord is passing through , 0
2
\ Put x =
x2 y 2
=1
4
5
a2 = 4, b2 = 5
Given
83.
(b)
x - x1
y - y1 z - z1
=
=
a
b
c
Given two lines
...(i)
20
x
y
z
=
=
1
-1 1
x -1
y +1 z
=
=
...(iii)
0
0
1
Since the line (i) is perpendicular to both the lines (ii)
and (iii), therefore
a b+c=0
...(iv)
2b + c = 0
...(v)
From (iv) and (v) c = 2b and a + b = 0, which are
not satisfy by options (c) and (d). Hence options (c)
and (d) are rejected.
Thus point (x1, y1, z1) on the required line will be
either (0, 0, 0) or (1, 1, 0).
Now foot of the perpendicular from point (0, 0, 0) to
the line (iii)
= (1, 2r 1, r)
and
85. (c)
-182
= 14
9 + 16 + 144
13
Now, magnitude of projection = 14.
Let A and E be any two events with positive
probabilities.
Consider statement-1 :
Eqn of plane is 2 x - y + l z + 4 = 0
Since, angle between the line and the plane is
therefore
p
2(1) + 2( -1) + 2( l )
=
6
1+ 4 + 4 4 +1+ l
1
2- 2+ 2 l
=
2
9 5+ l
r
Let xr = 3i - 6 j - k , y = i + 4 j - 3k and
r
z = 3i - 4 j - 12k
(1, 1 , 0)
sin
45
7
r r r
( x + y ).( z )
r r
Projection of x y on zr =
r
|z|
(iii)
(c)
3
l
9
=
4
5 + l 16
i j
k
r r
Now, x y = 3 -6 -1 = 22i + 8 j + 18k
1 4 -3
86. (a)
84.
5+ l
7l = 45 l =
(0, 0, 0)
(ii)
...(ii)
p
6
P(E A)
P(A)
...(1)
P(E A)
.P(E)
P(E)
= P(A E)
Clearly, from (1) and (2),
we have
...(2)
P(E/A) P(A E)
Thus, statement - 1 is true.
Similarly, statement-2 is also true.
87. (b)
x =
x1 + x2 + x3 + ... + xn
n
s2 =
1 n
( xi - x )2
n i =1
d1 + d 2 + d3 + .... + d n
n
( - x1 - a) + ( - x2 - a) + ( - x3 - a) + .... + (- xn - a)
n
x1 + x2 + x3 + .... + xn na
= -
- n
n
= -x - a
Since, di = xi a and we multiply or subtract each
21
observation by any number the mode remains the
same. Hence mode of xi a i.e. di and xi are same.
Now variance of d1, d2,...., dn
=
1 n
[di - ( - x - a)]2
n i =1
1 n
[ - xi - a + x + a]2
n i =1
1 n
( - xi + x ) 2
n i =1
Consider
43p
3p
tan -1 cot
= tan -1 cot 10 p +
4
p 3p
-1
= tan tan -
2 4
2p - 3p -p
p 3p
=
=
2 4
4
4
Given statement can be written in implication form as
I am not feeling well I will go to the doctor.
Contrapositive form :
I will not go to the doctor I am feeling well.
i.e. - If I will not go to the doctor, then I am feeling
well.
=
90.
(c)
3p
-1
= tan cot
4
1 n
2
= ( x - xi ) = s2
n i =1
88. (c)
89.
p
.
2
p
.
2
(c)