APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

SafetyDataSheet

Section1:IdentificationoftheSubstance/MixtureandoftheCompany/Undertaking

1.1Productidentifier

APPPolyesterFRSeries:APP180FR,APP180FRCOOL,APP
PremiumFR
1.2Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
ProductName

Relevantidentifieduse(s)

Construction

1.3Detailsofthesupplierofthesafetydatasheet
Manufacturer

FirestoneBuildingProductsCompany
250West96thStreet
Indianapolis,IN46260
UnitedStates

firestonemsds@bfdp.com
Telephone(General) 8004284442

1.4Emergencytelephonenumber
Manufacturer

(800)4249300CHEMTREC
(703)5273887CHEMTRECInternational

Manufacturer

Section2:HazardsIdentification
EU/EEC
Accordingto:Regulation(EC)No1272/2008(CLP)/REACH1907/2006[amendedby453/2010]
Accordingto:EUDirective67/548/EEC(DSD)or1999/45/EC(DPD)

2.1Classificationofthesubstanceormixture
CLP

SpecificTargetOrganToxicityRepeatedExposure1H372
Harmful(Xn)
R48/20

DSD/DPD

2.2LabelElements
CLP

DANGER

Hazardstatements H372Causesdamagetoorgansthroughprolongedorrepeatedexposure.
Precautionarystatements
Prevention P260Donotbreathedust,fume,gas,mist,vapoursand/orspray.
P264Washthoroughlyafterhandling.
P270Donoteat,drinkorsmokewhenusingthisproduct.
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

Response P314Getmedicaladvice/attentionifyoufeelunwell.
Storage/Disposal P501Disposeofcontentand/orcontainerinaccordancewithlocal,regional,
national,and/orinternationalregulations.
DSD/DPD

Riskphrases R48/20Harmful:dangerofseriousdamagetohealthbyprolongedexposurethrough
inhalation.

2.3OtherHazards
CLP

AccordingtoRegulation(EC)No.1272/2008(CLP)thismaterialisconsidered
hazardous.
AccordingtoEuropeanDirective1999/45/ECthismaterialisconsidereddangerous.

DSD/DPD

UnitedStates(US)
Accordingto:OSHA29CFR1910.1200HCS

2.1Classificationofthesubstanceormixture
OSHAHCS2012

SpecificTargetOrganToxicityRepeatedExposure1

2.2Labelelements
OSHAHCS2012

DANGER

Hazardstatements Causesdamagetoorgansthroughprolongedorrepeatedexposure.
Precautionarystatements
Prevention Donotbreathedust,fume,gas,mist,vapoursand/orspray.
Washthoroughlyafterhandling.
Donoteat,drinkorsmokewhenusingthisproduct.
Response Getmedicaladvice/attentionifyoufeelunwell.
Storage/Disposal Disposeofcontentand/orcontainerinaccordancewithlocal,regional,national,and/or
internationalregulations.

2.3Otherhazards
OSHAHCS2012

UnderUnitedStatesRegulations(29CFR1910.1200HazardCommunication
Standard),thisproductisconsideredhazardous.

Canada
Accordingto:WHMIS

2.1Classificationofthesubstanceormixture
WHMIS

OtherToxicEffectsD2B

2.2Labelelements
WHMIS

OtherToxicEffectsD2B
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2.3Otherhazards
WHMIS

InCanada,theproductmentionedaboveisconsideredhazardousunderthe
WorkplaceHazardousMaterialsInformationSystem(WHMIS).

Section3Composition/InformationonIngredients
3.1Substances

Materialdoesnotmeetthecriteriaofasubstance.

3.2Mixtures

Composition
Chemical
Name

Identifiers

%
40%TO
60%

LD50/LC50
Ingestion/OralRatLD50
>5000mg/kg
InhalationRatLC50>94.4
mg/m

Asphalt

CAS:8052424
EINECS:2324909

Colemanite

CAS:1318338

<30%

NDA

Limestone

CAS:1317653
ECNumber:215
2796

5%TO
25%

NDA

Quartz

CAS:14808607
ECNumber:238
8784

<10%

NDA

ClassificationsAccordingto
Regulation/Directive

Comments

EUDSD/DPD: XiR38
EUCLP: SkinIrrit2,H315
OSHAHCS2012: SkinIrrit2

NDA

EUDSD/DPD: NotClassified
EUCLP: NotClassified
OSHAHCS2012: NotClassified
EUDSD/DPD: XnR48/20
EUCLP: STOTRE1(Lung,Inhl),H372
OSHAHCS2012: STOTRE1(Lungs,
Inhl)
EUDSD/DPD: NotClassified
EUCLP: NotClassified
OSHAHCS2012: NotClassified

NDA

NDA

NDA

SeeSection16forfulltextofHstatementsandRphrases.

Section4FirstAidMeasures
4.1Descriptionoffirstaidmeasures
Inhalation
Skin
Eye
Ingestion

Removetofreshair,applyartificialrespirationand/oroxygenifnecessaryandget
medicalattention.
Removecontaminatedclothingandwashexposedskinwithsoapandwater.If
irritationdevelopsorpersists,seekmedicalattention.
Ifforeignmatterenterseyes,immediatelyflushwithlargeamountsofwaterforatleast
15minutesoruntilirritationsubsides.Ifirritationdevelops,orpersists,seekmedical
attention.
Consultaphysicianifunusualreactionisnoted.Productisnotintendednorisitlikely
tobeingestedoreaten.

4.2Mostimportantsymptomsandeffects,bothacuteanddelayed
RefertoSection11ToxicologicalInformation.

4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded
NotestoPhysician
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressinthe
patient.Considerationshouldbegiventothepossibilitythatoverexposuretomaterials
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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

otherthanthisproductmayhaveoccurred.

Section5FirefightingMeasures
5.1Extinguishingmedia
SuitableExtinguishingMedia Usewater,foam,CO2ordrychemicalextinguisherstocontainfire.
UnsuitableExtinguishing
Nodataavailable.
Media
FirefightingProcedures
Firefightersshouldavoidinhalinganycombustionproducts.

5.2Specialhazardsarisingfromthesubstanceormixture
UnusualFireandExplosion
Hazards
HazardousCombustion
Products

Burningofthisproductwillproducethickblacksmoke.
Carbondioxide,carbonmonoxideandpartiallyburnedcarbon.

5.3Adviceforfirefighters
Firefightersshouldwearfullface,selfcontainedbreathingapparatusandimpervious
protectiveclothingtoavoidsmokeinhalationandlackofoxygen.

Section6AccidentalReleaseMeasures
6.1Personalprecautions,protectiveequipmentandemergencyprocedures
PersonalPrecautions
EmergencyProcedures

Nospecialprecautionsexpectedtobenecessaryifmaterialisusedunderordinary
conditionsandasrecommended.

Noemergencyproceduresareexpectedtobenecessaryifmaterialisusedunder
ordinaryconditionsasrecommended.

6.2Environmentalprecautions
Avoidrunofftowaterwaysandsewers.

6.3Methodsandmaterialforcontainmentandcleaningup
Containment/Cleanup
Measures

Pickuplargepieces.Vacuumdust.Ifsweepingisnecessary,useadustsuppressant
suchaswater.Theseprocedureswillhelptominimizepotentialexposures.Scoopup
materialandputintoasuitablecontainerfordisposalasanonhazardouswaste.

6.4Referencetoothersections
RefertoSection8ExposureControls/PersonalProtectionandSection13Disposal
Considerations.

Section7HandlingandStorage
7.1Precautionsforsafehandling
Handling

Avoidbreathingdustsorfumesgeneratedfromcuttingorheatingthismaterial.Use
thisproductwithadequateventilation.Alwayswashworkclothesseparatelyfrom
otherclothing.Washthoroughlyafterhandling.Usepersonalprotectiveequipmentas
describedinSection8.

7.2Conditionsforsafestorage,includinganyincompatibilities
Storage

Storeindoorsinacool,dry,wellventilatedarea.Donothandleorstorenearanopen
flame,heatorothersourcesofignition.
SpecialPackagingMaterials Nodataavailable.
IncompatibleMaterialsor
Thisproductwillreactwithstrongoxidizingagents,reducingagents,strongacidsand
IgnitionSources
alkalis.

7.3Specificenduse(s)
Preparation Date: 03/January/2012
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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

RefertoSection1.2Relevantidentifieduses.

Section8ExposureControls/PersonalProtection
8.1Controlparameters
ExposureLimits/Guidelines
Result

Limestone
(1317653)

Quartz
(14808607)

Asphalt
(8052424)

CanadaAlberta

CanadaBritish
Columbia

Australia

Belgium

Notestablished

Notestablished

10mg/m3TWA

10mg/m3TWA

10mg/m3TWA(total
dust)3mg/m3TWA
(respirablefraction)

STELs Notestablished

Notestablished

Notestablished

Notestablished

20mg/m3STEL(total
dust)

0.1mg/m3TWA
(respirabledust)

0.1mg/m3TWA
(alveolardust)

0.025mg/m3TWA
(respirable
particulate)

0.025mg/m3TWA
(respirable)

TWAs

ACGIH

TWAs

0.025mg/m3TWA
(respirablefraction)

TWAs

0.5mg/m3TWA
5mg/m3TWA
(fume,inhalable
5mg/m3TWA(fume) 5mg/m3TWA(fume) (PetroleumBitumen,
fraction,asbenzene
fume)
solubleaerosol)

0.5mg/m3TWA
(inhalablefume,as
Benzenesoluble
aerosol)

ExposureLimits/Guidelines(Con't.)
Result

Limestone
(1317653)

Quartz
(14808607)

Asphalt
(8052424)

CanadaManitoba

CanadaNew
Brunswick

TWAs

Notestablished

10mg/m3TWA
(particulatematter
containingno
Asbestosand<1%
Crystallinesilica)

TWAs

0.025mg/m3TWA
(respirablefraction)

0.1mg/m3TWA
(respirablefraction)

TWAs

0.5mg/m3TWA
(fume,inhalable
5mg/m3TWA
fraction,asBenzene (petroleumfumes)
solubleaerosol)

STELs Notestablished

Notestablished

CanadaNorthwest
Territories

CanadaNova
Scotia

CanadaNunavut

5mg/m3TWA
(respirablemass)10
Notestablished
mg/m3TWA(total
mass)

5mg/m3TWA
(respirablemass)10
mg/m3TWA(total
mass)

0.1mg/m3TWA
(respirablemass)
0.025mg/m3TWA
0.3mg/m3TWA(total (respirablefraction)
mass)

0.1mg/m3TWA
(respirablemass)
0.3mg/m3TWA(total
mass)

5mg/m3TWA
(Petroleumfumes)

0.5mg/m3TWA
(fume,inhalable
5mg/m3TWA
fraction,asBenzene (Petroleumfumes)
solubleaerosol)

10mg/m3STEL
(Petroleumfumes)

Notestablished

10mg/m3STEL
(Petroleumfumes)

ExposureLimits/Guidelines(Con't.)
Result

CanadaOntario

Canada
Saskatchewan

CanadaQuebec

STELs Notestablished

Notestablished

TWAs

10mg/m3TWAEV
(Limestone,
containingno
10mg/m3TWA
Asbestosand<1%
Crystallinesilica,total
dust)

Limestone
(1317653)
Notestablished

Notestablished

CanadaYukon

China

20mg/m3STEL

16mg/m3STEL(total
dust)8mg/m3STEL
(respirabledust)

30mppcfTWA10
mg/m3TWA

8mg/m3TWA(total
dust)4mg/m3TWA
(respirabledust)

2mg/m3STEL
(containing1050%
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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

STELs Notestablished

Notestablished

Notestablished

Notestablished

0.05mg/m3TWA
(respirablefraction,
listedunderSilica
crystalline)

0.7mg/m3TWA
(containing5080%
freeSiO2,totaldust)
0.3mg/m3TWA
(containing5080%
freeSiO2,respirable
dust)1mg/m3TWA
(containing1050%
freeSiO2,totaldust)
300particle/mLTWA
0.7mg/m3TWA
(listedunderSilica)
(containing1050%
freeSiO2,respirable
dust)0.5mg/m3
TWA(containing
>80%freeSiO2,total
dust)0.2mg/m3
TWA(containing
>80%freeSiO2,
respirabledust)

Notestablished

Notestablished

10mg/m3STEL
(fume)

5mg/m3TWAEV
(fume)

0.5mg/m3TWA(fume
5mg/m3TWA(fume,
andinhalablefraction,
5mg/m3TWA(fume) asBenzenesoluble
asBenzenesoluble
matter)
aerosol)

Quartz
(14808607)

TWAs

0.10mg/m3TWA
(designated
substances
0.1mg/m3TWAEV
regulation,respirable, (respirabledust)
listedunderSilica,
crystalline)

STELs Notestablished
Asphalt
(8052424)
TWAs

0.5mg/m3TWA
(fume,inhalable,as
Benzenesoluble
aerosol)

freeSiO2,totaldust)
1.4mg/m3STEL
(containing5080%
freeSiO2,totaldust)
1mg/m3STEL
(containing>80%
freeSiO2,totaldust)
1.4mg/m3STEL
(containing1050%
freeSiO2,respirable
dust)0.6mg/m3
STEL(containing50
80%freeSiO2,
respirabledust)0.4
mg/m3STEL
(containing>80%
freeSiO2,respirable
dust)

12.5mg/m3STEL
(fume,asBenzene
solublematter)

ExposureLimits/Guidelines(Con't.)
Result

Denmark

NIOSH

OSHA

Limestone
(1317653)

TWAs

Notestablished

10mg/m3TWA(total
dust)5mg/m3TWA
(respirabledust)

15mg/m3TWA(total
dust)5mg/m3TWA
(respirablefraction)

Quartz
(14808607)

TWAs

0.3mg/m3TWA(total)
0.1mg/m3TWA
(respirable)

0.05mg/m3TWA
(respirabledust)

Notestablished

TWAs

1mg/m3TWA
(Cyclohexanefraction
oftotaldust,fume)

Notestablished

Notestablished

Ceilings

Notestablished

5mg/m3Ceiling(fume,
15min)

Notestablished

Asphalt
(8052424)

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

ExposureControlNotations
CanadaOntario
Quartz(14808607):DesignatedSubstances:(0.10mg/m3TWA(respirablefraction,listedunderSilica,crystalline))
CanadaQuebec
Quartz(14808607):Carcinogens:(C2carcinogeneffectsuspectedinhumans)
ACGIH
Asphalt(8052424):Carcinogens:(A4NotClassifiableasaHumanCarcinogen(fume,coaltarfree))
Quartz(14808607):Carcinogens:(A2SuspectedHumanCarcinogen)
GermanyDFG
Asphalt(8052424):Carcinogens:(Category2(consideredtobecarcinogenicforman,aerosolandvapour))|Skin:(skinnotation(aerosol
andvapour))
Quartz(14808607):Carcinogens:(Category1(causescancerinman,alveolafraction))

ExposureLimitsSupplemental
OSHA
Quartz(14808607):MineralDusts:((30)/(%SiO2+2)mg/m3TWA,totaldust(250)/(%SiO2+5)mppcfTWA,respirablefraction(10)/(%SiO2
+2)mg/m3TWA,respirablefraction)
ACGIH
Asphalt(8052424):BEIs:(Medium:urineTime:endofshiftatendofworkweekParameter:1Hydroxypyrenewithhydrolysis(nonquantitative))|
TLVBasisCriticalEffects:(eyeandupperrespiratorytractirritation(fume))
Quartz(14808607):TLVBasisCriticalEffects:(lungcancerpulmonaryfibrosis)

8.2Exposurecontrols
Engineering
Measures/Controls

Thismaterialisdesignedtobeusedoutdoors,inroofingapplications.Goodgeneral
ventilationshouldsuffice.Adequateventilationsystemsasneededtocontrol
concentrationsofairbornecontaminantsbelowapplicablethresholdlimitvalues.
PersonalProtectiveEquipment
Respiratory
Respiratoryprotectionisnotnormallyrequired.UseaNIOSHcertifiedrespiratorwhen
theexposurelimitsareexceeded.Useaparticulatefilterrespiratorforparticulate
concentrationsexceedingtheOccupationalExposureLimit.
Eye/Face
Safetyglasseswithsideshieldsshouldbewornataminimum.
Hands
Skin/Body
GeneralIndustrialHygiene
Considerations
EnvironmentalExposure
Controls

Leatherorcottonglovesmaybeworntopreventskincontactandirritation.
Normalworkclothing(longsleevedshirtsandlongpants)isrecommended.
Usegoodindustrialhygienepracticesinhandlingthismaterial.
Followbestpracticeforsitemanagementanddisposalofwaste.

Keytoabbreviations
AmericanConferenceofGovernmental
ACGIH =
IndustrialHygiene
BEI

= BiologicalExposureIndices

NationalInstituteofOccupationalSafety
andHealth
OccupationalSafetyandHealth
OSHA =
Administration
NIOSH =

STEL

= ShortTermExposureLimitsarebasedon15minuteexposures

TLV

TWA

= TimeWeightedAveragesarebasedon8h/day,40h/weekexposures

ThresholdLimitValuedeterminedbytheAmericanConferenceofGovernmental
IndustrialHygienists(ACGIH)

TWAEV = TimeWeightedAverageExposureValue

Section9PhysicalandChemicalProperties
9.1InformationonPhysicalandChemicalProperties
MaterialDescription
Polyesterreinforced,fireretardant
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

polymermodifiedasphalticmaterial
withsand,ceramicgranulesand/or
plasticfilmcoveredsurfacesand
anasphaltodor.Availablein
variouscolors.

PhysicalForm

Solid

Appearance/Description

Color

Variouscolors.

Odor

OdorThreshold

Datalacking

BoilingPoint

Datalacking

MeltingPoint/FreezingPoint

290F(143.3333C)

DecompositionTemperature

Datalacking

pH

Datalacking

SpecificGravity/RelativeDensity

=1.05Water=1

WaterSolubility

Insoluble

Viscosity

Datalacking

ExplosiveProperties

Datalacking

OxidizingProperties:

Datalacking

VaporPressure

Datalacking

VaporDensity

EvaporationRate

Datalacking

FlashPoint

>432F(>222.2222C)COC
(ClevelandOpenCup)

UEL

Datalacking

LEL

Datalacking

Autoignition

Datalacking

Flammability(solid,gas)

Datalacking

Octanol/WaterPartitioncoefficient Datalacking

Slightasphaltodor.

GeneralProperties

Volatility
Datalacking

Flammability

Environmental

9.2OtherInformation
Noadditionalphysicalandchemicalparametersnoted.

Section10:StabilityandReactivity
10.1Reactivity
Nodangerousreactionknownunderconditionsofnormaluse.

10.2Chemicalstability
Stableundernormalconditionsofuse.

10.3Possibilityofhazardousreactions
Hazardouspolymerizationwillnotoccur.

10.4Conditionstoavoid
Incompatiblematerials.

10.5Incompatiblematerials
Thisproductwillreactwithstrongoxidizingagents,reducingagents,strongacidsand
alkalis.

10.6Hazardousdecompositionproducts
Burningwillproducesmoke,carbonmonoxide,andcarbondioxide.

Section11ToxicologicalInformation
11.1Informationontoxicologicaleffects

Preparation Date: 03/January/2012

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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

Components
Asphalt(40% 8052
TO60%)
424

AcuteToxicity: Ingestion/OralRatLD50>5000mg/kgGastrointestinal:Hypermotility,diarrhea
Mutagen: MicronucleustestUnreportedRouteRatOtherCellType57.8g/L
Tumorigen/Carcinogen: SkinMouseTDLo905g/kg2Year(s)IntermittentTumorigenic:NeoplasticbyRTECS
criteriaLungs,Thorax,orRespiration:TumorsSkinandAppendages:Other:Tumors

Limestone
1317
(5%TO25%) 653

MultidoseToxicity: InhalationRatTCLo84mg/m4Hour(s)40Week(s)IntermittentLungs,Thorax,or
Respiration:Fibrosis(interstitial)Liver:OtherchangesKidney,Ureter,andBladder:Otherchanges InhalationRat
TCLo250mg/m2Hour(s)24Week(s)IntermittentLungs,Thorax,orRespiration:Fibrosis,focal
(pneumoconiosis)

Quartz(<
10%)

AcuteToxicity: InhalationRatTCLo1mg/kgLungs,Thorax,orRespiration:Otherchanges
Biochemical:Metabolism(intermediary):Effectoninflammationormediationofinflammation
Mutagen: MicronucleustestUnreportedRouteHamsterLung(Somaticcell)160g/cm
Tumorigen/Carcinogen: InhalationRatTCLo50mg/m6Hour(s)71Week(s)Intermittent
Tumorigenic:CarcinogenicbyRTECScriteriaLiver:Tumors

14808
607

GHSProperties

Classification

Respiratorysensitization

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Seriouseyedamage/Irritation

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Acutetoxicity

EU/CLP Datalacking
OSHAHCS2012 Datalacking

AspirationHazard

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Carcinogenicity

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Skincorrosion/Irritation

EU/CLP Datalacking
OSHAHCS2012 Datalacking

Skinsensitization

EU/CLP Datalacking
OSHAHCS2012 Datalacking

STOTRE

EU/CLP SpecificTargetOrganToxicityRepeatedExposure1
OSHAHCS2012 SpecificTargetOrganToxicityRepeatedExposure1

STOTSE

EU/CLP Datalacking
OSHAHCS2012 Datalacking

ToxicityforReproduction

EU/CLP Datalacking
OSHAHCS2012 Datalacking

GermCellMutagenicity

EU/CLP Datalacking
OSHAHCS2012 Datalacking

PotentialHealthEffects
Inhalation
Acute(Immediate)
Chronic(Delayed)

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

Temporaryirritationofnoseandthroatmayoccur.
ThisproductcontainscrystallinesilicawhichislistedbyIARCasasuspect
carcinogen.Silicosis(pulmonaryfibrosisorseverelungscarring)mayoccurif
exposedtohighlevelsorrepeatedencounterswithdust.Exposuretoairborne
particlesthatexceedthelimitslistedmaycauselungcancer.Thisproductalso
containspetroleumasphalt.Ifheated,thereislimitedevidencethatderivativesof
asphaltfumesmaycausecarcinogeniceffectsinanimals.Thereisinadequate
evidencetosupportthatasphaltfumesalonearecarcinogenictohumans.

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Skin
Acute(Immediate)

Mechanicalirritationoftheskin/skinabrasionmayoccurcharacterizedbyitchingor
redness.
Nodataavailable

Chronic(Delayed)

Eye
Acute(Immediate)

Mechanicalirritationoftheeyemayoccurcharacterizedbyitchingorredness.
Nodataavailable.

Chronic(Delayed)

Ingestion
Acute(Immediate)

Ingestionofthisproductunlikely.
Nodataavailable.

Chronic(Delayed)
CarcinogenicEffects

Whenusedundernormalconditions,thisproductisnotconsideredacarcinogen.
BaseduponthenewlypublishedIARCclassificationsforbitumen/asphaltfumes,it
hasbeendeterminedthattheIARCcarcinogendesignationdoesnotapplytothis
materialasitdoesnotcontainmaterialidentifiedbyIARC.Thisproductcontains
crystallinesilica.IARCMonographsonEvaluationofCarcinogenicRiskofChemicals
toHumans(Monograph68,1997)concludesthatthereissufficientevidenceforthe
carcinogenicityofcrystallinesilicatohumans,IARC(GroupI).CrystallineSilicais
classifiedasaKnownCarcinogenaccordingtotheNTP.
CarcinogenicEffects
CAS

Quartz

IARC

14808607

Group1Carcinogenic

NTP
KnownHumanCarcinogen

Keytoabbreviations
LD = LethalDose
TC = ToxicConcentration
TD = ToxicDose

Section12EcologicalInformation
12.1Toxicity
Noinformationavailablefortheproduct.

12.2Persistenceanddegradability
Noinformationavailablefortheproduct.

12.3Bioaccumulativepotential
Noinformationavailablefortheproduct.

12.4MobilityinSoil
Noinformationavailablefortheproduct.

12.5ResultsofPBTandvPvBassessment
NoPBTandvPvBassessmenthasbeenconducted.

12.6Otheradverseeffects
EcologicalFate

Noinformationavailablefortheproduct.

12.7OtherInformation
Thisproducthasnotbeentested.Basedoninformationrelatedtoallrawmaterialsin
thefinishedproductitisnotexpectedtoharmecosystemsthroughitsapplieduse.

Section13DisposalConsiderations
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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13.1Wastetreatmentmethods
Productwaste

Disposeofcontentand/orcontainerinaccordancewithlocal,regional,national,and/or
internationalregulations.
Disposeofcontentand/orcontainerinaccordancewithlocal,regional,national,and/or
internationalregulations.

Packagingwaste

Section14TransportInformation

14.1UN
number

14.2UNproper
shippingname

14.3Transporthazard
class(es)

14.4Packing
group

14.5Environmental
hazards

DOT

NDA

NotRegulated

NDA

NDA

NDA

TDG

NDA

NotRegulated

NDA

NDA

NDA

IMO/IMDG

NDA

NotRegulated

NDA

NDA

NDA

ADN

NDA

NotRegulated

NDA

NDA

NDA

ADR/RID

NDA

NotRegulated

NDA

NDA

NDA

IATA/ICAO

NDA

NotRegulated

NDA

NDA

NDA

14.6Specialprecautionsfor Nonespecified.
user
14.7Transportinbulk
Datalacking.
accordingtoAnnexIIof
MARPOL73/78andtheIBC
Code

Section15RegulatoryInformation
15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceor
mixture
SARAHazardClassifications Chronic
StateRightToKnow
MA

NJ

PA

Asphalt

Component

8052424

CAS

Yes

Yes

Yes

Colemanite

1318338

No

No

No

Limestone

1317653

Yes

Yes

Yes

Quartz

14808607

Yes

Yes

Yes

Inventory
Component

CAS

CanadaDSL

CanadaNDSL

China

EUEINECS

EUELNICS

Asphalt

8052424

Yes

No

Yes

Yes

No

Colemanite

1318338

No

No

No

No

No

Limestone

1317653

No

Yes

Yes

Yes

No

Quartz

14808607

Yes

No

Yes

Yes

No

Inventory(Con't.)
Component

CAS

Asphalt

8052424

Colemanite

1318338

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

JapanENCS

KoreaKECL

TSCA

Yes

Yes

Yes

No

Page 11 of 19

No

No
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Limestone

1317653

Yes

Yes

Yes

Quartz

14808607

Yes

Yes

Yes

Australia
Labor

AustraliaWorkHealthandSafetyRegulationsHazardousSubstancesRequiringHealthMonitoring

Asphalt
8052424
NotListed
Limestone
1317653
NotListed
Demographic,medicaland
occupationalhistoryRecords
ofpersonalexposure
Standardisedrespiratory
Quartz
14808607 questionnairetobecompleted
Standardisedrespiratory
functiontest,forexample,
FEV1,FVCandFEV1/FVC
ChestXrayfullsizePAview
Colemanite
1318338
NotListed

AustraliaHighVolumeIndustrialChemicalsList

Asphalt
8052424
Limestone
1317653
NotListed
Quartz
14808607
Colemanite
1318338
NotListed

AustraliaListofDesignatedHazardousSubstancesClassification

Selfclassificationrequired
Asphalt
8052424
(petroleumfumes)
Limestone
1317653
NotListed
Quartz
14808607 Selfclassificationrequired
Colemanite
1318338
NotListed

Environment
AustraliaNationalPollutantInventory(NPI)SubstanceList
Asphalt
Limestone
Quartz
Colemanite

AustraliaOzoneProtectionActScheduledSubstances
Asphalt
Limestone
Quartz
Colemanite

AustraliaPriorityExistingChemicalProgram
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

Belgium
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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Labor
BelgiumSubstancesandPreparationsCarcinogensandMutagens
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

Bulgaria
Environment
BulgariaAirQualityMaximumAdmissibleHazardousContaminantLevels24Hour
Asphalt
8052424
Limestone
1317653
Quartz
14808607
Colemanite
1318338

BulgariaAirQualityMaximumAdmissibleHazardousContaminantLevels30Minute
Asphalt
8052424
Limestone
1317653
Quartz
14808607
Colemanite
1318338

BulgariaAirQualityMaximumAdmissibleHazardousContaminantLevelsAnnual
Asphalt
8052424
Limestone
1317653
Quartz
14808607
Colemanite
1318338

NotListed
NotListed
NotListed
NotListed

NotListed
NotListed
NotListed
NotListed

NotListed
NotListed
NotListed
NotListed

Canada
Labor

CanadaWHMISClassificationsofSubstances
Asphalt
Limestone

8052424
1317653

Quartz

14808607

Colemanite

CanadaWHMISIngredientDisclosureList
Asphalt
Limestone
Quartz
Colemanite

1318338

NotListed
D2A
D2A(Incertaincases,this
classificationdoesnotapply.
Formoreinformation,consult
thesectionSubstanceSpecific
IssuesSilica,crystalline,
encapsulatedonHealth
Canada'sWHMISDivision
website.)
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
1%
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

Environment

CanadaCEPAPrioritySubstancesList
Asphalt
Limestone
Quartz
Colemanite
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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China
Other

ChinaAnnexI&IIControlledChemicalsLists
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

Denmark
Environment
DenmarkListofUndesirableSubstancesProductGroups/Function
Asphalt
Limestone
Quartz
Colemanite

Europe
Other
EUCLP(1272/2008)AnnexVITable3.2Classification
Asphalt
Limestone
Quartz
Colemanite

EUCLP(1272/2008)AnnexVITable3.2ConcentrationLimits
Asphalt
Limestone
Quartz
Colemanite

EUCLP(1272/2008)AnnexVITable3.2Labelling
Asphalt
Limestone
Quartz
Colemanite

EUCLP(1272/2008)AnnexVITable3.2NotesSubstancesandPreparations
Asphalt
Limestone
Quartz
Colemanite

EUCLP(1272/2008)AnnexVITable3.2SafetyPhrases
Asphalt
Limestone
Quartz
Colemanite

Germany
Labor
GermanyImmissionControlQualifyingQuantitiesforMajorAccidentPrevention
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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Asphalt
Limestone
Quartz
Colemanite

GermanyImmissionControlQualifyingQuantitiesforSafetyReporting
Asphalt
Limestone
Quartz
Colemanite

GermanyTRGS505SpecificLeadRegulations
Asphalt
Limestone
Quartz
Colemanite

GermanyTRGS511SpecificAmmoniumNitrateRegulations
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

Environment
GermanyTALuftTypesandClasses
Asphalt
Limestone
Quartz
Colemanite

GermanyTALuftEmissionLimitsforCarcinogenicSubstances
Asphalt
Limestone
Quartz
Colemanite

GermanyTALuftEmissionLimitsforFibers
Asphalt
Limestone
Quartz
Colemanite

GermanyTALuftEmissionLimitsforInorganicDusts
Asphalt
Limestone
Quartz
Colemanite

GermanyTALuftEmissionLimitsforInorganicGases
Asphalt
Limestone
Quartz
Colemanite

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

Page 15 of 19

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GermanyTALuftEmissionLimitsforOrganicSubstances
Asphalt
Limestone
Quartz
Colemanite

GermanyWaterClassification(VwVwS)Annex1

8052424
1317653
14808607
1318338

1318338

IDNumber326,notconsidered
hazardoustowater
IDNumber317,notconsidered
hazardoustowater
IDNumber849,notconsidered
hazardoustowater
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653

Asphalt

8052424

Limestone

1317653

Quartz

14808607

Colemanite

GermanyWaterClassification(VwVwS)Annex2WaterHazardClasses
Asphalt
Limestone
Quartz
Colemanite

GermanyWaterClassification(VwVwS)Annex3
Asphalt
Limestone

NotListed
NotListed
NotListed
NotListed

Quartz

14808607

Colemanite

1318338

NotListed
NotListed
IDNumber849,notconsidered
hazardoustowater
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

UnitedStates
Labor
U.S.OSHAProcessSafetyManagementHighlyHazardousChemicals
Asphalt
Limestone
Quartz
Colemanite

U.S.OSHASpecificallyRegulatedChemicals
Asphalt
Limestone
Quartz
Colemanite

Environment
U.S.CAA(CleanAirAct)1990HazardousAirPollutants
Asphalt
Limestone
Quartz
Colemanite

U.S.CERCLA/SARAHazardousSubstancesandtheirReportableQuantities
Asphalt
Limestone
Quartz
Colemanite

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

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U.S.CERCLA/SARARadionuclidesandTheirReportableQuantities
Asphalt
Limestone
Quartz
Colemanite

U.S.CERCLA/SARASection302ExtremelyHazardousSubstancesEPCRARQs
Asphalt
Limestone
Quartz
Colemanite

U.S.CERCLA/SARASection302ExtremelyHazardousSubstancesTPQs
Asphalt
Limestone
Quartz
Colemanite

U.S.CERCLA/SARASection313EmissionReporting
Asphalt
Limestone
Quartz
Colemanite

U.S.CERCLA/SARASection313PBTChemicalListing
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

U.S.CaliforniaProposition65CarcinogensList
Asphalt
Limestone

8052424
1317653

Quartz

14808607
1318338

NotListed
NotListed
carcinogen,initialdate10/1/88
(airborneparticlesof
respirablesize)
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

UnitedStatesCalifornia
Environment

Colemanite

U.S.CaliforniaProposition65DevelopmentalToxicity
Asphalt
Limestone
Quartz
Colemanite

U.S.CaliforniaProposition65MaximumAllowableDoseLevels(MADL)
Asphalt
Limestone
Quartz
Colemanite

U.S.CaliforniaProposition65NoSignificantRiskLevels(NSRL)
Preparation Date: 03/January/2012
Revision Date: 10/August/2015

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APP Polyester FR Series: APP 180 FR, APP 180 FR COOL, APP Premium FR

Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

U.S.CaliforniaProposition65ReproductiveToxicityFemale
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

U.S.CaliforniaProposition65ReproductiveToxicityMale
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

U.S.PennsylvaniaRTK(RighttoKnow)EnvironmentalHazardList
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

U.S.PennsylvaniaRTK(RighttoKnow)SpecialHazardousSubstances
Asphalt
Limestone
Quartz
Colemanite

8052424
1317653
14808607
1318338

NotListed
NotListed
NotListed
NotListed

UnitedStatesPennsylvania
Labor

15.2ChemicalSafetyAssessment
NoChemicalSafetyAssessmenthasbeencarriedout.

15.3OtherInformation
WARNING:ThisproductcontainsachemicalknowntotheStateofCaliforniato
causecancer.

Section16OtherInformation
RelevantPhrases(code&fulltext)
H315Causesskinirritation

R38Irritatingtoskin.
RevisionDate
PreparationDate
Disclaimer/Statementof
Liability

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

10/August/2015
03/January/2012
Theinformationcontainedhereinisbasedondataconsideredaccuratewhichhas
beenobtainedfromothercompaniesandorganizations.However,nowarrantyor
representationisexpressedorimpliedthattheinformation,isaccurate,completeor
representative.FirestoneBuildingProductsCompany,LLCassumesnoresponsibility
forinjurytothebuyer,thebuyer'semployees,oranythirdpersons,ifreasonable
safetyproceduresarenotfollowed.Additionally,FirestoneBuildingProducts

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Company,LLCassumesnoresponsibilityforinjurytobuyer,thebuyer'semployees,
oranythirdpersonscausedbyabnormaluseofthismaterial,evenifreasonable
safetyproceduresarefollowed.
Keytoabbreviations
NDA = NoDataAvailable

Preparation Date: 03/January/2012

Revision Date: 10/August/2015

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WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012