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MEETING TOMORROWS
dEMANdS TOdAy
VAE-based Emulsions for the Indian paints and Coatings Market
VAE EMULSIONS
Wacker Chemie AG
O
O
H 3C
O
O
O
O
CH 3
Fig. 1: Vinyl acetate-ethylene copolymer structure
CH 3
VAE EMULSIONS
reducing the overall formulated cost of
the paint.
Further, VAE emulsions feature high
binding power and good rheological
behavior as well as excellent
applicability and workability. For this
reason, VAE emulsions are able to fulfill
higher application and performance
demands.
Improved performance
In paints and coatings, VAE emulsions
serve as binders: They impart adhesion,
cohesion, and enhance important
VAE EMULSIONS
grade vinyl acrylic (VA/BA) system, each
monomer seeks to react with "itself,"
creating a "blockier" copolymer with
long chains of both vinyl acetate and
butyl acrylate. This phenomenon makes
vinyl acrylics more susceptible to
hydrolysis, or "unzipping," in the
presence of an alkaline solution.
In a structural comparison of VAE
copolymers to VA/BA copolymers,
ethylene is incorporated into the
polymer backbone and provides main
chain flexibility (Fig. 4). This is
advantageous for VAE copolymers
because it allows the polymer chains to
be more flexible, making it easier for
them to entangle and coalesce. Butyl
acrylate, on the other hand, is attached to
the polymer backbone as a pendant
group, which makes the chain less
flexible, hindering entanglement and
coalescence.
VAE copolymers exhibit inherently
good coalescing properties (Fig. 5). The
graph clearly illustrates the inherently
better coalescing properties of VAEbased emulsions compared to styreneacrylic (SA) emulsions. That's one reason
these dispersions are becoming the
industry standard in low-odor interior
paints - minimizing coalescing solvents
for reduced odor and lower formulation
cost. VAE copolymers also offer
improved coalescence at low
temperatures. This provides better lowtemperature touch-up properties, a factor
critical to the contractor paint market.
Conclusion
www.wacker.com/vinnapas
The data presented in this information sheet are in accordance with the present state of our knowledge but do not absolve the user from carefully checking all supplies
immediately on receipt. We reserve the right to alter product constants within the scope of technical progress or new developments. The recommendations made in this
information sheet should be checked by preliminary trials because of conditions during processing over which we have no control, especially where other companies raw
materials are also being used. The information provided by us does not absolve the user from the obligation of investigating the possibility of infringement of third parties
rights and, if necessary, clarifying the position. Recommendations for use do not constitute a warranty, either express or implied, of the fitness or suitability of the product
for a particular purpose.
6972e/01.13