Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
(Continued)
1.313
1.314
TABLE 1.67 Solubility of Gases in Water (Continued)
1.315
1.316
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures
Solubilities are expressed as the number of grams of substance of stated molecular formula which when dissolved in 100 g of water make a saturated solution
at the temperature stated (C).
(Continued)
1.317
1.318
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures (Continued)
(Continued)
1.319
1.320
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures (Continued)
(Continued)
1.321
1.322
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures (Continued)
(Continued)
1.323
1.324
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures (Continued)
Substance
(Continued)
1.325
1.326
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures (Continued)
Substance
(Continued)
1.327
1.328
TABLE 1.68 Solubility of Inorganic Compounds and Metal Salts of Organic Acids in Water at Various Temperatures (Continued)
Substance
1.329
1.330
SECTION ONE
Formula
[Al(H2O)6]3+
NH4+
H3AsO3
H3AsO4
H3BO3
HOBr
H2CO3
Chloric(I) acid
Chloric(III) acid
Chromium(III) ion (hydrated)
Hydrazinium ion
Hydrocyanic acid
Hydrofluoric acid
Hydrogen peroxide
Hydrogen sulphide
HOCl
HClO2
[Cr(H2O)6]3+
N2H5+
HCN
HF
H2O2
H2S
+
Hydroxyammonium ion
Iodic(I) acid
Iodic(V) acid
Iron(III) ion (hydrated)
Lead(II) ion (hydrated)
Nitrous acid
Phosphinic acid
Phosphoric(V) acid
NH3OH
HOI
HIO3
[Fe(H2O)6]3+
[Pb(H2O)n]2+
HNO2
H3PO2
H3PO4
Phosphonic acid
H3PO3
Silicic acid
H2SiO3
Sulphuric acid
Sulphurous acid
H2SO4
H2SO3
pKa
4.9 (pK1)
9.25
9.22 (pK1)
2.30 (pK1)
9.24 (pK1)
8.70
6.38a (pK1)
10.32 (pK2)
7.43
2.0
3.9 (pK1)
7.93
9.40
3.25
11.62 (pK1)
7.05 (pK1)
12.92 (pK2)
5.82
10.52
0.8
2.22 (pK1)
7.8 (pK1)
3.34
2.0
2.15 (pK1)
7.21 (pK2)
12.36 (pK3)
2.00 (pK1)
6.58 (pK2)
9.9 (pK1)
11.9 (pK2)
1.92 (pK2)
1.92 (pK1)
7.21 (pK2)
{
{
{
a
Some of the unionized acid exists as dissolved CO2 molecules rather than H2CO3: pK1 for
the molecular species H2CO3 is approximately 3.7.
1.331
INORGANIC CHEMISTRY
Formula
pKsp
Ksp
(Continued)
1.332
SECTION ONE
Formula
pKsp
Ksp
INORGANIC CHEMISTRY
1.333
Formula
pKsp
Ksp
(Continued)
1.334
SECTION ONE
Formula
pKsp
Ksp
INORGANIC CHEMISTRY
1.335
Formula
pKsp
Ksp
(Continued)
1.336
SECTION ONE
Formula
pKsp
Ksp
INORGANIC CHEMISTRY
1.337
Formula
pKsp
Ksp
(Continued)
1.338
SECTION ONE
Formula
pKsp
Ksp
INORGANIC CHEMISTRY
1.339
Formula
pKsp
Ksp
(Continued)
1.340
SECTION ONE
Formula
pKsp
Ksp
INORGANIC CHEMISTRY
1.341
Formula
pKsp
Ksp
(Continued)
1.342
SECTION ONE
pKsp
Formula
Ksp
[Cu( NH 3 )24+ ]
[Cu 2 + ][NH 3 ]4
The higher the stability constant the more stable the complex ion. v denotes the stoichiometric number of a
molecule, atom or ion, and is positive for a product and negative for a reactant.
Equilibrium
Ag+ + 2CN- = [Ag(CH)2]
Ag+ + NH3 = [Ag(NH3)]+
[Ag(NH3)]+ + NH3 = [Ag(NH3)2]+
Ag+ + 2NH3 = [Ag(NH3)2]+
Ag+ + 2S2O32 = [Ag(S2O3)2]3
Al3+ + 6F = [AlF6]3
Al(OH)3 + OH = [Al(OH)4]
Cd2+ + 4CN = [Cd(CN)4]2
Cd2+ + 4I = [CdI4]2
Cd2+ + 4NH3 = [Cd(NH3)4]2+
Co2+ + 6NH3 = [Co(NH3)6]2+
Co3+ + 6NH3 = [Co(NH3)6]3+
Cr(OH)3 + OH = [Cr(OH)4]
Cu+ + 4CN = [Cu(CN)4]3
Cu2+ + 4Cl = [CuCl4]2
Cu+ + 2NH3 = [Cu(NH3)2]+
Kstab
(mol dm 3 ) v
10 1021
25 103
63 103
17 107
10 1013
6 1019
40
71 1016
2 106
40 106
77 104
45 1033
1 102
20 1027
40 105
1 1011
Kstab
log10
3 v
(mol
dm
)
210
34
38
72
130
198
16
169
63
66
49
337
2
273
56
11
1.343
INORGANIC CHEMISTRY
Kstab
log10
3 v
(mol dm )
Kstab
(mol dm 3 ) v
Equilibrium
20 104 (K1)
42 103 (K2)
10 103 (K3)
17 102 (K4)
14 1013
(K = K1K2K3K4)
ca. 1024
ca. 1031
8 102
14 102
16
1
25 1041
17 1016
20 1030
71 102
48 107
50
5 103
5 1016
38 109
10
43
36
30
22
131
ca. 24
ca. 31
11
21
12
0
414
162
303
29
77
17
37
167
96
10
Substance
acetanilide
p-acetophenetidin
p-acetotoluide
alanine
aluminum ammonium sulfate
aluminum chloride hydrated
aluminum fluoride
aluminum potassium sulfate
aluminum sulfate
Formula
C6H5NHCOCH3
C6H4(OC2H5)NHCH3CO
CH3CONHC6H4CH3
CH3CH(NH2)COOH
Al2(SO4)3(NH4)2SO4 24H2O
AlCl3 6H2O
Al2F6 5H2O
AlK(SO4)2
Al2(SO4)3 18H2O
Temp,
C
25
25
25
25
25
25
20
25
25
g/100 g
satd
soln
0.54
0.0766
0.12
14.1
12.4
55.5
0.499
6.62
48.8
g/100 ml
satd
soln
0.54
0.0766
0.12
14.7
13
75
0.5015
7.02
63
ml
water/
100 ml
satd
soln
99.2
99.92
99.7
89.5
92
60
100.0
99.1
66
Specific
gravity
0.997
1.00
0.9979
1.042
1.05
1.35
1.0051
1.061
1.29
(Continued)
1.344
SECTION ONE
Substance
o-aminobenzoic acid
DL-a-amino-n-butyric acid
DL-a-aminoisobutyric acid
ammonium arsenate
ammonium benzoate
ammonium bromide
ammonium carbnonate
ammonium chloride
ammonium citrate, dibasic
ammonium dichromate
ammonium iodide
ammonium molybdate
ammonium nitrate
ammonium oxalate
ammonium perchlorate
ammonium periodate
ammonium persulfate
ammonium phosphate,
dibasic
ammonium phosphate,
monobasic
ammonium salicylate
ammonium silicofluoride
ammonium sulfate
ammonium sulfite
ammonium thiocyanate
amyl alcohol
aniline
aniline hydrochloride
aniline sulfate
L-asparagine
barium bromide
barium chlorate
barium chloride
barium iodide
barium nitrate
barium nitrite
barium perchlorate
benzamide
benzoic acid
beryllium sulfate
boric acid
n-butyl alcohol
cadmium bromide
cadmium chlorate
cadmium chloride
cadmium iodide
cadmium sulfate
calcium bromide
g/100 g
satd
soln
g/100 ml
satd
soln
ml
water/
100 ml
satd
soln
NH4Cl
(NH4)2HC6H5O7
(NH4)2Cr2O7
NH4I
(NH4)6Mo7O24 4H2O
NH4NO3
(NH4)2C2O4 H2O
NH4ClO4
NH4IO4
(NH4)2S2O8
(NH4)2 HPO4
25
25
25
20
25
15
25
15
25
25
25
25
25
25
25
16
25
14.5
0.52
17.8
13.3
32.7
18.6
41.7
20
26.3
48.7
27.9
64.5
30.6
68.3
4.95
21.1
2.63
42.7
56.2
0.519
18.6
13.7
40.2
19.4
53.8
22
28.3
60.5
33
106.2
39
90.2
5.06
23.7
2.68
53
75.5
99.4
86.2
89.5
83.0
84.7
75.2
88
79.3
61.5
85
58.3
88
41.8
97.0
88.7
99.2
71
58.8
0.999
1.046
1.031
1.228
1.040
1.290
1.10
1.075
1.22
1.18
1.646
1.27
1.320
1.019
1.123
1.018
1.24
1.343
NH4H2PO4
25
28.4
83
1.16
NH4C7H5O3
(NH4)2SiF6
(NH4)2SO4
(NH4)2SO3.H2O
NH4CNS
C5H11OH
C6H5NH2
C6H5NH2 HCl
(C6H5NH2)2 H2SO4
NH2COCH2CH(NH2)COOH
BaBr2
Ba(ClO3)2
BaCl2
BaI2 712 H2O
Ba(NO3)2
Ba(NO2)2
Ba(ClO4)2
C6H5CONH2
C7H6O2
BeSO4 4H2O
H3BO3
CH3(CH2)2CH2OH
CdBr2 4H2O
Cd(ClO3)2 12H2O
CdCl2 212 H2O
CdI2
3(CdSO4) 8H2O
CaBr2
25
17.5
20
25
25
25
22
25
25
25
20
25
20
25
25
17
25
25
25
25
25
25
25
18
25
20
25
20
50.8
15.7
42.6
39.3
62.2
2.61
3.61
49
5.88
2.44
51
28.5
26.3
68.8
9.4
40
75.3
1.33
0.367
28.7
4.99
79.7
52.9
76.4
54.7
45.9
43.4
58.8
56.4
92.3
71.7
73.2
43
96.9
96.2
56
96
98.2
83.8
92.6
93.8
71.1
97.9
89.4
47.8
98.6
99.63
93.0
97
17.1
83.9
54.0
80.8
86.3
91.8
75.0
1.145
1.095
1.248
1.204
1.14
0.995
0.998
1.10
1.02
1.007
1.710
1.294
1.27
2.277
1.080
1.490
1.936
0.999
1.00
1.301
1.02
0.845
1.775
2.284
1.778
1.590
1.619
1.82
Formula
C6H4NH2COOH
CH3CH2CH(NH2)COOH
(CH3)2C(NH2)COOH
NH4H2AsO4
NH4C7H5O2
NH4Br
Temp,
C
33
58.2
17.2
53.1
47.3
71
2.60
3.61
54
6
2.46
87.2
36.8
33.4
157.0
10.2
59.6
145.8
1.33
0.367
37.3
5.1
67.3
94.0
174.5
97.2
73.0
70.3
107.2
Specific
gravity
INORGANIC CHEMISTRY
1.345
Substance
calcium chlorate
calcium chloride
calcium chromate
calcium ferrocyanide
calcium iodide
calcium lactate
calcium nitrite
calcium sulfate
camphoric acid
carbon disulfide
cerium nitrate
cesium bromide
cesium chloride
cesium iodide
cesium nitrate
cesium perchlorate
cesium periodate
cesium sulfate
chloral hydrate
chloroform
chromic oxide
chromium potassium sulfate
citric acid
cobalt chlorate
cobalt nitrate
cobalt perchlorate
cupric ammonium chloride
cupric ammonium sulfate
cupric bromide
cupric chlorate
cupric chloride
cupric nitrate
cupric selenate
cupric sulfate
dextrose
ether
ethyl acetate
ferric ammonium citrate
ferric ammonium oxalate
ferric ammonium sulfate
ferric chloride
ferric nitrate
ferric perchlorate
ferrous sulfate
gallic acid
D-glutamic acid
glycine
hydroquinone
m-hydroxybenzoic acid
Formula
Ca(ClO3)2 2H2O
CaCl2 6H2O
CaCrO4 2H2O
Ca2Fe(CN)6
CaI2
Ca(C3H5O3)2 5H2O
Ca(NO2)2 4H2O
CaSO4 2H2O
C8H14(COOH)2
CS2
Ce(NO3)3 6H2O
CsBr
CsCl
CsI
CsNO3
CsClO4
CsIO4
Cs2SO4
CCl3CHO H2O
CHCl3
CrO3
Cr2K2(SO4)4 24H2O
(CH2)2COH(COOH)3 H2O
Co(ClO3)2
Co(NO3)2
Co(ClO4)2
CuCl2 2NH4Cl 2H2O
CuSO4 (NH4)2SO4
CuBr2
Cu(ClO3)2
CuCl2 2H2O
Cu(NO3)2 6H2O
CuSeO4
CuSO4 5H2O
C6H12O6 H2O
(C2H5)2O
CH3COOC2H5
Fe(NH4)3(C2O4)3 3H2O
FeSO4 (NH4)2SO4
FeCl3
Fe(NO3)3
Fe(ClO4)3 10H2O
FeSO4 7H2O
C6H2(OH)3COOH H2O
C5H9O4N
NH2CH2COOH
C6H4(OH)2
C6H4OHCOOH
Temp,
C
g/100 g
satd
soln
g/100 ml
satd
soln
18
25
18
25
20
25
18
25
25
22
25
21.4
25
22.8
25
25
15
25
25
29.4
18
25
25
18
18
26
25
19
25
18
25
20
21.2
25
25
22
25
25
25
16.5
25
25
25
25
25
25
25
20
25
64.0
46.1
14.3
36.5
67.6
4.95
45.8
0.208
0.754
0.173
63.7
53.1
65.7
48.0
21.9
2.01
2.10
64.5
79.4
0.703
62.5
19.6
67.5
64.2
49.7
71.8
30.3
15.3
55.8
62.2
53.3
56.0
14.7
18.5
49.5
5.45
7.47
67.7
51.5
19.1
73.1
46.8
79.9
42.1
1.15
0.86
20.0
6.7
0.975
110.7
67.8
16.4
49.6
143.8
5
65.7
0.208
0.754
0.173
119.9
89.8
126.3
74.1
26.1
2.03
2.13
129.8
120
0.705
106.3
22
88.6
119.3
78.2
113.5
35.5
17.3
102.5
105.2
80
94.5
17.2
22.3
59
5.34
7.44
97
65
22.4
131.1
70.2
132.1
52.8
1.15
0.86
21.7
6.78
0.975
ml
water/
100 ml
satd
soln
62.3
79.2
98.7
86.2
69.0
96
77.8
99.70
99.246
99.63
68.2
79.5
65.9
80.5
92.9
99.0
99.5
71.7
31
99.57
64.0
90
42.7
66.5
79.1
44.7
82
96.0
81.2
64.1
70
74.3
99.4
98.7
60
93.0
92.1
46
61
94.3
48.3
79.8
33.2
72.7
99.05
99.15
86.8
94.4
99.03
Specific
gravity
1.729
1.47
1.149
1.357
2.125
1.01
1.427
0.999
1.00
0.998
1.880
1.693
1.923
1.545
1.187
1.010
1.017
2.013
1.51
1.0028
1.703
1.12
1.311
1.857
1.572
1.581
1.17
1.131
1.84
1.692
1.50
1.688
1.165
1.211
1.19
0.985
0.996
1.43
1.26
1.165
1.793
1.50
1.656
1.255
1.002
1.0002
1.083
1.012
1.000
(Continued)
1.346
SECTION ONE
Substance
lactose
lead acetate
lead bromide
lead chlorate
lead chloride
lead iodide
lead nitrate
DL-leucine
L-leucine
lithium benzoate
lithium bromate
lithium carbonate
lithium chloride
lithium citrate
lithium dichromate
lithium fluoride
lithium formate
lithium iodate
lithium nitrate
lithium perchlorate
lithium salicylate
lithium sulfate
magnesium bromide
magnesium chlorate
magnesium chloride
magnesium chromate
magnesium dichromate
magnesium iodate
magnesium iodide
magnesium molybdate
magnesium nitrate
magnesium perchlorate
magnesium selenate
magnesium sulfate
manganese chloride
manganese nitrate
manganese silicofluoride
manganese sulfate
mercuric acetate
mercuric bromide
mercury bichloride
methylene blue
methyl salicylate
monochloracetic acid
b-naphthalenesulfonic acid
nickel ammonium sulfate
nickel chlorate
nickel chlorate
nickel nitrate
Formula
C12H22O11 H2O
Pb(C2H3O2)2
PbBr2
Pb(ClO3)2
PbCl2
PbI2
Pb(NO3)2
C6H13O2N
C6H13O2N
LiC7H5O2
LiBrO3
Li2CO3
LiCl H2O
Li3C6H5O7
Li2Cr2O7 H2O
LiF
LiCHO2
LiIO3
LiNO3
LiClO4 3H2O
LiC7H5O3
Li2SO4 H2O
MgBr2 6H2O
Mg(ClO3)2
MgCl2 6H2O
MgCr2O4 7H2O
MgCrO7 5H2O
Mg(IO3)2 4H2O
MgI2.8H2O
MgMoO4
Mg(NO3)2 6H2O
Mg(ClO4)2 6H2O
MgSeO4
MgSO4 7H2O
MnCl2
Mn(NO3)2 6H2O
MnSiF6
MnSO4
Hg(C2H3O2)2
HgBr2
HgCl2
C16H18N3ClS 3H2O
C6H4OHCOOCH3
CH2ClCOOH
C10H7SO3H
NiSO4(NH4)2SO4 6H2O
Ni(ClO3)2
Ni(ClO3)2 6H2O
Ni(NO3)2 6H2O
Temp,
C
g/100 g
satd
soln
g/100 ml
satd
soln
25
25
25
18
25
25
25
25
25
25
18
15
25
25
18
18
18
18
19
25
25
25
18
18
25
18
25
18
18
25
25
25
20
25
25
18
17.5
25
25
25
25
25
25
25
30
25
18
18
25
15.9
36.5
0.97
60.2
1.07
0.08
37.1
0.976
2.24
27.7
60.4
1.36
45.9
31.8
52.6
0.27
27.9
44.6
48.9
37.5
52.7
27.2
50.1
56.3
62.5
42.0
81.0
6.44
59.7
15.9
42.1
49.9
35.3
55.3
43.6
57.3
37.7
39.4
30.2
0.609
6.6
4.25
0.12
78.8
56.9
9.0
56.7
64.5
77
17
49.0
0.98
117.0
1.08
0.08
53.6
0.975
2.24
30.4
110.5
1.38
59.5
38.6
82.9
0.27
31.8
69.9
64.5
47.6
63.6
33
83.1
90.0
79
59.7
138.8
6.95
114.0
18.4
58.6
73.6
50.8
72
63.2
93.2
54.5
59.1
38
0.610
6.96
4.3
0.12
105
67.9
9.5
94.2
107.2
122
ml
water/
100 ml
satd
soln
90
85.1
99.6
77.3
99.6
99.7
91.0
98.9
97.85
79.6
72.5
100.0
70.2
82.8
74.8
99.9
80.4
86.8
67.5
79.5
57.1
88.5
82.8
69.7
47.5
82.5
32.6
100.8
77.1
97.4
80.5
73.9
93.0
58.5
82.0
69.2
90.1
90.8
88
99.6
98.5
97
99.88
28
51.4
96
72.0
59.1
36
Specific
gravity
1.07
1.340
1.006
1.944
1.007
0.998
1.445
0.999
1.0012
1.100
1.830
1.014
1.296
1.213
1.574
1.002
1.140
1.566
1.318
1.269
1.206
1.21
1.655
1.594
1.26
1.422
1.712
1.078
1.909
1.159
1.388
1.472
1.440
1.30
1.449
1.624
1.446
1.499
1.26
1.0023
1.054
1.01
1.00
1.33
1.193
1.05
1.658
1.661
1.58
INORGANIC CHEMISTRY
1.347
Substance
nickel perchlorate
nickel perchlorate
nickel sulfate
DL-norleucine
oxalic acid
phenol
b-phenylalanine
m-phenylenediamine
p-phenylenediamine
phenyl salicylate
phenyl thiourea
phosphomolybdic acid
phosphotungstic acid
potassium acetate
potassium antimony tartrate
potassium bicarbonate
potassium bitartrate
potassium bromate
potassium bromide
potassium carbonate
potassium chlorate
potassium chloride
potassium chromate
potassium citrate
potassium dichromate
potassium ferricyanide
potassium ferrocyanide
potassium fluoride
potassium formate
potassium hydroxide
potassium iodate
potassium iodide
potassium meta-antimonate
potassium nitrate
potassium nitrite
potassium oxalate
potassium perchlorate
potassium periodate
potassium permanganate
potassium sodium tartrate
potassium stannate
potassium sulfate
quinine salicylate
resorcinol
rubidium bromate
rubidium bromide
rubidium chloride
rubidium iodate
rubidium iodide
rubidium nitrate
Formula
Temp,
C
Ni(ClO4)2
26
Ni(ClO4)2 9H2O
18
25
NiSO4 6H2O
C6H13NO2
25
H2C2O4 2H2O
25
20
C6H5OH
C6H5CH2CH(NH2)COOH
25
C6H8N2
20
20
C6H8N2
C6H4OHCOOC6H5
25
CS(NH2)NHC6H5
25
20MoO3 2H3PO4 48H2O
25
Approx. 20WO3 2H3PO4 25H2O
25
KC2H3O2
25
KSbOC4H4O6
25
KHCO3
25
KC4H5O6
25
KBrO3
25
KBr
25
K2CO3 112H2O
25
KClO3
25
KCl
25
K2CrO4
25
K3C6H5O7
25
K2Cr2O7
25
K3Fe(CN)6
22
K4Fe(CN)6
25
KF 2H2O
18
KCHO2
18
KOH
15
KIO3
25
KI
25
KSbO3
18
KNO3
25
KNO2
20
K2C2O4 H2O
25
KClO4
25
KIO4
13
KMnO4
25
KNaC4H4O6 4H2O
25
K2SnO3
15.5
K2SO4
25
C20H24N2O2 C6H4(OH)COOH.2H2O 25
C6H4(OH)2
25
RbBrO3
16
RbBr
25
RbCl
25
RbIO3
15.6
RbI
24.3
RbNO3
25
g/100 g
satd
soln
g/100 ml
satd
soln
ml
water/
100 ml
satd
soln
70.8
52.4
47.3
1.13
9.81
6.1
2.88
23.1
3.69
0.015
0.24
74.3
71.4
68.7
7.64
26.6
0.65
7.53
40.6
52.9
8.0
26.5
39.4
60.91
13.0
32.1
24.0
48.0
76.8
51.7
8.40
59.8
2.73
28.0
74.3
28.3
2.68
0.658
7.10
39.71
42.7
10.83
0.065
58.8
2.15
52.7
48.6
2.72
63.6
40.1
112.2
82.7
64
1.13
10.3
6.14
2.89
23.8
3.70
0.015
0.24
135
160
97.1
8.02
31.6
0.65
7.89
56.0
82.2
8.41
31.2
54.1
92.1
14.2
38.1
28.2
72.0
120.6
79.2
8.99
103.2
2.81
33.4
121.5
34
2.72
0.661
7.43
51.9
69.2
11.8
0.065
67.2
2.18
85.6
72.8
2.78
117.7
55.0
46.4
75.1
71
98.97
94.2
94.5
97.5
79.3
96.67
99.84
99.6
46
64
44.3
96.9
87.5
99.3
97.5
82.0
73.5
96.6
86.8
83.7
59.2
95.0
80.8
89.2
78.0
36.4
74.2
98.0
69.1
99.7
86.0
42.3
86
99.0
99.83
97.3
78.8
92.9
96.9
99.84
47.2
99.4
76.9
77.1
99.5
67.3
82.4
Specific
gravity
1.584
1.576
1.35
0.999
1.044
1.0057
1.0035
1.032
1.0038
0.999
0.998
1.81
2.24
1.413
1.049
1.188
0.999
1.054
1.380
1.559
1.051
1.178
1.381
1.514
1.092
1.187
1.173
1.500
1.571
1.536
1.071
1.721
1.025
1.193
1.649
1.20
1.014
1.005
1.046
1.308
1.620
1.086
0.999
1.142
1.016
1.625
1.050
1.022
1.850
1.375
(Continued)
1.348
SECTION ONE
Substance
rubidium perchlorate
rubidium periodate
rubidium sulfate
silicotungstic acid
silver acetate
silver bromate
silver fluoride
silver nitrate
silver perchlorate
sodium acetate
sodium ammonium sulfate
sodium arsenate
sodium benzenesulfonate
sodium benzoate
sodium bicarbonate
sodium bisulfate
sodium bromide
sodium carbonate
sodium chlorate
sodium chloride
sodium chromate
sodium citrate
sodium dichromate
sodium ferrocyanide
sodium fluoride
sodium formate
sodium hydroxide
sodium hypophosphite
sodium iodate
sodium iodide
sodium molybdate
sodium nitrate
sodium nitrite
sodium oxalate
sodium paratungstate
sodium perchlorate
sodium periodate
sodium phenolsulfonate
sodium phosphate dibasic
sodium phosphate tribasic
sodium pyrophosphate
sodium salicylate
sodium selenate
sodium silicofluoride
sodium sulfate
sodium sulfate
sodium sulfide
sodium sulfite, anhydrous
sodium thiocyanate
Formula
RbClO4
RbIO4
Rb2SO4
H4SiW12O40
Ag(C2H3O2)
AgBrO3
AgF 2H2O
AgNO3
AgClO4 H2O
NaC2H3O2
NaNH4SO4
Na3AsO4 12H2O
NaC6H5SO3
NaC7H5O2
NaHCO3
NaHSO4 H2O
NaBr 2H2O
Na2CO3 10H2O
NaClO3
NaCl
Na2CrO4
Na3C6H5O7 5H2O
Na2Cr2O7
Na4Fe(CN)6
NaF
NaCHO2
NaOH
NaH2PO2
NaIO3 H2O
NaI
Na2MoO4
NaNO3
NaNO2
Na2(CO2)2
(Na2O)3(WO3)7 16H2O
NaClO4
NaIO4 3H2O
C6H4(OH)SO3Na
Na2HPO4
Na3PO4
Na2H2P2O7 6H2O
NaC7H5O3
Na2SeO4
NaSiF6
Na2SO4
Na2SO4 10H2O
Na2S 9H2O
Na2SO3
NaCNS
Temp,
C
g/100 g
satd
soln
25
16
25
18
25
25
15.8
25
25
25
15
17
25
25
15
25
25
25
25
25
18
25
18
25
25
18
25
16
25
25
18
25
20
25
0
25
25
25
17
14
25
25
18
20
25
25
25
25
25
1.88
0.645
33.8
90.6
1.10
0.204
64.5
71.5
84.5
33.6
25.2
21.1
16.4
36.0
8.28
59
48.6
22.6
51.7
26.5
40.1
48.1
63.9
17.1
3.98
44.7
50.8
52.1
8.57
64.8
39.4
47.9
45.8
3.48
26.7
67.8
12.6
16.1
4.2
9.5
13.0
53.6
29.0
0.773
21.8
27.7
52.3
23
62.9
g/100 ml
satd
soln
1.90
0.648
45.6
258
1.11
0.2037
168.4
164
237.1
40.5
29.6
23.5
17.6
41.5
8.80
87
75.0
28.1
74.3
31.7
57.4
61.2
111.4
19.4
4.14
58.9
77
72.4
9.21
124.3
56.6
66.7
62.3
3.58
35.2
114.1
13.9
17.4
4.4
10.5
14.4
67.0
38.1
0.737
26.4
33.3
63
28.5
87
ml
water/
100 ml
satd
soln
99.3
99.85
89.7
26.8
99.40
99.65
92.7
65.5
43.5
80.0
87.9
88.0
90.1
73.9
97.6
60
79.4
96.5
69.6
88.1
85.7
66.0
63.0
93.9
99.7
73.0
74
66.6
98.5
67.7
87.0
72.5
73.8
99.1
96.5
54.1
96.2
90.5
99.9
99.8
95.8
58.0
93.4
99.76
94.5
87.0
57
95.5
51
Specific
gravity
1.012
1.0052
1.354
2.843
1.0047
0.9985
2.61
2.29
2.806
1.205
1.174
1.119
1.076
1.152
1.061
1.47
1.542
1.242
1.440
1.198
1.430
1.272
1.743
1.131
1.038
1.316
1.51
1.386
1.075
1.919
1.435
1.391
1.359
1.025
1.316
1.683
1.103
1.079
1.043
1.103
1.104
1.248
1.313
1.0054
1.208
1.207
1.20
1.24
1.38
INORGANIC CHEMISTRY
1.349
Substance
sodium thiosulfate
sodium tungstate
stannous chloride
strontium chlorate
strontium chloride
strontium iodide
strontium nitrate
strontium nitrite
strontium perchlorate
strontium salicylate
succinic acid
succinimide
sucrose
tartaric acid
tetraethyl ammonium iodide
tetramethyl ammonium
iodide
thallium chloride
thallium nitrate
thallium nitrite
thallium perchlorate
thallium sulfate
trichloroacetic acid
uranyl chloride
uranyl nitrate
urea
urea phosphate
urethan
D-valine
DL-valine
zinc acetate
zinc benzenesulfonate
zinc chlorate
zinc chloride
zinc iodide
zinc phenolsulfonate
zinc selenate
zinc silicofluoride
zinc sulfate
zinc valerate
ml
water/
100 ml
satd
soln
Temp,
C
g/100 g
satd
soln
g/100 ml
satd
soln
Na2S2O3 5H2O
Na2WO4 10H2O
SnCl2
Sr(ClO3)2
SrCl2 6H2O
SrI2 6H2O
Sr(NO3)2
Sr(NO2)2
Sr(ClO4)2
Sr(C7H5O3)2
(CH2)2(COOH)2
(CH2CO)2NH H2O
C12H22O11
C2H2(OH)2(COOH)2
N(C2H5)4I
N(CH3)4I
25
18
15
18
15
20
25
19
25
25
25
25
25
15
25
25
66.8
42.0
72.9
63.6
33.4
64.0
44.2
39.3
75.6
4.58
7.67
30.6
67.89
58.5
32.9
5.51
93
66.1
133.1
117.0
45.5
137.8
65.3
56.8
158.5
4.68
7.82
32.7
90.9
76.9
36.2
5.60
46
91.3
49.5
67.0
90.7
77.5
82.5
87.8
50.8
97.5
94.5
74.2
43.0
54.7
74.0
96.1
1.39
1.573
1.827
1.839
1.36
2.15
1.477
1.445
2.084
1.019
1.021
1.067
1.340
1.31
1.102
1.016
TlCl
TlNO3
TlNO2
TlClO4
Tl2SO4
CCl3COOH
UO2Cl2
UO2(NO3)2 6H2O
(NH2)2CO
CO(NH2)2 H3PO4
NH2CO2C2H5
(CH3)2CHCH(NH2)COOH
(CH3)2CHCH(NH2)COOH
Zn(C2H3O2)2
Zn(C6H5SO3)2
Zn(ClO3)2
ZnCl2
Znl2
(C6H5OSO3)2Zn 8H2O
ZnSeO4
ZnSiF6 6H2O
ZnSO4 7H2O
Zn(C5H9O2)2
25
25
25
25
25
25
18
25
25
24.5
25
25
25
25
25
18
25
18
25
22
20
25
25
0.40
10.4
32.1
13.5
5.48
92.3
76.2
68.9
53.8
52.4
82.8
8.14
6.61
25.7
29.5
65.0
67.5
81.2
39.8
37.8
32.9
36.7
1.27
0.40
11.4
43.7
15.2
5.74
149.6
208.5
120
62
66.1
88.8
8.26
6.68
30.0
34.9
124.4
128
221.3
47.3
58.9
47.2
54.6
1.27
99.6
98.0
92.5
97.1
99.0
12.41
65.2
54.5
53.5
60.1
18.5
93.3
94.5
86.5
83.4
67.0
61
51.2
71.5
97.0
96.3
94.7
98.8
1.0005
1.093
1.360
1.122
1.047
1.615
2.736
1.74
1.15
1.26
1.073
1.015
1.012
1.165
1.182
1.914
1.89
2.725
1.185
1.559
1.434
1.492
1.001
Formula
Specific
gravity
1.350
SECTION ONE
[H + ][B]
[HB]
The most common charge types for the acid HB and its conjugate base B are
CH3COOH = H+ + CH3COO(acetic acid, acetate ion)
HSO4 = H+ + SO42 (hydrogen sulfate ion, sulfate ion)
NH4+ = H+ + NH3 (ammonium ion, ammonia)
Acids which have more than one acidic hydrogen ionize in steps, as shown for phosphoric acid:
H3PO4 = H+ + H2PO4
H2PO4 = H+ + HPO42
HPO42 = H+ + PO43
pK1 = 2.148
pK2 = 7.198
pK3 = 11.90
K1 = 7.11 103
K2 = 6.34 108
K3 = 1.26 1012
pH = log [acid]
pH = 14.00 + log [base]
pH = 1/2pKa 1/2 log [acid]
pH = 14.00 1/2pKb + 1/2 log [base]
INORGANIC CHEMISTRY
[acid ] + [H 3O + ] [OH ]
0 =
[H + ]n
[H A]
= n
+ n
+ n 1
+ n2
Cacid
[H ] + K1[H ] + K1K2 [H ] + L + K1K2 L Kn
1 =
K1[H + ]n1
[H n1A ]
=
Cacid
[H + ]n + K1[H + ]n1 + K1K2 [H + ]n2 + L + K1K2 L Kn
2 =
+ n
+ n 1
[H ] + K1[H ]
[H A 2 ]
K1K2 [H + ]n2
= n2
+ n2
+ K1K2 [H ] + L + K1K2 L Kn
Cacid
M
n =
+ n
+ n 1
[H ] + K1[H ]
[A n ]
K1K2 L Kn
=
+ n2
+ K1K2 [H ] + L + K1K2 L Kn
Cacid
1.351
1.352
TABLE 1.74 Proton Transfer Reactions of Inorganic Materials in Water at 25C
Substance
Formula or remarks
pK1
pK2
(Continued)
1.353
1.354
TABLE 1.74 Proton Transfer Reactions of Inorganic Materials in Water at 25C (Continued)
Substance
Formula or remarks
pK1
pK2
(Continued)
1.355
1.356
TABLE 1.74 Proton Transfer Reactions of Inorganic Materials in Water at 25C (Continued)
Substance
Formula or remarks
pK1
pK2
Source: J. J. Christensen, L. D. Hansen, and R. M. Izatt, Handbook of Proton Ionization Heats and Related Thermodynamic Quantities, Wiley-Interscience, New York, 1976; D. D. Perrin, Ionisation
Constants of Inorganic Acids and Bases in Aqueous Solution, 2d ed., Pergamon Press, 1982.
INORGANIC CHEMISTRY
1.357
Stepwise
stability constants
K1
K2
k1
k1k2
Kn
k1k2 kn
As an example, the entries in Table 1.75 for the zinc ammine complexes represent these equilibria:
Zn2+ + NH3 = Zn(NH3)2+
K1 =
[ Zn( NH 3 )2 + ]
[ Zn 2 + ][ NH 3 ]
K2 =
[ Zn( NH 3 )22 + ]
[ Zn 2 + ][ NH 3 ]2
K3 =
[ Zn( NH 3 )32 + ]
[ Zn 2 + ][ NH 3 ]3
K4 =
[ Zn( NH 3 )24+ ]
[ Zn 2 + ][ NH 3 ]4
If the stepwise stability or formation constants of the reactions are desired, for the first step log K1 =
log k1 = 2.37. For the second and succeeding steps the equilibria and corresponding constants are as
follows:
Zn(NH3)2+ + NH3 = Zn(NH3)22+
Zn(NH3)22+
+ NH3 =
Zn(NH3)32+
Zn(NH3)32+
+ NH3 =
Zn(NH3)42+
The reverse of the association or formation reactions would represent the dissociation or instability constant for the systems, i.e., log Kf = log Kinstab.
The data in the tables generally refer to temperatures of about 20 to 25C. Most of the values in
Table 1.75 refer to zero ionic strength, but those in Table 1.76 often refer to a finite ionic strength.
1.358
SECTION ONE
TABLE 1.75 Cumulative Formation Constants for Metal Complexes with Inorganic Ligands
log K1
log K2
log K3
log K4
log K5
log K6
INORGANIC CHEMISTRY
1.359
TABLE 1.75 Cumulative Formation Constants for Metal Complexes with Inorganic Ligands (Continued)
log K1
log K2
log K3
log K4
log K5
log K6
(Continued)
1.360
SECTION ONE
TABLE 1.75 Cumulative Formation Constants for Metal Complexes with Inorganic Ligands (Continued)
log K1
log K2
log K3
log K4
log K5
log K6
INORGANIC CHEMISTRY
1.361
TABLE 1.75 Cumulative Formation Constants for Metal Complexes with Inorganic Ligands (Continued)
log K1
log K2
log K3
log K4
log K5
log K6
(Continued)
1.362
SECTION ONE
TABLE 1.75 Cumulative Formation Constants for Metal Complexes with Inorganic Ligands (Continued)
log K1
log K2
log K3
log K4
log K5
log K6
INORGANIC CHEMISTRY
1.363
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands
Temperature is 25C and ionic strengths are approaching zero unless indicated otherwise: (a) At 20C, (b) at
30C, (c) 0.1 M uni-univalent salt, (d) 1.0 M uni-univalent salt, (e) 2.0 M uni-univalent salt present.
log K1
log K2
log K3
log K4
(Continued)
1.364
SECTION ONE
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands (Continued)
log K1
log K2
log K3
log K4
INORGANIC CHEMISTRY
1.365
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands (Continued)
(Continued)
1.366
SECTION ONE
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands (Continued)
INORGANIC CHEMISTRY
1.367
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands (Continued)
(Continued)
1.368
SECTION ONE
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands (Continued)
Next Page
INORGANIC CHEMISTRY
1.369
TABLE 1.76 Cumulative Formation Constants for Metal Complexes with Organic Ligands (Continued)
(Continued)