www.eenadupratibha.

net

BOARD OF INTERMEDIATE EDUCATION

SENIOR INTER CHEMISTRY

t
e

MODEL PAPER (ENGLISH VERSION)

n
.
a

TIME: 3 HOURS

MAX.MARKS: 60

h
b
i

SECTION - A
I.

i) Very Short Answer Type questions.

t
a
r

ii) Answer ALL questions.

ii) Each question carries TWO marks.

10 2 = 20

p
u
d

1.

What is an "ideal solution"?

2.

What are pseudo first order reaction? Give one example.

3.

Define the terms 'slag' and 'gangue'.

4.

Iron becomes passive in Conc. HNO3. Why?

5.

HF is a liquid while HCl is a gas. Explain.

6.

Aqueous Cu+2 ions are blue in colour. Whereas aqueous Zn+2 ions are colourless. Why?

7.

What are 'Antibiotics'? Give 2 examples.

8.
9.
10.

a
n

e
e
.
w
w

t
e
n

What are "biodegradable detergents" and "non biodegradable detergents"? Give one example for each.

What is "Cannizzaro reaction"?

b
i
t

SECTION - B
II.

.
a
h

What is "Decarboxylation"?

i) Short Answer Type questions.

a
r
p

ii) Answer any SIX questions.

iii) Each question carries FOUR marks.
11.

Derive Bragg's equation.

12.

What is "Van't Hoff factor"?

6 4 = 24

u
d
a

0.6 ml of acetic acid having density 1.06 g/ml is dissolved in 1 lit. of water. The depression of freezing
point observed for this solution is 0.0205C. Calculate the Van't Hoff factor.

n
e
e
.
ww

13.

How are colloids classified on the basis of interaction between dispersed phase and dispersion
medium.

14.

Explain the purification of Sulphide ore by froth flotation method.

15.

Write the formulae of the following compounds.

a) Potassium Trioxalatoaluminate (III)
b) Penta amminechloro Cobalt (III) Chloride
c) Diammine Chloronitrito - N - Platinum (II)
d) Potassium tetra Cyanonickelate (II)

ONLINE-MP-2016

www.eenadupratibha.net

NEW SYLLABUS

www.eenadupratibha.net
16.

What are Hormones? Give one example for each.

i) Steroid hormones ii) Poly peptide hormones
iii) Amino acid derivatives

17.

t
e

a) What is Vulcanization of rubber?

n
.
a

b) What are "Thermosetting Polymers"? Give 2 examples.

18.

a) What is "Kolbe's reaction"?

b) What is "Aspirin"? How is it prepared?

h
b
i

SECTION - C

t
a
r

III. i) Long Answer Type questions.

ii) Answer any TWO questions.
iii) Each question carries EIGHT marks.
19.

2 8 = 16

p
u
d

a) State Faraday's First Law of Electrolysis.

A solution of CuSO4 is electrolysed for 10 minutes with a current of 1.5 amperes. What is the mass of
Copper deposited at the Cathode?

a
n

b) Explain the terms

e
e
.
w
w

i) Collision Frequency (Z)

t
e
n

ii) Probability factor (P)

20.

a) Describe the manufacture of H2SO4 by contact process briefly.

b) Explain the reaction of the following with water

a) xeF2 b) XeF4

21.

.
a
h

c) XeF6

a) How do you prepare Ethyl Cyanide and Ethyl isocynanide from a common alkyl halide.

b
i
t

b) Explain the mechanism of SN2 with one example.

a
r
p

u
d
a

n
e
e
.
ww

www.eenadupratibha.net

www.eenadupratibha.net
ANSWERS
SECTION - A

t
e

1.

What is an ''ideal solution"?

A:

The solution that obeys Raoult's law over the entire range of concentration and temperature.
mix H = 0

n
.
a

mix V = 0

e.g.: Bengene + Toluene

2.

What is pseudo first order reaction? Give one example.

A:

The first order reaction which appear to be 2nd order reaction.

h
b
i

t
a
r

H+
CH3COOC2H5 + H2O CH3COOH + C2H5OH
Rate = K [CH3COOC2H5]

p
u
d

Order the of reaction = 1

3.

Define the terms 'slag' and 'gangue'.

A:

Slag: The product formed when gangue reacts with flux.

a
n

FeO + SiO2 FeSiO3

flux
gangue
slag

e
e
.
w
w

Gangue: Unwanted earthy material present in an ore.

4.
A:

t
e
n

Iron become passive in Conc. HNO3. Why?

Iron becomes passive due to formation of protective non reactive film of oxide on the metal surface
when it is in contact with conc. HNO3.

.
a
h

5.

HF is liquid while HCl is a gas. Explain.

A:

Due to presence of intermolecular Hydrogen bonding HF molecules associate to get liquid state.

b
i
t

.......... H - F .......... H - F .......... H - F .......... H - F

As HCl does not form Hydrogen bonding it exists as gas.

a
r
p

6.

Aqueous Cu+2 ions are blue in colour. Where as aqueous Zn+2 ions are colourless. Why?

A:

Cu+2 = [Ar] 4S0 3d9

u
d
a

Zn+2 = [Ar] 4S0 3d10

Due to presence of one unpaired d-electron in 3d sub-shell of Cu+2, due to d-d transition, it absorbs
yellow colour and transmits blue colour. So aqueous Cu+2 ions are blue in colour. Aqueous Zn+2 ions
are colourless due to absence of unpaired electrons.

n
e
e
.
ww

7.

What are "Antibiotics"? Give 2 examples.

A:

A substance that is produced partly or fully by Chemical synthesis, which inhibits the growth or
destroys disease causing micro organisms.

e.g.: Ofloxacin, Tetracycline.

8.
A:

What are "Bio degradable detergents" and "non-biodegradable detergents"? Give one example
for each.
Biodegradable detergents: Detergents which can be decomposed by natural bacteria.

www.eenadupratibha.net

www.eenadupratibha.net
e.g.: H3C - (CH2)10 - CH

CH3

SO3 Na

t
e

Non biodegradable detergents: Detergents which can not be decomposed by natural bacteria.
e.g.: H3C - CH - CH2 - CH - CH2 - CH - CH2 - CH

CH3
CH3
CH3
CH3

SO3 Na

n
.
a

9.

What is "Decarboxylation"?

A:

The Phenomenon of lose of CO2 from Sodium Salt of Carboxylic acid when it is heated with soda lime
(3 Parts NaOH + 1 part CaO) to form an alkane is called decarboxylation.

h
b
i

t
a
r

CaO
CH3 COONa + Na O H CH4 + Na2CO3

10.

What is Cannizzaro reaction?

A:

The reaction in which aldehydes (do not have alpha H) undergo disproportionation on heating with
strong alkali (Oxidised to carboxylic acid & reduced to alcohol is called Cannizzaro reaction.
H

a
n

e
e
.
w
w
C =O +

11.
A:

p
u
d

C = O + Conc. KOH CH3OH + H COOK

t
e
n

SECTION - B

Derive Bragg's equation.

.
a
h

A crystal has many planes. Atoms or ions are arranged in systematic geometry in these planes. When
X-Rays incident on these crystal planes, they undergo diffraction. When the waves are diffracted from
these atoms or ions, they may have constructive or destructive interferance. From the figure it is very
clear that 1st and 2nd X-rays travel the same distance till the wave front AD. Where as 2nd X-ray
travels an extra distance DB + BC (Path difference) than that of 1st X-ray. If the two waves are
present in the same phase ( Constructive Interference), the path difference must be equal to the wavelength or an integral multiple of wave length n.

b
i
t

a
r
p

DB
DB
In ADB, Sin = = DB = d Sin
AB
d

X
st

nd

y
ra

X
y
ra

n
e
e
.
ww

n = DB + BC = 2d Sin

u
d
a

BC
BC
In ABC, Sin = = BC = d Sin
AB
d

n = 2d Sin

This relation is known as Bragg's equation.

= Wave length of X-Ray

n = Order of diffraction

1st plane

2nd plane

= Angle of incident X-Ray

d = Interplanar distance

www.eenadupratibha.net

3rd plane

www.eenadupratibha.net
12.

What is Van't Hoff factor?

0.6 ml of acetic acid having density 1.06 g/ml is dissolved in 1 lit. of water. The depression of freezing
point observed for this solution is 0.0205 C. Calculate the Vant's Hoff Factor.

t
e

(Kf = 1.86 K. kg mol-1)

A:

Van't Hoff factor (i): The ratio of observed colligative property to calculated colligative property.

n
.
a

0.6 1.06
Number of moles of Acetic acid = = 0.0106
60
0.0106
Molality (m) = = 0.0106 mol/kg
1000 g 1

h
b
i

Tf = Kf.m
Tf = 1.86 0.0106 = 0.0197 K
Observed freezing point
Van't Hoff factor (i) =
Calculated freezing point

t
a
r

p
u
d

0.0205
= = 1.041
0.0197

a
n

13.

How are colloids classified on the basis of interaction between dispersed phase and dispersion
medium.

A:

Lyophilic Colloids: Lyo means liquid, philic means attraction. The stable colloid, which is prepared
by direct mixing. They are most reversible. The type of colloid in which much affinity is observed
between dispersion medium and dispersed phase.

e
e
.
w
w

t
e
n

e.g.: Starch solution.

Lyophobic colloids: Phobic means hate. The unstable colloid, which is prepared by special methods.
They are irreversible. The type of colloid in which repulsion is observed between dispersion medium
and dispersed phase. So they need stabilizing agent for their preservation.
e.g.: Gold sol.

14.

b
i
t

Explain the purification of sulphide ore by froth flotation method.

Rotating paddle

.
a
h

a
r
p

Air

Mineral froth

u
d
a

Pulp of ore + oil

Paddle (draws in air and stirs the pulp)

n
e
e
.
ww

Enlarged view of an air bubble showing mineral particles attached to it

Froth floatation process (schematic)

A:

This method is used to concentrate sulplide ore.

Finely powdered ore is take into a tank along with H2O.

Froth Collectors like Fine oil, Sodium ethyl xanthate are added for non- wettability of ore particles.
Stabilizers like cresols, aniline are added to stabilize the froth.
This suspension is agitated with a rotating paddle and air in order to form froth.
The Ore particles are wetted by oils and the gangue particals are wetted by water.
The Froth, floats on the water is separated and dried to recover the ore particles.

www.eenadupratibha.net

www.eenadupratibha.net
15.

Write the formulae of the following compounds.

a) Potassium Trioxalatoaluminate (III)
b) Penta amminechloro cobolt (III) Chloride

t
e

c) Diammine chloronitrato -N- Platinum (II)

n
.
a

d) Potassium-tetracyanonickelate (II)
A:

a) K3 [Al(C2O4)3]

h
b
i

b) [CO (NH3)5 Cl]Cl2

c) [Pt (NH3)2 Cl(NO2)]
d) K2 [Ni (CN)4]
16.

t
a
r

What are Hormones? Give one example for each.

i) Steroid hormones

A:

ii) Poly Peptide hormones

iii) Amino acid derivatives.

p
u
d

Hormones: Biomolecules that can act as intercellular messengers are called hormones.
i) Steroid hormones: Male Sex Hormones: Testosterone

a
n

Female Sex Hormones: Estradiol, Progesterone

ii) Polypeptide Hormones: Insulin, Oxytocin, Endorphin

e
e
.
w
w

iii) Amino acid derivatives: Thyroxine, Adrenaline or Norepinphrine

17.

t
e
n

a) What is "Vulcanization" of rubber?

b) What are "Thermosetting Polymers"?

A:

a) Vulcanization: The process of heating latex (raw rubber) with Sulphur between 373 K and 415 K
temperature in order to improvise qualities like elasticity, tensile strength etc.

.
a
h

b) Thermosetting Polymers: The polymers having cross linked or highly branched molecules, which
on heating becomes hard (infusible).

b
i
t

e.g.: Bakelite, Urea - formaldehyde, Resin.

18.

a) What is "Kolbe's reaction"?

a
r
p

b) What is "Aspirin"? How is it prepared?

A:

a) Kolbe's reaction: Sodium phenoxide on heating with CO2 & H+under pressure gives Salicylic acid.
OH

u
d
a

O Na

OH

i) CO2

NaOH

en

-H2O

e
.
ww

ii) H

COOH

(Salicyclic Acid)

b) ASPIRIN: Acetyl derivative of Salicylic acid is called Aspirin. Acetylation of Salicylic acid gives
Aspirin
COOH
COOH

OH

+ (CH3CO)2O

H+

COOCH3

+ CH3COOH

(ASPIRIN)

www.eenadupratibha.net

www.eenadupratibha.net
SECTION - C
19.

a) State Faraday's first law of Electrolysis?

t
e

A Solution of CuSO4 is electrolysed for 10 minutes with a current of 1.5 amperes. What is the
mass of Copper deposited at Cathode?

n
.
a

b) Explain the terms

i) Collision frequency (Z)
A:

ii) Probability factor (P)

a) Faraday's 1st Law of Electrolysis: The mass of substance deposited or liberated or dissolved at an
electrode during the electrolysis of an electrolyte (aqueous or molten) is directly proportional to the
quantity of electricity passing through it.

h
b
i

t
a
r

m = c.e.t where e = E/96487

1.5 63 10 60
m = = 0.2938 g.
2 96487

p
u
d

b) i) Collision frequency (Z): The number of collisions per second per unit volume of the reaction
mixture

a
n

Rate = = Z AB. e-Ea/RT

e
e
.
w
w

ZAB = Collision frequency of reactants A & B

ii) Probabiloity factor (P): The factor, that is used to account for effective collisions.

t
e
n

Rate = P ZAB. e-Ea/RT

Meanwhile collision molecules must be properly oriented.

20.

.
a
h

a) Describe the manufacture of H2SO4 by contact process briefly.

b) Explain the reaction of the following with water

b
i
t

i) XeF2 b) XeF4 C) XeF6

A:

a) Manufacture of H2SO4 (contact process)

H2SO4 is meanufactured by contact process by applying Lechatlier's principle in 3 stages as follows.

a
r
p

State-1: Burning of S or Sulphide Ore in air to give SO2.

S + O2 SO2

u
d
a

4 Fe S2 + 11 O2 2 Fe2O3 + 8 SO2

Stage - 2: Oxidation of SO2 to SO3 at optimum pressure 2 bar & optimum temperature 720 K in
presence of a catalyst V2O5.

n
e
e
.
ww

V2O5
2 SO2 + O2 2 SO3 H = -19.6 kJ/ mol
Stage - 3: Absorption of SO3 by H2SO4 to give Oleum.
SO3 + H2SO4 H2S2O7 (Oleum)

Oleum on dilution with water gives H2SO4.

H2S2O7 + H2O 2H2 SO4

b) Reaction of XeF2 with water:

XeF2 is readily hydrolysed to give Xe, HF and O2

www.eenadupratibha.net

www.eenadupratibha.net
2 Xe F2 + 2 H2O 2 Xe + 4 HF + O2
Reaction of XeF4 with water:
XeF4 on hydrolysis gives XeO3

t
e

6 XeF4 + 12 H2O 4 Xe + 2 XeO3 + 24 HF + 3 O2

n
.
a

Reaction of XeF6 with water:

XeF6 on partial hydrolysis gives XeOF4
XeF6 + H2O 2 HF + XeOF

h
b
i

XeF6 on complete hydrolysis gives XeO2F2

XeF6 + 2 H2O XeO2F2 + 4 HF
21.

t
a
r

a) How do you prepare Ethyl Cyanide and Ethyl iso-cyanide from a common alkyl halide?
b) Explain the mechanism of SN2 with one example.

A:

p
u
d

a) Alkyl halides reacts with alcoholic KCN to form alkyl Cyanide as major product while with
alcoholic AgCN to form alkyl isocyanide as major product (along with their isomers as minor
products)

a
n

C2H5Cl + alcoholic KCN C2H5CN

+ C2H5NC
(major product) (minor product)

e
e
.
w
w

C2H5Cl + alcoholic AgCN

C2H5NC

(major product)

C2H5CN

t
e
n

(minor product)

b) SN2 Mechanism:

.
a
h

Reaction of CH3Cl with OH- ion is the best example of SN2 mechanism. It is a single step process.
In this mechanism, nucleophile substitutes the leaving group in a single step without formation of any
intermediate compound (but transition state will be formed)
H
OH- + H -

b
i
t

- C - Cl HO ..... C...... Cl HO - C -H + Cl-

a
r
p

Rate = K [CH3Cl] [OH-]

It is a second order (as the rate of the reaction depends on concentration of both CH3Cl & OH-)
and bimolecular (as 2 molecules are taking part in the rate determining step).

u
d
a

Order of reactivity 1 - alkly halide > 2 - alkyl halide > 3 - alkyl halide

n
e
e
.
ww

Effect of leaving group: RI > RBr > RCl > RF

Stereochemistry: Complete inversion of configuration takes place. It is like turning of inside of
umbrella out when caught in strong wind.
Writer: A.N.S. Sankara Rao

www.eenadupratibha.net