Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
(RT60015)
by
Narayan Ch Das
Rubber Technology Centre
I.I.T Kharagpur 721302
Reference Books
Viscoelastic effects
Memory effects
Shear thickening and shear
thinning
For both the layperson and the technical person, rheology is a set of
problems or observations related to how the stress in a material or force
applied to a material is related to deformation (change of shape) of the
material.
PROCESSING:
Technique steps to get the final product from raw or gum
materials and also to get the shape or practical shape and
to set/retain the shape of the finish products.
Definition of Rheology
case of deformation
Deformation is a
special case of flow
Deformation
Flow
Elastic deformation
(takes place irreversible
(takes place instantaneously on application
and permanent deformation)
of force or stress and disappears instantaneously
upon release (reversible deformation)
Non-Newtonian
Bingham
plastics
Newtonian
Non-Bingham
plastics
Elastic viscous
Non-elastics viscous
Fundamentals of Rheology
The fundamental definition of rheology indicates that for a material to flow its
original structural composition must first exceed a critical limited deformation.
Rheology, the science of deformation and flow of materials characterizes
materials through parameters such as;
Course Content
Rheological or Constitutive Equations
(Different parameters models)
Viscoelastic Behaviour
(Static Stress Relaxations and Creep Test
(Dynamic Stress Relaxations and Creep Test)
Mechanical Model: Maxwell & Voigt Kelvin
Model
Parameters Influencing the Polymer Rheology
Effect of Temperature
Effect of Pressure
Effect of Mol. Wt and Polydispersity
Effect of Filler
Rheological Parameters
Force: Tensile, compressive, shear > Stress
Strain
Rate of strain
A mathematical function of the form
f ( , , ) 0
represents a general function between different rheological parameters
Materials
Viscous
Elastic
Hookean
Solids
Non-Hookean
Solids
Newtonian
Fluids
Basic properties
Modulus, G
Visco-elastic
Non-Newtonian
Fluids
f ( )
Basic properties
viscosity,
f ( )
Newtonian,
Pseudoplastics,
Dilatant,
Bingham Plastics,
Yield Stress,
n=1
n<1
n>1
n=1
Time ind.
Vis. fluid
f ( )
Time dep.
Vis. fluid
f ( , , t )
Linear
Visco-elastics
Non-Linear
Visco-elastics
f ( , , t )
Basic properties
Static & Dynamic
Moduli, creep
Compliances, tan
Basic
properties
independent of
input function
Basic
properties
change with
input function
Constitutive Equation
f ( , , ) 0
6
4
Viscosity, Pas
100
8
6
4
2
10
8
6
4
1
-2
10
E
-1
10
10
10
10
Shear rate, s
10
10
10
-1
Polymer solution and low Mol. Wt. melts shows all three region, but high Mol. Wt.
show melt fracture at high shear rate;
Constitutive Equation
Equation/model for non-Newtonian fluid can be categorized as:
1.
2.
3.
4.
5.
k ( ) n
Where k is consistency index and n is the non-Newtonian or the flow behavior index.
For n=1, the fluid is Newtonian, n<1, the fluid is Pseudoplastics, n>1, the fluid is Dilatant,
a / k ( ) n1
1
)
B
0, a A / B(constant)
This represents the Newtonian
behaviour at low shear rate.
y
0
for y
Where y is the yield stress and is consistency index or the coefficient of rigidity or
the coefficient of plastic viscosity.
y ( ) n
0
for y
1 / 2 at / 2
1
1
1 / 1 / 2
0 1
1/ n
0=1/0 is the fluidity of the system at very low shear rate
(0+)/2
o
1
and 1
0 1 / 2
As
0/2
1/2
A, B, C are three materials parameters. This model give a better representation for
the polymer as compared to the Ellis model. This is also applicable to different
temperatures
.
.
.
.
.
As 0 , A and as , A /(B )c
1 / m
0 Lim a ,
0
1/ 2
at o / 2
1/ n
(0+)/2
0/2
1/2
2. Modified power law model: Can be applied to the entire range range
of shear rate.
( b c d )