NARAYANA IIT ACADEMY

INDIA

CHEMISTRY-ASSIGNMENT-6
CHEMICAL EQUILIBRIUM & THERMODYNAMICS

Sec: Sr.IIT-IZ & NIZ-COSPARK

PONGAL WORKSHEET

MULTIPLE CHOICE QUESTIONS

1.

For the reaction AB2 (g) AB (g)+B(g)

If is negligiable w.r.t. 1 then degree of dissociation ( ) of AB2 is proportional to :
a).

2.

1
p

b).

1
v

c).

1
p

d).

Consider the reaction 2CO(g)+O 2 (g) 2CO 2 (g)+Heat under what conditions shift
is undeterminable ?
a). Addition of O 2 and decrease in volume

3.

4.

5.

b). Addition of CO and removal of CO 2 at constant volume

c). Increase in temperature and decrease in volume
d). Addition of CO and increase in temperature at constant volume
What will be the effect of constant addition of catalyst at constant temperature ?
a). The equilibrium constant will remain constant
b). H of the reaction will remain constant
c). K f and K b will increase up to same extent
d). equilibrium composition will change
Increase in the pressure for the following equilibrium : H 2O (l ) H 2O ( g ) result in
the :
a). formation of more H 2O (l )

b). formation of more H 2O ( g )

c). increase in b.p. of H 2O (l )

d). decrease in b.p. of H 2O (l )

N 2 ( g ) and H 2 (g) are allowed to each in a closed vessel at given temp. and pressure

for the formation of NH 3 (g)[N 2 (g)+3H 2 (g) 2NH3 (g)+22.4 kcal] if He(g) is added
at equilibrium at constant pressure then which is/are correct?
a). Concentration of N 2 (g) , H 2 (g) and NH 3 (g) decrease
b). Moles of NH 3 (g) decrease.
c). The extent of cooling depends on amount of He(g) added.
d). Concentration of N 2 and H 2 increases and concentration of NH 3 decreases.

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6.

Sr.IIT-IZ & NIZ-COSPARK_PONGAL WORKSHEET

Select the correct statement(s):

a). The rate of reaction decreases with decrease in temperature
b). The rate of reaction is uniform in zero order reaction
c). The rate of reaction depends upon the surface area of the solid reactants
d). Average and instantaneous rate of reaction defined for micro and macro-scopic
time interval respectively

7.

Select the correct statements(s) :

a). The rate law of the elementary reaction ; 2 A B C , must be r=k[A]2
b). The rate law for the complex reaction
A+B C, might not be r k [ A][ B ]

c). If the partial orders differ from the coefficients in the balanced reaction, the
reaction must be complex
d). If the partial orders are equal to corresponding coefficients in the balanced
reaction, the reaction must be elementary
8.

Select the correct statement(s):

a). Every substance that appears in the rate law of reaction must be a reactant or
product in that reaction
b). If we know the rate law of a reaction; we can deduce its mechanism must be
c). If the reaction has rate r k[ A][ B]3/2 then reaction may be elementary
d). A zero order reaction must be a complex reaction

9.

Consider a reaction A B C , in which both reaction are in the same phase may be
a). unimolecular elementary reaction
b). Exothermic
c). Heterogeneous
d). Photochemical

10.

Identify the true statement(s)

a). A catalyst is chemically unchanged at the end of a reaction
b). A catalyst may appear in the kinetic rate equation of the reaction
c). A catalyst will not affect the composition of an equilibrium mixture
d). A catalyst cannot cause a non-spontaneous (G 0) reaction to proceed

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Sr.IIT-IZ & NIZ-COSPARK_PONGAL WORKSHEET

K1 sec

11.

K 2 sec 1

For the reaction

following graph is given,

k1 =4 x 10-2 sec-1. Which is /are correct statement (s) (ln 2=0.7, ln 8/7=0.14)

a). Equilibrium constant is 4.0

b). Time taken for the completion of 50% of equilibrium conc. B is 14 sec.
c). Time taken for the completion of 10% of initial conc. Of A is 2.8sec.
d). Rate constant of backward reaction is 102 sec1
12.

Select the correct statement(s) :

a). In the reaction 92U 235 0 n1 56 Ba140 2 0n1 x , produced x is
b). In the reaction

11

36

Kr 94

Na 23 +z 12 Mg 23 +0n1 the bombarding particle z is deuteron

c). Very large amount of energy is produced during nuclear fission and nuclear fussion
d). In a fission reaction, a loss in mass occurs releasing a vast amount a energy
13.

Select the correct statement(s):

a). SI unit of radioactivity is Becquerel (Bq)
b). 1 ci=3.7 x 107 Bq
c). 3 Li7 +1H1 2 He4 is ( p, ) type reaction
d). The half-life of a particular radioactive isotope is a characteristics constant of that
isotope

14.

Select the correct statement(s) :

a). On bombarding 7 N14 unclei with - particle, the unclei of the product formed after
release of proton would be 8 O17
b). Decay constant does not depend upon tempareture
c). Nuclide and its decay product after - emission are called isodiaphers
d). Half-life of radium is 1580 years. Its average life will be 1097.22 years

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15.

16.

Sr.IIT-IZ & NIZ-COSPARK_PONGAL WORKSHEET

Select the correct statement (s) for positron emission by unstable uncleus:
a). X-ray emission takes place
b). A neutron is formed
n
c). of daughter uncleus increases
d). A neutron is consumed
p
Select the correct statement (s):
a). Mass number remains constant when positron emission takes place
0

b). One neutron converts into proton in ( 1e) emission process

17.
18.

19.

20.

c). Activity of a radioactive substance double when temp. increase from 300 K
to
310 K
d). Isodiaphers formed when one alpha particle emitted and isotopes formed when 2
beta particles emitted.
Identify the intensive quantities from the following :
a). Enthalpy
b). Temperature
c). Pressure
d). Mass
Which of the following statements is/are correct as per IUPAC sign convention ?
a). The work done by the system on the surrounding is negative
b). The work done by the surrounding on the system is positive
c). The heat absorbed by the system from the surrounding is positive
d). The heat absorbed by the surrounding from the system is positive
In adiabatic process, the work involved during expansion or compression of an ideal
gas is given by :

T P -T P
v
c). -nRPext 2 1 1 2 d). -2.303 RT log 2
V1
P1P2
One mole of an ideal gas is subjected to a two step reversible process
a). nC v T b).

nR
(T2 -T1 )
-1

(A

C ) The pressure at A and C is same . mark the correct statement(S):

B and B

a). Work involved in the path AB is zero

b). In the path AB work will be done on the gas by the surrounding
c). Volume of gas at C=3 x volume of gas at A
d). Volume of gas at B is 16.42 litres

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21.

Sr.IIT-IZ & NIZ-COSPARK_PONGAL WORKSHEET

Which of the following is/are correct?

a). H=U+(PV) when P and V both change
b). H=U+PV when pressure is constant
c). H=U+VP when volume is constant
d). H=U+PV+VP when P and V both changes

22.

23.

24.

For a process to be spontaneous :

a). (Gsystem )T,P =0

b). Ssystem +Ssurrounding >0

c). Ssystem +Ssurrounding <0

d). (Gsystem )T,P <0

When ice melts at 10C :

a). an increase in entropy

b). a decrease in enthalpy

c). a decrease in free energy

d). process is spontaneous

Which of the following statement(s) is /are false ?

a). All adiabatic processes are isoentropic (or isentropic) processes
b). When (G system )T,P <0 ; the reaction must be exothermic
c). dG=VdP-SdT is applicable for closed system, both PV and non- PV work
d). The heat vaporisation of water at 1000C is 40.6 KJ/mol. When 9 gm of water
vapour condenses to liquid at 1000C of 1 atm, then Ssystem =54.42 J/K

25.

From the following data, mark the option(s) where H is correctly written for the
given reaction
Given : H + aq +OH - (aq) H 2O(l);H=-57.3kJ

H solution of HA(g)=-70.7 kJ/mol

H solution of BOH(g)=20 kJ/mol
H ionization of HA=15kJ/mol and BOH is a strong base.

Reaction

H r (kJ/mol)

a). HA(aq)+BOH(aq) BA(aq)+H 2O

-42.3

b). HA(g)+BOH(g) BA(aq)+H 2O

-93

c). HA(g) H+ (aq)+A- (aq)

-55.7

d). B+ (aq)+OH- (aq) BOH(aq)

-20

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