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ELSEVIER
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Abstract
By XANES- and 29Si-MAS-NMR-spectroscopy, evidence has been obtained that commercially available solid silicon
monoxide is not really silicon(II)oxide. Instead, this SiO seems to be a composite of at least two compounds. This is in
contrast to a previous report in this Journal [M. Nagamori, J.-A. Boivin and A. Claveau, J. Non-Cryst. Solids 189 (1995)
270].
E T T E R TO THE EDITOI
. . . .
. . . .
20
. . . .
. . . .
. . . . . . . . . . . .
-20
. . . .
. . . .
-40
. . . .
....
-60
....
....
-80
. . . . . . . .
-liO0
. . . . . . . .
-l~2O
. . . . . . . .
-i140
203
. . . . . . . .
-1~60
. . . . . . . . . . . . .
-liSO
ppm
Fig. 1. 29Si-MAS-NMR-spectrum of commercially available silicon monoxide. The spectrum was performed on a Varian Unity 400 device.
Spinning rate = 6035 Hz, pulse width = 3 /~s, spectrometer frequency = 79.224 Hz, relaxation delay time = 900 s, line broadening = 50 Hz.
Silizium - V e r b i n d u n g e n
on der $ i - K - K o n t e
3.5
3.0
Acknowledgements
2.5
o
2.o
1.5
!/_j//"
0.5
:" J
0.0
1830
1840
18150
Energie
18160
1870
18180
/ eV
References
[1] M. Nagamori, J.-A. Boivin and A. Claveau, J. Non-Cryst.
Solids 189 (1995) 270.
[2] V. Belot, R.J.P. Corriu, D. Leclerq, P. Lef~vre, P.H. Mutin
and A. Vioux, J. Non-Cryst. Solids 127 (1991) 207.
[3] M. Jansen and B. Friede, diploma thesis B. Friede, University
of Bonn (1995).
[4] U. Scubert and G. Donh~irl, diploma thesis G. Donh~irl, University of Wi.irzburg (1994).