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STUDENT NAME :
SECTION A
[15 marks]
Answer all questions in this section
1.
Thermal decomposition of KClO3 yields KCl and O2. When 4.29 g of KClO3 undergo this
reaction, how many grams of oxygen are produced?
A.
1.12 g
2.
The diagram shows the mass spectrum of a sample of zinc. Use the data to calculate
the relative atomic mass of the sample :
B.
0.56 g
C.
2.24 g
D.
1.68 g
50
40
30
20
10
0
64
B.
65.5
65
C.
66
67
A.
65.3
65.8
D.
66.0
3.
Boron has the valence electron of 2s2 2p1. In which order are the electrons lost in
forming the B4+ ion?
1st
2nd
3rd
4th
p orbital
p orbital
s orbital
s orbital
p orbital
s orbital
s orbital
p orbital
p orbital
s orbital
s orbital
s orbital
p orbital
s orbital
s orbital
d orbital
4.
Which of the following statement are based on Bohr's hydrogen atomic theory?
I.
II.
III.
IV.
A.
C.
B.
D.
2
5.
A.
B.
The propanone molecule has a larger surface area than butane molecule.
The covalent bonds in the propanone molecule are stronger than those in the butane
molecule.
There are hydrogen bonds between propanone molecules, but not between butane
molecules.
There are dipole-dipole forces between propanone molecules, but only van der Waals'
forces between butane molecules
C.
D.
6.
In which one of the following pairs do the molecules have similar shapes?
A.
C.
7.
B.
D.
B.
A.
VT/
Volume
/ m3
m 3 oC
Temperature / 0C
Temperature/0C
D.
C.
1/V /
m-3
Volume
/ m3
Low P
High P
Temperature / 0C
T / 0C
8.
A.
B.
C.
D.
3
9.
Iodine reacts with propanone in the presence of dilute acids as represented by the
following equation:
I2 + CH3COCH3 HI + CH3COCH2I.
The graph of the concentration of propanone in the reaction mixture measured at
regular time intervals is given as follows :
[CH3COCH3]
/mol dm-3
x----
x/2 ---------------------------
time / s
Which of the following statements is correct with regard to the reaction above
A.
B.
C.
D.
10.
The initial concentration of a reactant, with a first order reaction, is 0.630 mol dm-3. What
will be its concentration after 3 half lives?
A.
C.
11.
A.
C.
12.
A.
B.
C.
D.
B.
D.
B.
D.
4
13.
The dissociation constant, Ka, for HOI(aq), hypoiodous acid, is 2.3 x 10-11 mol dm-3. What
is the pH of a 0.050 mol dm-3 solution of hypoiodous acid?
A.
C.
2.35
8.03
14.
Which one of the following is the most appropriate chemical indicator to use in the
titration of 0.100 mol dm-3 ammonia solution by 0. 100 mol dm-3 of hydrochloric acid,
HCl (aq)? Given that the titrant in this reaction is HCl (aq).
A.
B.
C.
D.
thymol blue, for which pKInd = 8.8, also H-Ind is yellow and Ind- is blue
methyl orange, for which pKInd = 3.8, also H-Ind is red and Ind- is yellow
thymolphthalein, for which pKInd = 9.9, also H-Ind is colorless and Ind- is blue
cresol red, for which pKInd = 7.9, also H-Ind is yellow and Ind- is red
15.
B.
D.
Boiling point / 0C
of X
5.97
11.65
Boiling point / 0C
of Y
Mol fraction of Y
A.
C.
B.
D.
5
SECTION B
[15 marks]
a)
80
2.40
82
11.70
Define isotopes
83
11.60
84
56.90
86
17.40
[1 mark]
b)
[1 mark]
c)
Calculate the relative atomic mass of krypton using the information above [2 marks]
d)
From the value calculated in (c), determine the pressure of krypton gas produced at
25.00C. Given the density of krypton gas : 3.75 g dm-3.
[3 marks]
6
17.
Boiling point / 0C
120
120
Azeotropic
mixture
100
100
80
80
60
60
0
20
40
60
80
100
The azeotropic mixture between nitric acid and water is at 68.0 % of composition of
nitric acid, which occur at 1200C.
(a)
[2 marks]
.......
.......
(b)
(i)
.......
(ii)
What is the forces of attraction between nitric acid and water, which results the
type of deviation as stated in (b)(i)?
[1 mark]
.......
(iii)
From
om the above graph, determine the vapour composition of the
th distillate when
the following composition by % of nitric acid solution is fractionally distilled for three
times.
[2 marks]
40.0% of nitric acid solution : ...............................................................................................
............................................
70.0% of nitric acid solution : ...............................................................................................
...............................................................................................
(c)
[1 mark]
.......
7
SECTION C
[30 marks]
Answer any 2 questions in this section
18.
Period 3 elements can form different fluoride based compound, for example MgF2, AlF3
and PF3.
a)
Melting point of MgF2, AlF3 and PF3 are described in the table below
Compound
Melting point / 0C
1264
1040
- 22
[4 marks]
Sulphur can also react with fluorine to form sulphur fluoride at different oxidation
states, namely sulphur difluoride, SF2, sulphur tetrafluoride, SF4, and sulphur
hexafluoride, SF6.
i.
Draw the Lewis structures of SF2, SF4 and SF6. Using the valence-shell electron-pair
repulsion theory, deduce the shapes of these molecules.
[9 marks]
ii.
Fluorine and bromine are both elements in Group 17. Explain why SBr6 does not exist.
[2 marks]
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8
19. (a)
State the assumptions made in the kinetic theory of gases, and discuss the validity
of these assumptions for a real gas.
[4 marks]
(b)
Sketch a graph of PV/RT against P for an ideal gas. on the same graph, sketch also,
the curve for ammonia gas and methane gas. Explain the negative deviation of
ammonia and methane
[6 marks]
(c)
A fluoride X is formed when krypton reacts with fluorine. Given that 0.100 g of X
occupies 104 cm3 at 2.00 x 104 Pa and 305 K, what is the relative molecular mass of
X. Hence deduce its molecular formula.
[5 marks]
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9
20.
0.00
2.00
4.00
6.00
8.00
10.00
12.00
14.00
15.00
16.00
18.00
20.00
pH of mixture
2.50
3.00
3.40
3.70
4.00
4.30
4.50
4.70
7.80
10.1
11.2
11.6
(a)
Define pH
(b)
Based on the table above, plot a graph of pH value against the volume of NaOH
added to the mixture
[3 marks]
(c)
(i)
[1 mark]
[2 marks]
[4 marks]
(iii) Using the end-point of the curve, calculate the concentration of lactic acid.
[3 marks]
(iv) Suggest an indicator suitable to be used during the titration, and state the colour
changes occur from the beginning to the end-point, and finally until the end of
experiment
[2 marks]
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10
Solution for Summative Test 1 2015
1.
2.
3.
D
B
C
4.
5.
6.
B
D
A
7.
8.
9.
C
D
B
10. C
11. A
12. A
b) PV/RT
13. B
14. B
15. D
CH4
1--
c)
AR =
AR = 83.90
d) PV = nRT @ P = dRT / MR
P = (3.75 g dm-3 / 1.0 x 10-3) x 8.31 x 298 / 83.90
P = 111 kPa
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
18. a) - MgF2 and AlF3 are hold by ionic crystal lattice [1]
- NF3 is simple covalent molecule hold by weak Van Der
Waals forces
[1]
- Al3+ in AlF3 has higher charge than Mg2+ in MgF2 [1]
- Al3+ has higher polarising power / covalency
[1]
b) - i. Each comparison [1] x 9
[9]
SF2
SF4
SF6
Lewis
P / atm
[2]
- Axis [1] ; ideal gas and CH4 curve
- CH4 is hold by weak Van Der Waals forces
[1]
- causing particles to collide less frequently with the wall
of container as P increase
[1]
- which results PV/RT < 1
[1]
20.(a) pH = -lg [H+] (or using words)
(b) Axis [1] plotting [1] curve [1]
[1]
[3]
14
12
pH
[1]
ideal gas
10
8
6
4
2
No of
2 l.p.e.
1 l.p.e.
lpe &
6 b.p.e
2 b.p.e
4 b.p.e
bpe
Shape
bent
See-saw
Octahedral
[l.p.e : lone pair electron ; b.p.e. : bond pair electron]
ii. Br has large atomic radius / size
[1]
- steric hindrance effect take place in SBr6
[1]
19.(a) Assumptions made are:
-. gas particles have negligible size / volume.
[1]
- gas particles have negligible intermolecular forces of
attraction.
[1]
- collisions of gas particles are perfectly elastic.
[1]
- real gas have significant size or volume, there are
significant intermolecular forces between gas molecules,
[1]
- kinetic energy lost when the gas molecules collide [1]
(c) - PV = nRT @ PV = (m/MR)RT
- (2.00 x 104)(104 x 10-6) = (0.100/MR)(8.31)(305)
- MR = 121.8
Since KrFa ; (83.8) + a (19.0) = 121.8 ; a = 2
molecular formula = KrF2
[1]
[1]
[1]
[1]
[1]
0
0
10
VNaOH / cm3
15
20
[1]
(c) i. 2.50 = - lg [H+] @ [H+] = 10-2.50
- [H+] = 3.16 x 10-3 mol dm-3
[1]
ii. Ka is pH located 1/2 of V at end point
[1]
+
- since the ratio of [H ] / [CH3CH(OH)COO ] (or [acid] /
[salt] is 1 : 1 at 1/2 of V at end point
[1]
- pH at 1/2 V = pKa = 4.0
[1]
- Ka = 1.0 x 10-4 mol dm-3
[1]
iii. CH3CH(OH)COOH + NaOH
CH3CH(OH)COONa + H2O
[1]
M A VA a
M A (25.0)
1
[1]
M B VB
(0.0500)(15.00)