H$moS> Z.

Series OSR/C

Code No.

amob Z.

56/3

narjmWu H$moS >H$mo Cma-nwpVH$m Ho$ _wI-n

>na Ad` {bIo &

Roll No.

Candidates must write the Code on the

title page of the answer-book.

H$n`m OmM H$a b| {H$ Bg Z-n _o _w{V n> 12 h &

Z-n _| Xm{hZo hmW H$s Amoa {XE JE H$moS >Z~a H$mo N>m Cma -nwpVH$m Ho$ _wI-n> na
{bI| &
H$n`m OmM H$a b| {H$ Bg Z-n _| >30 Z h &
H$n`m Z H$m Cma {bIZm ew$ H$aZo go nhbo, Z H$m H$_mH$ Ad` {bI| &
Bg Z-n H$mo nT>Zo Ho$ {bE 15 {_ZQ >H$m g_` {X`m J`m h & Z-n H$m {dVaU nydm
_| 10.15 ~Oo {H$`m OmEJm & 10.15 ~Oo go 10.30 ~Oo VH$ N>m Ho$db Z-n H$mo nT>|Jo
Ama Bg Ad{Y Ho$ XmamZ do Cma-nwpVH$m na H$moB Cma Zht {bI|Jo &

Please check that this question paper contains 12 printed pages.

Code number given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before
attempting it.
15 minutes time has been allotted to read this question paper. The question
paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the
students will read the question paper only and will not write any answer on
the answer-book during this period.

agm`Z {dkmZ (gmpVH$)

CHEMISTRY (Theory)

{ZYm[aV g_` : 3 KQ>o

A{YH$V_ AH$ : 70

Time allowed : 3 hours

56/3

Maximum Marks : 70
1

P.T.O.

gm_m` {ZX}e :
(i)

g^r Z A{Zdm` h &

(ii)

Z-g`m 1 go 8 VH$ A{V bKw-Cmar` Z h & `oH$ Z Ho$ {bE 1 AH$ h &

(iii)

Z-g`m 9 go 18 VH$ bKw-Cmar` Z h & `oH$ Z Ho$ {bE 2 AH$ h &

(iv)

Z-g`m 19 go 27 VH$ ^r bKw-Cmar` Z h & `oH$ Z Ho$ {bE 3 AH$ h &

(v)

Z-g`m 28 go 30 VH$ XrK-Cmar` Z h & `oH$ Z Ho$ {bE 5 AH$ h &

(vi)

Amd`H$VmZwgma bmJ Q>o~bm| H$m `moJ H$a| & H$Hw$boQ>am| Ho$ Cn`moJ H$s AZw_{V Zht h &

General Instructions :
(i)

All questions are compulsory.

(ii)

Questions number 1 to 8 are very short-answer questions and carry

1 mark each.

(iii)

Questions number 9 to 18 are short-answer questions and carry 2 marks

each.

(iv)

Questions number 19 to 27 are also short-answer questions and carry

3 marks each.

(v)

Questions number 28 to 30 are long-answer questions and carry 5 marks

each.

(vi)

Use Log Tables, if necessary. Use of calculators is not allowed.

1.

EH$ Am`{ZH$ R>mog H$s VwbZm _| EH$ Ymdr` R>mog H$m H$moB EH$ {d^oXH$ bjU {b{IE &

Write a distinguishing feature of a metallic solid compared to an ionic

solid.
2.

EOmB_ `m hmoVo h

What are enzymes ?

3.

Eobw{_{Z`_ Ama qOH$ Ho$ EH$-EH$ _wI A`H$ H$m Zm_ {b{IE &
Name the chief ores of aluminium and zinc.

56/3

4.

PCl5 (s) AUw

H$s gaMZm Amao{IV H$s{OE &

Draw the structure of PCl5 (s) molecule.

5.

monZ-2-AmoZ Ama n|Q>Z-3-AmoZ Ho$ ~rM AVa H$aZo Ho$ {bE EH$ OmM {b{IE &

Give a test to distinguish between propan-2-one and pentan-3-one.

6.

Cg EoH$mohmb H$m Zm_ {b{IE {OgH$m {ZZ EQ>a H$mo ~ZmZo _| Cn`moJ {H$`m OmVm h

Name the alcohol that is used to make the following ester :

7.

noQ>mBS> qbHo$O H$mo n[a^m{fV H$s{OE &

Define a Peptide linkage.

8.

hmo_monmbr_a, H$monmbr_a go H$go {^ hmoVm h

How does a homopolymer differ from a copolymer ?

9.

Q>S>S> S>mB gob Ho$ {bE ZoQ> g_rH$aU H$mo {b{IE & Bg g_rH$aU H$m `moJ H$aVo hE `h
XemBE {H$ Cn`moJ H$aZo Ho$ gmW ewH$ gob H$s dmoQ>Vm H$mo KQ>Zm Mm{hE &

Set up Nernst equation for the standard dry cell. Using this equation
show that the voltage of a dry cell has to decrease with use.
10.

EH$ A{^H$maH$ Ho$ gX^ _| EH$ A{^{H$`m {Vr` H$mo{Q> H$s h & `{X Bg A{^H$maH$ H$m
gmU (i) XJwZm hmo OmE (ii) AmYm hmo OmE, Vmo BgH$s A{^{H$`m Xa H$go ^m{dV hmoJr ?

A reaction is of second order with respect to its reactant. How will its
reaction rate be affected if the concentration of the reactant is (i) doubled
(ii) reduced to half ?
56/3

P.T.O.

11.

{ZZ H$_m| _| `oH$ Ho$ AmYma_yb {gmV H$m dUZ H$s{OE :

(i)
NaCN {db`Z Ho$ gmW {gda A`H$ H$mo {Zjm{bV H$aZo go m h E {db`Z go
{gda H$s nwZm{
(ii)
EH$ Aew YmVw H$m {dwV-AnKQ>Zr n[aH$aU

AWdm
{ZZ H$_m| _| `oH$ Ho$ nrN>o Omo H$m`H$mar {gmV h CgH$m dUZ H$s{OE
(i)
YmVw H$m OmoZ (_S>b) n[aH$aU
(ii)

YmVwAm| H$s dmn mdWm H$m n[aH$aU

Describe the underlying principle of each of the following processes :

(i)
Recovery of silver from the solution obtained by leaching silver ore
with a solution of NaCN
(ii)
Electrolytic refining of a crude metal
OR
Describe the principle involved in each of the following processes :
(i)
Zone refining of a metal
(ii)
12.

Vapour phase refining of metals

{ZZ amgm`{ZH$ g_rH$aUm| H$mo nyU H$s{OE

(i)

P4 + SOCl2

(ii)

F2 (A{YH$Vm) + Cl2

300 C

Complete the following chemical equations :

13.

(i)

P4 + SOCl2

(ii)

F2 (Excess) + Cl2

300 C

{ZZ{b{IV Ho$ H$maU ~VbmBE :

(i)
gH$_U YmVwE Ama CZHo$ ~hV go `m{JH$ AN>o CoaH$m| Ho$ $n _| H$m` H$aVo h &
(ii)
gH$_U YmVwE gm_m`V aJrZ `m{JH$ ~ZmVr h &
Assign reasons for the following :

56/3

(i)

Transition metals and many of their compounds act as good

catalysts.

(ii)

Transition metals generally form coloured compounds.

4

14.

{ZZ AmJ{ZH$ hbmoOZ `m{JH$m| H$s gaMZmE {b{IE

(i)

p-~mo_mobmoamo~oOrZ

(ii)

1-bmoamo-4-E{WbgmBbmoh
o goZ

Write the structures of the following organic halogen compounds :

15.

(i)

p-Bromochlorobenzene

(ii)

1-Chloro-4-ethylcyclohexane

(i)

{ZZ `m{JH$m| H$mo jmaH$ gm_` Ho$ ~T>Vo H$_ _| `dpWV H$s{OE
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH Ama CH3NH2
{ZZ `m{JH$m| H$mo pKb _mZm| Ho$ KQ>Vo H$_ _| `dpWV H$s{OE :
C2H5NH2, C6H5NHCH3, (C2H5)2NH Ama C6H5NH2

(ii)
(i)

Arrange the following compounds in an increasing order of basic

strength :
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2

(ii)

Arrange the following compounds in a decreasing order of pKb

values :
C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH2

16.

C^`H$maUr Zm{^H$Zohr (Eop~S>oQ> `ypbAmo\$mBg) `m hmoVo h

n> H$s{OE &

EH$ CXmhaU Ho$ gmW

2

What are ambident nucleophiles ? Explain with an example.

17.

{ZZ ~hbH$m| H$mo m H$aZo Ho$ {bE Omo EH$bH$ Cn`moJ _| bmE OmVo h CZHo$ Zm_ Ama
CZH$s gaMZmE {b{IE :
(i)
~yZm-S
(ii)
ZmBbmZ-6, 6

Write the names and structures of monomers used for getting the
following polymers :

56/3

(i)

Buna-S

(ii)

Nylon-6, 6
5

P.T.O.

18.

`m{JH$m| Ho$ {ZZ `w_m| Ho$ ~rM AVa H$aZo Ho$ {bE EH$-EH$ amgm`{ZH$ OmM Xr{OE
(i)
E{WbEo_rZ Ama Eo{ZbrZ
(ii)
Eo{ZbrZ Ama ~opObEo_rZ

Give a chemical test to distinguish between each of the following pairs of

compounds :

19.

(i)

Ethylamine and Aniline

(ii)

Aniline and Benzylamine

286.65 pm

{H$Zmao (gob) Ho$ {dVma Ho$ gmW Am`aZ H$m H$m` Ho$pV KZr` `y{ZQ> gob
h & Am`aZ H$m KZd 7.874 g cm3 h & Bg gyMZm H$m Cn`moJ H$aVo hE EodmoJmo g`m
H$m n[aH$bZ H$s{OE & (Fe H$m Jm_ na_mpdH$ `_mZ = 55.84 g mol1)

Iron has a body centred cubic unit cell with a cell dimension of
286.65 pm. The density of iron is 7.874 g cm3. Use this information to
calculate Avogadros number (Gram atomic mass of Fe = 55.84 g mol1).
20.

Xmo {^-{^ Vmn_mZm| na {dKQ>Z A{^{H$`m Ho$ {bE k Ho$ _mZ ZrMo {XE JE h
k1 = 2.15 108 L/(mol.s), 650 K na

k2 = 2.39 107 L/(mol.s), 700 K na

A{^{H$`m Ho$ {bE

Ea H$m

_mZ n[aH${bV H$s{OE &

(Log 11.11 = 1.046) (R = 8.314 J K1 mol1)

For a decomposition reaction, the values of k at two different

temperatures are given below :
k1 = 2.15 108 L/(mol.s) at 650 K
k2 = 2.39 107 L/(mol.s) at 700 K
Calculate the value of Ea for the reaction.
(Log 11.11 = 1.046) (R = 8.314 J K1 mol1)
21.

na 0.01 M NaCl {db`Z H$m {VamoY 200 h & `w$ MmbH$Vm-gob H$m gob
pWamH$ EH$ h & {db`Z H$s _moba MmbH$Vm n[aH${bV H$s{OE &
25 C

The resistance of 0.01 M NaCl solution at 25 C is 200 . The cell

constant of the conductivity cell used is unity. Calculate the molar
conductivity of the solution.
56/3

22.

H$maU XoVo hE {ZZ H$s `m`m H$s{OE :

(i)
gH$_U YmVwE XrK namg _| CnM`Z AdWmE X{eV H$aVr h &
(ii)
H$mo~mQ>(II) Obr` Kmobm| _| ~hV WmB h naVw ~b {bJS>m| H$s CnpW{V _|
gabVm go CnM{`V hmo OmVm h &
(iii) bWoZmo`S>m| H$s Anojm EopQ>Zmo`S>| ~hma namg _| CnM`Z AdWmE X{eV H$aVo
h &

Give reasons for the following :

23.

(i)

Transition metals exhibit a wide range of oxidation states.

(ii)

Cobalt(II) is very stable in aqueous solutions but gets easily

oxidised in the presence of strong ligands.

(iii)

Actinoids exhibit a greater range of oxidation states than

lanthanoids.

Cn`w$ CXmhaU XoVo hE `m`m H$s{OE {H$ A{YemofU Ho$ Xmo H$ma Ho$ H$_ (^m{VH$ d
amgm`{ZH$ A{YemofU) {H$g H$ma Vmn_mZ, A{YemofH$ Ho$ n>r` jo\$b Ama g{H$`U
D$Om Ho$ _mZ go ^m{dV hmoVo h ?

AWdm
n> $n go `m`m H$s{OE {H$ A{YemofU H$s n[aKQ>Zm {ZZ _| H$go AZw`moJ nmVr h
(i)

EH$ ~VZ _| {ZdmV nXm H$aZo _|

(ii)

{df_mJr CoaU _|

(iii)

YmVwH$_ _| \o$Z bdZ H$_ _|

Giving appropriate examples, explain how the two types of processes of

adsorption (physisorption and chemisorption) are influenced by the
prevailing temperature, the surface area of adsorbent and the activation
energy of the process ?
OR
Explain clearly how the phenomenon of adsorption finds application in

56/3

(i)

production of vacuum in a vessel

(ii)

heterogeneous catalysis

(iii)

froth floatation process in metallurgy

7

P.T.O.

24.

{ZZ H$mbogm| Ho$

AmKyU ^r Xr{OE :

IUPAC Zm_

(i)

[Co(NH3)5Cl]Cl2

(ii)

[CrCl3 (py)3]

(iii)

K4[Mn(CN)6]

(na_mUw H$_mH$

{b{IE Ama H$mbogm| Ho$ {{d_-agm`Z Ama Mw~H$s`

3

Cr = 24, Mn = 25, Co = 27, py = {n[aS>rZ)

Write down the IUPAC names of the following complexes and also give
stereochemistry and magnetic moment of the complexes :
(i)

[Co(NH3)5Cl]Cl2

(ii)

[CrCl3 (py)3]

(iii)

K4[Mn(CN)6]

(At. Nos. Cr = 24, Mn = 25, Co = 27, py = pyridine)

25.

{ZZ $nmVaU H$go {H$E OmVo h

(i)

monrZ H$mo monZ-2-Amb _|

(ii)

E{Wb_Zr{e`_ bmoamBS> H$mo monZ-1-Amb _|

(iii)

~opOb bmoamBS> H$mo ~opOb EoH$mohmb _|

How are the following conversions carried out ?

26.

(i)

Propene Propan-2-ol

(ii)

Ethylmagnesium chloride Propan-1-ol

(iii)

Benzyl chloride Benzyl alcohol

Amd`H$ Ama AZmd`H$ Eo_rZmo Ab `m hmoVo h ? `oH$ Ho$ Xmo-Xmo CXmhaU Xr{OE &
What are essential and non-essential amino acids ? Give two examples of
each.

56/3

27.

{ZZ Ho$ Cma Xr{OE

(i)

EnmQ>}_ H$m Cn`moJ R>S>o ImZo Ama no`m| _| hr `m| {H$`m OmVm h

(ii)

amoJmUwZm{e`m| go ny{VamoYr H$go {^ hmoVo h

(iii)

H$R>moa Ob _| gm~wZ `m| H$m_ Zht H$aVo h

Answer the following :

28.

(i)

Why is the use of aspartame limited to cold foods and drinks ?

(ii)

How do antiseptics differ from disinfectants ?

(iii)

Why do soaps not work in hard water ?

(a)

{ZZ `m{JH$m| Ho$

(b)

IUPAC

Zm_ {b{IE

(i)

CH3CO(CH2)4CH3

(ii)

Ph CH = CH CHO

{ZZ $nmVaUm| H$m dUZ Amn Xmo MaUm| go A{YH$ Zht _| H$go H$a|Jo
(i)

EWZmb H$mo 3-hmBS>mgr`yQ>Zb _|

(ii)

~oOmoBH$ Ab H$mo

(iii)

monZmoZ H$mo monrZ _|

m-ZmBQ>mo~opOb

EoH$mohmb _|
2, 3

AWdm
(a)

(b)

56/3

{ZZ `m{JH$m| H$s gaMZmE Amao{IV H$s{OE

(i)

4-bmoamon|Q>Z-2-AmoZ

(ii)

p-ZmBQ>momo{nAmo\$sZmoZ

`m{JH$m| Ho$ {ZZ `w_m| _| {^Vm H$aZo Ho$ {bE OmMm| H$mo Xr{OE
(i)

EWZb Ama monZb _|

(ii)

\$sZmb Ama ~oOmoBH$ Ab _|

(iii)

~oOpS>hmBS> Ama EogrQ>mo\$sZmoZ _|

9

2, 3
P.T.O.

(a)

(b)

Write the IUPAC names of the following compounds :

(i)

CH3CO(CH2)4CH3

(ii)

Ph CH = CH CHO

Describe the following conversions in not more than two steps :

(i)

Ethanol to 3-Hydroxybutanal

(ii)

Benzoic acid to m-Nitrobenzyl alcohol

(iii)

Propanone to Propene
OR

(a)

(b)

Draw the structures of the following compounds :

(i)

4-Chloropentan-2-one

(ii)

p-Nitropropiophenone

Give tests to

distinguish between the following

pairs

of

compounds :

29.

(i)

Ethanal and Propanal

(ii)

Phenol and Benzoic acid

(iii)

Benzaldehyde and Acetophenone

(a)

dQ> hm\$ H$maH$ `m hmoVm h

~ZZo _| {dbo` Ho$ AUw
(i)
{dK{Q>V hmoVo h ?
(ii) gJ{R>V hmoVo h ?

(b)

Na2CO3

BgHo$ _mZ {H$g H$ma Ho$ hmoVo h `{X {db`Z Ho$

Ama NaHCO3 Ho$ 1 g {_lU _| XmoZm| nXmWm] H$s g_mZ _moba _mmE
{_br hB h & Bg {_lU Ho$ gmW nyU $n go A{^{H$`m H$aZo Ho$ {bE 0.1 M HCl
{db`Z Ho$ {H$VZo mL H$s Amd`H$Vm hmoJr ?
(_moba `_mZ

: Na2CO3 = 106 g, NaHCO3 = 84 g)

AWdm
56/3

10

2, 3

(a)

n[a^mfm {b{IE :
(i)
_mob ^me
(ii) _mobbVm
(iii) amCQ> H$m {Z`_

(b)

nyU $n go {d`mo{OV _mZVo hE, Cg {db`Z H$m `m{eV {h_mH$ n[aH${bV

H$s{OE Omo 0.100 kg Ob _| bm~a bdU (gmr), Na2SO4 . 10 H2O Ho$
6.00 g H$mo KwbmZo go ~Zm`m J`m hmo &
(Ob Ho$ {bE Kf = 1.86 K kg mol1, na_mUw `_mZ : Na = 23, S = 32,
O = 16, H = 1)

(a)

(b)

3, 2

What is vant Hoff factor ? What types of values can it have if in

forming the solution the solute molecules undergo
(i)

Dissociation ?

(ii)

Association ?

How many mL of a 0.1 M HCl solution are required to react

completely with 1 g of a mixture of Na2CO3 and NaHCO3
containing equimolar amounts of both ?
(Molar mass : Na2CO3 = 106 g, NaHCO3 = 84 g)
OR

(a)

(b)

Define
(i)

Mole fraction

(ii)

Molality

(iii)

Raoults law

Assuming complete dissociation, calculate the expected freezing

point of a solution prepared by dissolving 6.00 g of Glaubers salt,
Na2SO4.10 H2O in 0.100 kg of water.
(Kf for water = 1.86 K kg mol1, Atomic masses : Na = 23, S = 32,
O = 16, H = 1)

30.

56/3

(a)

Cg CH$> Jg nrerO H$m gy {b{IE Ama CgH$s gaMZm H$m dUZ H$s{OE Omo
{ZZ Ho$ gmW g_gaMZm_H$ hmo :

(i)

IBr2

(ii)

BrO3

11

P.T.O.

(b)

(a)

(b)

(a)

(b)

{ZZ Ho$ H$maU {b{IE :

(i)
SF6 J{VH$V {ZpH$` hmoVm h &
(ii) NF3 EH$ D$_mjonr `m{JH$ h O~{H$ NCl3 Eogm Zht h &
(iii) HF H$s Anojm HCl ~bVa Ab h `{n bwAmoarZ bmoarZ H$s Anojm
A{YH$ {dwV-G$Um_H$ h &
AWdm
~S>o n_mZo na A_mo{Z`m H$go ~ZmB OmVr h ? Cg H$_ H$m Zm_ Xr{OE Ama Bg
H$_ mam A_mo{Z`m Ho$ CnmXZ Ho$ {bE AZwHy$bV_ n[apW{V`m| H$m CoI
H$s{OE &
{ZZ Ho$ {bE H$maU {b{IE :
(i)
H2O H$s Anojm H2S A{YH$ Abr` h &
(ii) PH3 H$s Anojm NH3 A{YH$ jmar` h &
(iii) AmgrOZ H$s Anojm g\$a _| mIbZ H$s d{m A{YH$ h &
Write the formula and describe the structure of a noble gas species
which is isostructural with

(i)

IBr2

(ii)

BrO3

Assign reasons for the following :

(i)

SF6 is kinetically inert.

(ii)

NF3 is an exothermic compound whereas NCl3 is not.

(iii)

HCl is a stronger acid than HF though fluorine is more

electronegative than chlorine.
OR

56/3

(a)

How is ammonia prepared on a large scale ? Name the process and

mention the optimum conditions for the production of ammonia by
this process.

(b)

Assign reasons for the following :

(i)

H2S is more acidic than H2O.

(ii)

NH3 is more basic than PH3.

(iii)

Sulphur has a greater tendency for catenation than oxygen.

12

2, 3

2, 3