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aDepartment of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, 373-1
Kusung-dong, Yusung-gu, Taejon, South Korea
bpolymer Composite Research Laboratory, Korea Research Institute of Chemical Technology, 100 Jang-dong,
Yusung-gu, Taejon, South Korea
Received 2 May 1994; in revised form 2 August 1994
Abstract
The crack propagation behaviour during three-point bending of a monolithic A1203 and PMC/AI2OJPMC (where PMC denotes
polymer matrix composite) laminated composites have been investigated. The laminated composites were fabricated by bonding two
PMC layers on both sides of an AI203 plate. Carbon-epoxy and aramid-epoxy composites with two different stacking sequences, i.e.
carbon(0/90)4 (C(0/90)), carbon( + 4 5 / - 45)4 (C( + 4 5 / - 45)), aramid(0/90)4 (A(0/90)) and aramid( + 4 5 / - 45)4 (A( + 4 5 / - 45)), were
laminated with A1203 plate. The total fracture energy of the PMC/AIzO3/PMC laminated composite increased more than two orders
of magnitude compared with that of monolithic AI203.The three-point bending process of the PMC/A1203/PMClaminated composite
could be divided into three regimes related to the crack initiation and propagation. The PMC/AIzO3/PMC laminated composite
deformed elastically in regime I. A crack was initiated and opened in the A1203 layer in regime II, and the outer PMC layer were
deformed without complete debonding at A1203-PMC interface in regime III. The crack initiation stress at AI203 layer is proportional
to the elastic modulus of PMC and the energy absorbed in regime I is the energy for elastic deformation of PMC/AIzO3/PMC
laminated composites. The C(0/90)/A1203/C(0/90 ) and A(O/90)/A1203/A(O/90) composites, in which the laminated PMCs have
higher flexural stress and modulus, fractured by the debonding at the AI203-PMC interface. The C( + 4 5 / - 45)/A1203/C ( + 4 5 / - 45)
and A( +45/- 45)/A1203A( + 4 5 / - 4 5 ) composites, in which the laminated PMCs have lower flexural stress and modulus, did not
debond at the A1203-PMC interface but fractured by the deformation of PMC layer.
1. Introduction
Ceramic materials are attractive for their excellent
resistance to heat and wear with high specific strength
and good oxidation resistance. However, the major
problem of using ceramics as structural materials is
their inherent brittleness. T h e r e have been many
studies on ceramic matrix composites in order to
enhance the toughness through composite toughening
by the addition of reinforcements. Two different kinds
of ceramic matrix composites have been focused on.
Firstly, the fibre-reinforced ceramic matrix composites,
such as S i C - A I 2 0 3 [1], SiC-Si3N 4 [2], C - A 1 2 0 3 [3],
SiC-glass [4] and C-glass [5], exhibited much better
158
[a3].
In this study, the crack propagation behaviour
during three-point bending of a monolithic A1203
specimen and PMC/AlzO3/PMC (where PMC denotes
polymer matrix composite) laminated composite were
investigated. The laminated composites were fabricated by bonding two PMC layers on both sides of
an AI203 plate. Four different laminated composites,
C(0/90)/A1203/C(0/90),
C( + 4 5 / - 4 5 ) /
A1203/C(+45/-45), A(O/90)/AI203/A(O/90 ) and
A( +45/-45)/AI203/A( + 4 5 / - 4 5 ) , where C(0/90)
denotes
carbon(0/90)4,
C(+45/-45)
denotes
carbon( + 45/-45)4, A(0/90) denotes aramid(0/90)4
and A ( + 4 5 / - 4 5 ) denotes aramid( + 4 5 / - 4 5 ) 4 , were
fabricated using two types of prepregs stacked with
different sequences. The crack initiation and propagation characteristics in each layer of the PMC/A1203/
PMC laminated composites were investigated during
three-point bend tests. The effect of a PMC layer on
the crack initiation stress and the crack propagation
mode in PMC/A1203/PMC laminated composites was
discussed. The effect of the properties of PMC layers
on fracture energies of the PMC/AI203/PMC laminated composites was analysed.
2. Experimental details
An epoxy system composed of 100 parts of tetraglycidyl ether of diaminodiphenyl methane (MY720
from Ciba Geigy), 27 parts of 4.4'-diaminodiphenyl
sulphone and 1 part of boron trifluoride monoethyl
amine was formulated to impregnate fibre mats. Two
types of fibre mats, plain woven carbon fabric (6644B
from Toray Industries) and plain woven aramid fabric
(T240 from Teijin), were used. Four plies of the fabrics
were stacked with two different stacking sequences
(0/90)4 and ( + 4 5 / - 4 5 ) 4 . The prepregs were cured in
an autoclave at 120 C for 45 min followed by 170 C
for 2 h. The autoclave pressure was maintained at 0.5
MPa during curing. A vacuum bagging procedure was
employed to cure the prepregs.
PMC/AIzO3/PMC laminated composites were
fabricated by bonding two layers of 1.2 mm thick
PMCs on both sides of 3.8 mm thick A1203 plate using
an adhesive (American Cyanamid FM123-2). Sintered
AI203 plates with purity of 98.5% were used. The cure
condition used to bond PMC with A120 3 plate was
80C for 30 rain followed by 150C for 3 h in
an autoclave. Four different laminated composites
The stress-strain curves obtained from the threepoint bend tests of the monolithic Al203 and PMC/
A1203/PMC laminated composites are shown in Fig. 1.
The monolithic A1203 was deformed elastically to a
maximum stress (flexural strength) and then fractured
catastrophically as shown in Fig. l(a). The laminated
composites exhibited an increased maximum stress and
ductility, which resulted in a marked increase in the
fracture toughness. Figs. l(b)-l(e) show the threepoint bending behaviour of the PMC/AI203/PMC
laminated composites. The three-point bending behaviour of the PMC/A1203/PMC composites was affected
by the type of fibre and the stacking sequences of
prepregs in the PMC. The C(0/90)/A1203/C(0/90 ) and
A(0/90)/AI203/A(0/90 ) composites exhibited catastrophic stress drop after maximum stress, while a
considerable amount of plastic deformation was
observed after maximum stress in the C ( + 4 5 /
- 4 5 ) A 1 2 0 3 / C ( + 4 5 / - 4 5 ) and A ( + 4 5 / - 4 5 ) / A I 2 0 3 /
A( + 4 5 / - 45) composites.
The elastic modulus and the flexural strength of
A1203 and PMCs measured by three-point bend tests
are listed in Table 1. Carbon fibre reinforced PMCs
have a higher elastic modulus and flexural strength
than aramid fibre reinforced PMCs. The elastic
modulus and flexural strength of (0/90) lay-up PMCs
are higher than those of ( + 4 5 / - 45) lay-up PMCs.
The crack propagation behaviour in the PMC/
AIzO3/PMC laminated composites during the threepoint bend tests is shown in Fig. 2. The crack
propagation in the PMC/AIzO3/PMC laminated composites was sensitively affected by the characteristics of
the PMC. A crack was initiated and propagated in the
A1203 layer initially, and then followed by
AI203-PMC interface debonding and plastic deformation of the PMC layer when the crack reached an
0.
400
400
300
300
400
2OO
Io
I O0
ooo' o.oos
'
o.o~o
200
1O0
100 ~
~o.oo
o.o2o
o.os
0.20
'6.00
O.lS
o.zo
Strain, m m / m m
300
0.05
O0.O0
o.io
(c)
i~
oot./
o.os
400
300
O.lS
(b)
,oo[
W
o.1o
Strain, m m / m m
Strain, m m / m m
(a)
lJ
200
' O.OlS
300
G.
Ii
o
159
0.10
0,15
0.20
Strain, m m / m m
'
0 O0 00.05 0.10
0.15
0.20
Strain, m m / m m
(d)
(e)
Fig. 1. The stress-strain curves obtained from three-point bend tests of a monolithic A1203 and PMC/A1203/PMC laminated
composites: (a) monolithic A1203; (b) C(0/90)/A1203/C(0/90); (c)C( +45/-45)/A1203/C ( + 4 5 / - 4 5 ) ; (d) A(0/90)/AI203/A(0/90); (e)
A( + 4 5 / - 45)/A1203/A(+45/-45).
Table 1
The flexural moduli and flexural strengths measured by the three
point bend tests of a monolithic AI203 and four types of polymer
matrix composites
Material
E (GPa)
a (MPa)
AI203
Carbon(0/90) 4
Carbon( +45/-45)4
Aramid(0/90)4
Aramid( +45/-45)4
62
23
10
14
5
143
360
220
240
150
AlzO3/PMC laminated composites deformed elastically in regime I. The load drop at point A is related
to the crack initiation in the A1203 layer of the PMC/
AI203/PMC laminated composite. The strain to the
first load drop at point A was identical; however, the
stress at point A was dependent on the properties of
the PMC as shown in Figs. l(b)-l(e).
The monolithic A1203 fractured catastrophically
after crack initiation, and the crack initiated in the
A1203 layer of the PMC/AlzO3/PMC laminated composite was opened slowly in regime II from point A to
point B in Fig. 1. In regime II, the PMC layers were
deformed elastically and the crack was opened in
A1203 layer of the laminated composites. The crack
opening in the AlzO3 layer was suppressed by the PMC
layers laminated on both sides of the A1203 plate. The
stress increased with strain until the second stress drop
at point B, which is related to the crack initiation in the
PMC layer or debonding at the AI203-PMC interface.
The C(0/90)/A1203/C(0/90 ) and A(0/90)/AI20 fl
A(0/90) composites, in which the laminated PMC has
higher flexural stress and modulus, fractured at point B
by debonding at the A1203-PMC interface, while
the C ( + 4 5 / - 4 5 ) / A 1 2 0 3 / C ( + 4 5 / - 4 5 ) and A ( + 4 5 /
-45)/A1203/A ( + 4 5 / - 4 5 ) composites, in which the
laminated PMC has lower flexural stress and modulus,
] 60
II
.
(a)
I lcm
L~
...................................................................
.
I Icm
(b)
ffflll
. . . . .
m,] .....
1 Icm
,5
.....................
(c)
,.
J,
(d)
.......................
, ,,,,,,,~,, ..........
. . . .
llllll ' ~
..... ~
,' Icm
~ - -
Fig. 2. The crack initiation and propagation processes during three-point bend tests of PMC/AI203/PMC laminated composites: (a)
C(0/90)/A120~/C(0/90); (b) C( + 4 5 / - 45)/A1203/C( +45/-45); (c)A(0/90)/AI2O3/A(0/90); (d) A( + 4 5 / - 45)/AI203/A(+45/-45).
did not fracture at the AI203-PMC interface but exhibited deformation of the PMC layer. Regime Ill from
point B to point C in Fig. l(c) and Fig. l(e) is related
to the deformation of the outer PMC layer without
complete debonding at A1203/PMC interface. It is
suggested that the C(0/90)/A1203/C(0/90 ) and
A(0/90)/AI203/A(0/90 ) laminated composites failed
at the A1203-PMC interface, since the ratio of flexural
strength to tensile stress in the PMC layer is higher
than the ratio of interfacial strength to shear stress at
the AI203-PMC interface. The C( + 4 5 / - 4 5 ) / A 1 2 0 3 /
C ( + 4 5 / - 4 5 ) and A( + 4 5 / - 4 5 ) / A 1 2 0 3 / A ( + 4 5 / - 4 5 )
laminated composites fractured at the PMC layer, since
the ratio of flexural strength to tensile stress in the
PMC layer is lower than the ratio of interracial strength
to shear stress at the AI203-PMC interface.
The three-point bending behaviours of the PMC/
A1203/PMC laminated composites in regime I were
similar, but the peak stress and modulus were depen-
50
161
Load(P)
150
Elastic Modulus
40
Peak stress
ca
o.
~oo
~.
k
(a)
30
-'
"6
Q
20
Or
< oe
so
o
_=
a.
10
69
G9
~D oc
uJ
C(0/90)
C(+45/-45) 1(0/90)
k(+45/.,45)
Types of PMC
G,-
3PL
2
2 bh~
(1)
3 P
(2)
r ' = 4 bh~.,
where P is the applied load, L is the span length, b is
the width of the specimen, h t is the total thickness of
the specimen and h~ is the thickness between the
loading point and AlzO3-PMC interface as shown in
Fig. 4(a). at is the tensile stress acting perpendicular to
the PMC layer, and r~ is the shear stress at the
A1203-PMC interface induced by the applied load P.
o~ and ri increase linearly with different slopes with
increasing applied load as shown in Fig. 4. Once the
crack initiated in the AI203 layer reaches the
AI203-PMC interface, it is observed that the fracture
behaviours of PMC/AlzO3/PMC laminated composites proceeded by two different modes, i.e. fracture
in the PMC layer or debonding at the AIzO3-PMC
interface.
Load(P)
Load(P)
Co)
(c)
162
Table 2
The tensile stresses at the outer polymer matrix composite layer and the shear stresses at AI203-PMC interface of PMC/AI203/PMC
laminated composites at the point B in stress-strain curves in Fig. 1
C(0/90)/A1203/C(0/90)
C( + 45/- 45)/A1203/C( + 45/-- 45)
A(O/90)/AI203/A(0/90)
A( + 45/- 45)/AI203/A( + 45/- 45)
oB(MPa)
rB (MPa)
Fracture mode
243
141
215
96
36
24
32
14
Interface debonding
Fracture of PMC layer
Interface debonding
Fracture of PMC layer
Table 3
The energies absorbed in each regime during three-point
bending of a monolithic AlzO3 and PMC/AleO3/PMClaminated
composites
Energies (kJ m -2)
El
AI203
C(0/90)/A1203/C(0/90)
C( +45/- 45)/A1203/C(+45/-45)
A(O/90)/A1203/A(O/90)
A( + 4 5 / - 45)/AI203/A(+45/-45)
Eli
EIII
13.5
7.4
25.2
5.5
0.2
21.0
1.2
> 30.0
0.5
1.4
1.0
1.1
0.9
4. Conclusions
S.H. Hong et aL
[6]
[7]
[8]
[9]
[10]
References
[1] RE Becher and G.C. Wei, J. Am. Ceram. Soc., 67 (1984)
298.
[2] R.W. Rice, Ceram. Eng. Sci. Proc., 2 (1981) 661.
163
[11]
[12]
[13]