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ALL INDIA OPEN TEST-1 (AIOT-1)

(JEE ADVANCED PATTERN)

Targe t : JEE (Main+Advanced) 2015

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9.

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B.

(ORS)

Use only Black ball point pen only for filling the ORS.

ORS

Write your Roll no. in the boxes given at the top left 8.
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(
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MATHEMATICS

SECTION 1 : (Only One option correct Type)


1:(
)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
8
(A), (B), (C)
(D)
1.

(sin 1, 1) and t1 = (sin1 x)sin

Let x
then
x

(sin 1, 1)

(A) t1 > t2 > t3 > t4


2.

If Areas of triangles

, t2 = (sin1 x)cos

, t2 = (sin1 x)cos

t1 = (sin1 x)sin

(B) t4 > t3 > t1 > t2


OAB,

OBC,

, t3 = (cos 1 x)sin

and t4= (cos 1 x)cos

, t3 = (cos 1 x)sin

t4 = (cos 1 x)cos

(C) t1 > t2 > t4 > t3

,
,

(D) t4 > t3 > t1 > t2

ODC are 1, 3, 6 square units respectively, then the area of

triangle AOD in the figure given below is


OAB, OBC, ODC

1, 3, 6

AOD

(A)

5
2

(B)

3
2

(C) 3

(D) 2

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P1JRAIOT1ADV220215C0-1

MATHEMATICS

PART- I : MATHEMATICS

MATHEMATICS

If exy f(xy) = ex f(x) + ey f(y),

x, y

exy f(xy) = ex f(x) + ey f(y),


(A) e

nx + 1

(B) e

x, y

R+ and f (1) = e, then f(x) is


R+

f (1) = e,
(C) e

nx

f(x)

(D) e x

nx

nx

11

4.

If ninth term in the expansion of

1
log3 (9 x1 7)
3

1
3

(A) 4

(B) 1 or 2

is 660, then the value of x is

1
log3 (3 x1 1)
8

(C) 0 or 1

(D) 3

11

1
log3 (9 x1 7)
3

1
3

(A) 4

5.

(B) 1

nx

Let (k) =
0

1
3

(C) 0

kx k 2

dx (k >0)

(B)

k (k) (1) =

(C) e

x
1

dx, (k >0) and k (k) (1) =

kx k 2
nx

(k) =

(A)

660

1
log3 (3 x1 1)
8

(D) 3

then value of k is

3/2
(D) e

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P1JRAIOT1ADV220215C0-2

MATHEMATICS

3.

6.

7.

Let P be a point on the ellipse x2 + 2y2 = 2 with foci S and S. The locus of incentre of PSS is a
conic of eccentricity
P
x2 + 2y2 = 2
S
S
PSS
(A)

8.

21

(B) 3 2

(C)

2 1

2( 2 1)

(D)

x 1 y 3 z 4
in the plane 2x y + z + 3 = 0 be L. A plane
3
5
2
7x + By + Cz + D = 0 is such that it contains the line L and perpendicular to the plane 2x y+ z + 3= 0,
then find the value of B + 3C + D.
x 1 y 3 z 4
2x y + z + 3 = 0
L
7x + By + Cz + D = 0
3
5
2
L
2x y+ z + 3 = 0
B + 3C + D
(A) 0
(B) 4
(C) 3
(D) 5
Let image of the line

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MATHEMATICS

MATHEMATICS

a2
A hunters chance of shooting an animal at a distance r is 2 (r > a). He fires when r = 2a if he
r
misses, he reloads and fires again when r = 3a. Further if he misses at r = 3a then he tries again at
r = 4a. This process continuous till r = na. If he misses at a distance na, the animal escape. Find
odd against the event that animal is shot
a2
r
(r > a)
r = 2a
r2
r = 3a
r = 3a
r = 4a
r = na
na
"
"
(A) (n + 1) : 2n
(B) (n +1) : (n 1)
(C) (n 1) : 2n
(D) (n 1) : (n + 1)

MATHEMATICS

2 : (

MATHEMATICS

SECTION-2 : (Matrix - Match Type)


)

This section contains 2 questions. Each question contains statements


given in two columns, which have to be matched. The statements in
Column-I are labelled A, B, C and D, while the statements in Column-II
are labelled p, q, r, s and t. Any given statement in Column-I can have
correct matching with ONE OR MORE statement(s) in Column-II. The
appropriate bubbles corresponding to the answers to these questions
have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s
and t; then the correct darkening of bubbles will look like the following :
2

(statements)
(match)

D
t

-I (Column-I)

A, B, C

-II (Column-II)

p, q, r, s

-I (Column-I)

-II (Column-II)

A-p, s

t ; B-q

r; C-p

q;

D-s

t ;

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MATHEMATICS

Column-
(A)

Column-

The number of those tangents to the curve

(p)

(q)

(r)

(s)

(t)

y 2x 4y + 8 = 0 which pass through the point


2

(1, 2) is . Then

(B)

(C)

= lim
x

sin( cos2 x)
x2

, integral multiple of

If greatest value of tan1


then

(D)

is divisible by

1 x
,x
1 x

[0, 1] is

is

is divisible by

If the absolute difference of greatest and least value of


cos1 x2, x

1
2

1
2

, is

k
, then k is less than or equal to
6

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P1JRAIOT1ADV220215C0-5

MATHEMATICS

9.

MATHEMATICS

(A)

y2 2x3 4y + 8 = 0

= lim
x

(q)

(r)

(s)

(t)

(1, 2)

(B)

(p)

sin( cos2 x)
x2

1 x
,x
1 x

(C)

tan1

(D)

cos1 x2, x

k
6

[0, 1]

1
2

1
2

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P1JRAIOT1ADV220215C0-6

MATHEMATICS

MATHEMATICS

Column - I

Column - II
y

[tan1 x]dx
(A)

= lim

If

1
y

1
1
dx
x

+ 3 is divisible by

(p)

(q)

(r)

(s)

(t)

([.] represents greatest integer function) is

(B)

If tan1

1 x2 1
: tan1 x = a : 1
x

then 2a is greater than or equal to

(C)

(D)

lim

x 2 .sin(x!)
is less than or equal to
(x 1)

The number of real solution of the equation

1 cos 2x = 2 sin1 (sin x),


Integral multiple of

is .

is

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P1JRAIOT1ADV220215C0-7

MATHEMATICS

10.

MATHEMATICS

-
y

[tan1 x]dx
= lim

(A)

1
y

1
1
dx
x

([.]

+3

(p)

(q)

(r)

(s)

(t)

tan1

(B)

1 x2 1
: tan1 x = a : 1
x

2a

(C)

(D)

lim

x 2 .sin(x!)
(x 1)

1 cos 2x =

2 sin1 (sin x),

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P1JRAIOT1ADV220215C0-8

MATHEMATICS

SECTION 3 : (Integer value correct Type)


3:(
)
This section contains 8 questions. The answer to each question is a Single digit integer, ranging
from 0 to 9 (both inclusive).
8
0 9
11.

Q) satisfying 4 x 3

The value of x(x

4x 3

1
2

= 3

1
2

1
2

22x 1

= 3

1
2

22x 1 , is p, then value of 6p is


x(x

Q)

6p

12.

If a + b = 3 cos 4 and a b = 4 sin 2 , then find maximum value of ab.


a + b = 3 cos 4
a b = 4 sin 2 ,
ab

13.

Let a and b be unit vectors that are perpendicular to each other, then box product

14.

a b

a b

a b is equal to
a

a b

a b

a b

A point D is taken on the side AC of an acute triangle ABC, Such that AD = 1, DC = 2 and BD is an
altitude of ABC. A circle of radius 2, which passes through points A and D, touches the
N2
circumcircle of triangle BDC at point D. If area of ABC is N, then the value of
.
15
ABC
AC
D
AD = 1, DC = 2
BD, ABC
2
A
D
BDC
D
ABC

N2
15

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P1JRAIOT1ADV220215C0-9

MATHEMATICS

MATHEMATICS

15.

The sequence { an } is defined by ak + 1 =

1
1
1
1
+ ak, a1 =
and P =
.
..........
2
a1 1 a2 1
a100 1

(where [.] the greatest integer function). The value of P + 4 is


1
2
1
1
1
{ an }
ak + 1 = ak + ak, a1=
P=
.
..........
2
a1 1 a2 1
a100 1
(

16.

[.]

Let 2
2

17.

).

+6
2

+6

+5

+5

= 1, where
2

= 1,

P+4

R. Then maximum value of (2


R

(2

1) is

1)

If z1, z2, z3 are the vertices of an equilateral triangle inscribed in the circle |z| = 1 then find square
of area of quadrilateral formed by z1 , z2 , z3 , z2 .
z1, z2, z3

18.

|z| = 1

z1 , z2 , z3 , z2

A pair of fair dice is rolled together till a sum of either 5 or 7 is obtained. If P denotes the probability
that 7 comes before 5, find 5P.
5
7

5P

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P1JRAIOT1ADV220215C0-10

MATHEMATICS

MATHEMATICS
2
ak

PHYSICS

SECTION-1 : (Only One option correct type)


1 : (
)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
8
(A), (B), (C)
(D)

19.

In the circuit shown in the figure key k1 is open. The charge on capacitor C in steady state is q1.
Now the key is closed and at steady state charge on C is q2. The ratio of charges q1/q2 is
k1
C
q1
C

q2

K1

R1 = 2

E
(A) 5/3
20.

q1/q2

R2 = 3

(B) 3/5

(C) 1

(D) 2/3

A ray is incident normally on face AC of a right angled prism as shown in the figure. The total
deviation in the path of this ray as it emerges out of the prism is :
AC
A

Space for Rough Work / 45


(

=2
C

(A) 120

(B) 0
Space for Rough Work / (

(C) 180

(D) 150
)

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PHYSICS

PART - II : PHYSICS

21.

An ac circuit consists of L(XL = 7 ), R = 4 and C(XC = 4 ) in series. The potential difference


across R and C is V1 and that across L, C and R is V2.The phase angle between V1 and V2 is :
L(XL = 7
V1
(A) 45

22.

L,C

), R = 4

V2

(B) 82

C(XC = 4
V1

V2

(C) 98

C
:

(D) 53

In the circuit shown, after sufficiently long time in position 1 of the switch, so that current is steady
in the circuit, the switch is changed over to position 2. the maximum voltage that can be develop
across L.
1
2

(A) 100 V
23.

(B) 100 2V

(C) 100 5V

(D) 200 V

Two identical bricks of length L are piled one on top of the other on a table as shown in the figure. The
maximum distance S the top brick can overhang the table with the system still balanced is:
L
S

L
Space for Rough Work / (

S
(A)

1
L
2

(B)

2
L
3

Space for Rough Work / (

(C)

3
L
4

(D)

7
L
8

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P1JRAIOT1ADV220215C0-12

PHYSICS

PHYSICS

A long plank of mass M is initially at rest on a frictionless surface. A small block with mass m and
initial speed u0 slides on top of the larger plank. The coefficient of friction between the block and
plank is . Net work done by friction on system if the top block falls off the plank after sliding over its
length L is
M m
M
gL
gL
(A) mgL
(B)
(C)
(D) MgL
M
M m

u0
M
L

m
u0
L

(A) mgL
25.

M m
gL
M

(B)

M
gL
M m

(C)

(D) MgL

A girl throws a ball with an initial velocity v at an angle of 45. The ball strikes a smooth vertical
wall at a horizontal distance d from the girl and after rebound returns to her hands. What is the
2
coefficient of restitution between wall and ball ? (v > dg)
v
45
d
2

(v > dg)
(A)
26.

v2

gd
gd

(B)

gd
v gd
2

(C)

gd
v2

(D)

v2
gd

An ideal organ pipe resonates at successive frequencies of 50 Hz, 150 Hz, 250 Hz, etc.
(speed of sound = 340 m/s) The pipe is
(A) open at both ends and of length 3.4 m
(B) open at both ends and of length 6.8 m
Space for Rough Work / (
)
(C) closed at one end, open at the other, and of length 1.7 m
(D) closed at one end, open at the other, and of length 3.4 m
50 Hz, 150 Hz, 250 Hz,
(
= 340 m/s)
(A)
3.4 m
(B)
6.8 m
(C)
1.7 m
(D)
3.4 m
Space for Rough Work / (

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P1JRAIOT1ADV220215C0-13

PHYSICS

PHYSICS

24.

PHYSICS

2 : (

PHYSICS

SECTION-2 : (Matrix - Match Type)


)

This section contains 2 questions. Each question contains statements


given in two columns, which have to be matched. The statements in
Column-I are labelled A, B, C and D, while the statements in Column-II are
labelled p, q, r, s and t. Any given statement in Column-I can have correct
matching with ONE OR MORE statement(s) in Column-II. The appropriate
bubbles corresponding to the answers to these questions have to be darkened as illustrated in the
following example. If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t;
then the correct darkening of bubbles will look like the following :
(statements)

2
(match)

-I (Column-I)
-II (Column-II)

A, B, C

p, q, r, s

-I (Column-I)

-II

(Column-II)
A-p, s
q;

D-s

t ; B-q

r; C-p

t ;

Space for Rough Work / (

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27.

A circular wire lying in the X Y plane has charge density = 0 sin ( 0 is positive). Points A, B,
C and D are shown in the figure. Point E lies on Z axis above origin. Match the description in
Column with the points in Column .

Column

Column

(A) Direction of electric field is along j

(p) A

(B) Direction of electric field is along j


(C) Potential is zero (taking infinity as reference)
(D) Potential is positive (taking infinity as reference)

(q) B
(r) C
(s) D
(t) E

A,B, C

= 0 sin
E, Z

XY

Space for Rough Work / (

(A)

(p) A

(B)

(q) B

(C)
(D)

)
)

Space for Rough Work / (

(r) C
(s) D
(t) E
)

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PHYSICS

PHYSICS

28.

Entries in column-I describe quantities x and y and certain change in physical situation. Match
these entries to all possible entries in column-II describing corresponding changes in x and y.
Column-I
Column-II
(A) If radius of capillary tube is decreased
(p) x increases
x = mass of liquid rising in a capillary tube of sufficient length
y = height of liquid rising in a capillary tube of sufficient length
(B) If the spring is replaced by a smaller piece of same spring to
(q) x decreases
keep a block at rest

x = extension of spring supporting the block at rest in equilibrium


y = elastic potential energy stored in the spring
(C) If oscillation amplitude is increased from 1 to 2
x = Time period of simple pendulum
y = Oscillation energy of simple pendulum
(D) A sphere is projected vertically downwards with speed more than
terminal speed then as time passes
x = Magnitude of acceleration of the sphere
y = viscous force on the sphere.
-I

(r) x remains unchanged


(s) y increases
(t) y decreases

-II

-I

-II

(A)

(p) x
x=
y=

(B)

(q) x
Space for Rough Work / (

x=
y=
(C)

(r) x

x=
y=
(D)

(s) y
x=
y=

(t) y
Space for Rough Work / (

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P1JRAIOT1ADV220215C0-16

PHYSICS

PHYSICS

SECTION-3 : (Integer value correct Type)


3 : (
)
This section contains 8 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive)
8
0 9
29.

Monochromatic light of wavelength passes through a pair of slits S1 and S2, separated by a
distance equal to fringe width . There is a screen placed at a distance D in which two parallel slits

S1 and S 2 are cut at the positions of 3rd and 4th maxima. Again there is a screen at a distance

D. P is a point at a distance of
from the central line of the first pair of slits S1 and S2 ,, while Q
2
is on the central line of the second pair of slits

S1 and S 2 . All slits are of same widths. If the


x
intensity of light at the point P is and the intensity at Q is
, then find the value of x.
4
S1

S2

S1

S2

S1

S2

Q,

S1

S2

x
4

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P1JRAIOT1ADV220215C0-17

PHYSICS

PHYSICS

A large open tank is filled with water upto a height H. A small hole is made at the base of the tank.
H
It takes T1 time to decrease the height of water to
(n > 1) and it takes T2 time to take out the
n
remaining water. If T1 = T2, then the value of n is :
H
H
(n > 1)
T1
T2
n
T1 = T2
n
:

31.

A 1kg ball is suspended in a uniform electric field with the help of a string fixed to a point. The ball
0

is given a charge 5 coulomb and the string makes an angle 37 with the vertical in equilibrium
position. In the equilibrium position the tension is double the weight of the ball. Find the magnitude
of the electric field in N/C.
1kg
0

32.

37

Uniform magnetic field 5T exists in a circular region of radius 1m. A particle having specific charge
q
enters the region with velocity v0 as shown. v0 is such that the particle passes through the
m
q
center O of the region. If V0 =
p , then find the value of p. [Assume = 30]
m
q
5T
1m
v0
m
v0
O
q
= 30]
V0 =
p
p Space for Rough
[ Work
/(
)
m

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P1JRAIOT1ADV220215C0-18

PHYSICS

PHYSICS

30.

33.

A sphere P(emissivity =1) of radius 2R and another sphere Q (emissivity =1/2) of radius R are
placed in vacuum at some distance. There are no other objects. The temperature of the sphere Q
is maintained at 200K by the means of a heater. A fraction 1/32 of the power emitted by the
sphere Q falls on the sphere P. If the equilibrium temperature of the sphere P is 10 T, find the
value of T.
2R
P (
=1)
R
Q(
=1/2)
Q
Q
,

34.

1/32

200K
P

10 T

A block of mass m is released on a smooth inclined wedge of inclination 30 and mass M. Height
2
of the block (from ground) varies with time as h = 1.5 1.5t . (h in metre and t = time in second).

x
2
m/s . Find the value of x :
3

The acceleration of M is
M

30

m
h = 1.5 1.5t

x
2
m/s
3

(h

t=

Space for Rough Work / (


Space for Rough Work / (

)
)

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P1JRAIOT1ADV220215C0-19

PHYSICS

PHYSICS

PHYSICS

An ideal gas has adiabatic exponent . In a process its molar heat capacity varies with temperature
as C =
W=

. Work performed by one mole of gas during its heating from T0 to nT0 is given by

n5

4RT0
then find the value of n.
1
C =
T0

W=

36.

n5

4RT0
1

nT0
n

A soap bubble of radius R is surrounded by another soap bubble of radius 2R, as shown. Take
surface tension = S. The pressure inside the smaller soap bubble, in excess of the atmospheric
nS
pressure is
, then find the value of n.
R

Atmosphere
R

2R

nS
R

= S

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P1JRAIOT1ADV220215C0-20

PHYSICS

35.

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION 1 : (Only One option correct Type)
1:(
)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
8
(A), (B), (C)
(D)
37.

Fe(+III) and Ru(+III) form basic acetates of the type [Fe3O(CH3COO)6(H2O)3] .


The structure consists of a triangle of three Fe atoms with an O atom at the centre. The six acetate
groups act as bridges between the Fe atoms, two groups across each edge of the triangle. Thus
each Fe atoms is linked to four acetate groups and the central O and the sixth position of the
octahedron is occupied by water or another ligand. Spin only magnetic moment of
+

[Fe3O(CH3COO)6(H2O)3] per octahedral unit is :

Space for Rough Work / (


(A) Zero

(B) 1.73 BM
Space for Rough Work / (

)
(C) 4.9 BM

(D) 5.9 BM
)

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P1JRAIOT1ADV220215C0-21

CHEMISTRY

PART III : CHEMISTRY

CHEMISTRY
+

Ru(+III), [Fe3O(CH3COO)6(H2O)3]

CHEMISTRY

Fe(+III)

Fe
Fe
Fe

th

(A)

[Fe3O(CH3COO)6(H2O)3]

(B) 1.73 BM

Space for Rough Work / (

(C) 4.9 BM

(D) 5.9 BM

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P1JRAIOT1ADV220215C0-22

CHEMISTRY

What is difference in the density (in gram/litre) of dry air at 1 atm and 27C and moist air with
relative humidity 40% under same condition. Given that the vapour pressure of water is 19 torr at

1

atm mol K ]
12

27C and dry air has 80% N2 and 20% O2 by volume. [Take R =
27C

1 atm
(

80% N2

40.

27C

20% O2

(A) 2.32 10
39.

40%

[
3

g/L

(B) 6.24 10

g/L

19
R=

1

atm mol K ]
12
3

(C) 1.64 10 g/L

(D) 4.32 10 g/L

Which reaction is possible ?

(A) MgCl2 (aq) + NaNO3 (aq)

(B) BaCO3 (s) + CH3COOH (aq)

(C) BaSO4 (s) + HCl(aq)

(D) CoCl2 (aq) + H2S(aq) + HCl (aq)

A real gas obeys the equation P(Vm b) = RT, where b = 0.1 L/mol. If 2 mole of gas is slowly
compressed from 1.2 L to 0.6 L at a constant temperature of 300 K, calculate the work done by the
gas in this process.
P(Vm b) = RT
2

(A) 4.59 KJ

1.2 L

b = 0.1 L/mol

300 K

0.6 L

(B) 3.65 KJ

Space for Rough Work / (

(C) 5.35 KJ

(D) Zero

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P1JRAIOT1ADV220215C0-23

CHEMISTRY

38.

CHEMISTRY

Which of the following statements is incorrect ?


(A) CH3COCH3 & CHCl3

Hsolution < 0 & Vsolution < 0

(B) When mercuric iodide is added to an aqueous solution of potassium iodide then freezing point
of KI solution is raised and its boiling point is lowered.
(C) NaCl is less soluble in acetone than H2O.
(D) H2O and (CH3)3OH

(A) CH3COCH3

CHCl3

Hsolution < 0 & Vsolution < 0

<0

<0

(B)

KI

(C) NaCl, H2O


(D) H2O

42.

(CH3)3OH

<0

<0

(i) S8 + NaOH(aq)

(ii) SF4 + H2O(l)

(iii) Na2S2O3 + HCl(aq)

(iv) H2S(aq) + SO2(g)

Which of the above reactions give one of the product as precipitate?


(A) (i) only

(B) (i) and (iii)

(C) (iii) and (iv)

(D) (ii) and (iv)

(A)

(B) (i)

(C) (iii)

(D) (ii)

(i)

(iii)

Space for Rough Work / (

(iv)

(iv)

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P1JRAIOT1ADV220215C0-24

CHEMISTRY

41.

CHEMISTRY

CHEMISTRY

CONH2
43.
Which statement is incorrect :
(A) Reduced product of P and Q will be metamers to each other.
(B) By dry distillation of hydrolysed products of P with Ca(OH)2, gives benzophenone.
(C) Hydrolysed product of Q, reacts with NaNO2 + HCl followed by reaction with phenol, gives
orange red dye.
(D) Electrophile involved in the formation of Q is dichlorocarbene.

(A) P

(B) P
(C) Q

Ca(OH)2
NaNO2 + HCl

(D) Q

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P1JRAIOT1ADV220215C0-25

CHEMISTRY

Match each of the following four structures with one of the compounds AD on the basis of the
following experimental facts. Compounds A, B and C are optically active, but compound D is not.
Compound C gives the same products as compound D on treatment with periodic acid, but
compound B gives a different product. Compound A does not react with periodic acid.
A-D
A, B

CH2OCH3

CH2OH

CHOCH3
(I)

CHOH

(II) H

OH

OH

(III) HO

CH2OCH3

CH2OCH3

CH2OCH3

CH2OCH3

OH

CHOCH3
(IV)

CHOH
CH2OH

CH2OCH3

Choose the correct match :

(A) A III ; B II ; C I ; D IV

(B) A III ; B I ; C IV ; D II

(C) A I ; B IV ; C III ; D II

(D) A I ; B IV ; C II ; D III

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P1JRAIOT1ADV220215C0-26

CHEMISTRY

44.

SECTION - 2
Matrix - Match Type
This section contains 2 question. Each question contains statements given in
two columns, which have to be matched. The statements in Column-I are
labelled A, B, C and D, while the statements in Column-II are labelled p, q, r, s
and t. Any given statement in Column-I can have correct matching with ONE
OR MORE statement(s) in Column-II. The appropriate bubbles corresponding
to the answers to these questions have to be darkened as illustrated in
the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct
darkening of bubbles will look like the following :

-2
2

(statements)

(match)

A, B, C

-I (Column-I)

p, q, r, s

-II (Column-II)
-I (Column-I)

A-p, s

t ; B-q

D
t

-II (Column-II)

r; C-p

q;

Space for Rough Work / (

D-s

t ;

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P1JRAIOT1ADV220215C0-27

CHEMISTRY

CHEMISTRY

CHEMISTRY

Match the column :


Columnn

Columnn

(A) [CoF6]

(p) Hybridisation of central atom involving

penultimate

d-orbital(s)
3

(B) [Co(C2O4)3]

(q) Paramagnetic

2+

(C) [Cu(NH3)4]

(r) Chelating ligand

(D) [RhC (PPh3)3]

(s) Central atom belonging to 5d series.


(t) One of the d-orbital used in hybridisation of central
2 2
y

atom is dx
:

(A) [CoF6]

(p)

(penultimate)
d-

(B) [Co(C2O4)3]

2+

(q)

(C) [Cu(NH3)4]

(r)

(D) [RhC (PPh3)3]

(s)

5d

(t)

Space for Rough Work / (

d-

2 2
y

dx

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P1JRAIOT1ADV220215C0-28

CHEMISTRY

45.

CHEMISTRY

Columnn

Columnn

(Reaction)

(Stereochemistry of product)

CH3CH2

CH3

Pt

Bayers reagent

(B)
D

(p) stereoselective

(q) stereospecific

(i) BH3/THF

(C)
CH3

(D)

H2

C=C

(A)

CH3

CH 3

CH2CH3
C=C

(r) syn addition

(ii) H2O2/OH

Br 2
CCl4

(s) anti addition

(t) meso compound

Space for Rough Work / (

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P1JRAIOT1ADV220215C0-29

CHEMISTRY

46.

CHEMISTRY

CH3CH2

CH3

H2

C=C

(A)

CHEMISTRY

Pt

(B)

(p)

(q)
D

(i) BH3/THF

(C)

CH3

CH 3

(D)

CH2CH3
C=C

(r)

(ii) H2O2/OH

CH3

Br 2
CCl4

(s)

(t)

Space for Rough Work / (

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P1JRAIOT1ADV220215C0-30

SECTION 3 : (Integer value correct Type)


3:(
)
This section contains 8 questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive).
8
0 9
47.

How many of the following give colourless gas/gases with conc. H2SO4 :
H2SO4

48.

H2C2O4,

NaCl,

K,

HCOOH,

KClO3,

Na2CO3

KBr,

Na3PO4,

K4[Fe(CN)6]

It is observed that the voltage of a galvanic cell using the reaction M(s) + xH

x+

M +

x
H2
2

varies linearly with the log of the square root of the hydrogen pressure and the cube root of the M

x+

concentration. The value of x is :


M(s) + xH

x+

log

x
H2
2

x+

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P1JRAIOT1ADV220215C0-31

CHEMISTRY

CHEMISTRY

CHEMISTRY

Solid BaF2 is added to a solution containing 0.1 mole of sodium oxalate solution (1 litre) until
6

equilibrium is reached. If the Ksp of BaF2 and BaC2O4(s) is 10

& 10

respectively. Assume

addition of BaF2 does not cause any change in volume and no hydrolysis of any of the cations or

116 = 10.77)

anions. (Given :

2+

If concentration of Ba

ions in resulting solution at equilibrium is represented as 2.7 10 , then x

is :
0.1

(1

BaC2O4(s)

Ksp

10

)
7

10

BaF2
BaF2
(

2+

116 = 10.77)

Ba

50.

BaF2

2.7 10 ,

Consider the following chemical reaction and the corresponding kinetic data showing the initial
reaction rate as a function of the initial concentrations of the reactants :
+

H3AsO4(aq) + 2H3O (aq) + 3I-(aq)


-5

Initial Rate 10 (M/sec)

HAsO2(aq) + I3-(aq) + 4H2O(liq)


+

[H3AsO4]

[H3O ]

[I-]

3.7

0.001

0.01

0.10

7.4

0.001

0.01

0.20

7.4

0.002

0.01

0.10

3.7

0.002

0.005

0.20

Using the data, establish the correct reaction composite order.

Space for Rough Work / (

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P1JRAIOT1ADV220215C0-32

CHEMISTRY

49.

H3AsO4(aq) + 2H3O (aq) + 3I-(aq)


-5

10 (M/sec)

51.

CHEMISTRY

CHEMISTRY

HAsO2(aq) + I3-(aq) + 4H2O(liq)


+

[H3AsO4]

[H3O ]

[I-]

3.7

0.001

0.01

0.10

7.4

0.001

0.01

0.20

7.4

0.002

0.01

0.10

3.7

0.002

0.005

0.20

How many of the following involves carbon reduction during extraction of metal from ore?
Bauxite

Al

Copper pyrites

Galena

Pb

Carnallite

Zinc blende

Cassiterite

Sn

Al

Cu ;
Mg
Zn

Pb

;
Sn

Mg

Zn

Space for Rough Work / (

Haematite

Sylvine

Silica

Fe
K
Si

Cu ;

Fe

Si

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P1JRAIOT1ADV220215C0-33

CHEMISTRY

How many of the following statements are correct?


(1) Soap acts as emulsifier in its cleansing action
(2) Bredigs arc method is particularly suitable for preparing sulphur sol.
(3) Coagulation of sol can be caused by electrophoresis.
(4) Greater is the zeta potential, greater is the stability of colloid.
(5) Methylene blue sol is a negatively charged sol whereas TiO2 sol is a positively charged sol.

CHEMISTRY

52.

(1)
(2)
(3)
(4)
(5)

53.

TiO2

A six membered cyclic compound A (C7H14O) gives instant turbidity with lucas reagent and forms a
compound B. B on reaction with alcoholic KOH gives major product C. C on reductive ozonolysis
gives D. D in aq. alkali medium forms an
unsaturated carbonyl compound E. Find the sum of
ring size (if any) and degree of unsaturation (hydrogen deficency index) of E.
A (C7H14O)
B
D

KOH
D

Space for Rough Work / (

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P1JRAIOT1ADV220215C0-34

CHEMISTRY

Consider the figure :

mixture
of amino
acids

CHEMISTRY

54.

separation
of amino
acids

filter paper
Buffer solution
(pH = 5.0)

Buffer solution
(pH = 5.0)

(After Electrophoresis)

(Electrophoresis)

pKa Values
S.No.

Amino acids

side chain

1.

Arginine

2.17

9.04

12.48

2.

Alanine

2.34

9.69

------

3.

Aspartic acid

2.09

9.82

3.86

4.

Lysine

2.18

8.95

10.79

Glutamic acid

2.19

9.67

4.25

6.

Valine

2.32

9.62

------

Calculate :
Spaceamino
for Rough
Work
/(
Number of non essential
acids move
towards
cathod = x

Number of essential amino acids move towards anode = y


Number of amino acids move towards cathod = z
FIND

x+y+z=?
Space for Rough Work / (

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P1JRAIOT1ADV220215C0-35

CHEMISTRY

CHEMISTRY

(pH = 5.0)

(pH = 5.0)

Space for Rough Work / (

)
=x
=y
=z

x+y+z=?
Space for Rough Work / (

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P1JRAIOT1ADV220215C0-36

P A P E R -1

CODE - 0
IMPORTANT INSTRUCTIONS /

C.

Question Paper Format

C.

The question paper consists of three parts


(Mathematics, Physics and Chemistry). Each part
consists of three sections.
14. Section 1 contains 8 multiple choice questions. 14.
1
Each question has Four choices (A), (B), (C) and (D)
(B), (C)
out of which only ONE is correct.

(A),

8
(D)

15. Section 2 contains 2 question. Each question 15.


2
2
contains statements given in two columns which have
(statements)
to be matched. Statements in Column I are labelled
(Column-I)
as A, B, C and D whereas statements in Column II
are labelled as p, q, r, s and t. The answers to these
questions have to be appropriately bubbled as
illustrated in the following example.
16. Section 3 contains 8 questions. The answer to each 16.
question is a single-digit integer, ranging from 0 to 9
(both inclusive).

(match)
(A, B, C, D)
(p, q, r, s, t)

(Column-II)

D. Marking Scheme
D.
17. For each question in Section 1, you will be awarded
17.
3 marks if you darken the bubble corresponding to
only the correct answer and zero mark if no bubbles
are darkened. In all other cases, minus one (1)

1
(BUBBLES)

3
(0)

mark will be awarded.

(1)

18. For each question in Section 2, you will be awarded 18.


3 marks for each row in which you have darkened the

2
3

bubble corresponding to the correct answer. Thus,


each question in this section carries a maximum of
12 marks. There is no negative marking for incorrect

12

answer(s) in this section.


19. For each question in Section 3, you will be awarded 19.
3 marks if you darken the bubble corresponding to
only the correct answer and zero mark if no bubbles
are darkened. There is no negative marking for

3
(BUBBLES)

3
(0)

incorrect answer(s) in this section.

Name of the Candidate (

):

Roll Number (

):

I have read all the instructions and shall


abide by them

I have verified all the information filled by


the candidate.

......................................
Signature of the Candidate

......................................
Signature of the Invigilator

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