Chapter Practice Problems

CHENNAI CENTRE
Subject: Chemistry
NAME:

FIITJEE

Topic: Liquid Solutions - 1

1.

The Vant Hoff factor i for CaCl2 in an aqueous solution 2.8. The degree of dissociation of CaCl2 in this solution is
(a) 0.85
(b) 0.90
(c) 0.80
(d) 0.95

2.

XA in a binary liquid mixture of two substances A and B is 0.3. Its vapour pressure is 80 torr. Vapour pressure of pure
B is 100 torr. Vapour pressure of pure A = __________ torr
(a) 33
(b) 50
(c) 66
(d) 25

3.

A mixture of benzene and toluene with Xbenzene = 0.4 behaves ideally and has a vapour pressure of 46 torr. P o of
benzene = 75 torr Xbenzene in the vapour phase = __________
(a) 0.65
(b) 0.27
(c) 0.75
(d) 0.35

4.

A 0.01M complex of CoCl3 and NH3 ( I molal ratio 1 : 5) has a freezing point of 0.0558C. K
1.86 K molal1. Formula of the complex is:
3
(a) CoCl6
(b) Co NH 3 4 Cl2 Cl (c) Co NH3 5 Cl Cl 2
(d) Co NH3 3 Cl3

5.

A dilute solution of a non-volatile non-electrolyte (MW = 60) in 94.5g of benzene shows a lowering a of vapour
pressure of 1.3mm Hg form 100mm and freezes at 0.847C lower than the freezing point of pure benzene. Calculate
the Kf of benzene (K.molal1)
(a) 2
(b) 3
(c) 4
(d) 5

6.

A 0.2m solution of a weak acid HX in water is 20% ionized. Kf of water = 1.86K.molal1. Freezing point of the
solution is ________ C.
(a) 0.45
(b) 0.90
(c) 0.35
(d) 0.53

7.

Two liquids A and B form an ideal solution for which at a given temperature the vapour pressure P (mm) = 120 x + 135,
where x: mole fraction of A in the solution. PA / PB _______ .
(a) 8 : 9
(b) 9 : 8
(c) 17 : 9
(d) 18 : 17

8.

Two liquids A and B have vapour pressures in the ratio 1 : 2 at a certain temperature T. X A in the vapour phase on a
solution of A and B with XA = 1/3 at this temperature is __________.
(a) 0.25
(b) 0.20
(c) 0.50
(d) 0.33

9.

A pure liquid has a vapour pressure p at 30C. xg of a non-volatile solute is dissolved in y gms of the liquid when the
vapour pressure of the solvent was found to be lowered by 1/20 th of P. Molecular weight of solute is 5 times the
Molecular weight of solvent. x : y =
(a) 5 : 19
(b) 1 : 19
(c) 1 : 20
(d) 1 : 4

for H2O =

10. Assuming 100% dissociation of electrolytes, which of the following has the highest freezing point?
(i) 0.05M NaCl
(ii) 0.06M BaCl2
(iii) 0.15M urea
(a) (i)
(b) (ii)
(c) (iii)
(d) (ii) = (iii)
11. Mass in g of NaCl ( = 1) that must be added to 100g of water to depress the freezing point of water by 0.2K is _____
(a) 0.54
(b) 3.15
(c) 31.5
(d) 0.315
12. At 60C, the vapour pressures of ethyl acetate and propyl acetate are 415mmm and 172mm respectively. If the weight
percentage of ethyl acetate in a mixture is 30, vapour pressure of the mixture at 60C is _________ mm.
(a) 125
(b) 250
(c) 500
(d) 62.5
13. Two immiscible liquids A and B when distilled together boil at 70C under one atm, PB at this temperatue = 400mm.
MA/MB = 0.8, WA / WB = __________.
(a) 0.28
(b) 0.72
(c) 0.4
(d) 0.6
14. Dry air is drawn through two sets of bulbs A and B connected in series; A contains a solution of 10g of a non-volatile
non-electrolyte in 100g of water. B contains pure water. The loss in weight suffered by A and B are in the ratio 1:0.03.
Molecular weight of the solute =
(a) 40
(b) 50
(c) 60
(d) 80
15. i for a solution of 20g C6 H5OH in 1kg of benzene having Tf = 0.69C is _________ (Kf of C6H6 = 5.12k molal1)
(a) 0.37
(b) 0.63
(c) 0.80
(d) 0.20
FIITJEE

Chennai Centre. New no: 11, 29th Cross Street, Indira Nagar, Adyar, Chennai-20. Ph.: 43950450, email:
adyar@fiitjee.com.

Chapter Practice Problems

******
LIQUID SOLUTIONS 1 ANSWERKEY
1. B

2. A

3. A

4. C

5. D

6. A

7. C

8. B

9. A

10. A

11. B

12. B

13. B

14. C

15. B

FIITJEE

Chennai Centre. New no: 11, 29th Cross Street, Indira Nagar, Adyar, Chennai-20. Ph.: 43950450, email:
adyar@fiitjee.com.