Tarea 3 Fisico Quimica

R*T
SolveBP
V Hb + VL
V-b
::T -
, TF
Hb - VL HA + b P V + P V2 L
R V Hb + VL
8.31451 * 200.15
NSolveBP
40 - 0.089
88P 40.2891<<
R*T
V-b
R
-b + V
V Hb + VL
40 H0.089 + 40L
, PF
, TF
R*T
SolveBP
A
-
V-b
RT
P
::V
2256.898
DB
>>
Ib +
RT
P
, VF
A b P2 + b2 P2 RT + b P RT2 + b P R RT T + R RT2 T
P HA P + b P RT + RT2 L
A b P2 + b2 P2 RT + b P RT2 + b P R RT T + R RT2 T
DB
>>
, TF
b P R RT + R RT2
473.15
573.15
89.7250 + H0.0489 TL + H- 0.0000542 T ^ 2L + H0.00000002112 T ^ 3L< T +

0.089 * P * 8.31451 ^ 2 * 573.15 + 8.31451 ^ 2 * 573.15 ^ 2
573.15 *
8- 3302.49<
273.15
40 P -
30
40.2891
30
40.2891
P H2256.898 * P + 0.089 * P * 8.31451 * 573.15 + 8.31451 * 573.15 ^ 2L
89.7250 + H0.0489 TL + H- 0.0000542 T ^ 2L + H0.00000002112 T ^ 3L< T
9- 4141.82 + 9.725 T + 0.02445 T2 - 0.0000180667 T3 + 5.28 10-9 T4 =
tarea 3 fisico quimica.nb
PlotB99- 10773.913711552525` + 9.725` T + 0.02445` T2 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,
9- 13198.778269460207` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

5.28`*^-9 T4 + 411.564 - 1366.09=, 9- 15671.107979805443` + 9.725` T +
0.02445` T2 - 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,
9- 18174.14041062959` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

5.28`*^-9 T4 + 411.564 - 1366.09=, 9- 4141.8152728016275` + 9.725` T +
0.02445` T2 - 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09==,

J
8T, 273.15, 800.15<, AxesLabel :"THKL", "HH
L">F
mol
J
HH
mol
10 000
5000
THKL
400
500
600
700
800
-5000
-10 000
-15 000
Show@%69, ImageSize LargeD

J
HH
mol
10 000
5000
THKL
400
-5000
-10 000
-15 000
500
600
700
800
Plot3DB99H = - 10773.913711552525` + 9.725` T + 0.02445` T2 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,
9H = - 13198.778269460207` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

5.28`*^-9 T4 + 411.564 - 1366.09=, 9H = - 15671.107979805443` + 9.725` T +
0.02445` T2 - 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,
9H = - 18174.14041062959` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

5.28`*^-9 T4 + 411.564 - 1366.09=,
9H = - 4141.8152728016275` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +
5.28`*^-9 T4 + 411.564 - 1366.09==, 8T, 273.15, 800.15<,

J
8H, - 3302.49, - 15 000<, AxesLabel :"THKL", "HH
L", "PHkPaL">F
mol
10 000
PHkPaL
0
-5000
-10 000
J
-10 000
HH
400
mol
THKL
600
800
-15 000
NSolveA
V I339.26 * 0.089 * 2002 + 0.0892 2002 8.31451 * 1629.42 + 0.089 * 200 * 8.31451 * 1629.422 +
0.089 * 200 * 8.31451 ^ 2 * 1629.42 ^ 2 + 8.31451 ^ 2 * 1629.42 ^ 3M
I200 I339.26 * 200 + 0.089 * 200 * 8.31451 * 1629.42 + 8.31451 * 1629.422 MM, VE
88V 67.6228<<
NSolve@
c 89.7250 + H0.0489 603.15L + H- 0.0000542 603.15 ^ 2L + H0.00000002112 603.15 ^ 3L<, cD
88c 24.1358<<
23.15 *
650.15
603.15
dT
T
10
17.5346
R
dv
V-b
527.23
23.15
T
603.15
- 7.81572
23.15
T
603.15
603.15
10
23.15
T +
T +
8.31451
10
17.5346
V - 0.089
8.31451
V
17.5346
V - 0.089
527.23
3.11435
8.31451
V
17.5346
V - 0.089
- 4.70137
1
T
603.15
PlotB8823.15 * Log@T - 603.15D - 4.701374962944591`<,
823.15 * Log@T - 703.15D - 4.701374962944591`<,

823.15 * Log@T - 790.15D - 4.701374962944591`<,
823.15 * Log@T - 820.15D - 4.701374962944591`<,
823.15 * Log@T - 873.15D - 4.701374962944591`<<,
J
8T, 527.23, 1500<, AxesLabel :"THKL", "SH
L">F
mol
J
SH
mol
140
120
100
80
60
THKL
800
1000
1200
1400

J
SH
mol
140
120
100
80
60
THKL
800
1000
8.31451 * 1629.42
NSolveBP
88P 493.722<<
1629.42
493.722
1400
399.26
27.5 - 0.089
1200
27.5 H0.089 + 27.5L
, PF
24.15
652.95
22.0847
661
0.089 * P * 8.31451 ^ 2 * 652.95 + 8.31451 ^ 2 * 652.952

P I1754.52 * P + 0.089 * P * 8.31451 * 652.95 + 8.31451 * 652.952 M
- 1.92125
PlotB8824.15 * Log@T - 652.95D - 1.92125<, 824.15 * Log@T - 692.95D - 1.92125<,

824.15 * Log@T - 725.95D - 1.92125<, 824.15 * Log@T - 825.95D - 1.92125<,
824.15 * Log@T - 875.95D - 1.92125<<, 8T, 1629.42, 3000<, AxesLabel :"THKL", "SH
J
SH
mol
185
J
mol
180
175
170
165
160
THKL
2000
2200
2400
2600
2800
3000

J
SH
mol
185
180
175
170
165
160
THKL
2000
2200
2400
2600
2800
3000
L">F
Plot3DB88S = 24.15 * Log@T - 652.95D - 1.92125<,
8S = 24.15 * Log@T - 692.95D - 1.92125<, 8S = 24.15 * Log@T - 725.95D - 1.92125<,

8S = 24.15 * Log@T - 825.95D - 1.92125<, 824.15 * Log@T - 875.95D - 1.92125<<,
J
8T, 1629.42, 3000<, 8S, 164.326, 200<, AxesLabel :"THKL", "PHpKaL", "SH
L">F
mol
SH
J 180
L
mol 170
200
190
160
180 PHpKaL
2000
THKL
170
2500
3000
8.31451 * 1023.15
NSolveBP
25 - 0.089
88P 339.825<<
-
1023.15
333.15
164.326 T +
- 229 889.
164.326 T
333.15
164.326 H- 333.15 + TL
5000
25 P
25 H- 5000 + PL
1047.90
25 H0.089 + 25L
339.825
5000
25 P
, PF
Plot@88- 164.326` H- 333.15` + TL - 116 504<, 8- 200 H- 333.15` + TL - 117 500<,

8- 300 H- 333.15` + TL - 118 750<, 8400 H- 333.15` + TL - 120 000<,
8450 H- 333.15` + TL - 100 000<<, 8T, 333.15, 1500<, AxesLabel 8"THKL", "GHJL"<D
GHJL
400 000
200 000
THKL
600
800
1000
1200
1400
-200 000
-400 000

GHJL
400 000
200 000
THKL
600
-200 000
-400 000
800
1000
1200
1400
Plot3D@88G = - 164.326 H- 333.15 + TL - 116 504<,

8- 200 H- 333.15 + TL - 117 500<, 8- 300 H- 333.15 + TL - 118 750<,
8400 H- 333.15 + TL - 120 000<, 8G = 450 H- 333.15 + TL - 100 000<<,
8T, 333.15, 1500<, 8G, - 400 000, 400 000<, AxesLabel 8"THKL", "PHpKaL", "GHJL"<D
400 000
200 000
GHJL 0
400 000
-200 000
200 000
-400 000
0
500
PHpKaL
-200 000
THKL 1000
1500
-400 000
298.15
23.15 T - 298.15
1629.42
23.15
T
298.15
23 364.5
T + 101.325 * H67.6228 - 25.50L
23.15 T
298.15
23.15 H- 298.15 + TL
- 298.15
23.15
298.15
ConditionalExpressionB- 6902.17 H- 5.6976 + Log@TDL,

1
ReB
- 298.15 + T
F 0 ReB
0 < T < 298.15
- 298.15 + T
- 298.15 + T
101.325 * H10 - 25.50L

- 1570.54
RealsF
F - 0.00335402 && HT Reals Re@TD 298.15L
10
Plot@8823.15` H- 298.15` + TL 6902.172499999999` H- 5.697596716569115` + Log@TDL + 4268.09271`<,

823.15` H- 298.15` + TL - 6902.172499999999` H- 5.697596716569115` + Log@TDL +
4508.962500000001`<, 823.15` H- 298.15` + TL 6902.172499999999` H- 5.697596716569115` + Log@TDL + 5522.212500000001`<,
823.15` H- 298.15` + TL - 6902.172499999999` H- 5.697596716569115` + Log@TDL +
7548.712500000001`<, 823.15` H- 298.15` + TL 6902.172499999999` H- 5.697596716569115` + Log@TDL - 1570.5375000000001`<<,
8T, 1629.42, 5000<, AxesLabel 8"THKL", "HKJL"<D
HKJL
80 000
60 000
40 000
20 000
THKL
2000
2500
3000
3500
4000
4500
5000

HKJL
80 000
60 000
40 000
20 000
THKL
2000
2500
3000
3500
4000
4500
5000
11

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Tarea 3 Fisico Quimica

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R*T

89.7250 + H0.0489 TL + H- 0.0000542 T ^ 2L + H0.00000002112 T ^ 3L< T +

P H2256.898 * P + 0.089 * P * 8.31451 * 573.15 + 8.31451 * 573.15 ^ 2L

89.7250 + H0.0489 TL + H- 0.0000542 T ^ 2L + H0.00000002112 T ^ 3L< T

9- 4141.82 + 9.725 T + 0.02445 T2 - 0.0000180667 T3 + 5.28 10-9 T4 =

tarea 3 fisico quimica.nb

PlotB99- 10773.913711552525` + 9.725` T + 0.02445` T2 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,

9- 13198.778269460207` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

0.02445` T2 - 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,

9- 18174.14041062959` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

0.02445` T2 - 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09==,

Show@%69, ImageSize LargeD

Show@%62, ImageSize LargeD

tarea 3 fisico quimica.nb

Plot3DB99H = - 10773.913711552525` + 9.725` T + 0.02445` T2 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,

9H = - 13198.778269460207` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

0.02445` T2 - 0.000018066666666666668` T3 + 5.28`*^-9 T4 + 411.564 - 1366.09=,

9H = - 18174.14041062959` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

9H = - 4141.8152728016275` + 9.725` T + 0.02445` T2 - 0.000018066666666666668` T3 +

5.28`*^-9 T4 + 411.564 - 1366.09==, 8T, 273.15, 800.15<,

tarea 3 fisico quimica.nb

PlotB8823.15 * Log@T - 603.15D - 4.701374962944591`<,

823.15 * Log@T - 703.15D - 4.701374962944591`<,

tarea 3 fisico quimica.nb

Show@%123, ImageSize LargeD

27.5 H0.089 + 27.5L

0.089 * P * 8.31451 ^ 2 * 652.95 + 8.31451 ^ 2 * 652.952

tarea 3 fisico quimica.nb

PlotB8824.15 * Log@T - 652.95D - 1.92125<, 824.15 * Log@T - 692.95D - 1.92125<,

Show@%134, ImageSize LargeD

Show@%132, ImageSize LargeD

tarea 3 fisico quimica.nb

Plot3DB88S = 24.15 * Log@T - 652.95D - 1.92125<,

8S = 24.15 * Log@T - 692.95D - 1.92125<, 8S = 24.15 * Log@T - 725.95D - 1.92125<,

tarea 3 fisico quimica.nb

Plot@88- 164.326` H- 333.15` + TL - 116 504<, 8- 200 H- 333.15` + TL - 117 500<,

Show@%158, ImageSize LargeD

Show@%156, ImageSize LargeD

tarea 3 fisico quimica.nb

Plot3D@88G = - 164.326 H- 333.15 + TL - 116 504<,

T + 101.325 * H67.6228 - 25.50L

ConditionalExpressionB- 6902.17 H- 5.6976 + Log@TDL,

0 < T < 298.15

101.325 * H10 - 25.50L

F - 0.00335402 && HT Reals Re@TD 298.15L

tarea 3 fisico quimica.nb

Plot@8823.15` H- 298.15` + TL 6902.172499999999` H- 5.697596716569115` + Log@TDL + 4268.09271`<,

Show@%16, ImageSize LargeD

tarea 3 fisico quimica.nb

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