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JA = - DAB
dCA
dz
(1)
good for diffusion dominated problems
NA = - k CA
(2)
Therefore,
= = 1 2
(3)
2
=
= . = /
3
CA1
A&B
NA
CA2
= = 1 2
(3)
CA2 = pA2 / RT
= (pA1 pA2)
where = / RT
(4)
(5)
=
=
. 2 .
/
3 .
.
Liquid:
'
'
N A kc (c A1 c A2 ) k L (c A1 c A2 ) k x ( x A1 x A2 )
'
'
'
Substituting 1 =
, 2 = 2
'
c A1 c A2 k y
N A kc (c A1 c A2 ) k y ( y A1 y A2 ) k y ( ) (c A1 c A2 )
c
c
c
'
'
'
kc
'
ky
c
'
10
The flux equation obtained for steady state diffusion of A through non-diffusing B for
turbulent motion is
Where
Similar equations can be written for the liquid phase.
The flux equation for the diffusion of A through non-diffusing B for the liquid phase
is
= 1 2
Where
11
NB=0
'
kc
NA
(c A1 c A2 ) kc (c A1 c A2 )
xBM
'
kx
NA
( x A1 x A2 ) k x ( x A1 x A2 )
xBM
xBM
xB 2 xB1
x
ln( B 2 xB1 )
y BM
y B 2 y B1
y
ln( B 2 yB1 )
'
kc
kc
xBM
12
N A kc (c A1 c A2 ) kG ( p A1 p A2 ) k y ( y A1 y A2 )
Liquid:
N A kc (c A1 c A2 ) k L (c A1 c A2 ) k x ( x A1 x A2 )
13
14
turbulence
=
=
Where L is diameter Dp for sphere, diameter D for a pipe or
Length L for a flat plate. is the mass average velocity if is
diffussivity
=
=
15
=
=
=
=
=
=
=
=
2/3
2/3
=
( ) =
( ) = /( 3 )
16
For gases,
Reynolds number less than 15,000; = 0.664( )0.5
For liquid,
Reynolds number of 600-50,000;
= 0.99( )0.5
0.2
17
Ans:
kc= 5.85 x 10-6 m/s
NA= 1.726 x 10-7 kg mol /s.m2
18
Solution
Since the solution is quite dilute, the physical properties of water at
26.1 C can be used,
= 8.71 104 .
= 996 3
= 1.245 109 2 /
= 702
0.244(0.0610)(996)
Reynolds number, =
=
= 1.7 104
4
8.7110
0.5
For liquid, = 0.99( )
= 0.99(1.7 104 )0.5 = 0.00758
From definiton, =
( )2/3
= 5.85
19
Solution
This is the situation where A is diffusing through stagnant
B.
1 2 = (1 2 )
0.02948 0 = 1.726 10
. 2
7
20
1 2 = (1 2 )
= = 2.0
21
22
23
Solution
Since the conc of naphthalene is low, the physical properties of air at
45 C can be used,
= 1.93 105 .
= 1.113 3
= 6.92 106 2 /
= 2.505
0.0254(0.305)(1.113)
Reynolds number, =
=
= 446
1.93105
For gases, = 2 + 0.552( )0.53 1/3 = = 2 +
0.53
1/3
0.552(446)
(2.505)
From definiton, =
21 =
0.0254
,
6.92106
= 21
= 5.72
103 /
24
Solution
From table = =
5.72 103
=
=
= 2.163 109 /2
8314(318)
Since the gas is very dilute, 1.0, =
0.555
1 =
= 7.303 104 = 74
760
2 = 0 (Pure air)
= 1 2
= 2.163 109 (74-0)= 1.599 107 /2
Area of sphere = A = 2
Total amount evaporated = = 1.599 107 0.02542 = 3.238
1010 /
25
For gases:
NRe range of 10-10,000, in packed bed of spheres
0.4548
=
( )0.4069
26
0.4548
( )0.4069
1.1068
( )0.72
27
For sphere, =
6(1)
28
Ans:
kc= 4.447 x 10-6 m/s
cA2= 2.842 x 10-3 kg mol /m3
29
Solution
a) Since the solution is quite dilute, the physical properties of water at
26.1 C can be used,
= 8.71 104 .
= 996.7 3
= 1.245 109 2 /
0.006375(1.578104 )(996.7)
8.71104
= 702
= 1.150
30
Solution
Asumming = for dilute solution,
1.09
=
( )2/3 = 2.277
From definition, =
2/3
(
)
2/3
2.277=
(702)
1.578104
= 4.447 106 m/s
31
Solution
b) =
1 ( 2 )
ln( 1 )
= (2 1 )
1 = 0
32
For liquid:
NRe range of 50-50,00, NSc range of 0.6-2.6
= 0.600( )0.487
33
1.
2
1/3
2/3
=
+ 0.31( )
(
)
2
diameter of bubbles
- viscosity of solution
g- gravitational force, 9.81 m/s2
-density of continuous phase
-density of gas or solid particle, = =
(always positive)
34
= 0.42(
)0.5 (
1/3
)
2
diameter of bubbles
- viscosity of solution
g- gravitational force, 9.81 m/s2
-density of continuous phase
-density of gas or solid particle, = always
positive
35
36
Solution
The mass transfer resistance inside the gas bubble to the
37
= 215
2/3
=
+ 0.31( )
(
)
2
2(3.25 109 )
0.31 (993)(6.947 104 )(9.806) 1/3
=
+(
)(
)
4
2
1 10
35.9
994
= 2.290 104 /
38
Assuming =
= 1 2 = 5.18 108 2 / 2
Knowing the total number of bubbles and their area, the
maximum possible rate of transfer of O2 to the
fermentation liquid can be calculated.
39
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