CR-91 Event Shelby County, AL

Preliminary Air Monitoring Summary

September 21, 2016 05:00

Prepared by
Center for Toxicology and Environmental Health, L.L.C. (CTEH)
On Behalf of Colonial Pipeline

Introduction
On September 9, 2016, the Center for Toxicology and Environmental Health, L.L.C. (CTEH) initiated air monitoring
in support of response efforts to the gasoline release in Shelby County, AL. This report presents the real-time air
monitoring data recorded from September 20 2016 05:00 to September 21, 2016 05:00 CDT.

Real-Time Air Monitoring1

Real-time air monitoring was conducted to evaluate the potential airborne presence of gasoline-associated
constituents, if any, during response operations. All instrumentation was calibrated at least once per day or per
manufacturers recommendations. Target analytes were measured as total volatile organic compounds (VOCs),
oxygen, benzene, gasoline, hexane, naphthalene, xylene, and flammability as the percent of the lower explosive
limit (LEL) using remote telemetering RAESystems AreaRAEs, hand-held instruments such as RAESystems MultiRAE
Pro/Plus and UltraRAEs, as well as Gastec colorimetric detection tubes.
During this monitoring period, four benzene, two LEL, and 22 VOC detections were recorded above the action level
concentration during worker activity monitoring. During those instances when detections were sustained, workers
were either wearing respiratory protection, or egressed the area in accordance with the approved sampling and
analysis plan.
Table 1, below, presents the results of real-time air monitoring using hand-held instruments. Maps of the incident
site location and locations of hand-held real-time air monitoring readings are provided in Appendix I.

Real-time air monitoring refers to the use of hand-held instruments that provide near-instantaneous readings of an airborne chemical
concentration without the need for laboratory analysis.

2016-09-21 Page 2 of 6

Table 1: Hand-Held Real-Time Air Monitoring Summary1

September 20, 2016 05:00 to September 21, 2016 05:00
Location Category

Count of
Readings

Count of
Detections

Range of Detections2,3

181

43

0.05 - 1.6 ppm

Gastec #101L

15 ppm

Gastec #102L

<1 ppm

MultiRAE Plus

74

<1 %

MultiRAE Pro

372

2-8%

Gastec #60

<0.1 ppm

Gastec #122

<1 ppm

Gastec #122L

2.5 ppm

MultiRAE Plus

75

11

1.2 - 35.2 ppm

MultiRAE Pro

415

220

0.1 - 500 ppm

Xylene

Gastec #123

2.5 - 2.5 ppm

Benzene

UltraRAE

70.75 ppm

%LEL

MultiRAE Pro

6 35 %

VOCs

MultiRAE Pro

882.1 ppm

Analyte

Instrument

Benzene

UltraRAE

Gasoline
Hexane
%LEL
Worker Activity
Monitoring

Naphthalene
Toluene

VOC

Site Characterization
1Please

Note: The data displayed in the above table has not undergone complete QC analysis and is presented in a preliminary
format.
2Maximum detections preceded by the < symbol are considered non-detections below the instrument limit of detection (LoD)
value to the right.
3Numbers are the raw values, no correction factors have been applied.

In addition to worker activity monitoring, remote telemetering equipment established as an early warning system
recorded no detections of VOCs above the site-specific action level of 300 ppm and 297 detections of LEL above
the action level of 10% (3% as raw values on LEL sensors). Table 2 (below) summarizes remote telemetering
AreaRAE data for this monitoring period, which may contain drift events2. Appendix I and Appendix II include
location maps and graphs for remote telemetering data, respectively.

Drift is defined as any interference in the PIDs or electrochemical sensors ability to accurately report the concentration of a chemical in the
atmosphere. Humidity, rapid temperature changes, and compromised batteries are examples of common sources of drift.
2

2016-09-21 Page 3 of 6

Table 2: Remote Telemetering Real-time Air Monitoring Summary1,3

September 19, 2016 05:00 to September 20, 2016 05:00
Unit
AR01

Location Description
2A Recovery

AR04

2A Frac Tank Staging

AR05

2A Compressors

AR06

East of Release Site/Near

Stopple 2

AR07

2B Recovery

AR08

Main Staging Area Frac Tanks

AR09

Release Site

Count of
Readings

Count of
Detections

Range of Detections2

LEL

4531

10

1.1 - 3.4 %

O2

1836

1836

20.9 - 21.2 %

VOC

4531

4002

0.1 - 701.2 ppm

LEL

5179

<1 %

VOC

5179

2410

0.1 - 45.4 ppm

LEL

2282

<1 %

VOC

2282

1627

0.1 - 141.4 ppm

LEL

5325

<1 %

VOC

5325

3694

0.1 - 189.3 ppm

LEL

5094

<1 %

VOC

5094

3946

0.1 - 88.1 ppm

LEL

5185

<1 %

VOC

5185

2063

0.1 - 13.1 ppm

LEL

3669

<1 %

O2

3669

3669

20.4 - 20.9 %

VOC

3669

2838

0.1 - 402 ppm

Analyte

AR10

On path between Recovery 2A

and Recovery 2B.

LEL

4329

<1 %

VOC

4329

2941

0.1 - 100.5 ppm

AR11

Main Staging Entrance East of

TRG checkpoint

LEL

5131

<1 %

VOC

5131

1503

0.1 - 12.7 ppm

AR12

Boom Site #2

LEL

5758

<1 %

VOC

5758

1235

0.1 - 1.8 ppm

AR13

TRG Checkpoint 2 - access to

stopple 1, Recovery 2A and 2A
Frac Tank Staging Area.

LEL

5116

<1 %

VOC

5116

1547

0.1 - 12.2 ppm

LEL

4801

<1 %

O2

844

844

20.9 - 20.9 %

VOC

4801

2411

0.1 - 31.7 ppm

AR14

Cab of excavator at release

site

1Please

note: The data displayed here has not undergone complete QA/QC analysis and is presented in a preliminary format.
2Maximum detections preceded by the < symbol are considered at the limit of detection (LoD) value to the right.
3LEL and VOC values are raw values, correction factors have not been applied.

2016-09-21 Page 4 of 6

Appendix I:
Site Location, Hand-Held Real-Time
Air Monitoring Location, and
Remote Telemetering Air Monitoring
Location Maps

2016-09-21 Page 5 of 6

CR-91 Event
Site Location

Project: 108465
Client: Colonial Pipeline
Location: Shelby County, AL

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PROJECTION SYSTEM: UTM16

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COORDINATE SYSTEM: WGS84

Main Staging SIte

0.25

0.5 Miles

2B Recovery

n
!

Underflow Dam

Right of Way

2A Recovery

2B Frac Tank Staging Area

S
"

Release Site

ArtificialPath

2A Frac Tank Staging Area

Restoration Area

Stopple

Creek/Stream

Print Date: 9/20/2016

Radio-telemetering Real-time Air Monitoring Station Locations

CR-91 Event 9/21/2016

Project: 108465
Client: Colonial Pipeline
Location: Shelby County, LA

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PROJECTION SYSTEM: UTM Zone 16

COORDINATE SYSTEM: WGS84

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Legend

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)
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1,000
Feet

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Radio-telemetering Station
Release Site
Ponds

Creek/Stream
Print Date: 9/21/2016

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1,500

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

2,000

2,500

3,000
Feet

COORDINATE SYSTEM: WGS84

Creek/Stream
Ponds

Print Date: 9/21/2016

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Real-Time Benzene Reading (PPM)

<0.1
0.05 - 0.25

250 500

1,000

1,500

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

2,000

2,500
Feet

COORDINATE SYSTEM: WGS84

0.26 - 0.49
> 0.50

Print Date: 9/21/2016

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Legend
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250

500

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

1,000

1,500
Feet

COORDINATE SYSTEM: WGS84

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Site
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RdReal-Time

<0.1
5 - 30

Gasoline Reading (PPM)

31 - 50
>50

Print Date: 9/21/2016

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Legend
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Release Site
ArtificialPath

Creek/Stream

Ponds
Real-Time LEL Reading (%)
<0.1

250 500

1,000

1,500

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

2,000

2,500

3,000
Feet

COORDINATE SYSTEM: WGS84

1 - 10
11 - 30
>30

Print Date: 9/21/2016

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Legend
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d
ReleaseRSite
t
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ArtificialPath
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Rd
CoReal-Time

<0.1

Toluene Reading (PPM)

0.5 - 20.0
0

250

20.5 - 50.0

500
Feet

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

>50.0
COORDINATE SYSTEM: WGS84

Print Date: 9/21/2016

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Rd

Legend
S
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Release Site
ArtificialPath

Creek/Stream
Ponds

Real-Time VOC Reading (PPM)

<0.1
0.1 - 29.9

250 500

1,000

1,500

PROJECTION SYSTEM: UTM Zone 16

*GPS coordinates are approximate

2,000

2,500

3,000
Feet

COORDINATE SYSTEM: WGS84

30.0 - 299.9
>300.0

Print Date: 9/21/2016

Appendix II:
Remote Telemetering Air Monitoring
Graphs

2016-09-21 Page 6 of 6

Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|LEL
CR91Event|9/
20/
201605:
00t
o9/
21/
201604:
59
Uni
t/Loc
at
i
on

15
AR01/2ARec
over
y

10
5

15
AR04/2AFr
acTankSt
agi
ngAr
ea

10
5

15
AR05/2ACompr
essor
s

10
5

15
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2

10
5

15
AR07/2B Rec
over
y

10
5

15
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks

10
5

15
AR09/Rel
easeSi
t
e

10
5

15
AR10/Onpat
hbet
weenRec
over
y
2AandRec
over
y2B

10
5

15
AR11/Mai
nSt
agi
ngEnt
r
anc
eEast
ofTRGc
hec
kpoi
nt

10
5

15
AR12/Boom Si
t
e#2

10
5

15
AR13/TRGChec
kpoi
nt2

10
5

15
AR14/Cabofexc
avat
oratr
el
ease
si
t
e

10
5
9/
20/
201605:
00

9/
20/
201609:
00

9/
20/
201613:
00

9/
20/
201617:
00
Dat
e/Ti
me

LELr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.

9/
20/
201621:
00

9/
21/
201601:
00

9/
21/
201605:
00

Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|Oxygen
CR91Event|9/
20/
201605:
00t
o9/
21/
201604:
59
Uni
t/L
oc
at
i
on

AR01/2ARec
over
y

20
10
0

AR09/Rel
easeSi
t
e

20
10
0
9/
20/
201605:
00

9/
20/
201609:
00

9/
20/
201613:
00

9/
20/
201617:
00
Dat
e/Ti
me

9/
20/
201621:
00

9/
21/
201601:
00

9/
21/
201605:
00

Remot
eTel
emet
er
i
ngReal
t
i
meAi
rMoni
t
or
i
ng|VOC
CR91Event|9/
20/
201605:
00t
o9/
21/
201604:
59
Uni
t/L
oc
at
i
on

PPM

150
AR01/2ARec
over
y

100
50
0

PPM

150
AR04/2AFr
acTankSt
agi
ngAr
ea

100
50
0

PPM

150
AR05/2ACompr
essor
s

100
50
0

PPM

150
AR06/EastofRel
easeSi
t
e/
Near
St
oppl
e2

100
50
0

PPM

150
AR07/2B Rec
over
y

100
50
0

PPM

150
AR08/Mai
nSt
agi
ngAr
eaFr
acTanks

100
50
0

PPM

150
AR09/Rel
easeSi
t
e

100
50
0

PPM

150
AR10/Onpat
hbet
weenRec
over
y2A
andRec
over
y2B

100
50
0

PPM

150
AR11/Mai
nSt
agi
ngEnt
r
anc
eEastof
TRGc
hec
kpoi
nt

100
50
0

PPM

150
AR12/Boom Si
t
e#2

100
50
0

PPM

150
AR13/TRGChec
kpoi
nt2

100
50
0

AR14/Cabofexc
avat
oratr
el
ease
si
t
e

PPM

150
100
50
0
9/
20/
201605:
00

9/
20/
201609:
00

9/
20/
201613:
00

9/
20/
201617:
00
Dat
e/Ti
me

VOCr
eadi
ngsar
eat
r
uer
epr
esent
at
i
onofat
mospher
i
cc
ondi
t
i
ons(
appr
opr
i
at
ec
or
r
ec
t
i
onf
ac
t
or
shavebeenappl
i
edt
of
i
el
dval
ues)
.

9/
20/
201621:
00

9/
21/
201601:
00

9/
21/
201605:
00