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Introduction:
Tannins are secondary metabolites, non nitrogenous, phenolic/polyphenous compounds,
present in vacuoles or surface wax or cell sap of the plant that precipitate proteins
(astringent property).
Derived from French word tannin meaning tanning substance
Chemically, mixtures of very diverse group of oligomers and polymers, generally with odihydroxy or o-trihydroxy group on a phenyl ring. (Phenolic class)
Unripe parcemons contains large amount of tannin
Found in
Bud tissues
Seed tissues
Leaf tissues
Stem tissues
Root tissues
Classification of Tannins:
Pseudotannins:
HT
yr
du
oe
y
l
z
at
ba
eenn
tn
nnii
nn
ns
Gallotannins:
Tannic acid
Ellagitannins:
Resistant to hydrolysis
Also called condensed tannins or Proanthocyanidins or catecholic phenols
More widely distributed
Soluble in water
Found in cinchona, male fern, areca seeds, cherry bark, amla
Chemically oligomers or polymers of flavonoid units linked by C-C bonds which
cannot be cleared by hydrolysis
Characteristics of tannins:
Colloidal with water
Non crystalline
Soluble in
o Water
o Glycerine
o Alcohol
o Dilute alkalies
o Acetone
Insoluble in
o Organic solvents
Molecular weight: 500 - >20,000
Uses:
Promote healing and formation of new tissues on wound
Treat
o Varicose ulcer
o Hemorrhoids
o Minor burns
o Frostbite
o Gum inflammation
Diarrhea
Intestinal catarrh
Heavy metal poisoning (anti dote)
Nux vomica poisoning (treat by green tea. Contain large amount of tannins;
alkaloids are precipitated)
o AIDS (anti viral activity)
As mordant in dyeing
Manufacture of ink
Sizing paper and silk
Printing fabrics
In manufacture of gallic acid and pyrogallol
In leather industry to convert animal hide into leather
Oak tree containing tannins are used for storing old wine. Tannin leach into it and
give bitter taste
Reagent in analytical chemistry
Green tea contains large amount of tannins. Nux Vomica
o
o
o
o
Some river water is black due to tannins which come from trees nearby as they
leach into water.
Some well water is bitter due to tannins
Starch
Uses:
Local astringent
Manufacture of ink, dye, and tannic acid
In ointment
In suppository
Hamamelis leaf:
Botanical Source: Obtained from dried leaves of Witch hazel leaves Hamamelis
virginiana (Hamameliaceae)
Chemical Constituents:
Gallotannins
Ellagitannins
Free gallic acid
Proanthocyanidins
Volatile oils (traces, mainly saffrole)
Uses:
Astringent
Treat
o Sprains
o Bruises
o Superficial wounds
o Piles
o Inflammatory swelling
o Diarrhea
o Dysentery
o Mucus discharge
Ingredient of eye lotion
Tonic
Sedative
Valuable in checking external and internal hemorrhage
Pale Catechu/Gambier:
Botanical Source: Dried aqueous extract prepared from leaves and young shoots of
Roxburgh
Uncaria gambier (Rubiaceae)
Collection: Collected first at second year growth when 2 meter in height and then
every year at regular interval of 4-6 months till 15 years. Maximum yield is at 8th year
Material is cut and put into boiling water for 3 hours and stirred well. Leaves and twigs
are taken out and placed on sloping for draining the liquid left. Extract is decanted.
Mark is pressed and washed. Liquid transferred to vessel. Liquid is concentrated till
becomes yellowish-green, thick pasty mass. Cooled till crystallization of catechin.
Cooled semi solid mass is solidified in tray and cut into cubes of uniform size and dried
under sun.
7-33% catechin
22-25% catechutannic acid
Catechu red
Quercetin
Gambier fluorescin
Uses:
Treat diarrhea
In lozenges
Local astringent
Used in dye
Tanning industries
Technical purpose
Eaten with betel
Black catechu:
Botanical source: Dried aqueous extract prepared from heartwood of Willdenow Acacia
Catechu (Leguminosae)
Collection: Bark and sapwood are stripped from trunk. Chips of heartwood are boiled in
earthen pots with water for decoction. Decoction is filtered and evaporated for
concentrating the filtrate in an iron vessel and color becomes darker due to tannins.
Continuous stirring cause formation of catechin crystals. Evaporation is continued till a
syrupy liquid is obtained. Then spread on leaves of cassia fistula arranged on a wooden
frame and dried for a night. Then cut into pieces.
2-12% catechin
25-30% catechutannic acid
4-12% aca-catechin or acacia catechin
Catechu red
Quercetin
Uses:
In medicine as Astringent
Treat
o Throat disease
o Diarrhea
o Mouth trouble
Dyeing
Increase appetite
Calico printing
Tanning industries