Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
ASSISTS IN COMPLEX
FORMATION EVALUATION*
BY
WALTER H. FERTL
Dresser Atlas Division, Dresser Industries, Inc.
Houston, Texas
ABSTRACT
I
I
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I
f \
*This paper was presented at the SPWLA Sixth European Symposium, March 26-27, 1979, London.
THE LOG ANALYST
I
TABLE I
Gamma-Ray Lines' in the Spectra of the
Important Naturally Occurring Radionuclides
U R A N I U M SERIES
NUCLIDE
M O D E OF
DISINTEGRATION
90 Th234
24.1 d
pa234m
91
8. IT
91
6.66 hr
92
2.48 x 10' yr
lo
90 Th230
8.0 x 10' yr
Ra
88 Ra226
1620 yr
ux2
uz
UII
u234
1.18 min
3.82 d
Rn
86Em222
RaA
84P0218
a,P
3.05 min
a, P
2 sec
RaA'
RaA"
Ra B
RaC
RaC'
RaC"
RaD
RaE
RaF
RaE'
RaG
85 At218
86Em218
82 Pb214
Bi214
83
26.8 min
a,P
19.7 min
1.6 x lo-' sec
TI2''
1.32 min
82 Pb2Io
19.4 yr
a. P
5.01 d
Bizlo
83
84 PO2I0
81
82 Pb206
138.4 d
4.2 min
1.42 x 10'" yr
MsThl
88
Ra228
6.7 yr
MsTh2
89 Ac228
6.13 hr
RdTh
90
Th228
1.91 yr
ThX
88 Ra224
3.64 d
Tn
86Em220
51.5 sec
ThA
84
Po216
0.16 sec
ThB
82 Pb2I2
10.6 hr
Bi2I2
a, P
60.5 min
Po212
0.30 gsec
ThC"
T 208
3.10 min
ThD
82 PbZo8
83
84
81
90 Th232
ThC'
po2I4
84
HALF LIFE
Th
ThC
1.3 sec
M O D E OF
DISINTEGRATION
NUCLIDE
4.51 x 10' yr
UI
UX I
H A L F LIFE
Stable
Stable
NUCLIDE
Bi2 I d ( Rac)
NUMBER OF P H O T O N S
PER DISINTEGRATION
IN EQUILIBRIUM MIXTURE
G A M M A - R A Y ENERGY.
Mev
0 609
0 769
I I20
1.238
1.379
1.764
2.204
0 17
0.06
0 05
0. I6
0 05
T12"(ThC')
0.51 I
0533
2.614
-
0 II
C.28
0.35
*With intensities greater than 0.05 photons per disintegration and energies greater than 100 kev
SEPTEMBER-OCTOBER, 1979
INSTRUMENT SPECIFICATIONS
SCHEMATIC OF INSTRUMENTATION
2703
Series:
2703
Diameter:
3.63"
(9.22 cm)
3.5"
(8.89 cm)
Length
7.0'
(2.13 m)
7.0'
(2.13 m)
Weight:
115 Ib
(52.2 kg)
97 Ib
(44.63 kg)
4.0
(10.2 cm)
4.0"
(10.2 cm)
Max. Temperature:
400F
(204C)
400" F
(204' C)
Max. Pressure:
20,000 psi
(137.9 MPa)'
15:OOO psi
(103.4 MPa)'
10'lmin
(3.05 m/min)
* MPa
Megapascal ( I psi
(10'/min)
(3.05 mlmin)
1:o
210
Gamma Ray Energy - MEV
3.0
FIGURE 1
THE LOG ANALYST
5
..
,, .
. .
Unstripped count rates based on an average scintillation crystal and the mix bucket calibrator now in use are
for potassium: 11200 CPM k 400 CPM (corresponds to
approximately 15% K by volume), uranium: 7300 CPM k
300 CPM (corresponds to approximately 125 ppm U),
thorium: 4400 CPM k 150 CPM (corresponds approximately to 465 ppm Th), total counts: 180000 CPM k 1200
CPM.
Depth of Investigation is primarily a function of gamma ray energy, borehole size, type of fluid in borehole, and
cement and casing thickness. Studies have shown that for
I .764 MeV gamma rays reaching a 6-inch uncased borehole
containing 10 lb/gal mud, the distance of 100 percent response extends to 16 inches horizontally from the borehole
and intersects the wellbore 25 inches above and below the
detector.
SEPTEMBER-OCTOBER, 1979
u
aJ
0.
v1
L
r.
IJ)
P
-
G
O
U
FIGURE 2
THE LOG ANALYST
TABLE II
Potassium (K), Uranium (U), and Thorium (Th) Distribution
in Several Rocks and Minerals
U
(PPm)
K
(O h )
Th
(PPm)
Accessory Minerals
30-700
5-150
20-50
500-3000
100-700
500-3.4XlO'
300-3000
500-5000
20-1 50
50-500
O4
2 . 5 ~O4-2Ox1
1
100-600
Low
100-2500
1.7
2.9
0.8
2.0
1.9
2.0
0.61
0.61
<1.4
<0.6
<1.3
1.7
0.99
0.53
<1.4
0.25
0.50
1.7
4.6
1.96
3.9
<0.05
<2.0
6.8
Allanite
Apatite
Epidote
Monazite
Sphene
Xenotime
Zircon
Andesite (av )
A , Oregon
Basalt
Alkali basalt
Plateau basalt
Alkali olivine basalt
Tholeiites (orogene)
(non orogene)
Basalt in Oregon
Carbonates
Range (average)
Calcite, chalk, Limestone,
dolomite (all pure)
Dolomite, West Texas (clean)
Limestone (clean)
Florida
Cretaceous Trend, Texas
Hunton Lime, Okla.
West Texas
Clay Minerals
Bauxite
Glauconite
Bentonite
Montmorillonite
Kaolinite
lllite
Mica
Biotite
Muscovite
Diabase, Va.
Diorite, Quartzodiorite
Dunite, Wa.
Feldspars
Plagioclase
Orthoclase
Microcl ine
<
<
0.1-9.0(2.2)
0.0-2.0(0.3)
<O.l
0.1-0.3
< 0.4
<0.3
<0.2
<0.3
5.08-5.30
<0.5
0.16
0.42
4.5
0.1-7.0(1.7)
<l.O
1.5-10
<0.5
<2.0
2.0
1.5-15
<l.O
<1.5
< 2.0
1.5
<1.5
<1.5
3-30
10-130
1-20
2-5
1.5-3
1.5
6-50
14-24
6-19
< 0.01
6.7-8.3
7.9-9.8
<O.Ol
<l.O
1. I
<0.02
<l.O
2.0
<O.Ol
0.54
11.8-14.0
10.9
2.4
8.5
0.01
<
< 0.01
< 0.01
< 0.01
0.46-0.58
.a4-.9
2.75-4.26
4.5-5
3.5-5
2-6
3.6-4.7
4.2
12-16
3.2-4.6
19-20
25-52
50-62
14-27
2-2.5
2.6
2.-2.5
9.3-1 1
11.0-12.1
5.5
<4.0
0.2
Phosphates
Rhyolite
'4.2
0.7-3.8 (1.1)
< O 15
<I2
0 37
03
Shales
"Common" Shales (range (av ))
Shales (200 samples)
Schist (biotite)
Syenite
Tuff (feldspatic)
2.7-3.85
up to 500
1-30
0.01
Q.05
100-350
1-5
5
0.2-0.6(0.5)
< 0.4
1 6-4 2(2 7 )
20
27
2 04
0.7-2.0(1.7)
<0.2
0.84
3.97
0.8
2.8
11.27
2.07
1.5-5.5(3.7)
6 .O
2.4-4.7
2500
5.96
8-la(12.0)
12.0
13-25
1300
1.56
SEPTEMBER-OCTOBER, 1979
TABLE 111
Thorium and Thorium-BearingMinerals (After Frondel et al., 1956)
Name
,
I
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I
Thorium minerals
Cheral ite
Huttonite
Pi1barite
Thorianite
Thorite**
Thorogu m m ite* *
Tho, content,
(Th,Ca,Ce) ( P04Si04)
ThSi04
T h o 2 U 0 3 PbO 2Si02 4H20
Tho;!
ThSi04
Th(Si0,)l-x(OH)4-x; x 0.25
<
Thorium-bearing minerals
Allanite
( Ca,Ce,Th)2(AI,Fe,Mg)3Si30,2(OH)
Bastnaesite
( Ce, La) Co3F
Betafite
About (U,Ca)(Nb,Ta,Ti),Og nH,O
Brannerite
About (U,Ca,Fe,Th,Y)3Ti50,6
Euxenite
(Y,Ca,Ce,U,Th) (Nb,Ta,Ti),05
(Ce ,Ca,Fe,Th) (Ti,N b)206
Eschynite
Ferg uson ite
(Y ,Er,Ce,U,Th)(Nb,Ta,Ti)04
Monazite*
(Ce,Y ,La,Th)P04
Samarskite
(Y ,Er,Ce,U, Fe,Th) ( Nb,Ta),06
Hydrocarbon mixture containing U, Th,
Thucholite
rare earth elements
U 0 2 (ideally) with Ce, Y, Pb, Th, etc.
U raninite
Yttrocrasite
About (Y ,Th,U,Ca)n(Ti,Fe,W),O,,
Zircon
ZrSiO,
**
OO
/
30, variable
81.5 (ideal)
31, variable
lsomorphous series to U 0 2
25 to 63 - 81.5 (ideal)
24 to 58 or more
0 to about 3
Less than 1
0 to about 1
0 to 12
0 to about 5
0 to 17
0 to about 5
0 to about 30; usually 4 to 12
0 to about 4
0 to 14
7 to 9
Usually less than 1
Most important commercial ore of thorium. Deposits are found in Brazil, India, USSR, Scandinavia,
South Africa, and U.S.A.
Potential thorium ore minerals.
Repeatability of Spectralog
TABLE IV
Uranium Minerals
AUTUNITE
TYUYAMUNITE
CARNOTITE
~ L T W O O D I T E
WEEKSITE
Similar to conventional gamma ray logging, the Spectralog response is affected by borehole size and fluid, casing,
and cement. These effects will increase for centralized versus
non-centralized logging tools.
U-silicate high in Ca
TOTAL COUNTS
DEPTH
TOTAL COUNTS
DEPTH
REPEAT SECTION
RFPFAT SFCTION
Two Spectralogsand their repeatsare shown overa PermianCarbonatesection intwo wells, located in Kansas. Since the
Spectralog records the natural formation radioactivity, statistical variations become important and no perfect repeatsof
the K, U or Th curves should be expected, particularly at low count rate levels.
Also noteworthy are thecorrelative geologic features in the shales and particularlyin the Permian. Carbonates(inc1uding
the U-hot streak). Correlative Spectralog features are shown in both wells which are located in adjacent counties,
Kansas.
FIGURE 3
10
SEPTEMBER-OCTOBER, 1979
This effect has to be kept in mind if different mud systems have been applied in area wells and the Spectralog is
used for detailed correlation, sand quality studies, or quantitative shaly sand analysis.
TOTAL COUNTS
DEPTH
Reducing Environment. Subsurface waters associated with petroleum occurrences normally exhibit a negative
redox (Eh) potential. In presence of organic matter, hydrogen sulfide, and sulfur dioxide, the available uranium ions,
transported in migrating subsurface waters, will precipitate
as UOZ.
f ihslc
Therefore, precipitated uranium may be found concentrated along geologic fault planes, natural fracture and
fissure systems of some areal extent, or - under the proper
conditions - in any permeable clastic, argillaceous and
igneous rocks, carbonates, etc. Among the probable source
rocks of uranium, one has to consider tuffaceous, arkosic,
and granitic rocks.
DEPTH
I
I
OpprnThlM
Russian investigations of radioactive elements in subsurface waters have established correlations of radium (Ra)
with water salinity, geologic age of formations, gas component of subsurface waters, etc. Generally speaking, subsurface waters in contact with hydrocarbon reservoirs show
an increase in Ra-content. Also, Ra was found to be higher
in chloride-calcium waters compared to bicarbonatesodium waters.
m
I
SEPTEMBER-OCTOBER, 1979
TOTAL COUNTS
DEPTH
IJRANlllM
-41
SPECTRALOG 11978)
THORIUM
The field case shown is a well completed in the Mississippian Madison Limestone, Colorado. The formation is a light t o dark gray, pink and buff limestone,
dolomitic limestone, dolomite, and limey dolomite,
which is predominately crystalline and fine-grained.
Parts of the formation are porous and caverneous with
calcite fillings. A gamma ray log, run in 1967, and the
Spectralog, run in 1978, are shown for comparison.
The well produced oil over several years from perforations at x738-ft. t o x754-ft. When the zone watered
out, thru-casing logs were run t o investigate the recompletion potential in several permeable stringers
above these perforations. These logs indicated the
entire interval t o be essentially depleted. Note that the
Spectralog (i.e., total counts and U-curves) clearly
confirms the depleted reservoir condition. A faulty
cement job (despite several squeeze attempts in the
past) probably allowed complete reservoir drainage,
despite the limited perforations within this thick Madison limestone reservoir.
CI:
FIGURE 6
13
The Spectralog, hence, allows a continuous monitoring of the source rock potential of shales in both open and
cased wellbores. The potential of the Spectralog to hydrocarbon exploration thus becomes obvious (Figure 8). New
and old wells can be logged to determine source rock potential variations both versus depth and on a regional basis
using the appropriate mapping techniques.
(oxygenated)
(Inorganic or organic)
Typical organic-rich shales are well known on a worldwide basis (Kimmeridge Shale, North Sea; Lower Mississippian and Devonian Shales in U.S.A.; Miocene Monterey
Shale in California, etc.).
a Decay
Leacning
Solution
Spectralog Response in
PotentialShale Reservoir Rocks
Typical organic-rich shales are well known worldwide. These highly radioactive, black, organic-rich shales
are encountered in several areas in the U.S.A. and elsewhere.
Localized, these shale formations become potential
reservoir rocks due to presence of natural fracture systems,
interbedded silt, chert, or carbonate beds.
Antrim-Chattanooga- Woodford Shales of Lower Mississippi and Upper Devonian age are well-known examples
of black, organic shale formations. The Woodford Shale in
Oklahoma and Texas is a dark-brown to black, fissile, carbonaceous shale, which is locally interbedded by thin beds of
black pyritic chert, siliceous shales, and siltstones.
14
SEPTEMBER-OCTOBER, 1979
W
-J
v)
ORGANIC CARBON, %
ORGANIC CARBON, %
Organic Carbon Content (%) versus Uranium/potassium ratio (left) and Uranium content (right) in
New Albany Shale. (After Supernaw et al., 1978)
FIGURE 8
FIGURE 9
Potassium and Thorium Variations in
Several Clay Minerals
.)----.
K-Feldspars
Bauxite
--
Glauconite
am-
Muscovite.lllite
--
Mixed
Kaolinite
Layer
Kaolite.Chlorite
I Ilite.Muscovite
Montrnorillonite
..._
0.25
0.5
0.75
Al2O3I(AI2O3 + S O 2 )
1 .o
1.oo
.rl
10
. ,..
Bauxite
100
T~IK
Thorium content variations in glauconite, montmorillonite, illite, muscovite, kaolinite, and bauxite
minerals. (After Hassan et al., 1976)
I
15
I
!I
TABLE V
Geological Significance of Spectralog Ratio Values
REMARKS
RATIOS
Thorium/Uranium
(Th/U)
Th/U
Uran ium/Potassi um *
(U/K)
*
*
*
Thorium/Potassium
(Th/K)
*
*
*
*
*
SEPTEMBER-OCTOBER, 1979
>
TOTAL COUNTS
ocpw
Polowum
0
(121
CD
Uranium
1 2 4 w m CD
Thorium
CPM
0
15wo
1 1 0"m CD
17
TOTAL COUNTS
DEPTH
Both K and Th concentrations provide reliable shaliness estimates based on either linear or exponential
correlations.
VSHI= (A-AMIN)(AMAXAMIN)
where
A
AMIN
VSH
0.083 (23'7VSH
- 1.0)-Tertiary
Clastics
Th versus K crossplots have been proposed to quantitatively determine the quartz, clay, and radioactive mica
components in the Jurassic North Sea reservoir sands.27
Figure 13 shows the effect ofthese radioactive heavy minerals
on conventional log responses, whereas Figures 14 through
17 present SEM photos of the mica in this Jurassic rock.
Figure I8 shows the laboratory-derived relationship
between Th-gamma spectral measurements and clay volume
determinations based on X-ray diffraction analysis for
Jurassic core samples from the North Sea.28 Such relationships apply despite the presence of various amounts of K-rich
but Th-deficient mica minerals.
THORIUM
LO^.^^
18
SEPTEMBER-OCTOBER, 1979
COMPENSATED NEUTRON
lAPl UNITS1
CALIPER
~1
(INCHES1
,dl
DENSITY
.-..-. . .
gm cc
Photos of mica "seam" which forms dense, essentially tight horizontal barriers. The latter not only affect
response of several geophysical well logging tools but
also drastically change vertical reservoir rock permeability. Magnification 1OOX (above) and 500X
(below).
FIGURE 13
FIGURE 14
19
oz
I2
/
/
/
/
///
I S A l VN W 901 3 H l
TOTAL
COUNTS
DLPTM
Poloaium
n
29uICD
FIGURE 19
22
SEPTEMBER-OCTOBER, 1979
TOTAL COUNTS
10
oEPw
lhorium
CPM
487ppmCI
20 wo
TOTAL COUNTS
DEPTH
Potassium
0
0145%iCD
Uronium
073pr,m/cn
CPM
0
Thorium
14 a4 ~ l l ~ i c o
3wM)
m
0
Note that the high total counts (i.e., gamma ray curve)
values in the top part of the sand are caused by the
localized excessively high U-concentration. The latter
was found to correlate closely with oil shows found
in the full sized core samples taken. Similar observations have been made in other area wells and elsewhere
in the U.S.A. (After Fertl et al., 1978)
Spectralog was run in cased hole with oil in the borehole. Zone between x420-ft. t o x490-ft. shows presence of low potassium, but high uranium and high
thorium content. Gamma ray (total counts) "hot"
zone at x 450-ft. is believed to be bentonitic, tuffaceous streak due t o >>Th but decreasing K-values.
Lower section between x775-ft. to x960-ft. again
clearly shows the complete ineffectiveness of the
gamma ray (total counts) curve, as a shaliness indicator, due t o sporadic but drastic increase in uranium
concentration within several sandstone formations.
FIGURE 21
FIGURE 22
dj
I
23
eb4
t C 1
1
ZONE OF TUFFACEOUS
SWALV SANDSTONE
1.60
1.58
0.50
1 .oo
1 .so
POTASSIUM, '10
An empirical correlation between the Spectralogderived potassium (K) values and the presence of tuffaceous, shaley sandstones (based on detailed core
analysis data) is successfully being used in Argentina.
The Chubutiano formation, located in the San Jorge
Basin in Southern Argentina, contains low and abruptly varying formation water salinities and locallychanges
from non-permeable tuffites to more or less shaley
formations.
Evaporite Formations
Representative logging constants for several radioactive and non-radioactive evaporite minerals are listed in
Table VI.30
FIGURE 23
24
SEPTEMBER-OCTOBER, 1979
TOTAL COUNTS
DW-
POTASSIUM
Zone B -
Zone A
Zone D Zone C
25
L
TOTAL COUNTS
DWH
..
Uranium
0 13 porn/CD
Thorium
Ln acoustic-type log for fracture identification (Microseismogram) was used t o initially perforate the well in
the intervals marked on the log. Based on this completion the Austin Chalk reservoir tested at less than
20 BOD.
FIGURE 25
26
SEPTEMBER-OCTOBER, 1979
LZ
lSA7WNW 901 3 H l
6L6L 'ki38013O-ki38W32d3S
82
U BULK VOLUME
to
_______s.lzlroa
1
Jb
0125
OllW
FORMAlIDN
Jb BULK VOLUME
Figure 33 shows the computerized crossplot3*of Spectralog-derived K-versus the Densilog (g/cc) response in the
Salado formation located in Eddy and Lea Counties, New
Mexico. Such crossplots provide the basis for continuous
quantitative in-situ potash evaluation.
Coal Seam Evaluation
Detection and evaluation of coal seams using geophysical well logging techniques is a well-established and
commonly used method.
Coal seams usually exhibit low total radioactivity.
Presence of clay minerals in the seam as thin dirt partings,
however, will cause an increase in the measured natural
radioactivity. Under localized conditions, the ash content of
coal has been empirically related to the gamma ray response.
Presence of large and drastically varying clay mineral
content, such as the potassiumdeficient kaolinite and/or
localized secondary enrichment of uranium (U02) under
prevailing reducing conditions (i.e., negative Eh-potential),
will make such gamma-ray-derived ash content determinations totally unreliable. Thoriumderived correlations using
the Spectralog, however, are still applicable.
Numerous coal seams, particularly low rank coals, are
known to contain excessively high uranium content. This
includes: Eocene sub-bituminous coal at Rosa, Yugoslavia
(G300 ppm U); sub-bituminous Hungarian coals (<100
ppm U): coal at Wackersdorf, West Germany; Trimmelkamm, Austria (GO, 5%); Sweetwater County, Wyoming;
Paleocene lignite in Harding County, South Dakota; etc.
High uranium content of coals is well known from the
U.S.A., U.K., France, Germany, Austria, Hungary, Czechoslovakia, Yugoslavia, U.S.S.R., etc. In general, coals have
been encountered with U-concentrations up to a few thousand ppm, but concentrations above 100 ppm are not too
common.
Well established prolific oil accumulation is contained
within this complex reservoir rock of Permianage. Production comes from a series of formations containing
anhydrite, sandstone, and dolomite with vuggy to
caverneous porosity and very high permeability. Note
that the presence of an oil-filled, natural cavern from
x260-ft. to x288-ft. is defined by response of caliper,
porosity, and the Spectralog (>>U). A check of the old
drilling records revealed that the bit dropped over the
distance of about 204% during drilling at this depth,
thus confirming the presence of this natural subsurface cavern.
FIGURE 30
THE LOG ANALYST
29
SEPTEMBER-OCTOBER, 1979
F
l
DEPTH
API UNITWCD
POTASSIUM
2WCD
URANIUM
ACOUSTILOU POROSITY
NEUTRON RATIO
2U))pmlCD
THORIUM
Spectralog and Dual Detector Lifetime log (DNLL) were run in an old, cased West Texas well t o investigate recompletion targets in the Mississippian Lime section. Also available in this well was an openhole acoustic log.
The calculated C-derived porosity is used in comparison with the DNLL Ratio porosity and acoustic log porosity
values for qualitative hydrocarbon identification. Note the slightly increasing porosity trend below 0x790-ft.,
which corresponds t o a drastic increase in gamma ray deflection. Also note that the Spectralog over this higher
porosity interval clearly shows a marked buildup in U-concentration. Well was successfully perforated in this U-rich
interval between 0x790-ft. t o 0x822-ft. and put on production at over 100 BOD.
FIGURE 31
SPECIFIC
Pma
Atma +NEU GR(d=8in) K 2 0
GRAVITY (g/cm3) (psec/ft) (%)
(API)
(%)
MINERAL
CHEMICAL COMPOSITION
ANHYDRITE
GYPSUM
HALITE
TRONA
TACHYDRITE
CaSO,
CaSO, 2H20
NaCl
NaCO, NaHCO, H 2 0
CaCl 2 (MgCI,) 12H20
2.96
2.32
2.16
2.1 2
2.97
2.35
2.03
2.10
1.66
50
52
67
65
94
0
49
4
40
62.5
0
0
0
0
0
0
0
0
0
0
SYLVITE
CARNALLITE
LANGBEINITE
POLYHALITE
KAI N ITE
KCI
KCI MgCI, * 6 H 2 0
K2S0, 2MgS0,
K2S04 MgSO, 2CaS0,
MgSO, KCI 3H2O
1.98
1.61
2.83
2.78
2.13
1.86
1.57
2.82
2.79
2.1 2
74
78
52
57.5
0
65
0
15
45
500
200
275
180
225
63
17
22.6
15.5
18.9
2H20
TABLE VI
Logging Constants Representativeof
Several Evaporite Minerals (After Tixier et al., 1967)
30
SEPTEMBER-OCTOBER, 1979
742
744
K VS DEN
746
Li
W
Y
748
.ANHYDRITE
___._
tw 750
0
752
754
756
2000
COUNTS PER MINUTE
1000
3000
4000
PI
5%
10%
APPARENT POTASSIUM
15%
20%
c/'
31
r
'
1m.m
..
I I
DEPTH
COUNTSPER MINUTE
1m.m
.
-
6L.w
2o.m
xow.~xzw.
140.00
OR
TOTAL COUNTS
RTVS.GR
.................................................................................
0.63
63
6.32
26
632.46
RT
Emphasis on coal deposits as an alternate energy resource has again brought into focus the development
and improvement of logging techniques and associated interpretation concepts for in-situ evaluation of
coal seams and the log-derived determination of the
elastic rock constants.
FIGURE 35
FIGURE 34
32
SEPTEMBER-OCTOBER, 1979
TOTAL COUNTS
-I
UN-STRIPPED
OUTPUT
D
UN-STRIPPED
OUTPUT
TOTAL COUNTS
STRIPPED
REPEAT
Uraivm
ILwppnllCD
7
M
r
n
U.34ppnlCI
FIGURE 36
OUTPUT
I
STRIPPED
OUTPUT
REPEAT
33
TABLE VII
Gamma Ray Spectral Average Data for Various Groups of
Granitic Rocks (After Whitfield et al., 1959)
CLASS1FICAT1ON
Rocky Mountains
Canadian Shield
Pre-Cam brian
Post-Cam brian
K
(O h )
3.3
2.5
3.2
2.2
1.8
Th/U
(PPm)
Th
(PPm)
Average Th
Average U
2.9
1.8
2.6
3.0
3.1
15.7
11.0
14.0
8.6
8.5
6.9
5.9
5.6
3.3
2.9
5.4
6.1
5.4
2.9
2.7
lo
4 -
2ix
w
v)
10
15
20
4
0
25
THORIUM.Th(pprnl
--
1
.5
---
o/
$/
."/
4*'
-1
a
--a
.I
'
--
I
I
.05
B
WEATHE RING EFFECTS
.01
INTRUSION OF
BASIC D I K E S
1 1 1 1 1
10
20
1..y
40 60
100
Uranium (U) and Thorium (Th) content versus Potassium Feldspar/Plagioclase ratio of Granite rocks.
(After data from Whitfield et al., 1959).
FIGURE 39
34
SEPTEMBER-OCTOBER, 1979
1.1
TOTAL COUNTS
I
TOTAL COUNTS
DEPTH
Potassium
0
041% I CD
Uranium
4200
CPM
ZBwm/CD
Thorium
0
6 B m I C D
9100
4250
9150
43w
'
'
4350
REFERENCES
I.
9.
11.
b
15. Fertl, W. H., King, E. E., Kumar, R., 1978, Practical Log Analysis-7: Important S P and gamma ray log anomalies are explained,
Oil and Gas J.. 76(34):70-75.
12. King, R. L., Bradley, R. W., 1977. Gamma ray log finds bypassed
oil zones in six Texas Oil fields, Oil & Gas J.. April 4. 92-99.
3. Fertl, W. H., Hotz, R. F., 1978, The Spectralog in the Texas Cretaceous CarbonateTrend, Dresser Atlas Technical Memorandum,
#3331, July, 25 pp.
5.
17. Koczy, F. F., Antal, P. S., Joensuu, O., 1963, Die natiirlichen
radioaktiven Elemente in Sedimenten, Fortschr. Geol. Rheinld.
u. Wesrf:,10301-214, Krefled. Oct.
35
lo
10
b "
2Q
b 4
,4+
2Q
1.o
m
a0-A
-0
0
0
/'
0.
I .I I
0
Palisades
a Columbia river
"0
0
0
Hawaii
Karroo
Bushveld
Pidgeon Pt.
Japan
A
0
4
0.1
-_
i gh - A l -basalt
-h--/ X
Japan
-alkali
----basalts
---Japan
Oslo province
1.o
0.1
rrrr~l
10
I I
lIId
0.01
100
THORIUM, Th(ppm)
0.01
1.o
0.1
10
URANIUM, U (ppm)
Ioo1
e3
0 7
85
/
a
0.01
0.1
I I aaaa.8
1.o
1
10
URANIUM, U (pprn)
POTASSIUM, K(%)
Basalts and related rocks: potassium versus thorium, potassium versus uranium, and thorium versus uranium.
Lower right: potassium versus Th/U ratio in primary basic magma, (1) Japan, tholeiite; (2)Japan, high-aluminum
basalt; (3)
Japan, alkali olivine basalt; (4)Duluth, layered gabbro; (5)South California batholith, gabbro; (6)Columbia
River basalts; (7)Palisades sill (After Heier et al., 1963).
FIGURE 42
36
SEPTEMBER-OCTOBER, 1979
120
100
ka
F
r'
3
-
21. Valkovic, V., 1978, Trace Elemenrs in Peiroleum. The Petroleum Publishing Co., Tulsa, Oklahoma, 269 pp.
22. Beers, R. F., Goodman, C., 1944, Distribution of radioactivity
in ancient sediments, Bull. Geol. SOC. Amer.. 55:1229-1254,
October.
80
60
40
24. Supernaw, 1. R., McCoy, Arnold D., Link, A. J., 1978, Method
for in-situ evaluation of the source rock potential of each formations, US.Pateni 4,071,744, Jan 31.
20
26. Hassan, M., Hossin, A., Combaz, A., 1976, Fundamentals of the
differential gamma ray log-Interpretation Technique, Paper H,
Transactions SP WLA.
[r
100
8o
nr.
31. Lock, G. A., Hoyer, W. A., 1971, Natural gamma ray spectral
logging, 7he Log Analyst. 12(5):3-10,October.
10
20
30
40
36. Gasparini, P., Luonga, G. e Davia, G., 1963, Misure di radioattivita alla Solfatara di Pozzuoli, Atri Conv. Assoc. Geofis. Iral.,
12, Rome. pp. 41-50.
50
U R A N IUM,u(ppm)
37. Luongo, G. e Rapolla, A., 1964, Contributo allo studio dell'evoluzione del magma Somma-Vesuviano mediante le determinazione
delleconcentrazioni in isotopi r a d i ~ a t t i v i ~ ~ 232Th,
* U , 226Ta,e40K,
Ann. Osserv. Vesuviano, 6:45-66.
Thorium (Th)versus Uranium(U) in Italian lavas; Roccamonfina lavas: A = Leucite bearing rocks; B = trachytes to basalts. (After Civetta et al., 1966).
FIGURE 43
38. Civetta, L., Gasparini, P., Adams. J. A. S., 1965, Aspetti dell'evoluzione magmetica del vulcano di Rocmmonfina attraverso
misure di radioattivita, Ann. Osserv. Vesuviano, 7:77- 105.
37