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Chemistry HL
Candidate Name
Candidate Number
Date of Practical
Research Question
How does the concentration of a reactant (manipulated by using different concentrations of potassium
iodide solution) affect its rate of reaction with another reactant (hydrogen peroxide solution, of a fixed
concentration and volume), which is calculated as the inverse of the time measured for the triiodide ion
formation from the reaction to completely obscure the X mark at the bottom of a flask?
Introduction
There are a few factors that affect the rate of reaction: temperature, reactant concentration, reactant
surface area, pressure, the presence of catalyst and the physical states of reactants. This experiment will
investigate the effect of reactant concentration on the rate of reaction in the reaction between potassium
iodide and hydrogen peroxide. The hydrogen peroxide concentration is fixed while the concentration of
potassium iodide is manipulated; the formation of the product triiodide ions can be detected with the
blue-black starch complex. Because both of these reactants react quickly with each other, sodium
thiosulphate solution is used as a delaying mechanism to delay the formation triiodide ions by reacting
with the triiodide ions to reform more iodide ions. When the sodium thiosulphate is exhausted, remaining
triiodide ions form a blue-black starch complex with the starch present in the solution.
The chemical equations involved in this reaction are:
H2O2 (aq) + 3 I- (aq) + 2 H+ (aq) I3- (aq) + 2 H2O (l)
A stopwatch is used to measure the time taken for the triiodide ions to completely obscure a mark X at
the bottom of the flask; the times recorded are then inversed and the rate of reactions for individual runs
can be found.
This experiment is also known as the Iodine Clock Experiment.
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Hypothesis
The collision theory states effective collisions between reactant molecules must occur in order for the
reaction to occur. The more reactant particles present, the more frequently they collide effectively, and the
more often the reaction occurs to form products. Therefore, the increase in reactant concentration will
increase the rate of reaction.
Rate of reaction frequency of effective collision concentration of reactants
In this experiment, the concentration of one of the reactant, which is potassium iodide, is increased; this
means that there will be more potassium iodide available to effectively collide with hydrogen peroxide as
the concentration increases.
As such, the hypothesis for this experiment is that the rate of reaction will increase with the concentration
of potassium iodide.
Rate of reaction
Variables
Dependent variable
: Rate of reaction
Independent variable
0.1 mol dm-3 potassium iodide solution is prepared. The solution is then
diluted to form potassium iodide solutions of different concentrations
using dilution technique.
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Controlled variables
2. Amount of starch
Starch is the indicator of the presence of triiodide, the final product of the
iodine clock reaction.
3. pH or H+ concentration
4. Temperature
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Dropper
White tile
Beakers
Micropipette
Wash bottle
Measuring cylinder
Electronic balance, correct to 0.001 g
Procedure
1. 100 cm3 of 0.1 mol dm-3 potassium iodide solution is prepared by dissolving 1.66 g of potassium
iodide powder into 100 cm3 of distilled water in a volumetric flask.
2. 30 cm3 stocks of potassium iodide solutions of different concentration are prepared using the
dilution technique in measuring cylinder. A micropipette is used when necessary.
Volume of 0.1 mol dm-3
potassium iodide solution
measured / cm3
( 0.4 cm3)
Concentration of potassium
iodide solution, Mpotassium iodide
/ cm3
30
0.10
15.75
14.25
0.075
10.5
19.5
0.050
5.25
14.75
0.025
2.1
27.9
0.010
Table 1: Volumes required for the preparation of potassium iodide solutions of different concentrations
3. 10 ml of 6 % hydrogen peroxide, H2O2 solution is pipette into one conical flask. 6 drops of dilute
hydrochloric acid is added to acidify it. The conical flask is labeled A.
4. In another conical flask, 7 ml of 0.10 mol dm-3 of potassium iodide solution is measured with a
measuring cylinder, and poured into it. 10 ml of starch, and 1 ml of 0.025 mol dm-3 of sodium
thiosulphate solution are also poured into the conical flask. The conical flask is labeled B and
placed on a white tile with a mark x.
5. The contents of conical flask A are emptied into conical flask B, and the stopwatch is
immediately started. The x is viewed through the top of the conical flask B. The stopwatch is
immediately stopped when the x is obscured by the dark-blue formation in the solution in
conical flask. The time taken is recorded.
6. Steps 3 5 are repeated 2 times to obtain 2 more replicates.
7. Steps 3 6 are repeated with different concentrations: 0.075 mol dm-3, 0.05 mol dm-3, 0.0025 mol
dm-3 and 0.001 mol dm-3.
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Concentration of
potassium iodide
solution, Mpotassium iodide /
cm3
Run 2
Run 3
0.10
5.28
4.75
4.47
0.075
6.25
6.62
8.75
0.050
17.75
15.13
14.94
0.025
36.00
28.12
24.75
0.010
45.63
42.81
52.00
Data processing
The average time taken for each potassium iodide solution concentration is calculated:
Concentration of potassium
iodide solution, Mpotassium iodide
/ cm3
Rate of reaction,
/ s-1
0.10
5.28+4.75+4.47
3
= 4.83
1
4.83
= 0.207
0.075
5.28+4.75+4.47
3
= 7.21
1
7.21
= 0.139
= 15.94
1
15.94
= 0.063
0.050
6.25+6.62+8.75
3
0.025
36.00+28.12+24.75
3
= 29.61
1
29.61
= 0.034
0.010
45.63+42.81+52.00
3
= 46.81
1
46.81
= 0.021
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Data presentation
0.100
4.83, 0.1
0.080
7.21, 0.075
0.060
15.94, 0.05
0.040
29.61, 0.025
0.020
46.81, 0.01
0.000
0.00
5.00
10.00
15.00
20.00
25.00
30.00
35.00
40.00
45.00
50.00
Figure 2: Average time taken, t' / s against concentration of potassium iodide solution, Mpotassium iodide / mol dm-3
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0.10
0.207, 0.1
0.08
0.139, 0.075
0.06
0.063, 0.05
0.04
0.034, 0.025
0.02
0.021, 0.01
0.00
0.000
0.050
0.100
0.150
0.200
0.250
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Uncertainties
Uncertainty in time taken due to stopwatch = 0.01 s
Uncertainty in time taken due to human reaction time = 0.09 s
Total absolute uncertainty in time taken = 0.1 s
Percentage uncertainty in 0.10 mol dm-3 potassium iodide solution prepared in Step 1 of the Procedures
= percentage uncertainty due to electronic balance + percentage uncertainty due to volumetric flask
=(
0.001
1.66
0.1
= 0.16 %
Mpotassium iodide
Percentage uncertainty in
volume of potassium iodide
solution measured / %
Percentage uncertainty in
volume of distilled water
measured / %
/ mol dm-3
0.10
0.4
30
0.075
0.4
15.75
100 % = 2.540
0.4
14.25
0.050
0.4
10.5
100 % = 3.810
0.4
19.5
0.025
0.4
5.25
100 % = 7.619
0.4
14.75
0.010
0.4
2.1
100 % = 1.333
100 % = 19.048
0.4
0
0.4
27.9
100 % = 0.000
Percentage
uncertainty in 0.1
mol dm-3
potassium iodide
solution / %
0.16
100 % = 2.807
0.16
100 % = 2.05
0.16
100 % = 2.712
0.16
100 % = 14.434
0.16
Table 4: Calculation of the percentage uncertainties in the preparation of solutions of different concentrations
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Concentration of
potassium iodide
solution,
Mpotassium iodide
/ mol dm-3
0.10
0.075
0.050
0.025
0.010
Table 5: Calculation of the total percentage uncertainties in the preparation of solutions of different concentrations
Concentration of
potassium iodide
solution, Mpotassium
Absolute uncertainty
/ mol dm-3
0.10
1.493
0.075
5.507
0.050
6.02
0.025
10.491
0.010
33.684
iodide
/ mol dm-3
Table 6: Calculation of the absolute uncertainties in the preparation of solutions of different concentrations
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Percentage uncertainty
time taken / %
iodide
/ mol dm-3
0.10
0.1
4.83
100 % = 2.070
0.075
0.1
7.21
0.050
0.1
15.94
100 % = 0.627
0.025
0.1
29.61
100 % = 0.338
0.010
0.1
46.81
100 % = 0.214
100 % = 1.387
Table 7: Calculation of the percentage and absolute uncertainties in rate of reactions for different potassium iodide solution
concentrations
Conclusion
The rate of reaction increases as the concentration of potassium iodide increases; the graph of the
relationship between the rate of reaction and the concentration of potassium iodide shows a positive linear
regression curve. This result is in agreement with the hypothesis that the rate of reaction will increase
with the increase in concentration of potassium iodide solution.
Evaluation
Two reactions occur when contents in conical flask A is poured into conical flask B:
1. Between hydrogen peroxide solution and the iodide ions from the potassium iodide solution to
form triiodide ions:
H2O2 (aq) + 3 I- (aq) + 2 H+ (aq) I3- (aq) + 2 H2O (l)
2. Between triiodide ions and thiosulphate ions to re-form iodide ions.
I3- (aq) + 2 S2O32- (aq) 3 I- (aq) + S4O62- (aq)
Triiodide ions and starch molecules combine to form triiodide-starch complexes which give the solution
its dark blue colour.
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When the thiosulphate ions in the 2nd reaction is fully consumed, and thus hinder the reformation of
iodide ions, the triiodide ions will form complexes with starch and present the black-blue colour in the
solution. The stopwatch is stopped when the dark blue triiodide-starch complexes completely obscures the
X mark at the bottom of the flask.
If the time taken for the triiodide-starch complexes to obscure the X is to be prolonged, the
concentration of the sodium thiosulphate solution should be increased; and vice versa. This is because as
the more the amount of sodium thiosulphate solution present, the later the sodium thiosulphate solution
will be used up and thus delaying the formation of blue black triiodide-starch complexes.
The experiment can be carried out with potassium iodide concentrations of more than 0.200 mol dm-3 to
extend the linear regression curve in Figure 3. However the rate of reaction will stop increasing with the
increase of potassium iodide concentration at a point, where the hydrogen peroxide concentration
becomes the limiting factor. The rate of reaction remains constant; unless the concentration of hydrogen
peroxide solution is increased.
If the conical flasks are left on their own for some time, the dark-blue colour becomes more intense as
more triiodide starch complexes are formed. The colour will stop darkening when the hydrogen
peroxide solution or potassium iodide solution is completely used up; the reactant that is exhausted is the
limiting factor of the reaction.
There is a human reaction time that is included as part of the uncertainty due to stopwatch. This is
because there may be a delay between the first detection of an obscured X with when the thumb presses
the stop button.
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