C pt2

CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION 1 : (Maximum Marks : 80)
This section contains TWENTY questions
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
1.
Select correct statement(s) :

(A) KP depends upon equilibrium pressure
(B) Even at constant temperature, on changing the stoichiometric coefficients of the reaction, the
equilibrium constant (KC) changes.
(C) CaCO3(s)
CaO(s) + CO2(g) ; Kp = PCO2
On increasing number of moles of CaCO3, at equilibrium, moles of CO2 at new equilibrium

increases.
(D) During dissociation of PCl5(g)
PCl3(g) + Cl2(g), Mavg decreases with progress of reaction.
(Mavg Average molecular mass)
Space for Rough Work
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JRPT2300815C0-1
CHEMISTRY
CHEMISTRY
CHEMISTRY
Which one of the following are valid structure(s) for dinitrogen oxide?
(I) N
(A) I
3.
+
N
(B) II
(III) N
+
N
(C) III
(IV) N
+
O
(D) IV
Which of the following compounds contain 1 formal charge on any of O atom :

(A) O3
4.
(II) N
(B) H3PO4
(C) HNO3
(D) N2O5
Which is correct statement ?

(A) In CF2 = C = CF2 molecule, all the four fluorine atoms are not in the same plane.
(B) Ka2 of fumaric acid is more than Ka2 of maleic acid due to intra molecular hydrogen bonding in
maleic acid.
(C) The O O bond length in O2[AsF4] is shorter than in KO2.
(D) The bond angle order in halogen S halogen is OSF2 < OSCl2 < OSBr2
5.
Which of the following statements is incorrect?

(A) Octet rule is followed by N in NO
(B) BBr3 is hypervalent species and PCl5(g) is hypovalent species
(C) Cl O bond order in ClO3 is less than that in ClO4
(D) S O bond order in SO3 is less than that in SO42
JRPT2300815C0-2
CHEMISTRY
2.
CHEMISTRY
6.
Which is/are true statement(s) among the following :
CHEMISTRY
(A) PH5, SCl6 and FCl3 do not exist.

(B) p d bond is present in SO2 molecule.
(C) 12 PO bonds are present in P4O6 molecule.
(D) Cation of PCl5(s) has tetrahedral shape.
7.
Consider the reaction
P(g) + 2Q(g)
Initial conc.
2M
R(g) + S(g)
4M
then select correct statement(s)
8.
(A) At equilibrium [R(g)] = [S(g)]
~
2M
(B) At equilibrium [P(g)] = [Q(g)]
4
~
10 M
(C) At equilibrium [P(g)]
4
~
10 M
(D) At equilibrium [Q(g)]
4
~
2 10 M
Which of the following statements are false?

(A) The dipole moment of NF3 is more than NH3.
(B) trans-2, 3-dichloro-2-pentene does not have net permanent dipole moment.
(C) Carbon tetrachloride has no net dipole moment because of its regular tetrahedral structure.
(D) Dipole moment is zero for sulphur dioxide molecule.
JRPT2300815C0-3
CHEMISTRY
Consider the following equilibrium in a closed container. N2O4(g)
2NO2(g)
At constant temperature the volume of the reaction container is doubled. For this change, which of
the following statement is/are true when equilibrium is re-established?
(A) The ratio of partial pressure of NO2 and N2O4 is changed as compared to that at initial
equilibrium.
(B) Total pressure remains same, but degree of dissociation of N2O4 changes.
(C) Total pressure as well as degree of dissociation of N2O4 changes.
(D) The ratio of partial pressure of N2O4 and square of partial pressure of NO2 is same as that
initially.
10.
The equilibrium constant for some gaseous reactions are given below against each of the reaction.
(i) 2N2O5
(ii) 2NO
(iii) 2NO2
27
2N2 + 5O2
K = 10
15
N2 + O 2
K = 10
29
N2 + 2O2
K = 10
Which of the following statement(s) is/are correct for the decomposition of oxide into elements ?
11.
(A) The least stable oxide is NO2
(B) The most stable oxide is NO
(C) The stability order is N2O5 > NO2 > NO
(D) The stability order is NO2 > NO > N2O5
Choose the correct options.

(A) In O2F2, the OF, bond length is lesser than expected value.
(B) In trisilyl amine (SiH3)3 N, the bond length is lesser than expected value.
(C) The bond angle in OF2 is lesser than in Cl2O.
(D) The Be atom in BeCl2(s) is sp3 hybridised.
JRPT2300815C0-4
CHEMISTRY
9.
CHEMISTRY
Which of the following statement(s) is/are correct ?

(A) PH3 is weaker base than (CH3)3N.
(B) Amongst ClCl, NF, CF and OF, the CF bond is most polar.
(C) OF2 has higher dipole moment than H2O.
(D) An alcohol is less volatile than ether having same molecular formula on account of
intermolecular hydrogen bonding.
13.
In which of the following compounds all CO bond lengths are found to be equal.
(A) CH3 C O CH3

||
O
(B)
(C)
(D)
HO
ONa
C
O
14.
Which of the following is/are true for stability of carbanion.
(A)
>
(B)
> CF3
(C)
>
(D) CH3 CH2 (CH3 )3 C
JRPT2300815C0-5
CHEMISTRY
12.
CHEMISTRY
The order of electron density in the benzene ring in the following compounds :
OC2H5
OH
(A) I > II > III > IV

16.
(B) II > IV > I > III
(D) I > III > IV > II
The correct stability order of carbocation is / are :
(A)
>
(C)
17.
(C) IV > III > II > I
(B)
<
>
(D)
<
Which of the following is/are correct option for stability of alkene ?

(A)
(B) CH 3C=CHCH 3 > CH 2=CCH 2CH 3
>
CH3
(C)
18.
CH3
CH3
C= C
H
<
H
CH 3
H
C= C
H
CH3
(D)
CH3
<
Which of the following cation is not stablized by Resonance :

(A)
(B)
(C)
(D)
JRPT2300815C0-6
CHEMISTRY
15.
CHEMISTRY
Which of the following is/are correct order for stability of resonating structure?
+
(A) H 2C=N=N
>
(B)
<
(C)
>
(D)
20.
CHEMISTRY
19.
<
Select the correct statement :
(A)
>
(B)
(C)
(e density)
>
(stability of carbanion)
>
(stability of carbocation)
(D)
<
(Dipole moment)
JRPT2300815C0-7
This section contains THREE paragraphs
Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
Paragraph for Question Nos. 21 to 22

Definition : Resonance may be defined as the phenomenon in which two or more structures
involving identical position of atoms, can be written for a particular compound
Resonance Hybrid : It is the actual structure of all different possible structures that can be written
for the molecule, without violating the rules of covalence maxima for the atoms.
Resonance hybrid
JRPT2300815C0-8
CHEMISTRY
CHEMISTRY
Bond order =
e.g.,
Total No. of bonds formed between two atoms in all structures

Total No. of resonating structures
Bond order =
2 1 1
1.33
3
Resonance energy = Actual bond energy Energy of most stable resonating structure.
Stability of molecule resonance energy.
More is the number of covalent bonds in molecule more will be its resonance energy.
Resonance energy number of resonating structures.
21.
Equal bond lengths are present in :
22.
(A) I2Cl6
(B) CO32 (present in Na2CO3)
(C) NO3 (present in NaNO3)
(D) SO42 (present in Na2SO4)
Find the maximum number of equivalent bonds in S3O102 (Trisulphate ion)

(A) Five
(B) Four
(C) Six
(D) Nine
JRPT2300815C0-9
CHEMISTRY
CHEMISTRY
CHEMISTRY
All the boron trihalides except B3 may be prepared by direct reaction between the elements.
Boron trihalides consist of trigonal - planar BX3 molecules. Unlike the halides of the other elements
in the group they are monomeric in the gas, liquid and solid states. BF3 and BCl3 are gases, BBr3
is a volatile liquid and B3 is a solid. Boron trihalides are Lewis acids because they form simple
Lewis complexes with suitable bases, as in the reaction
BF3 (g) + :NH3 (g) F3B NH3 (s)
However, boron chlorides, bromides and iodides are susceptible (sensitive) to protolysis by mild
proton sources such as water, alcohols and even amines for example BCl3 undergoes rapid
hydrolysis:
BCl3 (g) + 3H2O() B (OH)3 (aq)+ 3HCl (aq)
It is supposed that the first step in the above reaction is the formation of the complex
Cl3B OH2 which then eliminates HCl and reacts further with water.
23.
Which of the following is the correct prediction about observed BX bond length, in BX3 molecules
(A) BF bond length in BF3 is found to be less than theoretical value because the electronegativity
values of B(2.04) and F(4.0) suggest the bond to be ionic and hence the attraction between
oppositely charged ions must decrease the bond length
(B) BF3 and [BF4] have equal BF bond length
(C) The decrease in the BF bond length in BF3 is due to delocalised p p bonding between
vacant 2p orbital of B and filled 2p orbital of F.
(D) The correct BX bond length order is BF > BCl > BBr > B
JRPT2300815C0-10
CHEMISTRY
CHEMISTRY
Which of the following is correct :

(A) B(OCH3)3 is much weaker lewis acid than BBr3
CHEMISTRY
24.
(B) B(OH)3 (aq) behaves as a triprotic acid

(C) AlF3 is a stronger lewis acid than BF3
(D) all the above are correct

Read the following passage carefully and answer the questions.
Reaction intermediates : Reaction intermediates are short lived species and are highly reactive.
They are formed by heterolytic and homolytic bond dissociation. There are various types of
reaction intermediates in which the most important are carbocation, carbanion and free radical.
Carbocation is an organic species which has a carbon atom bearing six electron in its outermost
orbit and has a positive charge on it. The stability of carbocation can be increased by positive
inductive effect or hyperconjugation. If -atom with respect to carbocation has one or more lone
pair of electrons then lone pair of electron strongly stabilise a carbocation due to delocalisation.
Anion of carbon is called carbanion. Carbanion carries three bond pairs and one lone pair. The
stability of carbanion can be increased by negative inductive effect and negative mesomeric effect.
Free radical is a species which bears seven electrons in its outmost orbit. The stability of free
radical can be increased by hyperconjugation and resonance.
JRPT2300815C0-11
CHEMISTRY
26.
Which of the following is the most stable carbocation intermediate.
(A)
(B)
(C)
(D)
CHEMISTRY
25.
The correct stability order of following free radicals is :
CH2=CHCH2
CH3CH2CH2
II
(B) II > III > I > IV
(C) I > III > II > IV
(D) III > I > II > IV
JRPT2300815C0-12
CHEMISTRY
This section contains TWO questions
Each question contains two columns, Column I and Column
Column I has four entries (A),(B), (C) and (D)
Column II has four entries (P),(Q), (R) and (S)
Match the entries in Column
CHEMISTRY
II
I with the entries in Column II

One or more entries in Column I may match with one or more entries in Column II
The ORS contains a 4 4 matrix whose layout will be similar to the one shown below :
(A)
(B)
(C)
(D)
JRPT2300815C0-13
CHEMISTRY
28.
Match the molecules given in column-I with the characteristic(s) given in column-II.
Column-I
Column-II
(A) SiCl4
(P) All the bonds (i.e. bond length) equal.
(B) OSF4
(Q) All the bond angles equal.
(C) SF4
(R) d-orbital(s) involved in hybridisation.
(D) XeO4
(S) p-d bond(s).
Match the column :

Column-I
Column-II
O
||
(A) Ph C NH2
(P)
Resonance possible
(B) Ph CH2
(Q)
Even number of p-electrons
O
||
(C) CH3 C ONa
(R)
Localized lone pair of e.
(D)
(S)
Delocalized lone pair of e.
JRPT2300815C0-14
CHEMISTRY
27.
CHEMISTRY
This section contains TEN questions
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
29.
Amongst the following, the total number of species which does/do not exist is :
SF6, BF63, XeF2, OF4, AlF63, PCl5, NCl5, HFO4
30.
Find the sum of total number of p-p bonds in one molecule each of CO2, H2SO4, P4O10 and SO3.
31.
The density of an equilibrium mixture of N2O4 and NO2 at 1 atm and
2400
K is 1.84 gm/L.
7
Calculate Kc for the equilibrium and report your answer to nearest integer, after multiplying with 50.
N2O4(g)
2NO2(g)
JRPT2300815C0-15
CHEMISTRY
CHEMISTRY
At a certain temperature, the equilibrium constant (Kc) is 9/4 for the reaction :
CO(g) + H2O(g)
CO2(g) + H2(g)
If we take 10 mole of each of the four gases in a one-litre container, what would be the equilibrium
mole percent of H2 (g) ? (Report your answer as y, where y =
33.
mole % of H2 at eq.
)
10
The number of equivalent contributing structures possible for N2O5 is m. The bond order of NO
bond is n (n > 1). Find (m n).
34.
In a heterogeneous equilibrium,
2A (s)
if log
Kp
Kc
B (g) +
n
C (g)
2
3 log RT = 0
Find n.
35.
The total number of contributing structures showing hyperconjugation (involving CH bonds) for
the following compound is :
JRPT2300815C0-16
CHEMISTRY
32.
CHEMISTRY
Consider the following compounds :
CHEMISTRY
36.
How many species are aromatic.
37.
The number of resonance structures for N is

NaOH
38.
Number of carbocations which are more stable than CH CH CH2 from the following is :
(i)
(ii)
(vii)
(viii)
(iii)
(iv)
(v)
(vi)
(ix)
JRPT2300815C0-17
jl k;u foK ku
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
[kaM 1 : (v f/kd re v ad : 80)
bl [kaM esachl iz'u gSaA
iz
R;s
d iz
'u es
apkj fod Yi (A), (B), (C) rFkk (D) gS
A bu pkj fod Yiks
a
aes
als,d ;k ,d lsv f/kd fod Yi lgh gS
A
a
1.
lgh d Fku@d Fkuksad kspqfu, %

(A) KP lkE; nkc ij fuHkZ
j d jrk gSA
(B) fLFkj rki ij] v fHkf ;k d s jl l ehd j.kferh; xq
.kkad ks d ks cny us ij] l kE; fLFkjkad (K C )
cny rk gSA
(C) CaCO3(s)
CaO(s) + CO2(g) ; Kp = PCO2
lkE;koLFkk ij CaCO3 d seks

y ksad h la[;k esao`f) d jusij] u;h lkE;koLFkk ij CO2 d seksy ksaesao`f)
gksrh gSA
(D) PCl5(g)
PCl3(g) + Cl2(g) d s fo;ks
t u d s nkSjku] vfHkf ;k d h izxfr d s lkFk Mavg ?kVrk gSA
(Mavg vkS
l r v.kqHkkj)
d Ppsd k;Zd sfy , LFkku
JRPT2300815C0-1
jl k;u foK ku
jlk;u foKku
2.
MkbukbVkst u vkWDlkbM d sfy, fuEu esalsd kSulh la

jpuk;saekU; gS\
(I) N
(II) N
(A) I
3.
(III) N
(B) II
+
N
(C) III
(IV) N
+
O
(D) IV
fuEu esalsd kSuls;kSfxd ksesa] fd lh Hkh O ijek.kqij 1 vkSipkfjd (formal) vkos'k gksrk gS\
(A) O3
4.
+
N
(B) H3PO4
(C) HNO3
(D) N2O5
fuEu esalsd kSulk@d kSulsd Fku lgh gS@ gSa\

(A) CF2 = C = CF2 v.kqes
alHkh pkjksy ksjhu
(B)
ijek.kqleku ry esaughagksrsgSaA
eSy sbd vEy maleic acid esavUr% vkf.od gkbMkst u cU/ku intra molecular hydrogen bonding d s
d kj.k ;wesfjd vEy fumaric acid d k Ka2, eSy sbd vEy d sKa2 lsvf/kd gksrk gSA
(C) O2[AsF4] es
aO O cU/k y EckbZ] KO2 d h vis{kk d e
(D) gS
y kst u S gSy kst u
5.
gksrh gSA
esacU/k d ks.k bond angle d k e OSF2 < OSCl2 < OSBr2 gSA
fuEu esalsd kSulk d Fku xy r gS\

(A) NO es
aN }kjk v"Vd
fu;e d k iky u gksrk gS

A
(B) BBr3 vfrla

;kst h rFkk PCl5(g) U;wula;kst h izt kfr
(C) ClO3 es
aClO4 d h vis{kk Cl O ca/k e
(D) SO3 esSO42
gSaA
d e gksrk gSA
d h vis{kk S O ca/k e d e gksrk gSA

JRPT2300815C0-2
jl k;u foK ku
jlk;u foKku
jlk;u foKku
fuEu esalsd kSulk@d kSulsd Fku lR; gS@ gSa\

(A) PH5,, SCl6 o FCl3 d k vfLrRo
ughagksrk gSA
(B) SO2 v.kqes

a] p d cU/k mifLFkr
gSA
(C) P4O6 v.kqes

a] 12 PO cU/k mifLFkr
(D) PCl5(Bks
l ) d k /kuk;u
7.
jl k;u foK ku
6.
gksrsgSaA
prq"Q y d h; vk fr j[krk gS
A
vfHkf ;k d k voy ksd u d hft ,

KC=10
izkjfEHkd lkUnzrk
12
P(g) + 2Q(g)
R(g) + S(g)
2M
4M
rkslgh d Fku@d Fkuksad k p;u d hft ,&
8.
(A) lkE;
ij [R(g)] = [S(g)]
(C) lkE;
ij [P(g)]
~
2M
4
~
10 M
(B) lkE;
ij [P(g)] = [Q(g)]
(D) lkE;
ij [Q(g)]
4
~
10 M
4
~
2 10 M
fuEu esalsd kSulsd Fku vlR; gSa\

(A) NF3 d k f}/kq
zo
vk?kw.kZNH3 lsvf/kd gksrk gSA
(B) foi{k-2, 3-MkbDyks

jks-2-isUVhu
(C) d kcZ
u
esad qy LFkk;h f}/kqzo vk?kw.kZ'kwU; ugh gksrk gSA
VsVkDy ksjkbM esad qy f}/kzqo vk?kw.kZugh gksrk gSD;ksafd bld h fu;fer prq"Q y d h; lajpuk gksrh gSA
(D) lYQ jMkbvkW

DlkbM
v.kqd sfy , f}/kqzo vk?kw.kZ'kwU; gksrk gSA

JRPT2300815C0-3
9.
,d cUn ik=k esafuEu lkE; d k voy ksd u d hft ;sA

N2O4(g)
2NO2(g)
fu;r rki ij] vfHkf ;k ik=k d k vk;ru nqxquk gkst krk gS

A bl ifjorZu d sfy ,] d kSulk@d kSulsd Fku lR;
gSt c lkE; iquZLFkkfir fd ;k t krk gS\
(A) iz
kjfEHkd
lkE; lsrqy uk d jusij NO2 o N2O4 d svka

f'kd nkc d k vuqikr ifjofrZr gks
rk gSA
(B) d q
y
nkc leku jgrk gS] y s

fd u N2O4 d sfo;kst u d h ek=kk ifjofrZr gksrh gSa
(C) d q
y
nkc d slkFk&lkFk N2O4 d sfo;kst u d h ek=kk HkhifjofrZr gksrh gSA
(D) N2O4 d svka

f'kd
nkc o NO2 d svkaf'kd nkc d soxZd k vuqikr leku jgrk gS] t S

l k fd izkjEHk esagksrk
gSA
10.
uhpsd qN xSl h; vfHkf ;kvksad sfy , lkE; fLFkjkad fn;sx;sgS\

(i) 2N2O5
(ii) 2NO
2N2 + 5O2
N2 + O 2
(iii) 2NO2
N2 + 2O2
27
K = 10
15
K = 10
29
K = 10
vkWDlkbM d srRoksaesafo;kst u d sfy ,] fuEu esalsd kSulk@d kS

ulsd Fku lgh gSA
(A) NO2 U;w
ure
(C) LFkkf;Ro
11.
LFkk;h vkWDlkbM gS
A
(B) NO lokZ
f/kd
d k e N2O5 > NO2 > NO gSA
(D) LFkkf;Ro
LFkk;h vkWDlkbM gS
A
d k e NO2 > NO > N2O5 gSA
lgh fod Yi d kspq

fu;sA
(A) O2F2, es
aOF ca/k y EckbZekusx,
eku lsd e gksrh gSA
(B) V
kbZfly kby ,ehu (SiH3)3 N esa] ca/k y EckbZekusx,
(C) OF2 es
aca/k d ks.kCl2O
eku lsd e gksrh gSA
d h rqy uk esad e gksrk gSA
(D) BeCl2(s) es
aBe ijek.kqsp3 lad fjr
gksrk gSA
JRPT2300815C0-4
jl k;u foK ku
jlk;u foKku
12.
fuEu esalsd kSulk@d kSulsd Fku lgh gS@ gSa\

(A) PH3 , (CH3)3N d h rq
y uk esanqcZy
{kkj gSA
(B) ClCl, NF, CF rFkk OF ca

/kksesals] CF ca/k vf/kd re
(C) OF2 d k f}/kq
zo
(D)
/kqzoh; gSA
vk?kw.kZ] H2O d h rqy uk esamPp gksrk gSA
,d ,Yd ksgy vUrjkvkf.od gkbM

kst u ca/k fuekZ.k d sd kj.k leku v.kqlw=k oky sbZFkj d h rqy uk esad e
ok"i'khy gksrk gSA
13.
fuEu esalsd kSuls;kSfxd ksaesalHkh CO cU/k y EckbZleku gksrh gSa\
(A) CH3 C O CH3

||
O
(B)
(C)
(D)
HO
ONa
C
O
14.
fuEufy f[kr esad kcZ_ .kk;u d sLFkkf;Ro d slanHkZesad kSulk@d kSulslgh gS@ gSa%
(A)
>
(B)
> CF3
(C)
>
(D) CH3 CH2 (CH3 )3 C
JRPT2300815C0-5
jl k;u foK ku
jlk;u foKku
jlk;u foKku
fuEufy f[kr ;kSfxd ksaesacsUt hu oy ; esaby sDVkWu ?kuRo d k lgh e d kSulk gS:
OC2H5
OH

16.
(B) II > IV > I > III
(C) IV > III > II > I
(D) I > III > IV > II
fuEufy f[kr esalsd kcZ/kuk;u d sLFkkf;Ro d k lgh e gS@ gSa%

(A)
>
(C)
17.
jl k;u foK ku
15.
(B)
<
>
(D)
<
fuEu esalsd kSulk@d kSulsfod Yi ,Yd hu d sLFkkf;Ro d k lgh e gS@ gSa\

(A)
(B) CH 3C=CHCH 3 > CH 2=CCH 2CH 3
>
CH3
(C)
18.
CH3
CH3
C= C
H
CH 3
<
H
H
C= C
H
CH3
(D)
CH3
<
fuEu esalsd kSulk@d kSuls/kuk;u vuqukn }kjk LFkk;h r ughagksrsgS@ gSa%

(A)
(B)
(C)
(D)
JRPT2300815C0-6
jlk;u foKku
fuEu esalsd kSulk@d kSuls e vuquknh lajpuk d sLFkkf;Ro d k lgh e gSa\

+
(A) H 2C=N=N
>
(B)
<
(C)
>
(D)
20.
jl k;u foK ku
19.
<
lgh d Fku d k p;u d hft , &
(A)
(B)
(C)
(D)
(by s
DVkWu
>
(d kcZ
_
>
?kuRo)
.kk;u d k LFkkf;Ro)
(d kcZ
/kuk;u
d k LFkkf;Ro)
>
<
(f}/kz
qo
vk?kw.kZ)
JRPT2300815C0-7
jl k;u foK ku
jlk;u foKku
bl [kaM esarhu vuqPNsn gSaA
izR;sd vuqPNsn ij nksiz'u gaSA
izR;sd iz'u esapkj fod Yi (A), (B), (C) rFkk (D) gSaA bu pkj fod Yiksaesalsd soy ,d fod Yi lgh gSaA
iz'u 21 l s22 d sfy , v uqPN sn

ifjHkk"kk %vuqukn ,d ,sl h izf ;k gSft lesaijek.kqd h leku fLFkfr j[kusokyh nks;k nkslsvf/kd lajpuk,
,d fuf'pr ;kSfxd d sfy , fy [k ld rsgS
A
v uquknh l ad j % ;g lHkh fofHkUu lEHkkfor la
jpukvksad h okLrfod la
jpuk gksrh gSA ft lsijek.kqv ksad sfy,
lgla;kst h fu;e d k my a?ku fd ;sfcuk gh v.kqv ksad sfy , fy[k ld rsgS
A
vuquknh lad j
JRPT2300815C0-8
jlk;u foKku
cU/k e =
mnk-,
jl k;u foK ku
lHkh lajpukvksaesanksijek.kqv ksad se/; fufeZ

r cU/kksad h d q
y la
[;k
vuquknh lajpukvksad h d q
y la
[;k
O
cU/k e =
2 1 1
1.33
3
vuqukn t kZ= okLrfod cU/k t kZ lokZf/kd LFkk;h vuquknh lajpuk d h t kZ
v.kqd k LFkkf;Ro vuqukn t kZ
v.kqesaft rusvf/kd lgla;kst d rk cU/k mifLFkr gksxsamld h vuquknh t kZmruh gh vf/kd gksxhA
vuqukn t kZ vuquknh lajpukvksad h la[;k
21.
fuEu esalsd kSulh izt krh;ksaesaleku ca/k y EckbZmifLFkr gSa\

(A) I2Cl6
22.
(B) CO32 (Na2CO3
(C) NO3 (NaNO3
esamifLFkr)
S3O102 (V
kblYQ sV
vk;u) esalerqY; cU/kksad h vf/kd re la[;k D;k gS\
esamifLFkr)
(D) SO42 (Na2SO4 es

amifLFkr)
(A) ik
p
(B) pkj
(C) N%
(D) ukS
JRPT2300815C0-9

B3
d ksNksM +d j lHkh cks

jkWu Vkbgsy kbMksad ksrRoksd se/; lh/ksla;ksx lscuk;k t k ld rk gSA BX3 v.kqv ksaesa
cksjkWu Vkbgsy kbM d h T;kferh f=kd ks.kh; lefer gksrh gSA viusoxZd svU; rRoksad sgs
y kbMksad sfoijhr ;s
xSl ] nzo rFkk Bksl voLFkk esa,d y d h; gksrsgSarFkk BF3 rFkkBCl3 xSl h; gS] BBr3 ok"i'khy nzo rFkk B3 Bksl
gksrk gSA cksjkWu Vkbgsy kbM y qbZ
l vEy gksrsgSD;ksa
fd ;smi;qDr {kkj d slkFk lk/kkj.k y qbZ
l lad qy cukrsgSA
t Sl k fd fuEu vfHkf ;k esagS&
BF3 (g) + :NH3 (g) F3B NH3 (s)
y sfd u cksjkWu DyksjkbM] czksekbM rFkk vk;ksMkbM] nqcZy izksVkW

u nkrk inkFkksZt Sl sfd t y ] ,Yd ksgkWy vkS
j ,ehu
d slkFk iz
ksVksuhvi?kVu vfHkf ;k iznf'kZr d jrsgSaA t Sl k fd BCl3 d k rst h lst y vi?kVu gksrk gSA
BCl3(g) + 3H2O() B (OH)3 (aq)+ 3HCl (aq)
,sl k ekuk t krk gSfd mijksDr vfHkf ;k d sigy sin esalad qy Cl3B OH2 curk gSft lesalsHCl
fud y t krk gSvkSj fQ j t y d slkFk vfHkf ;k gksrh gS
A
JRPT2300815C0-10
jl k;u foK ku
jlk;u foKku
23.
BX3 v.kqes
aBX cU/k y EckbZd sizsf{kr
(A) BF3
eku d sckjsesafuEu esalsd kSu lk vuqeku lgh gksxk \
esBF cU/k y EckbZd k izsf{kr eku lS) kfUrd eku lsd e gksxk D;ksafd fo|qr _ .krk d seku B(2.04)
rFkk F(4.0) d svk/kkj ij cU/k esavk;fud izd `fr gksxh ft ld h ot g lsfoijhr vkos'k d svk;u ,d nwl js
d ksvkd f"kZr d jrsgSavr% cU/k y EckbZd k eku d e gksuk pkfg,A
(B) BF3 rFkk[BF4] es
aBF cU/k y EckbZd k eku
(C) BF3
leku gksxkA
esaBF cU/k y EckbZd seku esad eh d k d kj.k B d sfjDr 2p d {kd rFkk F d siw.kZHkjsgq;s 2p
d {kd d schp foLFkkuhd `r p p cU/k d k cuuk gS

A
(D) BX cU/k y EckbZd k lgh e
24.
gksxk BF > BCl > BBr > B
fuEu esalslgh gS%

(A) B(OCH3)3 , BBr3 d h rq
y uk esavf/kd
(B) B(OH)3 (aq) ,d
f=kizksfVd vEy d h Hkk

fr O;ogkj d jrk gSA
(C) BF3 d h rq
y uk esaAIF3 izcy re
(D) mijks
Dr
nq
cZy y qbZl vEy gSA
y qbZl vEy gSA
lHkh lgh gSaA
JRPT2300815C0-11
jl k;u foK ku
jlk;u foKku

fuEu v uqPN sn d ks/;kuiwoZd i<+d j fuEu iz'uksad smkj fnft ,%
v fHkf ;k e/;orhZ%& vfHkf ;k e/;orhZvYi t hfor Lih'kht o mPp f ;k'khy gksrh gSA ;sfo"keka'k o leka'k
cU/k fo;kst u }kjk fufeZr gksrsgSaA vfHkf ;k e/;orhZd sfofHkUu izd kj gSft uesalokZ
f/kd egRoiw.kZd kcZ/kuk;u]
d kcZ_ .kk;u o eqDr ewy d gSA d kcZ/kuk;u ,d d kcZfud Lih'kht gSft lesad kcZu ijek.kqbld sck;re d {k esa
N% by sDVkWu j[krk gS
A rFkk bl ij /kukRed vkos'k jgrk gSA d kcZ/kuk;u d k LFkkf;Ro d ks/kukRed izsjf.kd
izHkko ;k vfrla;qXeu }kjk c<+k;k t k ld rk gS
A ;fn -ijek.kq] d kcZ/kuk;u d slUnHkZesa,d ;k vf/kd ,d kd h
by sDVkWu ;qXe j[krk gSrks,d kd h by sDVkWu ;qXe foLFkkfud j.k d sd kj.k d kcZ/kuk;u d ksiz
cy : i lsLFkkf;d `r
d jrsgSA
d kcZu d k _ .kk;u] d kcZ_ .kk;u d gy krk gSA d kcZ_ .kk;u rhu cU/k ;qXe o ,d ,d kd h ;qXe j[krk gS
A
d kcZ_ .kk;u d k LFkkf;Ro _ .kkRed izsjf.kd izHkko o _ .kkRed felksesfjd izHkko }kjk c<+k;k t k ld rk gSA
eqDr ewy d ,sl h Lih'kht gS] t ks vius ck re d {k esa 7 by sDVkWu j[krh gSA eqDr ewy d d k LFkkf;Ro
vfrla;qXeu o vuqukn }kjk c<+
k;k t k ld rk gSA
25.
fuEu esalsd kSulk lokZf/kd LFkk;h d kcZ/kuk;u e/;orhZgSA

(A)
26.
(B)
(C)
(D)
(C) I > III > II > IV
(D) III > I > II > IV
fuEu eqDr ewy d ksad sLFkkf;Ro d k lgh e gS&
CH2=CHCH2
CH3CH2CH2
II
(B) II > III > I > IV
JRPT2300815C0-12
jl k;u foK ku
jlk;u foKku
jl k;u foK ku
jlk;u foKku
bl [kaM esanksiz'u gSaA
izR;sd iz'u esanksd kWy e gSa] d kWy e I rFkk d kWy e II
d kWy e I esapkj izfof"V;k(A),(B), (C) rFkk (D) gSaA
d kWy e II esapkj iz
fof"V;k(P),(Q), (R) rFkk (S) gSaA
d kWy e I d h iz
fof"V;ksad k d kWy e II d h izfof"V;ksalslqesfy r d jsaA
d kWy e I d h ,d ;k ,d lsvf/kd iz
fof"V;k] d kWy e II d h ,d ;k ,d lsvf/kd iz
fof"V;ksalslqesfy r gks
ld rh gSaA
vks- vkj- ,l- esauhpsn'kkZ;h x;h t Sl h 4 4 vkO;wg nh x;h gS%

(A)
(B)
(C)
(D)
JRPT2300815C0-13
27.
28.
d kWy e-I esafn;sx;sv.kqv ksad ksd kWy e-II esafn;sx;sxq.k vFkok xq.kksad slkFk lqesfy r d hft ;sA
d kWy e-I
d kWy e-II
(A) SiCl4
(P) lHkh ca
/k (vFkkZr~ca/k y EckbZ
)
(B) OSF4
(Q) lHkh ca
/k d ks.k leku
(C) SF4
(R) la
d j.k esad-d {kd
(D) XeO4
(S) p-d ca
/kA
leku gSaA
gSaA
fufgr lfEefy r gSaA
l gh fey ku d hft ,&

d kWy e-I
d kWy e-II
O
||
(A) Ph C NH2
(P) vuq
ukn
lEHko
(B) Ph CH2
(Q) p-by s
DVkWuksad h le
O
||
(C) CH3 C ONa
(R) by s
DVkWu
d k LFkkuhd `r ,d kd h by sDVkWu ;qXe
(D)
(S) by s
DVkWu
d k foLFkkuhd `r ,d kd h by sDVkWu ;qXe
la[;k
JRPT2300815C0-14
jl k;u foK ku
jlk;u foKku
jl k;u foK ku
jlk;u foKku
bl [kaM esanl iz'u gSaA
izR;sd iz'u d k mkj 0 ls9 rd , nksuksa'kkfey ] d schp d k ,d ,d y va

d h; iw.kkd gSA
29.
fuEufy f[kr esalsd qy fd ruh ,sl h Lih'kht gSa] t ksvfLrRoghu gSa%

SF6, BF63, XeF2, OF4, AlF63, PCl5, NCl5, HFO4
30.
CO2, H2SO4, P4O10 rFkk SO3 iz

R;sd
31.
1 atm
rFkk
2400
K
7
d s,d v.kqesap-p cU/kksad h d qy la[;k d k ;ksx Kkr d hft ;sA
ij N2O4 rFkk NO2 d s,d lkE; feJ.k d k ?kuRo 1.84 gm/L gSA lkE; d sfy , Kc
ifjd fy r d hft , rFkk viuk mkj fud Vre iw.kkZd esa50 lsxq.kk d jd snhft , :
N2O4(g)
2NO2(g)
JRPT2300815C0-15
32.
vfHkf ;k]CO(g) + H2O(g)

9/4
CO2(g) + H2(g) d sfy ,
fd lh fuf'pr rki ij lkE;koLFkk fLFkjkad (Kc)
gSA ;fn ,d y hVj ik=k esapkjksaxSl ksad sizR;sd d s10 eksy fy ;sx;sgksa] rkslkE;koLFkk ij H2 (g) d k
eksy izfr'kr D;k gksxk \ (viuk mkj y d s: i esanhft ,, t gky =
33.
N2O5
lkE; ij H2 d k eksy izfr'kr

10
v.kqd sfy , ;ksxnku nsusoky h lHkh lEHko lerqY; lajpukvksad h la[;k m gSA ;fn NO ca/k d k ca/k
e 'n' gks] rks(m n) d k eku Kkr d hft ,A

34.
fo"kekaxh lkE; esa]

2A (s)
;fn log
n
35.
B (g) +
Kp
Kc
n
C (g)
2
3 log RT = 0
Kkr d hft ,A
fuEu ;kSfxd d sfy , vfrla;qXeu (CH cU/k 'kkfey ) n'kkZusoky h ;ksxnku lajpukvksad h d qy la[;k gS&
JRPT2300815C0-16
jl k;u foK ku
jlk;u foKku
36.
fuEufy f[kr ;kSfxd ksaij fopkj d hft , %

O
fd ruh Lih'kht ,sjkseS

fVd gSaA
37.
N d h vuq
uknh la
jpukvksa(resonance structures) d h la[;k gS
NaOH
38.
fuEu esalsfd rusd kcZ/kuk;u CH CH CH2 d h rqy uk esavf/kd LFkk;h gS\
(i)
(ii)
(vii)
(viii)
(iii)
(iv)
(v)
(vi)
(ix)
JRPT2300815C0-17
jl k;u foK ku
jlk;u foKku
CHEMISTRY
1.
Sol.
Sol.
Select correct statement(s)..

lgh d Fku@d Fkuksad kspqfu, ..
(A) KP of a particular reaction depends only
on temperature.
(D) During dissociation of PCl5(g), number of
moles increases, so Mavg decreases.
(A) ,d fuf'pr vfHkf ;k d kKP d s
oy rki ij
6.
Sol.
fuHkZ
j d jrk gS
A
(D) PCl5(g) d sfo;ks
t u d snkSjku] eksy ksad h
la[;k c<+rh gSvr%Mavg ?kVrk gSA
2.
Sol.
Which one of the following are ..

MkbukbVkst u vkWDlkbM d sfy, ..
I is not valid i.e. N cant expand its octet.
I ekU; ughagSvFkkZ
r~N viusv"Vd d k izl kj
gy
ughad j ld rk gSA
3.
Which of the following compounds ..

fuEu esalsd kSuls;kSfxd ksesa] fd lh Hkh ..
Sol.
In H3PO4 All O atom have F.C. = 0

H3PO4 es
a lHkh O ijek.kqv ksad k F.C. = 0
gSA
4.
Sol.
Which is correct statement ..

fuEu esalsd kSulk@d kSulsd Fku ..
Maleic acid
fumaric acid
O2[AsF4] = O2+
B.O = 2.5
so O2 has smaller bond length than O2
KO2 = O2
B.O = 1.5
Greater the size of the halogen atom greater
will be bond angle.
gy %
eSy sbd vEy

O2[AsF4] = O2
;wesfjd vEy
+
Consider the reaction ..

vfHkf ;k d k voy ksd u ..
Sol.
P(g) + 2Q(g)
R(g) + S(g)
12
KC = 10
Initial conc.
2M
4M
0
0
at equilibrium x
2x
2M
2M
conc.
(x 0)
Since KC it very large,
reaction will almost take place to completion.
(2)(2)
12
4
KC = 10 =
x = 10 M
x(2x)2
4
[P(g)]eq = 10 M
4
[Q(g)]eq = 2 10 M
B.O = 2.5
B.O = 1.5
gSy kst u ijek.kqd k vkd kj ft ruk vf/kd gksxk

mruk gh cU/k d ks.k vf/kd gksxkA
5.
Which of the following statements ..
fuEu esalsd kSulk d Fku xy r ..

Sol.
Refer to notes.
uksV~l nsa[ksA
d sd {kd ksad schp vf/kd t kZvUrj

d sd kj.k % d ksbZlad j.k ugha, SCl6 (Cl d k vkd kj
cM+k gksusd sd kj.k) vkSj FCl3 (F ij d-d {kd ksad h
vuqiy C/krk d sd kj.k) d k vfLrRo ugh gksrk gSA
(B) SO2 v.kqes
a,d p- d cU/k o ,d p- p
cU/k mifLFkr gksrsgSaA
(C) P4O6 v.kqes
a] 12 PO cU/k mifLFkr gksrsgSaA
(uks
V~l ns[ksa)
(D) PCl5 (Bks
l ) d k /kuk;u prq"Q y d h; vk fr
j[krk gSA (PCl4 + uksV~l ns[ksa)
(A) PH5 (P
7.
blfy , O2 d h O2 d h vis{kk cU/k y EckbZ d e

gksrh gSA
KO2 = O2
Which is/are true statement(s) ..

fuEu esalsd kSulk@d kSulsd Fku ..
(A) PH5 (due to large energy difference
between orbitals of P : No hybridisation),
SCl6 (due to larger size of Cl) and FCl3 (due
to non-availability of d-orbitals on F) do not
exist.
(B) One p- d bond and one p- p bond
are present in SO2 molecule.
(C) 12 PO bonds are present in P4O6
molecule.(Refer notes)
(D) Cation of PCl5(s) has tetrahedral shape.
(PCl4 + Refer notes)
[R(g)] = [S(g) = 2M
Sol.
P(g) + 2Q(g)
2M
4M
izkjfEHkd
lkUnzrk
lkE; x
lkUnzrk ij
2x
R(g) + S(g) KC = 10
0
0
2M
12
2M
D;ksafd KC cgqr vf/kd gS] vfHkf ;k

y xHkx iw.kZgkst k;sxhA
(x 0)
KC = 10
12
(2)(2)
x(2x)2
4
[P(g)]eq = 10 M
4
[Q(g)]eq = 2 10 M
[R(g)] = [S(g) = 2M
x = 10 M
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
SOLJRPT2300815-21
8.
Which of the following ..

fuEu esalsd kSulsd Fku vlR; ..
9.
Sol.
Sol.
(A)
Consider the following equilibrium ..

,d cUn ik=k esafuEu lkE; d k ..
N2O4(g)
2NO2(g)
As volume is doubled, reaction shifts in
forward direction. At new equilibrium, PNO2
and
PN2O4
are not same as at initial
equilibrium. Hence total pressure changes.

So NH3 has higher dipole moment than NF3.
(PNO2 )2
Kp does not change, So
PN2O4
(B)
PN2O4
It has some dipole moment
unsymmetrical molecule.
due
(PNO2 )2
to
gy %
(C)
do not change. But
PNO2
PN2O4
As reaction shifts in forward direction,

change.
N2O4(g)
2NO2(g)
(D)
Kp
due
PN2O4
to
(PNO2 )2
PN2O4
(A)
(PNO2 )2
ifjofrZr ugh gksrk gSA blfy ,
PNO2
Sol.
change.
t Sl sgh vk;ru nqxquk fd ;k t krk gS] rksvfHkf ;k

vxz fn'kk esa vxzl j gksrh gSaA u;s lkE; ij]
izkjfEHkd lkE; d sleku, PNO2 o PN2O4 leku ugha
gksrsgSa] blfy , d qy nkc ifjofrZr gksrk gSA
It does not have dipole moment due to

symmetrical molecule.
It has some dipole moment

unsymmetrical molecule.
or
ifjofrZr
PN2O4
ugha gksrk
gSA
vFkok
y sfd u
ifjofrZr gksrk gSA
t Sl sgh vxzfn'kk esvxzl j vfHkf ;k ifjorZu

10.
blfy , NH3 d k f}/kqzo vk?kw.kZNF3 lsvf/kd gksrk

gSA
Sol.
(B)
The equilibrium constant for ..

uhpsd qN xSl h; vfHkf ;kvksad s..
1
Stability of Reactant
equilibrium cons tan t
most stable oxide NO
least stable oxide NO2
bld k vlefer v.kqd sd kj.k d qN f}/kqzo vk?kw.kZ

gksrk gSA
Sol.
f ;kd kjd d k LFkkf;Ro
lkE; fLFkjkad
lokZf/kd LFkk;h vkWDlkbM NO
U;wure LFkk;h vkWDlkbM NO2
(C)
11.
;g lefer v.kqd sd kj.k f}/kzqo vk?kw.kZughaj[krk

gSA
(D)
Choose the correct ..
lgh fod Yi d ks..

Sol.
(B) Has partial double bond character due to

p-d delocalisation.
(C) OF2=103 (approximate) and OCl2 = 112
(approximate).
(D) Exist in polymeric structure as
in solid state.
bld k vlefer v.kqd sd kj.k d qN f}/kqzo vk?kw.kZ

gksrk gSA
SOLJRPT2300815-22
Sol.
foLFkkuhd j.k d s d kj.k vkaf'kd f}ca/k

y {k.k j[krk gS
A
(C) OF2=103 (y xHkx) rFkk OCl2 = 112
(y xHkx).
(D) Bks
l voLFkk esa
(B) p-d
13.
In which of the following compounds ..
fuEu esalsd kSuls;kSfxd ksaesalHkh CO cU/k

..
d s: i esa
Sol.
cgqy hd j.k lajpuk esafo|eku gksrk gSA

12.
Sol.
(due to
O
O
equivalent resonating structure CO bond
length are equal)
Which of the following statement(s) ..

fuEu esalsd kSulk@d kSulsd Fku lgh ..
(B) ClCl, the electronegativity difference is
zero; so it is non-polar. NF, the
electronegativity difference is 1. CF, the
electronegativity difference is 1.5. OF, the
electronegativity difference is 0.5. So, CF is
most polar bond.
(C) Dipole moment of H2O is greater than
that of OF2.
(In dianion of squaric acid all

CO bond length are equal due to equivalent
resonating)
(rq
Y;kad
Sol.
vuquknh lajpuk d sd kj.k CO cU/k y EckbZleku

gksrh gS
Sol.
(D) CH3CH2OH and CH3CH3

Ethyl alcohol exists as associated molecules
because of intermolecular H-bonding. So it
has higher boiling point than that of ether.
(B) ClCl es
afo|qr_ .krk vUrj 'kwU; gSvr% ;g
v/kqzoh; gksrk gSA NF esafo|qr_ .krk vUrj 1, C
F es
a fo|qr_ .krk vUrj 1.5 rFkk OF esa
fo|qr_ .krk vUrj 0.5 gS] vr% CF vf/kd re
/kqzoh; ca/k gS
A
(C) H2O d k f}/kq
zo vk?kw.kZ] OF2 d h rqy uk esamPp
gksrk gSA
(LD;w
osfjd
vEy d sf}_ .kk;u
esalHkh CO cU/k yEckbZrqY;ka

d h vuquknh lajpuk
d sd kj.k leku gksrsgS
14.
Which of the following is/are ..
fuEufy f[kr esad kcZ_ .kk;u d s..

Sol.
>
(due to conjugation
negative charge present on more

electronegative atom).
> CF3 (due to d-orbital conjugation.)
<
(D) CH3CH2OH rFkk CH3CH3
(due to conjugation and
,fFky ,Yd ksgy vUrjk v.kq

d H-ca/k fuekZ.k d s
d kj.k] laxqf.kr v.kqv ksad s: i esajgrk gS] vr%
bld k DoFkukad ] bZFkj d h rqy uk esamPp gksrk gS
A
aromatic)
CH3 CH2 (CH3 )3 C
(due to less + I effect)
SOLJRPT2300815-23
18.
Sol.
(vf/kd
>
Which of the following cation..
fuEu esalsd kSulk@d kSuls/kuk;u..
fo|qr_ .kh ijek.kq

Sol.
ij mifLFkr la;qXeh _ .kkRed vkos'k d sd kj.k)

> CF3 (d-d {kd
la;qXeu d sd kj.k)
(la
;qXeu
<
19.
Which of the following is/are..
Sol.
fuEu esalsd kSulk@d kSuls e..

All are correct. l Hkh l gh gS
aA
20.
Select the correct statement ..
rFkk ,s
jksesfVd rk d s
d kj.k)
CH3 CH2 (CH3 )3 C (d e +I iz

Hkko
d sd kj.k)
lgh d Fku d k p;u ..

Sol.
15.
The order of electron density ..
lHkh lgh gSA
fuEufy f[kr ;kSfxd ksaesacsUt hu ..

Sol.
+m group increases electron density in the

benzene ring.
21.
Sol.
csUt hu oy ; esa+m lewg by sDVkWu ?kuRo d ks

c<+krk gS
A
Sol.
Equal bond lengths ..

fuEu esalsd kSulh izt krh;ksa..
Refer to notes
uksV~l nsa[ksA
22.
16.
All are correct.
The correct stability order ..
Find the maximum number..

S3O102 (V
kblYQ sV vk;u) esa..
fuEufy f[kr esalsd kcZ/kuk;u ..

Sol.
Sol.
(A)
>
(due to +m effect)
(+m iz
Hkko
d sd kj.k)
23.
Sol.
(B)
>
(due to aromaticity)
(,s
jksesfVd rk d sd kj.k)
(C)
gksusd sd kj.k Js.kh esaBF3 y qbZl vEy lclsnqcZy

gSA
<
(due to +m
& +I effect) (+m o +I iz

Hkko
(D)
17.
d sd kj.k)
Which of the following is/are ..
fuEu esalsd kSulk@d kSulsfod Yi..

CH3
Sol.
CH3
C= C
H
H
CH 3
>
H
C= C
24.
Sol.
(fact) (rF;)
<
Which of the following is the ..

BX3 v.kqes
aBX cU/k y EckbZ..
Due to effective p p delocalised bonding
between B and F, BF3 is weakest lewis
acid in the series.
B o F d se/; iz
Hkkoh p pfoLFkkuh r cU/ku
H
CH3
Which of the following is ..

fuEu esalslgh ..
Effective p p bonding and bigger size of
OCH3 group.
BF3 is more acidic than AlF3 because of the
small size of B than that of Al.
izHkkoh p p cU/ku o OCH3 lewg d k cM+k
vkd kj
d h vis{kk vf/kd vEy h; gS bld k
d kj.k B d kAl d h vis{kk NksVk vkd kj d k gksuk gSA
BF3, AlF3
Ans. (A)
SOLJRPT2300815-24
25.
Which of the following is ..
fuEu esalsd kSulk lokZf/kd ..

Sol.
+m lew
g
26.
(B)
+m group increases stability of carbocation.
d kcZ/kuk;u d sLFkkf;Ro d ksc<+krk gSA
The correct stability order ..
v{kh; F-S-F ca/k d ks.k= 178.5 ; fo"kqorh; vFkok
fuEu eqDr ewy d ksad sLFkkf;Ro..

Sol.
Resonance, hyperconjugation and + I effect

increases stability of free radicals.
Sol.
vuqukn] vfrla;qXeu o +I izHkko] eqDr ewy d d s

LFkkf;Ro d ksc<+krk gSA
27.
Match the molecules given ..

d kWy e-I esafn;sx;sv.kqv ksa..
ry h; F-S-F ca/k d ks.k= 110
(C)
v{kh; F-S-F ca/k d ks.k = 179 ; fo"kqorh; vFkok

Sol.
(A)
ry h; F-S-F ca/k d ks.k= 103
(D)
(B)
Axial F-S-F angle = 178.5 ; Equatorial F-S-F

angle = 110
29.
Sol.
(C)
Axial F-S-F angle = 179 ; Equatorial F-S-F

angle = 103
(D)
gy
(A)
prq"Q y d h;
Amongst the following, the ..

fuEufy f[kr esalsd qy fd ruh ..
(1) BF63 does not exist as there is no vacant
d-orbital in B and hence it cannot exceed its
covalency beyond four.
(2) OF4 does not exist as oxygen cannot
exceed its covalency as it does not have dorbital.
(3) NCl5 does not exist as there is no dorbital with N.
(4) HFO4 does not exist as there is no vacant
d-orbital in F and hence it cannot exceed its
covalency.
(1) BF63 ughaik;k t krk gS
] D;ksafd B esafjDr d-
d {kd ughagksrk gS] blfy, ;g viuh la;kst d rk

d k pkj lsT;knk izl kj ughad j ld rk gSA
(2) OF4 ugha ik;k t krk gS
] D;ksafd vkWDlht u
viuh la;kst d rk d k izl kj ugha d j ld rk gS
D;ksafd blesad ksbZHkh fjDr d-d {kd ughagksrsgSaA
(3) NCl5 ugha ik;k t krk gS
] D;ksafd N esa d ksbZ
fjDr d-d {kd ughagksrsgSaA
(4) HFO4 ughaik;k t krk gS
] D;ksafd F esafjDr
d-d {kd ughagks
rk gS] blfy, ;g viuh la;kst d rk
d k izl kj ughad j ld rk gS
A
SOLJRPT2300815-25
30.
Sol.
Find the sum of total number ..

CO2, H2SO4, P4O10 rFkk SO3 iz
R;sd ..
CO2 (two p-p bonds), H2SO4 (No p-p
bonds), P4O10 (No p-p bonds) and SO3
(One p-p bond).
Sum = 2 + 1 = 3
CO2 (nks p-p cU/k), H2SO4 (d ks
bZ p-p cU/k
ugha), P4O10 (d ksbZ p-p cU/k ugha) o SO3 (,d

p-p cU/k).
;ksx = 2 + 1 = 3
31.
Sol.
Mole percent of H2 (g) at equilibrium =

100 = 30
Therefore, y =
gy -
CO(g) + H2O(g)
10 x
......... at eqb.
lkE;
32.
Sol.
At a certain temperature..
vfHkf ;k] CO(g) + H2O(g)
H2(g) ..
We have,
CO(g) + H2O(g)
10 x
10 x
10 x
CO2(g) + H2(g)
10 + x
10 + x
10 mole
izR;sd vfHkd eZd d h eksy la[;k gSA

K=
(10 x)2
(10 x)2
= 9/4 (fn;k gq
v k gS) ;k
10 x
= 3/2 ; x = 2
10 x
CO2(g) +
lkE; ij H2 (g) d k eksy izfr'kr =
10 x
100
40
= 30
10
mole
CO2(g) + H2(g)
10 + x
t gk x lkE; ij mRiknksa esa ifjofrZr gksus okys
10 + x
blfy ,, y =
33.
Moles at eqb.
Sol.
30
= 3.
10
The number of equivalent ..

N2O5 v.kqd sfy , ;ks
xnku ..
Bond order of N2O5 is 3/2 = n
or concentration at eqb.
where x is the number of moles of each
reactant changed to the products at
equilibrium.
(10 x)2
= 9/4 (given)
(10 x)2
10 x
= 3/2 ; x = 2
10 x
K=
eksy
vFkok lkE; ij lkUnzrk
t kursgS p =
10 mole 10 mole
Initial moles
10
d k v.kqHkkj =
dRT
M
1.84 x 1/ 12 x 2400 / 7
1=
92 / (1 x)
x = 0.75
36
4P 2
KP =
=
7
1 2
1
36
ng
KC = KP(RT)
=
= 0.18
7
RT
Ans.
0.18 50 = 9
We have, ge
10 eks
y
lkE; ij eksy
ij
Mol. wt. of mix. feJ.k
92(1 x) 46 2x
92
=
1 x
1 x
10 eks
y
izkjEHk esaeksy
izkjEHk esa
2x
30
= 3.
10
ge t kursgS] fd
10 eks
y
The density of an equilibrium ..

2400
1 atm rFkk
K ij N2O4 rFkk ..:
7
N2 O 4
2NO2
1M
0
.......
initial
(1 x)
10 x
40
or
It has 4 possible structures
m=4
Thus mn = 6
SOLJRPT2300815-26
Sol.
N2O5
v.kq d k ca/k e eku 3/2 = n gSA
Sol.
The given compound have 7

hyperconjugative hydrogen atom.
N2O5 v.kqd h 4 la
jpuk,salEHko
m=4
vr% mn = 6
Sol.
gSA
j[krk gSA
36.
34.
fn;k x;k ;kSfxd 7 vfrla;qXeh gkbMkst u ijek.kq
In a heterogeneous ..
Consider the following compounds .
fuEufy f[kr ;kSfxd ksaij fopkj d hft , ..
fo"kekaxh lkE; esa..

Sol.
KP = KC (RT)ng
log
log
Kp
Kc
Kp
Kc
Sol.
= ng log RT
are aromatic species. ,s

jkseSfVd
Lih'kht gSaA
ng log RT = 0
ng = 3
1+
35.
n
=3
2
n
=2
2
n = 4.
The total number of ..
fuEu ;kSfxd d sfy , ..

37.
The number of resonance ..

N d h vuq
uknh la
jpukvksa..
Sol.
SOLJRPT2300815-27
38.
Number of carbocations which ..
fuEu esalsfd rusd kcZ/kuk;u ..

Ans.
5 (i, ii, iv, v, vii)
SOLJRPT2300815-28
CHEMISTRY
1.
(BD)
8.
2.
(BCD) 3.
(ACD) 4.
(ABCD) 5.
(ABD) 6.
(ABCD) 7. (ACD)
(ABD) 9.
(ACD) 10.
(AB)
11.
(BCD) 12.
(ABD) 13.
(BC)
15.
(D)
16.
(ABCD) 17.
(ABD) 18.
(ABD) 19.
(ABCD) 20.
(ABCD) 21. (BCD)
22.
(C)
23.
(C)
(A)
(A)
26.
(D)
27.
(A P, Q) ; (B R, S) ; (C R) ; (D P, Q, S)
28.
(A P,Q,R,S) ; (B P,Q) ; (C P,Q,R,S) ; (D P,Q,R,S)
29.
(4)
30.
(3)
31.
(9)
33.
(6)
36.
(4)
37.
(9)
38.
(5)
24.
25.
32.
(3)
34.
(4)
14. (ABD)
35.
SOLJA*PT1040514-31
(7)

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CHEMISTRY

SECTION 1 : (Maximum Marks : 80)

This section contains TWENTY questions

Select correct statement(s) :

CaO(s) + CO2(g) ; Kp = PCO2

On increasing number of moles of CaCO3, at equilibrium, moles of CO2 at new equilibrium

PCl3(g) + Cl2(g), Mavg decreases with progress of reaction.

(Mavg Average molecular mass)

Space for Rough Work

Which of the following compounds contain 1 formal charge on any of O atom :

Which is correct statement ?

Which of the following statements is incorrect?

Which is/are true statement(s) among the following :

(A) PH5, SCl6 and FCl3 do not exist.

Consider the reaction

then select correct statement(s)

(A) At equilibrium [R(g)] = [S(g)]

(B) At equilibrium [P(g)] = [Q(g)]

(C) At equilibrium [P(g)]

(D) At equilibrium [Q(g)]

Which of the following statements are false?

Consider the following equilibrium in a closed container. N2O4(g)

(A) The least stable oxide is NO2

(B) The most stable oxide is NO

(C) The stability order is N2O5 > NO2 > NO

(D) The stability order is NO2 > NO > N2O5

Choose the correct options.

Space for Rough Work

Which of the following statement(s) is/are correct ?

(A) CH3 C O CH3

Which of the following is/are true for stability of carbanion.

(D) CH3 CH2 (CH3 )3 C

Space for Rough Work

(A) I > II > III > IV

(B) II > IV > I > III

(D) I > III > IV > II

The correct stability order of carbocation is / are :

(C) IV > III > II > I

Which of the following is/are correct option for stability of alkene ?

(B) CH 3C=CHCH 3 > CH 2=CCH 2CH 3

Which of the following cation is not stablized by Resonance :

Space for Rough Work

Select the correct statement :

Space for Rough Work

SECTION 2 : (Maximum Marks : 24)

This section contains THREE paragraphs

Based on each paragraph, there will be TWO questions.

Paragraph for Question Nos. 21 to 22

Space for Rough Work

Total No. of bonds formed between two atoms in all structures

Stability of molecule resonance energy.

Resonance energy number of resonating structures.

Equal bond lengths are present in :

(B) CO32 (present in Na2CO3)

(C) NO3 (present in NaNO3)

(D) SO42 (present in Na2SO4)

Find the maximum number of equivalent bonds in S3O102 (Trisulphate ion)

Space for Rough Work

Paragraph for Question Nos. 23 to 24

Which of the following is correct :

(B) B(OH)3 (aq) behaves as a triprotic acid

Paragraph for Question Nos. 25 to 26

Space for Rough Work