NARAYANA IIT ACADEMY

INDIA

CHEMISTRY-ASSIGNMENT-1
CHEMICAL BONDING, PRACTICAL CHEMISTRY, METALLURGY & COMPLEX COMPOUNDS
Sec: Sr.IIT-IZ & NIZ-COSPARK
PONGAL WORKSHEET

MULTIPLE CHOICE QUESTIONS

1. The metals which cannot be obtained by electrolysis of aqueous solution of their salts are
A) Ag
2.

C) Cu

D) Al

C) Ag

D) Cu

Bessemerization is carried out for

A) Mg

3.

B) Mg

B) Fe

In which of the following pair(s), the minerals are converted into metals by selfreduction process ?
A) Cu2 S , PbS

4.

B) PbS , HgS

C) PbS , ZnS

D) Ag 2 S , Cu2 S

The reaction(s) which does (do) not occur in the reduction zone in the extraction of
iron from haematite ore is(are)

5.

A) Fe2O3 CO 2 FeO CO2

B) FeO CO Fe CO2

C) Fe2O3 3C 2 Fe 3CO

D) CaO SiO2 CaSiO3

Which of the following reduction reactions are actually employed in commercial

extraction of Metals?
A) Fe2O3 2 Al Al2O3 2 Fe

B) Cr2O3 2 Al Al2O3 2Cr

C) 2 Na Au CN 2 Zn Na2 Zn CN 4 2 Au
D) Cu2 S Pb 2Cu PbS
6.

For which of the following metal, the carbon reduction cannot be used ?
A) Pb

7.

C) Na

D) Fe

Aqueous FeCl3 solution is used in the identification test for

A) Phenols

8.

B) Mg

B) Enols

C) Thiocyanide ions D) Cyanide ion

Benedict solution is used in the identification of

A) Glucose

B) Benzene-1,2-di-carboxylic acid

C) Acetaldehyde

D) Benzophenone

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9.

Sr.IIT-IZ & NIZ-COSPARK_PONGAL WORKSHEET

Which is (are) almost insoluble in water ?

A) PbSO4

10.

B) PbCrO4

B) KHCO3

B) Cd, As, Sn, Pb

B) ZnCl2

B) K 3 Fe CN 6

16.

B) Co 2

D) FeCl3

C) Fe4 Fe CN 6 D) K 4 Fe CN 6
3

C) Pb

D) Hg 2

A) is trigonal planar

B) has sp 2 -hybridisatin

C) is paramagnetic

D) is diamagnetic

Which of the following complexes is/are achiral ?

C) Pt C2O4 3

18.

C) HgCl2

The complex HgI 3

A) Cis Pt NH 3 2 Cl2

17.

D) Mg

Which of the following can be detected by the borax bead test ?

A) Ni 2

15.

C) Ca, Ba, Sr, Mg

Which will not give test of Fe 3 ion ?

A) FeCl3

14.

D) Mg HCO3 2

Which of the following will respond to positive chromyl chloride test ?

A) CuCl2

13.

C) Ca HCO3 2

Which is (are) precipitated on passing H 2 S in presence of alkali in mixture analysis ?

A) Zn, Mn, Co, Ni

12.

D) Ag 2 S

Which of the following can be obtained in the solid state ?

A) NaHCO3

11.

C) CaF2

B) Zn H 2O 2 Cl2 Tetrahedal
D) trans Pt NH 3 4 BrCl

The compound(s) that exhibit(s) geometrical isomerism is(are)

A) Pt en Cl2

B) Pt en 2 Cl2

C) Pt en 2 Cl2 Cl2

D) Pt NH 3 2 Cl2

Identify the correct statement(s) regarding Cr en 2 Cl2 and Co C2O4 2 NH 3 2

complex ions.
A) Both are chelate complexes
B) Both have octahedral geometry
C) Both can have three geometrical isomers
D) Both are organometallic compound
CHEMISTRY ASSIGNMENT-1

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19.

Sr.IIT-IZ & NIZ-COSPARK_PONGAL WORKSHEET

Among the following which is most stable ?

1) Fe CN 6

and FeF6

(X)
3) Cr CN 6

2) Fe CN 6

(Y)
3

and Cr CN 6

( P)

and Fe CN 6

(S)

(T)

(Q)

Choose the correct code:

20.

A) 1 X , 2 T , 3 Q

B) 1 X , 2 S , 3 Q

C) 1 X , 2 S , 3 P

D) 1 Y , 2 T , 3 Q

Which of the following can act as bridging ligands ?

A) OH

21.

C) CO

D) Cl

C) K 2Cr2O7

D) Co NH 3 6

d d transition is possible in
A) Cu NH 3 4

22.

B) H 2O

B) KMnO4

Which of the following compound has/have effective atomic number equal to the
atomic number of noble gas

23.

A) K Co CO 4

B) K 2 Fe CO 4

C) Co NH 3 6 Cl2

D) CoCl3 H 2O 3

Which of the following obey 18e rules

A) Cr CO 6

24.

25.

B) Ni CO 4
4

Complex ions NiCl6 and Ni CN 6

C) Cr C6 H 6 2
4

D) Fe C5 H 5 2

similar in their given properties

A) oxidation state, geometry

B) co-ordination number, EAN

C) Magnetic moment, geometry

D) Stability, colour

Which among the following is (are) isostructural pair(s) ?

NF3 , NO3 , BF3 , H 3O , NH 3

A) NF3 , H 3O

CHEMISTRY ASSIGNMENT-1

B) NF3 , NH 3

C) NF3 , NO3

D) NO3 , BF3

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