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Contents
PREFACE xiii
Part
l:
ATOMICBOND'NG 3
1.1
I.2
1.3
1.4
1.5
Introduction
Ionic Bonds
CovalentBonds
MetallicBonds
VanDerWaalsBonding
1.5.1 Hytlrogen Bonding
L6
1.7
i.8
2
BondingEnergies
Solids
SOLIDS 15
State
The Crystalline
12
THE ARCHITECIUREOF
2J,
Thermal Properties of
BondingForces
15
2.1.3
2.1.4
2.2
23
2.4
Crystals 17
Covalent Crystals,21
Ctystals
Md Unit Celh25
State
State
37
39
2.4.5
2.5
3
DEVELOPMENT OF MICROSTRUCIURE 5A
3.1
3.2
Introduction
50
Solidification 50
3.2.
3.2.2
3.3
3.4
55
Diagrams 55
3.4.1 One-comPonentSYstew55
Phase
j.4.2
Two'comPontent SYstems, 56
3.4.3
3.4.4
3.5
3.6
Cooling
Sinteriig
60
Microstructure
3.6.1
62'
PorositY'62
.4
66
SURFACEPRAPERTIES
4.1
4.2
4.3
4'4
4.5
4.6
43
- 4.8
Interfaces 69
Wetting
AdsorPtion 70
Surfactants 72
CaPillarY
Part
Effects
Adhesion
Colloids
73
75
76
4.8.1 Strucnre of
4.8.2
4.9
69
Colloi'ds,76
StabilitY of Colloids'77
The Double
LaYer
79
5 RESPONSf
5.1
83
OF MATERIALSIOSIRfSS B5
Tension 86
5.1.1 Elatic
Behaviot,ET
5.1.i
88
Propertia'97
5.1-4 Experinental Determirulion of Tewile
5.2
5,3
ComPression
Bendinc
S'i.l
94
96
5.4
vl
Contents
Torsion
100
5.4.3
Test
5.5
5.6
Direct Shear
Multiaxial
5.6.1
5.7
loading
104
107
.
6
103
Transverse Stresses,106
Hardness
5.7.1
103
6.1.
Failure
Theories
115
6.2
6.1
.3
6.1
.4
17
6.2.1 GrifithTheory,l22
6.2.2 Straylntensig Factor; 12j
6.2.3 Comprasive Failurql26
6,2.4 Notch
Sensitivity, 126
6.2.5 CrackVelocity,l2T
6.3
6.4
6.5
The Ductile-BrittleTransition
FractureEnergy 130
EffectofRateofloading
6.5.1
127
131
6.5.2
Sntic Fatigue,lj3
6.5.j
SOT'DS
'38
7.7
7.2
7.3
7.4
7.5
ElasticandViscousBehavior 138
Simple RheologicalModels 140
Rheology of
Fluids
RheologyofVscoelasticsolids
143
144
Creep of Engineering
7.5.1
7.5.2
7.5.3
Materials
146
B FATIGUE 152
i 8.1 Introduction
Contents
141
152
vtl
Failure
8.2
153
lnading
8.3
Types of Fatigue
8.4
157
Loading
157
Fatigue
160
8.7
FactorsAffectingFatigueLife
8.7.1 Strusing Conditrons, 164
Data
162
163
8.7.2 MateialProPeftiel169
8.7.i
Experimental Methods in
8.8
8.8.1 Falgw
8.8.2 Fatigue
Fatigue
Test
Procedares,
17j
Concretes
Particulate Composites: Portland Cement and Asphali
Part
lll:
lntroduction
9.1
9.2
179
Structure
9.3
ComPosition and
9.4
InterfacialhoPerties
186
9.5
MechanicalBehavior
187
IO
170
Machines 172
Composites
181
186
AGGREGATES 189
10.1
Introduction
10.2
Composition and
10.3
Characteristics 192
189
Structure
190
1 92
0.3. 1 G eometrical P roP ertiu,
10.3.2 PhYsiul ProPeniet 196
To ughness, I 99
1 0.3.3 Strength and
11
PORTLANDCfMTNICONCRETE
11.1 Introduction
11.2
204
204
of P9rlla1d
11'2.1 Conrposition and Hydration
11.2'2 Microstrucntre
Compositions'2|4
11.2.i Portland Cemens of Different
Adntixtures' z t t
1.2'4 Blendett Cemenls and Minerol
11.2.5 Porosity and Pore Strucnue'2l8
Contents
!erynt'206
177
ll.3
PropertiesofConcrete 222
11.j.1 Fruh Concrete, 223
1.3.2 Befuiuior duing Setting 227
I L3.3 Chemical AdmLrnres, 228
I 1.j.4 Propertia of Hartlened Concrete, 231
1
7L.4
Durability of Corcrete
I 1.4.1 Permeability
24'1.
11.5
,"t,
24g
249
lL.6
12
Concrete Mix
Design
252
LL.L Introduction
I22
256
2.2.
1 Int o duction,
257.
12.3 LiquidAtphalts
268
12.4
Binder-Aggregate
Bonding
72.5
269
2.5.
I ntro duction, 270
12.5.2 Composition and Stracture, 271
12.5.i ResponsetoAppliedLoads'272
12.5.4 Raponse to Moisnre,275
12.5.5 Response
Temperaare, 276
Atlditivu
and Fiuers,277
Part
tV
13
STEEL 283
l3.L
Introduction
13.2
CompositionandStructure 284
283
I3.3
13.3.2
1 3. 3.
13.4
MechanicalProperties 295
1 3.4.
Contents
tx
13.4.i We&ability,299
13.5
li.5.3 Conosion
13.6
14
Control, 302
WOODANDTIMBER 309
1,4.I Introduction
14.2
309
The Structure of
Wood
310
31
14.3
Wood
318
14.4
145
14.6 Grading
Timber
332
14,6.1 WualGradingj32
14.6.2 Meclnnical Grading, 332
14.6.3 Description of Visual Stras Grades' 332
74.7
14.8
14.9 DurabilitY
341
14.9'1 Fire,341
14.9.2 DecaY'342
14.9.3 Termites,343
I 4.9. 4 ltlurine B o rets, 3 44
14.9.5 Presemative Treatments, 344
15
.
'
Fillers
346
15.3
Additives and
15.4
353
15.4.4 Atlhesion,356
Contents
329
16
EIBER.REINFORCEDCOMPOS'IES
L6.L Introduction
L6.2
359
359
16.3
Fibers aad
Matrices
i69
371
Contents
XI