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Documenti di Professioni
Documenti di Cultura
of Atomic Hydrogen
The gas combines explosively in familiar environments to form
molecular hydrogen. A new technique that inhibits the reaction
makes it possible to study certain properties of a quantuIJ1 gas
by Isaac F. Silvera and Jook Walraven
66
of
identical
particles
can
PUMP A ND
E VA PORATION =----l-.l
LINES
LIQUID NITROGEN
(77 K.)
LIQUID HELIUM
(4.2 K.)
REFRIGERATOR
(.005 TO .6 K.)
SUPERCONDUCTING
MAGNET
HYDROG
STABILIZATION CELL
BOLOMETER
FILM OF
SUPERFLUID HELIUM
HELIUM VA POR
COMPRESSOR
ELECTRIC
DISCHARGE TUBE
TEFLON VALV E
in less than a thousandth of a second. The apparatus incorporates several nested refrigeration
units maintained at successively lower temperatures. Hot atomic hydrogen gas is emitted by
an electric discharge tube and piped past a series of cold surfaces. The chilled hydrogen then
enters the magnetic field, where it can be held for several hours. At a temperature of .3 degree
Kelvin densities as high as 1023 atoms per cubic meter have been attained for a few minutes.
67
1981 SCIENTIFIC AMERICAN, INC
W reduced
to 2. 18 degrees, howev
er, the liquid suddenly becomes such a
good conductor of heat that all boiling
stops. Evaporation and cooling contin
ue at the surface, but convection cur
rents alone redistribute the remaining
thermal energy throughout the volume.
Such currents can provide adequate
heat transport only in a fluid that moves
without viscosity, or resistance to flow.
Liquid helium 4 at or below 2.18 de
grees is therefore called a superfluid. If
it is set flowing in a tube closed on itself,
the liquid continues to flow without fric
tion, never coming to a stop as a normal
fluid would. It flows into the smallest
passages of its containing vessel, and
it has the remarkable ability to flow
through a densely packed powder as if
SPIN V ECTOR
MAGNETIC LINES
OF FORCE
that can be manipulated to keep the atoms from recombining. The spin is a vector quantity,
that is, one having both a magnitude and a direction. The magnitude of the vector can be inter
preted as the angular momentum of the spin, whereas the direction of the vector gives the sense
of the rotation according to the right-hand rule. (If the fingers of the right hand curl in the
same sense as the spin, the right thumb points in the direction of the vector.) A particle with
both mass and spin generates a magnetic field, and so the orientation of the particle can be in
fluenced by an externally applied magnetic field. For a negatively charged particle such as
the electron the magnetic north pole points in the direction opposite to that of the spin vector.
68
1981 SCIENTIFIC AMERICAN, INC
ELECTRON
SPIN VECTOR
,
A
STATE
MAGNETIC
NORTH POLE
ef CT
B
eSTATE
STATE
PROTON
SPIN VECTOR
<t f
o
STATE
SPIN OF THE HYDROGEN ATOM is the sum of the spins of its constituent proton and elec
tron. Both the proton- and the electron-spin vectors are quantized: the magnitude of the
spins has a value of 112 (when the angular momentum is measured in fundamental units) and
the vectors can point only up or down. Hence the hydrogen atom can assume only four config
urations with respect to spin. The quantum-mechanical spin states are identical with the four
configurations in an infinite magnetic field. The density of the electron cloud surrounding each
atomic nucleus represents the relative probability of finding the electron in a given region.
PROTON
SPIN VECTOR
ELECTRON
SPIN VECTOR
ATOMIC HYDROGEN
MOLECULAR HYDROGEN
ic molecule. In the absence of strong polarizing forces the electron-spin vectors are randomly
spin vectors (whether they are parallel or antiparalleI) need be considered to understand the
STABILIZATION OF ATOMIC HYDROGEN requires that the spin vectors of the electrons
in the atoms be polarized, or oriented in the same direction. Two atoms whose electron-spin
vectors point in opposite directions tend to share electrons and bind strongly to form a diatom
oriented and virtually all hydrogen atoms soon form pairs. If the electron-spin vectors are par
allel, however, the electrons cannot be shared, the interatomic forces become weak and the hy
drogen atoms remain in the monatomic state. Only the relative orientations of the two electron
formation of diatomic hydrogen; the actual directions of the vectors and the spins of the pro
tons are of secondary importance. Thus only two of the
69
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ATTRACTIVE FORCE
LlBRIUM SEPARATION
NUCLE AR SEPARATION
POTENTIAL ENERGY of two hydrogen atoms depends on the distance between them. At a
very large separation the potential energy
curve except the minimum there is a net force on the atoms that tends to drive them to a lower
energy. The point of minimum potential energy represents the equilibrium separation or rest
moved away from the first, the potential energy again increases and an attractive force acts to
restore the atoms to the equilibrium position.
change in their separation does not much alter the potential energy of the system: even a small
quantity of kinetic energy enables them to move about freely without significant interaction.
70
4
CONTINUUM OF STATES
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GROUND STATE
CONTINUUM OF STATES
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BOUND STATES
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potential energy, but they cannot lie at rest at the equilibrium separation because the position
of a quantum-mechanical particle cannot be precisely fixed. Instead,
they must occupy one of a series of discrete energy states; the lowest state, or ground state,
keeps them closest to tbe equilibrium separation. If the atoms are not bound, they can assume
any positive energy state along a continuum of values. When the two electron spins are anti
parallel, the ground state lies near the bottom of a deep potential well and the energy required
to dissociate the atoms is large. Hence the atoms minimize their total energy by forming a mo
lecular bond. The bond is strong enough to withstand the thermal motions of the atoms up to
high temperatures. When the spins are parallel, however, the attractive forces are so weak that
even the feeble atomic motions quantum mechanics predicts would persist at absolute zero
would keep the atoms from forming a bond. Hence no ground state exists. In the lower dia
gram the vertical scale is enlarged by a factor of about
71
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>-
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::>
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en
[(
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::::;
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LOADING OF POLARIZED
ATOMIC HYDROGEN
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DECAY OF POLARIZED
ATOMIC HYDROGEN
.2
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Q.
0
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30
90
60
120
TIME (MINUTES)
PRESSURE BUILDUP of the stabilized, spin-down hydrogen gas during the loading of the
stabilization cell is followed by a gradual decay after tbe loading stops. The decay is caused by
the slow recombination of the hydrogen atoms to form diatomic molecules. According to the
quantum theory, in a magnetic field of finite intensity a fraction of the polarized hydrogen
tron is up as well as down. The presence of the mixed state opens a channel to recombination.
atoms are in a "mixed" state where there is a small probability that the spin of a given elec
HELIUM
FIL M
OF HELIUM VAPOR
of a vertical tube packed with powder is heated, the superfluid helium will rise so rapidly in the
tube that it will form a fountain. Heat will also cause a film of helium to creep up the sides of a
tube, where it will evaporate, return to the colder region just above the liquid and condense. The
circulation of helium vapor was employed by the authors to help compress atomic hydrogen.
72
HELIUM VAPOR
COMPRESSOR
(arrows point
ing up) and attracts the spin-down atoms (ar
rows pointing down). One of the major goals
tensity repels the spin-up atoms
K.
FILM OF
MOLECULAR
HYDROGEN
(blue),
A CCOMMODATOR
TEFLON
COATING
73
fluid helium.
When the density of the gas is to be
measured, an electric current is passed
through the bolometer, causing it to
heat up. The superfluid helium evapo
rates from the chip faster than it can be
replenished by the superfluid flow along
the wires, and so the bare carbon surface
becomes exposed to the atomic hydro
1.2
TEMPERATURE
.10
>: 1.0
a:
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/ CRITICAL VOLUME
a:
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0..
K.
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SU PERFLUID
HELIUM F ILM
CENTER OF
M A GNETIC
FIELD
CONDENSATE
HYDROGEN
ATOMS
MAXIMUM
INTENSITY OF
MA GNETIC
FIELD
--+--- BOSE-EINSTEIN
.2
I
I
I
I
I
CONDENSATION
NORM AL
ATOMIC
HYDROGEN
GAS
moment, so that they can be localized in space by the gradient of a magnetic field. Atoms in the
lowest energy states tend to occupy the regions of the magnetic field with the highest intensity,
so that the Bose-Einstein-condensed atoms should tend to cluster where the field is strongest.
The strongest region of the field generated by a solenoid magnet lies at the sides of the central
plane of the magnet. Thus
of the magnet, the condensate atoms are expected to form a dense ring in the central plane.
74
B ut what d oes
fi l m , d rew an 8-shaped
appreciate.
fi l m is l e s s s t a b l e than "amateur" fi l m
it prove?
analemma
N ot everyone
blessed
with
such
anyway,
refrigerators
a re
m o re
likely
De partment 4 1 2-L.
K od a k ,
R ochester,
NY
j u s t i fi e s
d i ffe r e n c e s
refr ige ra t o r
out of business
a
is m u c h mi sta ken.
between
use
by
pro
t o i t . We t a k e t h i s i n t o account i n
fessionals
and
n o n-professionals
is
the years .