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INTRODUCTION
To a large extent, the economic and social welfare of modern
societies is supported by their scientic and technical
development (i.e., knowledge-based societies). For this reason,
improving the teaching of basic science is subject to profuse
research; its objective is to enhance the academic education of
scientists, engineers, and technologists.1 Such an improvement
of teaching implies that the students should achieve an
improved rationalization of basic concepts during their
university education.
Recent eorts toward the didactic improvement in the
teaching of sciences have featured the need for an
implementation of novel pedagogical techniques in the
teachinglearning process. These techniques focus on the
enhancement of the students attitudes toward the study of the
thematic content of their courses, and also toward the teacher
(empathy).2,3 Positive attitudes are achievable through activities
considered to be fun by the students, in a way radically dierent
from the traditional teaching approach of transmission of
knowledge. A generation of positive attitudes in the students
can thereby develop into an improved understanding of the
course topics, converting learning into understanding, one of
the hallmarks of the new science of learning.4
Attractive teaching activities applied as didactic strategies
include dramatizations,5 games,6 and animations,7 among
others.8 Activities of these kinds are particularly useful for
teaching thematic content considered to be dicult, as is the
case of the second law of thermodynamics (SLT) as a topic in
physical chemistry courses.
Here we report the implementation of a teaching activity that
consists of the observation of toys as an initial point to develop
the thematic content of the SLT. The aim of the activity is to
promote positive reactions in the students toward the
development of an understanding of the SLT.
2014 American Chemical Society and
Division of Chemical Education, Inc.
Activity
DIDACTIC STRATEGY
This didactic strategy comprises having students play with toys
that work as thermal machines: generating motion from a heat
ux. As part of this strategy, the students were separated into
groups and a dierent toy was assigned to each group. The
students played with the toys, and they were asked about the
working principle of each. The instructor eventually explained
in detail the operational mechanism of the function of the toys,
emphasizing the transfer of heat (q) between the hot (Th) and
cold (Tc) zones as the origin of the observed motion, which is a
physical manifestation of work (w). The purpose of this
experience is to make sense of the scheme of Figure 1 in a
pragmatic manner.
The toys used for this purpose were a drinking bird, a
radiometer, and a Stirling engine. In the following section, the
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Activity
black side than on the white side, and eventually these collisions
propel the rotor.25,26
After the observation of the radiometer in action, some
students suggested that the working principle is based on light
pressure caused by elastic collisions of photons on the white
sides of the rotor and absorption on the black sides; this
explanation is incorrect because it predicts rotations in the
inverse sense. Some students proposed, however, that a
temperature dierence must be established between the two
faces of the blades, which is a fact, and some other students
added that the rotation can be explained with convective
currents, which is incorrect (again, this idea predicts a rotation
in the opposite direction).
Figure 3. (a) A drinking bird. (b) Working of the toy and the
correlation of its parts with the generalized scheme of a heat engine in
which the motion is related to the work (w).
Stirling Engine
The Radiometer
thermal machines used to explain the origin of the SLT. For the
specic Stirling engine used in an experiment with students, the
temperature dierence needed for its working is achieved by
placing the bottom of the engine on a cup of hot water and
some pieces of ice on the top (see Figure 5). The assembled
Stirling engine involves a piston and a displacer; its function is
to reaccommodate the gas inside the engine to be alternatively
in contact with the hot zone (expansion of the gas) at one
moment and then in contact with the cold zone (contraction of
the gas). The alternating expansion and contraction of the gas
produces the motion of the piston (work).
This Stirling engine was really a black box for the students
(inner parts are not observable); it was, however, obvious to the
students that a dierence of temperature is involved in its
working principle, because of the involvement of hot water and
ice for the function of the toy.
Activity
CONCLUSION
This work shows the application of an activity in which
students play with toys that function as heat engines. This
didactic strategy was successful in causing students of physical
chemistry to entertain positive attitudes toward the development of the topics of SLT and entropy. The observation and
comprehension of the working principles through the operation
of the toys by the students strengthened at a cognitive level the
idea that a ux of heat produced by a dierence of temperature
can serve to generate work, as the students perceived and
understood the temperature dierence and observed the work
produced as motion. Given the success of this activity, it is
recommend that this or similar activities be applied in courses
of physical chemistry, general chemistry, and physics among
others in which the SLT is an essential topic.
ASSOCIATED CONTENT
S Supporting Information
*
AUTHOR INFORMATION
Corresponding Author
*E-mail: erick.castellon@ucr.ac.cr.
Notes
ACKNOWLEDGMENTS
I thank J. F. Ogilvie and Julio Mata-Segreda for comments on
this work.
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Activity
(Spanish); PearsonAddison
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(29) The questions evaluated in the examination were about: (1)
The Carnot cycle and its relation to the discovery of the state function
entropy; (2) Statement of the SLT and discussion of its importance;
(3) Statement of the third law of thermodynamics and discussion of its
importance; (4) Statement, using an example, of the erroneous
relation between entropy and disorder; (5) Calculation of the total
entropy change for a chemical reaction and prediction of its
spontaneity; and (6) Calculation of a third-law entropy of a substance
based on the variation of heat capacity with temperature Cp(T).
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