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Article history:
Received 18 April 2011
Received in revised form
7 November 2011
Accepted 17 November 2011
Available online 28 November 2011
One of the causes of pollution associated with the construction of transportation infrastructures is the
emission of greenhouse gases into the atmosphere. Even though the use of Warm Mix Asphalt technology
has many advantages that are not related to the reduction of gas emissions, WMA technology is also good for
the environment because it produces asphalt at temperatures 20e40 lower in comparison to Hot Mix
Asphalt. The temperature reduction achieved by WMA comes from the use of various technologies that
have been developed in recent years, and which can be classied in the following three groups: organic
additives, chemical additives, and water-based or water-containing foaming processes. Although all of
them pursue the same goal, the manufacturing process differs. Thus, their aim is mainly to reduce bitumen
viscosity, which in turn improves mix workability, produces fewer emissions, and generally creates better
working conditions. This paper is an overview of the different technologies used in the manufacturing of
WMA. It analyzes the materials, additives, mix design and performance of the asphalt made by this technology. It also describes its benets and drawbacks, and underlines the need for further research in this area.
2011 Elsevier Ltd. All rights reserved.
Keywords:
Warm mix asphalt
Pavement
Cleaner production
1. Introduction
One of the main sources of pollution stemming from industries
related to transportation infrastructures (i.e. road construction),
resides in the manufacturing, spreading, and conservation of
asphalt mixes. A cleaner production of bituminous mixes requires
lowering the manufacturing temperature of these mixes without
impoverishing or reducing their level of mechanical performance.
Warm Mix Asphalt (WMA) are mixes that are manufactured and
spread at lower temperatures than Hot Mix Asphalt. This temperature reduction of 20e40 C has led to the following temperaturebased classication of asphalt mixes: Hot Mix Asphalt or HMA (190150 C); Warm Mix Asphalt or WMA (100e140 C); Half- Warm Mix
Asphalt or HWMA (60e100 C); and cold mixes (0e40 C) (The use
of Warm Mix Asphalt., 2010; Vaitkus et al., 2009a,b).
The WMA temperature reduction is the result of recently
developed technologies that involve the use of organic additives,
chemical additives, and water-based or water-containing foaming
processes (You and Goh, 2008; Zaumanis, 2010). Even though these
technologies are quite different, they all target the same goals,
namely, lower bitumen viscosity, better mat workability, and
improved workability and emissions conditions.
Most of the bibliography consulted highlights the advantages of
these technologies, which include the following: (a) reduced
77
been tested for soft and medium bitumen grades (Butz et al., 2001).
Special precautions must be taken when adding water. In other
words, the quantity of water should be just enough to produce the
foaming effect, but not so much as to cause a stripping problem
(Smith, 2007).
Although the basic process is the same for most of these products and technologies, the way in which water is added to the
binder can vary. This means that foaming processes can either be
water-based (direct method technologies) or water-containing
(indirect method technologies) (Zaumanis, 2010).
2.1.1. Water-containing technologies
Water-containing technologies use synthetic zeolite to produce
the foaming process. The product is composed of aluminosilicates
of alkali metals, and has been hydro-thermally crystallized. The
crystallization is approximately 20% water, which is released from
the zeolite structure as the temperature rises. This causes a microfoaming effect in the asphalt mix (Smith, 2007), which lasts about
6e7 h (Chowdhury and Button, 2008; DAngelo et al., 2008). The
structure of the zeolites has large air voids where cations and even
molecules or cation groups (such as water) can be hosted. Their
ability to lose and absorb water without damaging the crystalline
structure is the main characteristic of this silicate framework
(Chowdhury and Button, 2008).
2.1.2. Water-based technologies
Water-based technologies use water in a more direct way. This
means that the water needed to produce the foaming effect is
Table 1
Products used in warm mix technologies.
WMA processes
Product
Foaming processes
Water-containing Aspha-Min
Water-containing Advera
Water-based
Water based
Water-based
Double Barrel
Green
Ultrafoam GX
LT Asphalt
Water-based
WAM-Foam
Water based
Low Energy
Asphalt
Low Emission
Asphalt
Water based
Company
Description
Water based
LEAB
Organic
FT Wax
Sasobit
Sasol
Fischer-Tropsch wax
Montan Wax
Asphaltan B
Romonta GmbH
Fatty Acid
Amide wax
Licomont BS
Clariant
Dosage of additive
Country where
Production
technology is used temperature C
(or reduction range)
USA, Germany,
(20e30 C)
France, worldwide
USA
(10e30 C)
USA
116e135 C
USA
Netherlands
and Italy
Worldwide
Not specied
90 C
USA, France,
Spain, Italy
USA
<100 C
Netherlands
90 C
100e120 C
90 C
Germany
(20e30 C)
3E LT or Ecoex Colas
Proprietary
France
(30e40 C)
CECA
Akzo Nobel
USA, France,
Worldwide
USA, France
USA, Norway
(30 C)
(30 C)
Chemical
Revix
Mathy-Ergon
85e115 C
Chemical
Chemical
Evoterm
Technologies
Cecabase RT
Rediset
Not specied
USA
(15e25 C)
Chemical
Iterlow T
IterChimica
Italy
120 C
Chemical
Chemical
Mead Westvaco
78
3. Mix design
The European Standards for Bituminous mixtures (EN 13108-1
to 7) have been in force since March 1, 2008. One of the conclusions that can be derived from them is that there are maximum
temperatures for mix production, but no minimum temperatures.
The only requirement is that the in situ density be satisfactory.
Therefore, the minimum temperature should be established by the
manufacturer. European Standards also address the use of additives, subject to demonstration of equivalent performance. Thus,
European Standards should not be regarded as a barrier to the use
of WMA because they do not prohibit the use of these mixtures
(The use of Warm Mix Asphalt., 2010).
Depending on the geographic location, the design methods to
determine the parameters of a hot mixture vary. Consequently, in the
USA, the SUPERPAVE design is widely implemented, whereas in
Europe the most common design method is the Marshall method
(Zaumanis, 2010). Both have been used to test WMA technologies.
Furthermore, WMA processes have also been tested with many
different types of asphalt materials (dense graded, stone mastic,
porous, mastic asphalt). Based on this research, there are no restrictions on the use of traditional design methods for WMA (Von Devivere
et al., 2011). However, most of the literature consulted states that such
methods should be slightly modied. Specic elements in the mix
design process are discussed in the following sections.
3.1. Aggregate gradation
The selection of aggregate gradation for mixes in all of the tests
followed HMA guidelines. It can thus be said that all types of
asphalt have been manufactured using WMA. In all cases, the test
process was the same. The same aggregate gradation was used in
both the HMA control mixes and the WMA mix, after which the
results for both were compared. No noticeable differences were
noted in the aggregate gradation of the WMA.
3.2. Additives
In reference to WMA technologies involving additives, the
dosage of each product should be selected according to manufacturer recommendations. When organic and chemical additives are
used, no other additives are normally required. However In those
cases when HMA requires additives, WMA should also use them
(DAngelo et al., 2008). Nevertheless, in foaming processes, because
of the potential loss of adhesion and coating of the binder and
aggregate, anti-stripping agents are also necessary. When choosing
an agent, it is necessary to bear in mind that lower WMA temperatures can reduce the anti-stripping effect of the product.
3.3. Laboratory mixing
Most laboratories that have worked with HMA are familiar with
the procedures followed in the analysis of asphalt mixtures, and know
how to interpret the results obtained. For these reasons, the analysis
of WMA should be based on the same tests routinely used in the
analysis of HMA (e.g., volumetrics, modulus, rut resistance, moisture
susceptibility, and dust proportion) and the same testing conditions.
Similarly, an in-depth analysis of WMA should include the tests
typically performed on HMA specimens. In most cases, the laboratory
testing of a eld-produced mix yielded the same results as those
obtained in the laboratory study (Chowdhury and Button, 2008).
This also applies to WMA with chemical and organic additives.
Nevertheless, technologies involving foaming processes are not so
easy to test in the laboratory, and thus no published research on
water-based WMA products was found. In the case of water-
79
80
Although the less ageing of the binder is one of the advantages of WMA mixes (longer durability of the pavement), it also
has a negative side since it can lead to permanent deformations.
For this reason, a different grade should possibly be chosen for
the binder. Based on studies in Montana (USA), a set of recommendations has been proposed. However, the difference in
design methods in Europe and the USA signify that these
guidelines are not internationally applicable (Zaumanis, 2010).
Despite this, one should not arbitrarily use a binder in WMA that
is one grade higher than the binder typically used in HMA
(Bonaquist, 2011). Furthermore, according to Romier et al.
(2006), LEA and HMA mixes use the same asphalt grades in the
same proportions. This is also the case for other WMA products
(Romier et al., 2006).
The use of lower performance grade as a virgin binder was
critical on offsetting the change of rheological binder properties
due to the warm additives and the aged binders (Kim et al.,
2010).
Most tests in the USA are performed by the National Center for
Asphalt Technologies (NCAT), which afrms that the optimum
asphalt content can be determined with standard HMA design
procedures without the inclusion of the warm mix additive.
However, certain authors have expressed concerns that because of
the enhanced compaction achieved by WMA technologies, the
optimum asphalt content can be reduced in half a percentage point
below that of a reference HMA. More specically, these concerns
are the following (Chowdhury and Button, 2008):
- Whether the lower mixing temperature for WMA means that
there is less binder absorption in the aggregates, and if this
effectively points to the need to reduce the binder content.
- WMA shows better compaction than HMA, and thus has fewer
air voids. This indicates that the mix has a smaller optimal
bitumen content.
81
Table 2
WMA data pertaining to reduction in gas emissions.
Vaitkus et al.
Bueche, N. Larsen, O.R.
DAngelo et al.a Evotherm
(Vaitkus et al., (Bueche,
(Larsen, 2001) (Vaitkus et al., website
2009a,b)
2009a,b)
2009)
CO2
SO2
VOC
CO
NOx
Dust
a
30e40%
35%
50%
10e30%
60e70%
20e25%
30e40%
e
50%
e
e
e
31%
e
e
29%
62%
e
15e40%
20e35%
gt; 50%
10e30%
60e70%
25e55%
46%
81%
30%
63%
58%
e
82
83
Table 3
Extracted from Chowdhury et al. (Chowdhury and Button, 2008).
WMA technology
WAM-Foam
Aspha-Min
Sasobit
Evotherm
Equipment modications
or installation costs
Royalties
$30.000- $70.000
$0-$40.000
$0-$40.000
Minimal
$15,000 rst yr
$5000/plant/yr
$0.30/ton
NA
NA
$0.30
None
None
None
$ 0.60/lb
0.3% by weight of mix
$3.60
$ 0.80/lb
1.5e3% by weight of binder
$1.30-$2.60
Cost of material
Dosage recommended
Approximate cost per ton of mix
84
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