a

Vn(g)

63.752

0.029677

270

0.08206

20.0000

1.1000
0.9879
0.9583
0.9491
0.9461
0.9451
0.9448
0.9447
0.9447
0.9446
0.9446
0.9446
0.9446
0.9446
0.9446

Vn+1(g)

Vn(liq)

Vn+1(liq)

0.9879
0.9583
0.9491
0.9461
0.9451
0.9448
0.9447
0.9447
0.9446
0.9446
0.9446
0.9446
0.9446
0.9446
0.9446

0.0568
0.0570
0.0572
0.0574
0.0575
0.0576
0.0576
0.0577
0.0577
0.0578
0.0578
0.0578
0.0578
0.0578
0.0578

0.0570
0.0572
0.0574
0.0575
0.0576
0.0576
0.0577
0.0577
0.0578
0.0578
0.0578
0.0578
0.0578
0.0578
0.0579

Vid
1.1078

P(area)
30.4724

b
T
63.752 0.029677

R
270

P
0.08206

V ideal
20 1.10781

Vn(g)

Vn+1(g) Vn(l)
Vn+1(l)
1.1 0.987898
0.033 0.041364
0.987898 0.958287 0.041364 0.046207
0.958287 0.949097 0.046207 0.049345
0.949097 0.94611 0.049345 0.051506
0.94611 0.945125 0.051506 0.053052
0.945125 0.944799 0.053052 0.054186
0.944799 0.944691 0.054186 0.055033
0.944691 0.944655 0.055033 0.055674
0.944655 0.944643 0.055674 0.056164
0.944643 0.944639 0.056164 0.056542
0.944639 0.944637 0.056542 0.056833
0.944637 0.944637 0.056833 0.05706
0.944637 0.944637 0.05706 0.057237
0.944637 0.944637 0.057237 0.057375
0.944637 0.944637 0.057375 0.057484
0.944637 0.944637 0.057484 0.057569
0.944637 0.944637 0.057569 0.057635
0.944637 0.944637 0.057635 0.057688
0.944637 0.944637 0.057688 0.057729
0.944637 0.944637 0.057729 0.057762
0.944637 0.944637 0.057762 0.057787
0.944637 0.944637 0.057787 0.057807
0.944637 0.944637 0.057807 0.057823
0.944637 0.944637 0.057823 0.057836
0.944637 0.944637 0.057836 0.057846

Dados calculados

Dados experimentais
T(K)
244.26
245.37
246.48
247.59
248.71
249.82
250.93
252.04
253.15
254.26
255.37
256.48
257.59
258.71
259.82
260.93
262.04
263.15
264.26
265.37
266.48
267.59
268.71
269.26
270.37
271.48
272.59
273.71
274.82
275.93
277.04
278.15
279.26
280.37
281.48
282.59
283.71
284.82
285.93
287.04
288.15
289.26
290.37
291.48

P(atm)
15.015
15.548
16.091
16.644
17.216
17.808
18.421
19.033
19.674
20.326
20.869
21.688
22.399
23.129
23.870
24.630
25.410
26.199
27.029
27.868
28.727
29.605
30.503
30.958
31.885
32.843
33.810
34.808
35.824
36.871
37.937
39.023
40.148
41.283
42.448
43.633
44.857
46.101
47.364
48.657
49.980
51.333
52.715
54.116

V(l)
42.69
42.82
42.96
43.10
43.26
43.43
43.59
43.77
43.95
44.14
44.34
44.56
44.77
44.98
45.20
45.53
45.65
45.87
46.11
46.35
46.60
46.84
47.11
47.25
47.52
47.79
48.09
48.38
48.69
49.03
49.36
49.72
50.09
50.48
50.90
51.34
51.79
52.27
52.77
53.31
53.87
54.48
55.16
55.90

V(g)
1144.05
1103.59
1064.60
1027.32
990.99
956.52
923.01
891.05
860.05
830.19
801.60
773.83
747.28
721.55
696.86
672.89
649.83
627.59
606.14
585.42
565.33
545.97
527.14
518.01
500.17
482.93
466.20
450.08
434.35
419.05
404.41
390.07
376.39
362.74
349.76
336.91
324.72
312.50
300.75
289.28
277.95
266.99
256.26
245.67

P
15.015
15.548
16.091
16.644
17.216
17.808
18.421
19.033
19.674
20.326
20.869
21.688
22.399
23.129
23.870
24.630
25.410
26.199
27.029
27.868
28.727
29.605
30.503
30.958
31.885
32.843
33.810
34.808
35.824
36.871
37.937
39.023
40.148
41.283
42.448
43.633
44.857
46.101
47.364
48.657
49.980
51.333
52.715
54.116

292.59
293.71
294.82
295.93
297.04
298.15
299.26
300.37
301.48
302.59
303.15
303.71
304.25

55.558
57.019
58.519
60.049
61.599
63.189
64.808
66.466
68.134
69.901
70.721
71.599
72.962

56.71
57.60
58.60
59.73
60.98
62.34
63.82
65.48
67.62
70.86
73.43
77.72
94.81

235.42
224.95
214.22
204.56
194.43
184.33
173.78
162.54
150.53
137.33
130.25
122.87
94.81

55.558
57.019
58.519
60.049
61.599
63.189
64.808
66.466
68.134
69.901
70.721
71.599
72.962

Dados calculados pela equao de Redlich-Kwong

T(K)
245
250
260
270
280
290
300

V(l)
47.43
48.72
51.76
55.73
60.99
68.80
84.85

V(g)
865.60
747.70
562.49
425.47
321.42
238.19
163.76

V
47.43
48.72
51.76
55.73
60.99
68.80
84.85
163.76
238.19
321.42
425.47
562.49
747.70
865.60

P
18.80
21.63
28.17
35.93
44.99
55.47
67.41
67.41
55.47
44.99
35.93
28.17
21.63
18.80

P
18.80
21.63
28.17
35.93
44.99
55.47
67.41

Dados obtidos de:

1 - CRC Handbook of Chemistry a
pages 2560-2561
2 - Lange's Handbook of Chemis

:
k of Chemistry and Physics, 44th ed.
1
book of Chemistry, 10th ed. page 1463.